CN104357706A - Alloy disinfection wire for removing heavy metals in liquor and liquor purification plant thereof - Google Patents

Alloy disinfection wire for removing heavy metals in liquor and liquor purification plant thereof Download PDF

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Publication number
CN104357706A
CN104357706A CN201410666866.6A CN201410666866A CN104357706A CN 104357706 A CN104357706 A CN 104357706A CN 201410666866 A CN201410666866 A CN 201410666866A CN 104357706 A CN104357706 A CN 104357706A
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sterilization silk
liquid
alloy sterilization
alloy
housing
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Chinese (zh)
Inventor
郑建国
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Shandong General Magnificent Purple Light Environmental Protection Equipment Co Ltd
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Shandong General Magnificent Purple Light Environmental Protection Equipment Co Ltd
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Priority to CN201410666866.6A priority Critical patent/CN104357706A/en
Publication of CN104357706A publication Critical patent/CN104357706A/en
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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
    • C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
    • C12H1/02—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material
    • C12H1/04—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material
    • C12H1/0432—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages combined with removal of precipitate or added materials, e.g. adsorption material with the aid of ion-exchange material or inert clarification material, e.g. adsorption material with the aid of ion-exchange material
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/14—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means with multiple outlet openings; with strainers in or outside the outlet opening
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/002—Grey water, e.g. from clothes washers, showers or dishwashers
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2307/00—Location of water treatment or water treatment device
    • C02F2307/04—Location of water treatment or water treatment device as part of a pitcher or jug
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00—Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20—Controlling water pollution; Waste water treatment
    • Y02A20/208—Off-grid powered water treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Biochemistry (AREA)
  • Genetics & Genomics (AREA)
  • Electrochemistry (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Water Treatment By Sorption (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treating Waste Gases (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Physical Water Treatments (AREA)
  • Filtering Materials (AREA)
  • Medicines Containing Plant Substances (AREA)

Abstract

The invention provides an alloy disinfection wire for removing heavy metals in liquor and a liquor purification plant thereof. The alloy disinfection wire for removing heavy metals in liquor is composed of the following components in percentage by weight: 50-61% of copper, 19-36% of zinc and 9-21% of silver, and preferably 60% of copper, 30% of zinc and 10% of silver. The liquor purification plant comprises a stainless steel shell, wherein the shell is provided with a sealed cavity; the alloy disinfection wire is installed in the cavity; the wall of the shell is provided with a plurality of through holes; the weight of the alloy disinfection wire in the shell is at least 3-10g; and the shell is provided with an openable cover. The alloy disinfection wire in the shell is a cylinder which is helical in the length direction. The alloy disinfection wire is used for removing heavy metals in traditional Chinese medicine liquor, so that the content of the heavy metals in the liquor is lowered.

Description

A kind of alloy sterilization silk and liquid refining plant thereof removing liquid heavy metal
Technical field
The present invention relates to cleaner, is a kind of alloy sterilization silk and liquid refining plant thereof of removing liquid heavy metal.
Background technology
Chinese medicine is that current people's disease therapy selects more medicine, because Chinese medicine is the many factors such as different physical appearances, sick time according to individual, and the result for the treatment of that medicine could produce because of people, therefore, the decoction of medicinal ingredients that the large more options Chinese medicine material of patient is made.In addition, Chinese patent medicine is also adopt to soak, decoct into liquid, dry the technique such as extractions and make, and the decoction of medicinal ingredients of Chinese medicine or the medicine material needed for Chinese patent medicine all need immersion, boil soup, and pharmaceutical compositions just can be made to be dissolved in liquid.But modern study shows, due to the heavy contamination such as air, soil, contain comparatively various heavy in Chinese medicine material, it also leaches in liquid with the stripping of Chinese medicine material pharmaceutical compositions, and patient, when taking medicine, takes in the lump into heavy metal.It is very large that heavy metal of body exceeds standard to the injury of people, its human organ such as the impariment of the liver, kidney.At present, all traditional Chinese medicine liquid all cannot removal heavy metal.
