CN104356803A - 一种阻燃耐腐蚀丙烯酸涂料 - Google Patents

一种阻燃耐腐蚀丙烯酸涂料 Download PDF

Info

Publication number
CN104356803A
CN104356803A CN201410570847.3A CN201410570847A CN104356803A CN 104356803 A CN104356803 A CN 104356803A CN 201410570847 A CN201410570847 A CN 201410570847A CN 104356803 A CN104356803 A CN 104356803A
Authority
CN
China
Prior art keywords
parts
water soluble
acrylic coating
epoxy
fire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410570847.3A
Other languages
English (en)
Inventor
朱恒衡
梅长林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI PROVINCE JINDUN PAINT Co Ltd
Original Assignee
ANHUI PROVINCE JINDUN PAINT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI PROVINCE JINDUN PAINT Co Ltd filed Critical ANHUI PROVINCE JINDUN PAINT Co Ltd
Priority to CN201410570847.3A priority Critical patent/CN104356803A/zh
Publication of CN104356803A publication Critical patent/CN104356803A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

本发明公开了一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂60-70份，水溶性酚醛树脂12-15份，丁苯橡胶8-11份，月桂酸二乙醇酰胺3-4份，羟丙基甲基纤维素2.8-3.1份，海泡石粉15-18份，滑石粉5-8份，蒙脱石粉1-2份，三聚氰胺磷酸酯2-3份，纳米氢氧化镁14-17份，磷酸三甲苯酯3-4份，全甲醚化氨基树脂10-15份，松香酸锰2-3份，环氧基硅烷偶联剂0.4-0.6份，颜料15-25份，增韧剂2.1-2.4份，消泡剂0.5-0.8份，平流剂0.7-1份，防霉剂0.4-0.5份，溶剂50-55份。本发明具有优异的耐热阻燃性能，而且耐腐蚀性能优秀。

