CN104356744A - UV (Ultraviolet) light curable extinction ink for glass - Google Patents
UV (Ultraviolet) light curable extinction ink for glass Download PDFInfo
- Publication number
- CN104356744A CN104356744A CN201410584674.0A CN201410584674A CN104356744A CN 104356744 A CN104356744 A CN 104356744A CN 201410584674 A CN201410584674 A CN 201410584674A CN 104356744 A CN104356744 A CN 104356744A
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- CN
- China
- Prior art keywords
- ultraviolet light
- glass
- light polymerization
- percent
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention relates to the field of ink, in particular to UV (Ultraviolet) light curable extinction ink for glass. The UV light curable extinction ink for the glass is prepared by the following raw materials in percentage by weight: 30-45 percent of aliphatic polyurethane acrylate oligomer and carboxylic acid modified polyester acrylate mixture, 5-12 percent of an initiator, 1-3 percent of a surface auxiliary agent, 5-10 percent of hydroxyphenyl sulfide, 10-20 percent of an active diluent, 1-2 percent of graphitized carbon nanofiber and 10-30 percent of an inert solvent. The UV light curable extinction ink has the benefit that the UV light curable extinction ink not only can achieve the beautifying and protecting functions of coatings, but also has excellent low chromatic number performance and leveling property and good extinction effect.
Description
Technical field
The present invention relates to ink area, particularly relate to a kind of glass ultraviolet light polymerization delustring ink.
Background technology
Ultraviolet-curing paint is since appearance, because it has the feature of 5E, i.e. efficient (Efficient), applicable wide (Enabling), economic (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, ultraviolet-curing paint is widely used in and closely bound up field of living by people, to play the effect beautifying object and protection object.
As a large kind of printing consumable material, glass compared with plastics, have that transparency is high, physical strength good, good weatherability etc. a little, simultaneously along with the rise of International Crude Oil, also comparatively plastics are low for the cost of manufacture of glass.But because glass has lower surface energy, ink not easily adheres to, for a long time, its application in printing industry is limited.
Along with the development of science and technology, Printing ink producing business adopts new synthetic resins and production technique, solves the problem that glass surface ink adhesion is not good, develops all kinds of glass ink, thus widened the application of glass baseplate in printing industry.
Summary of the invention
The present invention is directed to the above-mentioned state of the art, a kind of glass ultraviolet light polymerization delustring ink is provided, while the present invention possesses water-fast, resistance toheat, also there is good extinction effect.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
A kind of glass ultraviolet light polymerization delustring ink, is characterized in that: be prepared from by the raw material of following mass percent: aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture: 30% ~ 45%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Hydroxybenzene thioether: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Graphitization nano carbon fiber: 1% ~ 2%; Inert solvent: 10 ~ 30%.
Further, described a kind of glass ultraviolet light polymerization delustring ink is prepared from by the raw material of following mass percent: aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture: 40%; Initiator: 8%; Surface modifier: 1.5%; Hydroxybenzene thioether: 7.5%; Reactive thinner: 16.5%; Graphitization nano carbon fiber: 1.5%; Inert solvent: 25%.
Further, described aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture, both mass ratioes are 0.5 ~ 1.5:1.
Further, described reactive thinner is hydroxy methacrylate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
Further, described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
Further, described surface modifier is silicone based, organic fluorine class or said mixture.
Further, described inert solvent is methylpentanolone.
The invention provides a kind of glass ultraviolet light polymerization delustring ink, beneficial effect is as follows:
What a kind of glass ultraviolet light polymerization of the present invention delustring ink not only can meet that ink has completely beautifies and defencive function; the present invention also has splendid low chromatic number performance; possess good extinction effect, there is good flow leveling simultaneously, conveniently use.
The present invention adopts hydroxybenzene thioether, plays well change effect to refraction coefficient, thus makes the present invention without the need to adding flatting silica again; Add graphitization nano carbon fiber and play good snappiness, and certain VOC material can be absorbed, health environment-friendly more.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of glass ultraviolet light polymerization delustring ink is prepared from by the raw material of following mass percent:
Aliphatic urethane acrylate oligopolymer, carboxyl acid modified polyester acrylic ester mixture: 45%; Benzophenone: 8%; Organic fluorine class: 1.5%; Glycol ether: 7.5%; Hydroxy methacrylate, diacrylate ester mixture: 16.5%; Graphitization nano carbon fiber: 1.5%; Methylpentanolone: 20%.
Wherein, aliphatic urethane acrylate oligopolymer, carboxyl acid modified polyester acrylate mass ratio are 1.2:1; Hydroxy methacrylate, diacrylate mixture quality are than being 2:1.
Embodiment 2:
Described a kind of glass ultraviolet light polymerization delustring ink is prepared from by the raw material of following mass percent:
Aliphatic urethane acrylate oligopolymer, carboxyl acid modified polyester acrylate: 44%; 1-hydroxycyclohexyl phenyl ketone: 12%; Silicone based: 2%; Glycol ether: 9%; Hydroxy methacrylate, diacrylate ester mixture: 18%; Graphitization nano carbon fiber: 1%; Methylpentanolone: 14%.