Summary of the invention
The object of the invention is, provide a kind of alloy sterilization silk and the liquid refining plant thereof of removing liquid heavy metal, it is for removing the heavy metal in traditional Chinese medicine liquid, and the heavy metal content in liquid is reduced.
The present invention for achieving the above object, is achieved through the following technical solutions: a kind of alloy sterilization silk removing liquid heavy metal, alloy sterilization silk is made up of copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.The weight percent of alloy sterilization silk is: copper 60%, zinc 30% and silver 10%.
The liquid refining plant that described a kind of alloy sterilization silk removing liquid heavy metal is made, comprise Stainless Steel Shell, housing is provided with an enclosed cavity, alloy sterilization silk is installed in cavity, several through hole offered by the wall of housing, in housing, the weight of alloy sterilization silk is at least 3-10g, housing is arranged folding lid.Alloy sterilization silk in housing is right cylinder, and its length direction in the shape of a spiral.Alloy sterilization silk is flat-shaped body, and the length direction of alloy sterilization silk is bending, and alloy sterilization silk is made up of copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.The diameter of alloy sterilization silk is 10-50 micron.The diameter of alloy sterilization silk is 5-20 micron.The diameter of alloy sterilization silk is 8-16 micron.Alloy sterilization silk is wound in has elastic cylinder, spheroid or disc.Housing is spheroid, right cylinder or cuboid, the wall of housing is arranged chain form set collar.
Alloy sterilization silk of the present invention can remove the heavy metal in liquid, and the liquid refining plant made with alloy sterilization silk, when decocting herb, can place it in liquid until liquid has decocted rear taking-up.Alloy sterilization silk in refining plant of the present invention fully contacts with liquid, alloy sterilization silk forms electrostatic environment under moisture state, make alloy sterilize silk by the heavy metal in electric charge and electrostatic interaction absorption liquid, thus reach the object of the content reducing heavy metal in liquid.Liquid refining plant of the present invention has the effect of Adsorption of Heavy Metals of the present invention all the time within work-ing life.Refining plant of the present invention is as follows on liquid impact experiment after removal heavy metal in liquid:
One, experimental program:
1, experiment purpose: whether inspection this product has impact to the fried of general traditional Chinese medicine ingredients.
2, experimental group: censorship removing heavy metals sample and Chinese medicinal materials add ten times of water gagings and jointly decoct 1 hour, filters, constant volume.
Blank group: parallel running, Chinese medicinal materials adds ten times amount soak by water 1 hour, filters, constant volume.
Two, HPLC Testing index:
1, Chinese ephedra Ephedrine
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, gets 2ml, and methanol constant volume, to 10ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get ephedrine hydrochloride reference substance, accurately weighed, makes every milliliter containing the solution of 0.04mg, to obtain final product after adding methyl alcohol.
2) liquid-phase condition
Moving phase: acetonitrile-0.1% phosphoric acid (4:96); Determined wavelength: 210nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 1153654 165.08
Blank group 1016189 142.18
2, loganin in skunk bush
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, gets 2ml, and methanol constant volume, to 10ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get loganin reference substance appropriate, accurately weighed, adds 80% methyl alcohol and makes the solution of every 1ml containing 49.4 μ g, to obtain final product.
2) liquid-phase condition
Moving phase: acetonitrile-0.1% phosphoric acid (10:90); Determined wavelength: 240nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 1682627 287.72
Blank group 1394236 253.52
3, puerarin in the root of kudzu vine
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, gets 2ml, and methanol constant volume, to 10ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get puerarin reference substance appropriate, accurately weighed, adds 30% ethanol and makes the solution of every 1ml containing 100.60 μ g, to obtain final product.
2) liquid-phase condition
Moving phase: methanol-acetic acid-water (25:3:72); Determined wavelength: 250nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 1039004 149.62
Blank group 710631 105.07
4, ferulic acid in Chuanxiong
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get forulic acid reference substance appropriate, accurately weighed, puts in brown measuring bottle, adds 70% methyl alcohol and makes the solution of every 1ml containing 25.2 μ g, to obtain final product.
