CN104356857A - Rusty antirust primer - Google Patents
Rusty antirust primer Download PDFInfo
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- CN104356857A CN104356857A CN201410592176.0A CN201410592176A CN104356857A CN 104356857 A CN104356857 A CN 104356857A CN 201410592176 A CN201410592176 A CN 201410592176A CN 104356857 A CN104356857 A CN 104356857A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/47—Levelling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0893—Zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Abstract
The invention relates to a rusty antirust primer and mainly solves the problem that the construction quality is influenced by complicated sand-blasting and de-rusting construction processes of an existing rusty steel structure or pipeline. The rusty antirust primer consists of a component A and a component B, wherein the component A comprises the following components in percentage by weight: 37 percent of solid epoxy resin, 9 percent of anatase titanium dioxide, 1 percent of high-pigment carbon black, 15 percent of zinc phosphate, 12 percent of talcum powder, 4 percent of zinc powder, 4 percent of dimethylbenzene, 2 percent of n-butanol, 1 percent of organobentonite, 1 percent of an efficient wetting and dispersing agent, 1 percent of a dust-proof agent, 1 percent of a defoaming agent and 1 percent of a flatting agent; the component B comprises the following components in percentage by weight: 10 percent of a curing agent, 0.3 percent of dimethylbenzene and 0.7 percent of n-butanol. The rusty antirust primer has the benefits that the rusty antirust primer not only can be directly constructed on a rusty base material and form a protective passivation film through replacement reaction, but also can restrain the corrosion caused to steel and ferrous metal through active metal, so that the construction cost is reduced, and the working efficiency is improved.
Description
Technical field
The present invention relates to a kind of priming paint in paint field, especially a kind of band rust rust-proofing primer.
Background technology
Current domestic solvent type epoxy priming paint and polyurethane primer, anticorrosion year is limited to 15 years, but steel surface carries out derusting by sandblast before construction process requirement application, its quality should reach GB8923 specify in Sa2.5 level, surface answer non-corroding, free from dust, anhydrous mark, without greasy dirt.Encounter problems in construction as follows: (1) inefficiency, according to derusting by sandblast and two end two surface constructions, at least need more than 24 hours intervals.(2) operating environment is separately, Work places during derusting by sandblast will with spray paint, mopping operation separates, otherwise can affect antifouling paste construction effect.(3) consume human and material resources, time, increase working procedure, need professional and professional equipment to carry out derusting by sandblast.(4) cannot ensure construction quality, construction team, for trying to meet the deadline for the project, reduces derusting by sandblast working procedure to without rusty stain and the steel structure or pipeline lacking rusty stain, has a strong impact on quality.
Summary of the invention
The invention reside in overcome exist in background technology have the steel structure of rusty stain or the loaded down with trivial details problem affecting construction quality of pipeline derusting by sandblast working procedure, and provide a kind of band rust rust-proofing primer.This band rust rust-proofing primer, directly can construct, form protection passive film, suppress again the corrosion of iron and steel and ferrous metal by Active Metals, reduce construction cost, increase work efficiency by replacement(metathesis)reaction on band rust base material.
The present invention solves its problem and reaches by following technical scheme, this band rust rust-proofing primer, and its component and proportioning are as follows by weight percentage: be made up of component A and B component, in component A: solid epoxy 37%, anatase thpe white powder 9%, high-carbon black pigment 1%, zinc phosphate 15%, talcum powder 12%, zinc powder 4%, dimethylbenzene 4%, propyl carbinol 2%, organobentonite 1%, efficient wetting dispersing agent 1%, anti-settling agent 1%, defoamer 1%, flow agent 1%; In B component: solidifying agent 10%, dimethylbenzene 0.3%, propyl carbinol 0.7%.
Described component A and B component weight ratio are 8:1.
The principles of chemistry that this band rust rust-proofing primer utilizes are that iron rust main component is ferric oxide (Fe
2o
3), by unstable ferric ion (Fe
+ 3) become stable ferric oxide ion, easily oxidized iron (Fe) ion is protected, in formula, selects zinc phosphate and zinc powder, consumption and purposes as follows:
1, zinc phosphate: chemical formula: Zn
3(PO
4)
2, consumption 14%.Because of the rust-stabilising pigment that zinc phosphate is a kind of white non-toxic, the nontoxicity of new generation of antirust corrosive effect excellence, non-harmful rust-stabilising pigment, it effectively can substitute the traditional rust-stabilising pigment containing heavy metal lead, chromium, zinc phosphate gene has fine activity, complex compound can be generated with a lot of Action of Metal Ions, therefore there is good rust-proof effect.