Description

一种阻燃耐腐蚀丙烯酸涂料
技术领域
本发明涉及阻燃涂料技术领域，尤其涉及一种阻燃耐腐蚀丙烯酸涂料。
背景技术
目前在室内装修中木质材料及涂料用量逐年递增，由于木质材料和有些涂料本身的可燃性和易燃性，必然存在火灾隐患。近年来，由于装饰材料的大量使用，这种火灾呈上升趋势。制备新型的不燃、难燃装饰材料，受到国家有关部门的高度重视。因此阻燃涂料成为研究的热点，但现有的阻燃涂料仍然存在着一些不足，通过涂膜的催化成炭作用以实现对基材阻燃的现有技术，采用的脱水催化剂分解温度偏高而低温活性差，涂料的阻燃性能欠佳。因为火灾发生时，成膜物质往往先于脱水催化剂受热分解，产生较多的可燃的挥发性有机化合物，影响炭层的形成和结构，进而影响对基材的保护作用。
发明内容
基本背景技术存在的技术问题，本发明提出了一种阻燃耐腐蚀丙烯酸涂料，具有优异的耐热阻燃性能，而且耐腐蚀性能优秀。
本发明提出的一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂60-70份，水溶性酚醛树脂12-15份，丁苯橡胶8-11份，月桂酸二乙醇酰胺3-4份，羟丙基甲基纤维素2.8-3.1份，海泡石粉15-18份，滑石粉5-8份，蒙脱石粉1-2份，三聚氰胺磷酸酯2-3份，纳米氢氧化镁14-17份，磷酸三甲苯酯3-4份，全甲醚化氨基树脂10-15份，松香酸锰2-3份，环氧基硅烷偶联剂0.4-0.6份，颜料15-25份，增韧剂2.1-2.4份，消泡剂0.5-0.8份，平流剂0.7-1份，防霉剂0.4-0.5份，溶剂50-55份。
优选地，水溶性丙烯酸树脂、水溶性酚醛树脂和丁苯橡胶的重量比为67-69：13-14：9-10。
优选地，其原料按重量份包括：水溶性丙烯酸树脂67-69份，水溶性酚醛树脂13-14份，丁苯橡胶9-10份，月桂酸二乙醇酰胺3.4-3.6份，羟丙基甲基纤维素2.9-3份，海泡石粉16-17份，滑石粉6-7份，蒙脱石粉1.6-1.9份，三聚氰胺磷酸酯2.3-2.5份，纳米氢氧化镁15-16份，磷酸三甲苯酯3.3-3.7份，全甲醚化氨基树脂12-13份，松香酸锰2.4-2.8份，环氧基硅烷偶联剂0.45-0.55份，颜料17-20份，增韧剂2.2-2.3份，消泡剂0.6-0.7份，平流剂0.8-0.9份，防霉剂0.42-0.45份，溶剂53-56份。
优选地，溶剂为水、乙醇、丙酮、甲苯、二甲苯中的一种。
优选地，环氧基硅烷偶联剂为3-(2,3-环氧丙氧)丙基三甲氧基硅烷、2-(3,4-环氧环己烷)乙基三甲氧基硅烷、2-(3,4-环氧环己烷基)乙基三乙氧基硅烷、3-[(2,3)-环氧丙氧]丙基甲基二甲氧基硅烷、乙氧基二甲基[3-(环氧乙烷氧基)丙基]硅烷、三甲氧基[3-(环氧乙烷基甲氧基)丙基]硅烷中的一种。
全甲醚化氨基树脂的化学名称为六甲氧基甲基三聚氰胺甲醛树脂。
本发明采用水溶性丙烯酸树脂、水溶性酚醛树脂和丁苯橡胶作为成膜物质，使本发明具有良好的硬度以及耐候、耐磨、耐热阻燃性能，通过月桂酸二乙醇酰胺的乳化作用，使成膜物质能够溶于极性或非极性溶剂中；羟丙基甲基纤维素、海泡石粉、滑石粉和蒙脱石粉相互配合作为增稠剂，不仅能调整本发明的稠度，还大大提高了本发明的防触变性能，并降低制造成本，通过环氧基硅烷偶联剂与成膜物质接枝，大大提高了本发明的相容性，而且磷酸三甲苯酯作为增塑剂，可辅助海泡石粉、滑石粉和蒙脱石粉均匀分散在溶剂中；海泡石粉、滑石粉和蒙脱石粉具有防腐蚀的官能团，可大幅提高本发明的耐腐蚀能力；而三聚氰胺磷酸酯、磷酸三甲苯酯作为氮、磷系阻燃剂，和纳米氢氧化镁相互配合，不仅大大提高了本发明的耐热阻燃性能，而且还能抑制烟雾的生成；全甲醚化氨基树脂和松香酸锰配合，提高本发明的固化速度，可在140-160℃时烘15-20min即可完全干燥。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂69份，水溶性酚醛树脂13份，丁苯橡胶10份，月桂酸二乙醇酰胺3.4份，羟丙基甲基纤维素3份，海泡石粉16份，滑石粉7份，蒙脱石粉1.6份，三聚氰胺磷酸酯2.5份，纳米氢氧化镁15份，磷酸三甲苯酯3.7份，全甲醚化氨基树脂12份，松香酸锰2.8份，三甲氧基[3-(环氧乙烷基甲氧基)丙基]硅烷0.45份，颜料20份，增韧剂2.2份，消泡剂0.7份，平流剂0.8份，防霉剂0.45份，水53份。
实施例2
本发明提出的一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂60份，水溶性酚醛树脂15份，丁苯橡胶8份，月桂酸二乙醇酰胺4份，羟丙基甲基纤维素2.8份，海泡石粉18份，滑石粉5份，蒙脱石粉2份，三聚氰胺磷酸酯2份，纳米氢氧化镁17份，磷酸三甲苯酯3份，全甲醚化氨基树脂15份，松香酸锰2份，3-[(2,3)-环氧丙氧]丙基甲基二甲氧基硅烷0.6份，颜料15份，增韧剂2.4份，消泡剂0.5份，平流剂1份，防霉剂0.4份，乙醇55份。
实施例3
本发明提出的一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂67份，水溶性酚醛树脂14份，丁苯橡胶9份，月桂酸二乙醇酰胺3.6份，羟丙基甲基纤维素2.9份，海泡石粉17份，滑石粉6份，蒙脱石粉1.9份，三聚氰胺磷酸酯2.3份，纳米氢氧化镁16份，磷酸三甲苯酯3.3份，全甲醚化氨基树脂13份，松香酸锰2.4份，2-(3,4-环氧环己烷)乙基三甲氧基硅烷0.55份，颜料17份，增韧剂2.3份，消泡剂0.6份，平流剂0.9份，防霉剂0.42份，丙酮56份。
实施例4
本发明提出的一种阻燃耐腐蚀丙烯酸涂料，其原料按重量份包括：水溶性丙烯酸树脂60份，水溶性酚醛树脂15份，丁苯橡胶8份，月桂酸二乙醇酰胺4份，羟丙基甲基纤维素2.8份，海泡石粉18份，滑石粉5份，蒙脱石粉2份，三聚氰胺磷酸酯2份，纳米氢氧化镁17份，磷酸三甲苯酯3份，全甲醚化氨基树脂15份，松香酸锰2份，3-(2,3-环氧丙氧)丙基三甲氧基硅烷0.6份，颜料15份，增韧剂2.4份，消泡剂0.5份，平流剂1份，防霉剂0.4份，二甲苯55份。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (5)