2) liquid-phase condition
Moving phase: methyl alcohol-1% acetum (30:70); Determined wavelength: 321nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 998025 9.69
Blank group 847437 8.50
5, peoniflorin in the radix paeoniae rubrathe
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, gets 5ml, adds methanol constant volume to 50ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get peoniflorin reference substance appropriate, accurately weighed, adds methyl alcohol and makes the solution of every 1ml containing 84 μ g, to obtain final product.
2) liquid-phase condition
Moving phase: acetonitrile-0.1% phosphoric acid solution (14: 86); Determined wavelength: 230nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 1594210 659.45
Blank group 1583384 633.01
6, berberine hydrochloride in the coptis
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, gets 5ml, adds methanol constant volume to 100ml, filters, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get berberine hydrochloride reference substance appropriate, accurately weighed, adds methyl alcohol and makes the solution of every 1ml containing 27 μ g, to obtain final product.
2) liquid-phase condition
Moving phase: acetonitrile-0.3% phosphoric acid (25:75); Determined wavelength: 265nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 2427322 530.50
Blank group 2404253 523.10
7, salvianolic acid B in the red sage root
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, filters, to obtain final product.Experimental group, control group parallel running.Contrast preparation: get salvianolic acid B reference substance appropriate, accurately weighed, add 75% methyl alcohol and make the solution of every 1ml containing 0.14mg, to obtain final product.
2) liquid-phase condition
Moving phase: acetonitrile-0.05% phosphoric acid (22:78); Wavelength: 286nm; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 4456044 313.4
Blank group 4853355 319.3
8, Astragaloside IV in Radix Astragali
1) working method
Prepared by trial-product: after decocting, liquid is settled to 500ml, filters, gets 50ml, extract 4 times with water saturated propyl carbinol jolting, each 50ml, merge propyl carbinol liquid, fully wash 2 times with ammonia solution, each 50ml, discards ammoniacal liquor, propyl carbinol liquid evaporate to dryness, residue adds dissolve with methanol, is transferred in 5ml measuring bottle, adds methyl alcohol to scale, shake up, to obtain final product.Experimental group, control group parallel running.Prepared by reference substance: get Cyclosiversioside F reference substance appropriate, accurately weighed, adds methyl alcohol and makes the solution of every 1ml containing 0.21mg, to obtain final product.
2) liquid-phase condition
Moving phase: acetonitrile-water (32:68); Evaporative light detector: drift tube 105 DEG C, flow rate of carrier gas 2.7ml/min; Column temperature: 30 DEG C.
3) assay
Group Peak area Content mg/50g medicinal material
Experimental group (censorship product) 4033061 9.12
Blank group 2057707 6.00
Three, experiment conclusion:
1, liquid refining plant of the present invention on the main pharmacodynamics composition in general Chinese medicinal materials as the fried of glycoside (tetracyclic triterpene glycosides, iridoid glycoside etc.), alkaloids, phenolic acids, organic acid, brass class etc. there is no impact, analyze from data, experimental group also outline higher than blank group, liquid refining plant of the present invention does not adsorb main pharmacodynamics composition, can ensure each constituents extraction rate.
2, the assay of Astragaloside IV in Radix Astragali, experimental group extraction yield is apparently higher than blank group, and reason is speculated as, and liquid refining plant of the present invention can make water be weakly alkaline, facilitates the stripping of Cyclosiversioside F.
3, find in experiment, the liquid of laboratory sample group shows slightly clarification than blank group, and after liquid filters, submitted sample surface color is deepened, and infers and has adsorbed part small molecules pigment or oxidizing substance.Find through comparative experiments group and the blank mouthfeel organized, laboratory sample group bitter taste declines, the bitter taste of usual Chinese medicine, from alkaloid, tannin or metallic element, result is analyzed alkaloid and is not reduced, bitter taste decline be by heavy metal etc. caused by Adsorption.