Due to zinc phosphate Zn
3(PO
4)
2gene has fine activity, and can generate complex compound with a lot of metal, zinc phosphate and ferric ion have very strong complex ability, and zinc phosphate radical ion and iron anode react, and can be formed with tertiary iron phosphate FePO
4for the protective membrane of main body, this passive film is water insoluble, presents remarkable rustless property.
2, zinc powder: molecular formula: Zn, consumption 5%.Sacrificial anode protection, zinc powder comparatively iron ion is active, easily with oxygen generation oxidizing reaction in air, is made as anode by zinc powder, oxidizing reaction occurs and forms zinc oxide (ZnO), thus protects iron ion generation oxidizing reaction, 2Zn+2O
2↑=2ZnO.
Zinc oxide has outside certain tinting strength and opacifying power, has again antirust, anticorrosion and luminous function, and in addition, zinc oxide also has excellent ultraviolet screening ability, make its heavy industry antifouling paste anti-aging etc. in there is more outstanding characteristic.
The present invention can have following beneficial effect compared with above-mentioned background technology: this band becomes rusty the good rust transformation function of rust-proofing primer, capable of coating with rust, reduces derusting by sandblast working procedure; High-content metal zinc, has splendid galvanic protection effect, and the zinc oxide of formation can improve impact property, 50cm impulse detection, observes paint film flawless, wrinkle and peeling phenomenon.There is excellent wear resistance and weather resistance, strong adhesion, draw circle method sticking power grade and reach 1 grade.Have chemical reagent resistance widely, resistance to 10% sulphuric acid soln, resistance to 10% sodium hydroxide alkaline solution and resistance to sodium chloride salt >=50d, paint film non-scale does not come off.
Embodiment:
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
Take component A: NPEL-E44 epoxy resin 37g, anatase thpe white powder R-902 are 9g, high-carbon black pigment 1g, rust-stabilising pigment zinc phosphate 15g, 400 order talcum powder 12g, zinc powder 4g, dimethylbenzene 4g, propyl carbinol 2g, organobentonite 1g, efficient wetting dispersing agent BYK180 is 1g, and dust-proofing agent BYK410 is 1g, defoamer BYK066N is 1g, and flow agent BYK378 is 1g; B component: solidifying agent 5960 is 10g, dimethylbenzene 0.3g, propyl carbinol 0.7g; Component each in component A and B component is mixed respectively rear remix and be mixed with this band rust rust-proofing primer.
This band rust rust-proofing primer, has good rust transformation function, capable of coating with rust, reduces derusting by sandblast working procedure.High-content metal zinc, have splendid galvanic protection effect, the zinc oxide of formation can improve impact property, impacts grade >=50cm, is equivalent to this point of 50kg weight effect, and after impacting, paint film is intact.Have excellent wear resistance and weather resistance, strong adhesion, draw circle method sticking power grade 1 grade, sticking power is best.There is chemical reagent resistance widely, resistance to 10% sulphuric acid soln, resistance to 10% sodium hydroxide alkaline solution and resistance to sodium chloride salt >=50d, paint film non-scale does not come off, extend the work-ing life of antifouling paste, this performance is higher than grand celebration oil play standard (standard No.: Q/SY DQ1005-2004, acidproof alkali salt >=30d).Coating is dry rapidly, paint film inter-layer bonding force is strong, under constant temperature (temperature 23 DEG C) constant humidity (humidity 50%) condition, surface drying≤4h, do solid work≤16h), higher than industry standard (standard No.: SY/T 0320-2010, do solid work≤24h) and company standard (standard No.: Q/SY DQ1005-2004, does solid work≤24h).
Solid epoxy described in embodiment is NPEL-E44 epoxy resin, and producer is Tianjin Guo Long Chemical Co., Ltd., and anatase thpe white powder is anatase thpe white powder R-902, Dupont import; Efficient wetting dispersing agent BYK180, anti-settling agent BYK410, defoamer BYK066N, flow agent BYK378, above-mentioned auxiliary agent is all German Bi Ke import; Polyamide curing agent 5960, producer is Tianjin Guo Long Chemical Co., Ltd..