Wherein, aliphatic urethane diacrylate and bisphenol A epoxy diacrylate mass ratio are 1:1; Hydroxy methacrylate, diacrylate mixture quality are than being 2.5:1.
Embodiment 3:
Described a kind of glass ultraviolet light polymerization delustring ink is prepared from by the raw material of following mass percent:
Aliphatic urethane diacrylate and bisphenol A epoxy diacrylate mixture: 38%; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture: 12%; Silicone based, organic fluorine class mixture: 3%; Glycol ether: 10%; Hydroxy methacrylate, diacrylate ester mixture: 12%; Graphitization nano carbon fiber: 2%; Methylpentanolone: 23%.
Wherein, aliphatic urethane diacrylate and bisphenol A epoxy diacrylate mass ratio are 0.8:1; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture quality are than being 2.2:1; Hydroxy methacrylate, diacrylate mixture quality are than being 1.8:1.
Claims (7)
1. a glass ultraviolet light polymerization delustring ink, is characterized in that: be prepared from by the raw material of following mass percent: aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture: 30% ~ 45%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Hydroxybenzene thioether: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Graphitization nano carbon fiber: 1% ~ 2%; Inert solvent: 10 ~ 30%.
2. a kind of glass ultraviolet light polymerization delustring ink according to claim 1, is characterized in that: described a kind of glass ultraviolet light polymerization delustring ink is prepared from by the raw material of following mass percent: aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture: 40%; Initiator: 8%; Surface modifier: 1.5%; Hydroxybenzene thioether: 7.5%; Reactive thinner: 16.5%; Graphitization nano carbon fiber: 1.5%; Inert solvent: 25%.
3. a kind of glass ultraviolet light polymerization delustring ink according to claim 1 and 2, is characterized in that: described aliphatic urethane acrylate oligopolymer and carboxyl acid modified polyester acrylic ester mixture, both mass ratioes are 0.5 ~ 1.5:1.
4. a kind of glass ultraviolet light polymerization delustring ink according to claim 1 and 2, is characterized in that: described reactive thinner is hydroxy methacrylate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
5. a kind of glass ultraviolet light polymerization delustring ink according to claim 1 and 2, is characterized in that: described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
6. a kind of glass ultraviolet light polymerization delustring ink according to claim 1 and 2, is characterized in that: described surface modifier is silicone based, organic fluorine class or said mixture.
7. a kind of glass ultraviolet light polymerization delustring ink according to claim 1 and 2, is characterized in that: described inert solvent is methylpentanolone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584674.0A CN104356744B (en) | 2014-10-28 | 2014-10-28 | A kind of glass ultraviolet light polymerization delustring ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584674.0A CN104356744B (en) | 2014-10-28 | 2014-10-28 | A kind of glass ultraviolet light polymerization delustring ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104356744A true CN104356744A (en) | 2015-02-18 |
| CN104356744B CN104356744B (en) | 2016-03-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410584674.0A Expired - Fee Related CN104356744B (en) | 2014-10-28 | 2014-10-28 | A kind of glass ultraviolet light polymerization delustring ink |
Country Status (1)
| Country | Link |
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| CN (1) | CN104356744B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632006A (en) * | 2004-11-02 | 2005-06-29 | 东华大学 | Ultraviolet cured printing ink for digital flat ink jet printer and method for making same |
| EP2399966A1 (en) * | 2010-06-24 | 2011-12-28 | Agfa-Gevaert | Flexible, Scratch Resistant Radiation Curable Inkjets Inks |
| CN102367339A (en) * | 2011-07-01 | 2012-03-07 | 深圳市美丽华油墨涂料有限公司 | UV (Ultra Violet) hectograph printing ink used for printing |
| CN102702849A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Ultraviolet-light-cured glass transparent ink and preparation method thereof |
| CN103160169A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | UV glass protection ink |
-
2014
- 2014-10-28 CN CN201410584674.0A patent/CN104356744B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632006A (en) * | 2004-11-02 | 2005-06-29 | 东华大学 | Ultraviolet cured printing ink for digital flat ink jet printer and method for making same |
| EP2399966A1 (en) * | 2010-06-24 | 2011-12-28 | Agfa-Gevaert | Flexible, Scratch Resistant Radiation Curable Inkjets Inks |
| CN102367339A (en) * | 2011-07-01 | 2012-03-07 | 深圳市美丽华油墨涂料有限公司 | UV (Ultra Violet) hectograph printing ink used for printing |
| CN103160169A (en) * | 2011-12-13 | 2013-06-19 | 金甲化工企业(中山)有限公司 | UV glass protection ink |
| CN102702849A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Ultraviolet-light-cured glass transparent ink and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104356744B (en) | 2016-03-09 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Li Zhiwei Inventor before: Xi Xiaoshan Inventor before: Wang Jun Inventor before: Huang Bo |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20170704 Address after: 528000 Guangdong Province, Foshan city Shunde District Daliang Xingui Road No. 9 Austrian Park Vista 5 501 Patentee after: Foshan Norton Chemical Technology Co., Ltd. Address before: 610000 Sichuan city of Chengdu province high tech Zone Shiyang Industrial Park Patentee before: Chengdu Nashuo Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160309 Termination date: 20171028 |