The detected result of liquid refining plant removal heavy metal of the present invention is as follows: the Chinese medicine material kind of detection has the Radix Astragali, Chinese ephedra, Shan Zhu Sou, the root of kudzu vine, Ligusticum wallichii, the radix paeoniae rubrathe, the coptis, the bighead atractylodes rhizome, Radix Angelicae Sinensis, Chinese violet, field thistle, the tuber of pinellia, flax, Radix Glycyrrhizae, parsnip, safflower, Root of Indigowoad, Spica Prunellae, Radix Codonopsis, Leaf of Indigowoad, radix bupleuri, Rhizome of Lalang Grass, Rush, kuh-seng, Root of Kirilow Rhodiola, Motherwort Herb, do not place in the contrast liquid of refining plant of the present invention in above-mentioned raw materials, iron is 3.2-17.7mg/kg, manganese is 0.1-0.5mg/kg, mercury is 0.01-0.05mg/L, lead is 0.04-0.18mg/L, aluminium is 0.01-0.02mg/L, muriate 19.5-28.4mg/L, barium is 0.003-0.006mg/L, cadmium is 0.07-0.1mg/L, copper is 0.13-0.21mg/L, fluorochemical is 0.001-1.5mg/L, chromium is 0.11-0.73mg/L, in the liquid decocted after placing refining plant of the present invention, iron is 0.058-7.8mg/kg, manganese is 0.01-0.02mg/kg, mercury is 0.001-0.003mg/L, lead is 0.001-0.005mg/L, aluminium does not detect, muriate 14.46-16.2mg/L, barium does not detect, cadmium does not detect, chromium is 0.03-0.041mg/L, copper is 0.126-0. 51mg/L, fluorochemical does not detect, above-mentioned detected result contrast shows, liquid refining plant heavy metal of the present invention has obvious removal effect, and detrimentally affect is not produced to liquid composition, the extraction yield of most of pharmaceutical compositions is significantly improved.Above-mentioned experiment of the present invention is take Chinese medicine material as 50-300g, the weight of alloy sterilization silk is made for 3-10g.Muriate and fluorochemical adopt sulfate by ion chromatography, and mercury adopts atomic fluorescence method to detect, and other adopts inductively coupled plasma emission spectrography to detect.
Accompanying drawing explanation
Accompanying drawing 1 is the structural representation of one of the embodiment of the present invention; Accompanying drawing 2 is structural representations of embodiment two; Accompanying drawing 3 be in accompanying drawing 2 A to structural representation; Accompanying drawing 4 is three structural representations of embodiment; Accompanying drawing 5 is four structural representations of embodiment; Accompanying drawing 6 is Chinese ephedra Ephedrine reference substance-10ul collection of illustrative plates; Accompanying drawing 7 is Chinese ephedra Ephedrine blank group-10ul collection of illustrative plates; Accompanying drawing 8 is Chinese ephedra Ephedrine experimental group (adding wire)-10ul collection of illustrative plates; Accompanying drawing 9 is loganin reference substance-10ul collection of illustrative plates in skunk bush; Accompanying drawing 10 is loganin blank group-10ul collection of illustrative plates in skunk bush; Accompanying drawing 11 is that in skunk bush, loganin adds experimental group (adding wire)-10ul collection of illustrative plates; Accompanying drawing 12 is puerarin reference substance-2ul collection of illustrative plates in the root of kudzu vine; Accompanying drawing 13 is puerarin blank group-10ul collection of illustrative plates in the root of kudzu vine; Accompanying drawing 14 is puerarin experimental group (adding wire)-10ul collection of illustrative plates in the root of kudzu vine; Accompanying drawing 15 is ferulic acid in Chuanxiong reference substance-10ul collection of illustrative plates; Accompanying drawing 16 is ferulic acid in Chuanxiong blank group-10ul collection of illustrative plates; Accompanying drawing 17 is ferulic acid in Chuanxiong experimental group (adding wire)-10ul collection of illustrative plates; Accompanying drawing 18 is peoniflorin reference substance-10ul collection of illustrative plates in the radix paeoniae rubrathe; Accompanying drawing 19 is peoniflorin blank group-10ul collection of illustrative plates in the radix paeoniae rubrathe; Accompanying drawing 20 is peoniflorin experimental group (adding wire)-10ul collection of illustrative plates in the radix paeoniae rubrathe; Accompanying drawing 21 is berberine