1.一种阻燃耐腐蚀丙烯酸涂料，其特征在于，其原料按重量份包括：水溶性丙烯酸树脂60-70份，水溶性酚醛树脂12-15份，丁苯橡胶8-11份，月桂酸二乙醇酰胺3-4份，羟丙基甲基纤维素2.8-3.1份，海泡石粉15-18份，滑石粉5-8份，蒙脱石粉1-2份，三聚氰胺磷酸酯2-3份，纳米氢氧化镁14-17份，磷酸三甲苯酯3-4份，全甲醚化氨基树脂10-15份，松香酸锰2-3份，环氧基硅烷偶联剂0.4-0.6份，颜料15-25份，增韧剂2.1-2.4份，消泡剂0.5-0.8份，平流剂0.7-1份，防霉剂0.4-0.5份，溶剂50-55份。
2.根据权利要求1所述阻燃耐腐蚀丙烯酸涂料，其特征在于，水溶性丙烯酸树脂、水溶性酚醛树脂和丁苯橡胶的重量比为67-69：13-14：9-10。
3.根据权利要求1或2所述阻燃耐腐蚀丙烯酸涂料，其特征在于，其原料按重量份包括：水溶性丙烯酸树脂67-69份，水溶性酚醛树脂13-14份，丁苯橡胶9-10份，月桂酸二乙醇酰胺3.4-3.6份，羟丙基甲基纤维素2.9-3份，海泡石粉16-17份，滑石粉6-7份，蒙脱石粉1.6-1.9份，三聚氰胺磷酸酯2.3-2.5份，纳米氢氧化镁15-16份，磷酸三甲苯酯3.3-3.7份，全甲醚化氨基树脂12-13份，松香酸锰2.4-2.8份，环氧基硅烷偶联剂0.45-0.55份，颜料17-20份，增韧剂2.2-2.3份，消泡剂0.6-0.7份，平流剂0.8-0.9份，防霉剂0.42-0.45份，溶剂53-56份。
4.根据权利要求1-3任一项所述阻燃耐腐蚀丙烯酸涂料，其特征在于，溶剂为水、乙醇、丙酮、甲苯、二甲苯中的一种。
5.根据权利要求1-4任一项所述阻燃耐腐蚀丙烯酸涂料，其特征在于，环氧基硅烷偶联剂为3-(2,3-环氧丙氧)丙基三甲氧基硅烷、2-(3,4-环氧环己烷)乙基三甲氧基硅烷、2-(3,4-环氧环己烷基)乙基三乙氧基硅烷、3-[(2,3)-环氧丙氧]丙基甲基二甲氧基硅烷、乙氧基二甲基[3-(环氧乙烷氧基)丙基]硅烷、三甲氧基[3-(环氧乙烷基甲氧基)丙基]硅烷中的一种。
CN201410570847.3A 2014-10-23 2014-10-23 一种阻燃耐腐蚀丙烯酸涂料 Pending CN104356803A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410570847.3A CN104356803A (zh) 2014-10-23 2014-10-23 一种阻燃耐腐蚀丙烯酸涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410570847.3A CN104356803A (zh) 2014-10-23 2014-10-23 一种阻燃耐腐蚀丙烯酸涂料