Claims (4)
1. a band rust rust-proofing primer, its component and proportioning are as follows by weight percentage: be made up of, in component A component A and B component: solid epoxy 37%, anatase thpe white powder 9%, high-carbon black pigment 1%, zinc phosphate 15%, talcum powder 12%, zinc powder 4%, dimethylbenzene 4%, propyl carbinol 2%, organobentonite 1%, efficient wetting dispersing agent 1%, dust-proofing agent 1%, defoamer 1%, flow agent 1%; In B component: solidifying agent 10%, dimethylbenzene 0.3%, propyl carbinol 0.7%.
2. one band rust rust-proofing primer according to claim 1, is characterized in that: described component A and B component weight ratio are 8:1.
3. one band rust rust-proofing primer according to claim 1 and 2, it is characterized in that: described solid epoxy is NPEL-E44 epoxy resin, anatase thpe white powder is anatase thpe white powder R-902, efficient wetting dispersing agent is dispersant B YK180, anti-settling agent is anti-settling agent BYK410, defoamer is defoamer BYK066N, flow agent is flow agent BYK378, and solidifying agent is solidifying agent 5960.
4. one band rust rust-proofing primer according to claim 1 and 2, is characterized in that: described talcum powder is 400 order talcum powder.
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CN201410592176.0A CN104356857B (en) | 2014-10-29 | 2014-10-29 | A kind of band rust anti-corrosive primer |
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CN201410592176.0A CN104356857B (en) | 2014-10-29 | 2014-10-29 | A kind of band rust anti-corrosive primer |
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CN104356857A true CN104356857A (en) | 2015-02-18 |
CN104356857B CN104356857B (en) | 2017-08-29 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105713483A (en) * | 2016-02-02 | 2016-06-29 | 广东多正化工科技有限公司 | Multifunctional epoxy universal primer and preparation method thereof |
CN107523189A (en) * | 2017-09-12 | 2017-12-29 | 无锡市永兴金属软管有限公司 | A kind of effective impregnating fluid of wavy metal and preparation method thereof |
Citations (5)
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---|---|---|---|---|
CN1232065A (en) * | 1998-04-14 | 1999-10-20 | 林荫民 | Corrosion resisting paint without need of cleaning rust |
CN1343749A (en) * | 2001-10-17 | 2002-04-10 | 中国人民解放军海军舰船维修研究所 | Priming paint for wet and rusted surface |
CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料(深圳)有限公司 | Water-based epoxy zinc-rich primer |
CN102786864A (en) * | 2012-08-31 | 2012-11-21 | 上海经天新材料科技有限公司 | Anticorrosive paint for rusty coating and preparation method of anticorrosive paint |
CN103756512A (en) * | 2013-12-31 | 2014-04-30 | 上海大通涂料化工有限公司 | Anticorrosive paint coated under rusted and moist conditions |
-
2014
- 2014-10-29 CN CN201410592176.0A patent/CN104356857B/en active Active
Patent Citations (5)
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---|---|---|---|---|
CN1232065A (en) * | 1998-04-14 | 1999-10-20 | 林荫民 | Corrosion resisting paint without need of cleaning rust |
CN1343749A (en) * | 2001-10-17 | 2002-04-10 | 中国人民解放军海军舰船维修研究所 | Priming paint for wet and rusted surface |
CN101104771A (en) * | 2007-08-20 | 2008-01-16 | 维新环保涂料(深圳)有限公司 | Water-based epoxy zinc-rich primer |
CN102786864A (en) * | 2012-08-31 | 2012-11-21 | 上海经天新材料科技有限公司 | Anticorrosive paint for rusty coating and preparation method of anticorrosive paint |
CN103756512A (en) * | 2013-12-31 | 2014-04-30 | 上海大通涂料化工有限公司 | Anticorrosive paint coated under rusted and moist conditions |
Non-Patent Citations (4)
Title |
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杨红波等: "《新型多功能环氧防腐涂料的研制》", 《上海涂料》 * |
管从胜等: "《聚苯硫醚涂料及应用》", 31 May 2007, 化学工业出版社 * |
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陈克忠: "《金属表面防腐蚀工艺》", 30 June 2010, 北京:化学工业出版社, article "《金属表面防腐蚀工艺》" * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105713483A (en) * | 2016-02-02 | 2016-06-29 | 广东多正化工科技有限公司 | Multifunctional epoxy universal primer and preparation method thereof |
CN107523189A (en) * | 2017-09-12 | 2017-12-29 | 无锡市永兴金属软管有限公司 | A kind of effective impregnating fluid of wavy metal and preparation method thereof |
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