hydrochloride reference substance-5ul collection of illustrative plates in the coptis; Accompanying drawing 22 is berberine hydrochloride blank group-5ul collection of illustrative plates in the coptis; Accompanying drawing 23 is berberine hydrochloride experimental group (adding wire)-5 ul collection of illustrative plates in the coptis; Accompanying drawing 24 is salvianolic acid B reference substance-10 ul collection of illustrative plates in the red sage root; Accompanying drawing 25 is salvianolic acid B blank group-2ul collection of illustrative plates in the red sage root; Accompanying drawing 26 is salvianolic acid B experimental group (adding wire)-2ul collection of illustrative plates in the red sage root; Accompanying drawing 27 is Astragaloside IV in Radix Astragali reference substance-10ul collection of illustrative plates; Accompanying drawing 28 is Astragaloside IV in Radix Astragali reference substance-20ul collection of illustrative plates; Accompanying drawing 29 is Astragaloside IV in Radix Astragali blank group-10ul collection of illustrative plates; Accompanying drawing 30 is Astragaloside IV in Radix Astragali experimental group-10ul collection of illustrative plates.
In accompanying drawing: 1 housing 2 covers 3 first through hole 4 second through hole 5 alloy sterilization silk 6 shacks 7 links up with 8 handle 9 second housing 10 third through-hole 11 dividing plate 12 fourth holes.
Embodiment
A kind of alloy sterilization silk 5 removing liquid heavy metal of the present invention is made up of copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.This is the better scope that can reach Adsorption of Heavy Metals.
The liquid refining plant that a kind of alloy sterilization silk 5 removing liquid heavy metal of the present invention is made, comprise Stainless Steel Shell 1, housing 1 is provided with an enclosed cavity, alloy sterilization silk is installed in cavity, several through hole offered by the wall of housing 1, and in housing 1, the weight of alloy sterilization silk 5 is at least 3-10g, housing 1 is arranged folding lid, described alloy sterilization silk 5 is mixed by copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.The consumption of alloy sterilization silk 5 is relations proportional with the consumption of Chinese medicine material, calculate according to patient's one pair of medicine conventional amount used and need use 3-10g alloy sterilization silk 5, the object of removal heavy metal can be reached, one pair of conventional Chinese medicine material is generally 50-300g, that is: the Chinese medicine material of one pair of 50-300g, the weight of alloy sterilization silk 5 is 3-10g, can calculate the weight of the alloy sterilization silk 5 in large-scale liquid refining plant in this ratio.
In housing 1 of the present invention, alloy sterilization silk 5 is right cylinder, and in the shape of a spiral, this structure can increase solution and alloy and to sterilize the contact area of silk 5 its length direction, reaches the effect of removal heavy metal further.Another preferred version is: alloy sterilization silk 5 is flat-shaped bodies, and the length direction of alloy sterilization silk 5 is bending.
The further scheme of the present invention is: the diameter of alloy sterilization silk 5 is 10-50 micron, and this is the diameter range that can reach removal heavy metal effect.
Preferred embodiments of the present invention are: when identical weight, and the diameter of alloy sterilization silk 5 is 5-20 micron, and the program can make apparatus of the present invention better removal heavy metal in liquid.Further preferred version is: the diameter of alloy sterilization silk 5 is 8-16 micron, to reach the effect of better removal heavy metal.
Alloy of the present invention sterilization silk 5 is wound in has elastic cylinder, spheroid or disc, and it is in the volume situation reducing housing, and liquid and alloy silk 5 of sterilize can be made fully to contact, to reach the better effect purifying heavy metal in liquid.
Housing 1 of the present invention is spheroid, right cylinder or cuboid, the wall of housing 1 is arranged chain form set collar, and this is convenient to place and take out the preferred version that device of the present invention provides to reach.