Publications (1)

Publication Number Publication Date
CN104356803A true CN104356803A (zh) 2015-02-18

Family

ID=52524125

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410570847.3A Pending CN104356803A (zh) 2014-10-23 2014-10-23 一种阻燃耐腐蚀丙烯酸涂料

Country Status (1)

Country Link
CN (1) CN104356803A (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1380368A (zh) * 2002-04-11 2002-11-20 海洋化工研究院 膨胀型防火涂料
CN2673639Y (zh) * 2002-10-30 2005-01-26 赵毅 膨胀防火包覆材料
CN1590459A (zh) * 2003-08-05 2005-03-09 希尔蒂股份公司 用于防火的持久塑性捏合剂、其制备方法及其用途
KR20090073412A (ko) * 2007-12-31 2009-07-03 (주)디피아이 홀딩스 수성 투명 방염 도료, 이의 제조방법 및 방염 처리 도막의형성방법
CN102604503A (zh) * 2012-03-05 2012-07-25 厦门大学 一种近海钢结构建筑用涂料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1380368A (zh) * 2002-04-11 2002-11-20 海洋化工研究院 膨胀型防火涂料
CN2673639Y (zh) * 2002-10-30 2005-01-26 赵毅 膨胀防火包覆材料
CN1590459A (zh) * 2003-08-05 2005-03-09 希尔蒂股份公司 用于防火的持久塑性捏合剂、其制备方法及其用途
KR20090073412A (ko) * 2007-12-31 2009-07-03 (주)디피아이 홀딩스 수성 투명 방염 도료, 이의 제조방법 및 방염 처리 도막의형성방법
CN102604503A (zh) * 2012-03-05 2012-07-25 厦门大学 一种近海钢结构建筑用涂料及其制备方法

Similar Documents

Publication Publication Date Title
WO2008113609A3 (en) Geopolymer composition, coating obtainable therefrom and methods
CN104559766B (zh) 一种瓷砖防污剂及其制备方法
CN102382553A (zh) 用于钢质管道焊口部位高温防腐用无溶剂环氧底漆
CN107793884A (zh) 一种石墨烯防腐涂料及制备方法
CN104448237B (zh) 一种适用于钢管的硅氮磷协同阻燃环氧树脂粉末涂料及其制备方法
CN102417775A (zh) 一种硅溶胶-丙烯酸酯类乳液复合型底漆
CN102367354A (zh) 用于钢质管道焊口部位3pp防腐用无溶剂环氧底漆
CN105062303A (zh) 一种耐热阻燃粉末涂料
CN104356804A (zh) 一种阻燃丙烯酸涂料
CN105969162A (zh) 一种耐热高附着力的高稳定性涂料
CN105907240B (zh) 一种含有防闪锈剂的水性环氧防腐涂料及其制备方法
CN104356802A (zh) 一种水性丙烯酸氨基烤漆
CN103773151A (zh) 一种耐高温耐酸耐碱的涂料
CN105062304A (zh) 一种高阻燃耐腐蚀粉末涂料
CN104194574B (zh) 一种高阻燃高附着力涂料
CN104140756A (zh) 一种环氧重防腐导静电防火涂料的制备方法
CN104356803A (zh) 一种阻燃耐腐蚀丙烯酸涂料
CN105153842A (zh) 一种汽车零件专用高硬度高韧性环保水性涂料
CN104130710B (zh) 一种原油储罐内罐顶用弹性环氧复合防腐材料及其制备方法
CN109868020A (zh) 一种多功能涂层和一种水性环保多功能涂层液
CN103613291A (zh) 一种玻璃防霉隔离粉及其制备方法
CN106318106A (zh) 一种高阻燃环氧树脂重防腐涂料
CN103145952B (zh) 一种腰果壳油改性混胺固化剂及其制备方法
CN105385346A (zh) 变压器用耐高温涂料材料组合物和耐高温涂料的制备方法
CN110102707A (zh) 一种epc消失模铸钢涂料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150218

WD01 Invention patent application deemed withdrawn after publication