Preferred embodiments of the present invention are: alloy sterilization silk 5 is made up of copper, zinc and silver, and its weight percent is counted: copper 60%, zinc 30% and silver 10%.In alloy sterilization silk 5 interalloy sterilization silk, copper, zinc and silver also can have multiple combination by weight percentage:
1, copper 59%, zinc 29%, silver 12%.
2, copper 61%, zinc 30%, silver 9%.
3, copper 59.5%, zinc 29.5%, silver 11%.
4, copper 60.5%, zinc 30%, silver 9.5%.
5, copper 50%, zinc 30%, silver 20%.
6, copper 60%, zinc 19%, silver 21%.
7, copper 55%, zinc 36%, silver 9%.

Claims (10)

1. remove an alloy sterilization silk for liquid heavy metal, it is characterized in that: alloy sterilization silk (5) is made up of copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.
2. a kind of alloy sterilization silk removing liquid heavy metal according to claim 1, is characterized in that: the weight percent of alloy sterilization silk (5) is: copper 60%, zinc 30% and silver 10%.
3. the liquid refining plant that a kind of alloy sterilization silk removing liquid heavy metal described in claim 1 or 2 is made, it is characterized in that: comprise housing (1), housing (1) is provided with an enclosed cavity, in cavity, alloy sterilization silk (5) is installed, several through hole offered by the wall of housing (1), the weight of interior alloy sterilization silk (5) of housing (1) is at least 3-10g, and (1) arranges folding lid to housing.
4. a kind of liquid refining plant according to claim 3, is characterized in that: alloy sterilization silk (5) in housing (1) is right cylinder, and its length direction in the shape of a spiral.
5. a kind of liquid refining plant according to claim 3, it is characterized in that: alloy sterilization silk (5) is flat-shaped body, the length direction of alloy sterilization silk (5) is bending, alloy sterilization silk (5) is made up of copper, zinc and silver, by weight percentage: copper 50-61%, zinc 19-36% and silver-colored 9-21%.
6. a kind of liquid refining plant according to claim 3, is characterized in that: the diameter of alloy sterilization silk (5) is 10-50 micron.
7. liquid refining plant according to claim 3, is characterized in that: the diameter of alloy sterilization silk (5) is 5-20 micron.
8. liquid refining plant according to claim 3, is characterized in that: the diameter of alloy sterilization silk (5) is 8-16 micron.
9. liquid refining plant according to claim 3, is characterized in that: alloy sterilization silk (5) is wound in has elastic cylinder, spheroid or disc.
10. liquid refining plant according to claim 3, is characterized in that: housing (1) is spheroid, right cylinder or cuboid, and the wall of housing (1) arranges chain form set collar.
CN201410666866.6A 2014-01-09 2014-11-20 Alloy disinfection wire for removing heavy metals in liquor and liquor purification plant thereof Pending CN104357706A (en)

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CN201410282282.9A Expired - Fee Related CN104109775B (en) 2014-01-09 2014-06-23 A kind of B alloy wire of purifying drinking water
CN201410296034.XA Expired - Fee Related CN104071931B (en) 2014-01-09 2014-06-27 A kind of child's water purifying cup
CN201420349294.4U Expired - Fee Related CN203952761U (en) 2014-01-09 2014-06-27 A kind of portable motion water purifying cup
CN201420346943.5U Expired - Fee Related CN203999074U (en) 2014-01-09 2014-06-27 A kind of filter core water purifying cup
CN201410296523.5A Expired - Fee Related CN104138131B (en) 2014-01-09 2014-06-27 A kind of portable motion water purifying cup
CN201410293908.6A Expired - Fee Related CN104058485B (en) 2014-01-09 2014-06-27 A kind of filter core water purifying cup
CN201420348820.5U Expired - Fee Related CN203904119U (en) 2014-01-09 2014-06-27 Water purification cup for child
CN201410304770.5A Expired - Fee Related CN104108773B (en) 2014-01-09 2014-06-30 A kind of Portable miniature water purifier
CN201410302926.6A Expired - Fee Related CN104058524B (en) 2014-01-09 2014-06-30 A kind of infant Purified cup
CN201410305212.0A Expired - Fee Related CN104106959B (en) 2014-01-09 2014-06-30 The special water purifying cup of a kind of pregnant woman
CN201420355872.5U Expired - Fee Related CN203987299U (en) 2014-01-09 2014-06-30 The special-purpose water purifying cup of a kind of pregnant woman
CN201410304441.0A Expired - Fee Related CN104108817B (en) 2014-01-09 2014-06-30 A kind of Purified cup
CN201420354367.9U Expired - Fee Related CN203959968U (en) 2014-01-09 2014-06-30 A kind of infant's Purified cup
CN201420355721.XU Expired - Fee Related CN203904120U (en) 2014-01-09 2014-06-30 Purifying water cup
CN201410600220.8A Expired - Fee Related CN104341028B (en) 2014-01-09 2014-10-31 A kind of bath water purifier
CN201410666895.2A Pending CN104357303A (en) 2014-01-09 2014-11-20 Liquid purifier
CN201420700000.8U Expired - Fee Related CN204281730U (en) 2014-01-09 2014-11-20 A kind of liquid cleaning device
CN201410666866.6A Pending CN104357706A (en) 2014-01-09 2014-11-20 Alloy disinfection wire for removing heavy metals in liquor and liquor purification plant thereof
CN201420700045.5U Expired - Fee Related CN204275070U (en) 2014-01-09 2014-11-20 A kind of medicinal liquid purifier
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CN201410282282.9A Expired - Fee Related CN104109775B (en) 2014-01-09 2014-06-23 A kind of B alloy wire of purifying drinking water
CN201410296034.XA Expired - Fee Related CN104071931B (en) 2014-01-09 2014-06-27 A kind of child's water purifying cup
CN201420349294.4U Expired - Fee Related CN203952761U (en) 2014-01-09 2014-06-27 A kind of portable motion water purifying cup
CN201420346943.5U Expired - Fee Related CN203999074U (en) 2014-01-09 2014-06-27 A kind of filter core water purifying cup
CN201410296523.5A Expired - Fee Related CN104138131B (en) 2014-01-09 2014-06-27 A kind of portable motion water purifying cup
CN201410293908.6A Expired - Fee Related CN104058485B (en) 2014-01-09 2014-06-27 A kind of filter core water purifying cup
CN201420348820.5U Expired - Fee Related CN203904119U (en) 2014-01-09 2014-06-27 Water purification cup for child
CN201410304770.5A Expired - Fee Related CN104108773B (en) 2014-01-09 2014-06-30 A kind of Portable miniature water purifier
CN201410302926.6A Expired - Fee Related CN104058524B (en) 2014-01-09 2014-06-30 A kind of infant Purified cup
CN201410305212.0A Expired - Fee Related CN104106959B (en) 2014-01-09 2014-06-30 The special water purifying cup of a kind of pregnant woman
CN201420355872.5U Expired - Fee Related CN203987299U (en) 2014-01-09 2014-06-30 The special-purpose water purifying cup of a kind of pregnant woman
CN201410304441.0A Expired - Fee Related CN104108817B (en) 2014-01-09 2014-06-30 A kind of Purified cup
CN201420354367.9U Expired - Fee Related CN203959968U (en) 2014-01-09 2014-06-30 A kind of infant's Purified cup
CN201420355721.XU Expired - Fee Related CN203904120U (en) 2014-01-09 2014-06-30 Purifying water cup
CN201410600220.8A Expired - Fee Related CN104341028B (en) 2014-01-09 2014-10-31 A kind of bath water purifier
CN201410666895.2A Pending CN104357303A (en) 2014-01-09 2014-11-20 Liquid purifier
CN201420700000.8U Expired - Fee Related CN204281730U (en) 2014-01-09 2014-11-20 A kind of liquid cleaning device

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