CN104355934A - Secondary element composite fertilizer capable of increasing yield and improving quality and preparation method of secondary element composite fertilizer - Google Patents

Secondary element composite fertilizer capable of increasing yield and improving quality and preparation method of secondary element composite fertilizer Download PDF

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Publication number
CN104355934A
CN104355934A CN201410611723.5A CN201410611723A CN104355934A CN 104355934 A CN104355934 A CN 104355934A CN 201410611723 A CN201410611723 A CN 201410611723A CN 104355934 A CN104355934 A CN 104355934A
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CN
China
Prior art keywords
composite fertilizer
element composite
homogenizing
cao
secondary element
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Pending
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CN201410611723.5A
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Chinese (zh)
Inventor
雷志刚
柏连阳
齐绍武
雷星宇
夏国华
谢前浩
孙宇
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HUNAN XINYU AGRICULTURAL TECHNOLOGY Co Ltd
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HUNAN XINYU AGRICULTURAL TECHNOLOGY Co Ltd
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Priority to CN201410611723.5A priority Critical patent/CN104355934A/en
Publication of CN104355934A publication Critical patent/CN104355934A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80—Soil conditioners
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00—Calcareous fertilisers
    • C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a secondary element composite fertilizer capable of increasing yield and improving quality and a preparation method of the secondary element composite fertilizer. The composite fertilizer comprises silica or wollastonite containing SiO2, limestone or dolomite containing CaO, talcum, sepiolite or the like containing MgO and natural mineral such as gypsum or desulfurization gypsum containing SO3. The preparation method comprises the following steps: dosing; performing raw milling and homogenizing; calcining; cooling; grinding and homogenizing; checking and packaging. Compared with the prior art, local materials can be used according to circumstances, and the composite fertilizer can replenish silicon, calcium and magnesium in soil and especially has a good restoration function on farmland with heavy metal pollution.

Description

A kind of moderate-element composite fertilizer of energy increasing yield and improving quality and manufacture method thereof
Technical field
The present invention relates to a kind of moderate-element composite fertilizer and manufacture method thereof, belong to agrochemical technical field.
Background technology
China is vast in territory, forming process and the chemical composition thereof of soil in all parts of the country vary, along with the change of farming time, cropping system and temperature thereof, humidity, kind, there is significantly change in the chemical composition of its soil, effective constituent, although agricultural sector of China had carried out in recent years survey soil formula etc.-serial technological means, but large owing to putting few face, still can not entirely accurate ground reflect soil truth, thus cause having occurred " macroelement (N, P, K) is loss (cross and execute); Trace element is spraying; Moderate-element is out in the cold " phenomenon; Should be understood that, the existing large quantities of scholar of China is being engaged in the research of moderate-element, particularly the researcher of Henan Province's the earth physics Institute---the father Cai Delong of siliceous fertilizer just introduced siliceous fertilizer manufacturing technology from Japanese system before 20 right years, but China particularly the southern paddy rice liking silicon apply and not yet reach gratifying result.At present, the multiple institution of scientific research in the whole nation and a collection of science researcher, just how to obtain can balance nitrogen, phosphorus, potassium absorption, reduce the loss of potassium in soil, phosphorus of living is for phosphorus and reduce heavy metal in soil to the moderate-element composite fertilizer of pollution of agricultural products as great brainstorm subject.
Summary of the invention
The object of the invention is to: overcome the defect in above-mentioned existing chemical fertilizer application, provide oneplant moderate-element composite fertilizer and the manufacture method thereof of energy increasing yield and improving quality, in order to the phosphorus in activating soil, silicon, the absorption of the nitrogen simultaneously in balanced soil, phosphorus, potassium, supplement moderate-element calcium, magnesium, silicon, particularly suitably promote the pH value of soil, thus alleviate the pollution of heavy metal in soil to agricultural-food.
For solving its technical problem, the present inventor is through concentrating on studies for many years, carry out repeatedly balancing each element proportioning and solvability in composite fertilizer, the experiment of the katalysis of reinforced micro-element, combine the experimental data in Guangdong, Guangxi, Yunnan, Fujian, Hunan, Hubei, Jiangxi simultaneously, and implement more than 100 mu pilot scales in flakes in July, 2014, achieve gratifying pilot-scale experiment through contrast test; Experimentally the data obtained, in conjunction with the reality of the few phosphorus of China's soil potassium deficiency, particularly recent two decades disorderly digs super row causes great heavy metal contamination situation to soil, develop a kind of technical scheme of moderate-element composite fertilizer of energy increasing yield and improving quality, the weight percent of this each raw material of moderate-element composite fertilizer is as follows:
1、 SiO 2 32%～42%；
2、 CaO 30%～40%；
3、 MgO 20%～30%;
4、 SO 32%～4%。
Preferably, described SiO 2content be 34% ~ 40%;
Preferably, the content of described CaO is 32% ~ 38%;
Preferably, the content of described MgO is 22% ~ 28%;
Preferably, described SO 3content be 2.5% ~ 3.5%.
The moderate-element composite fertilizer of this energy increasing yield and improving quality, the source of its material is natural mineral or pure-oxide:
1, SiO 2: be silica or wollastonite;
2, CaO: be Wingdale or rhombspar;
3, MgO: be rhombspar, serpentine, sepiolite or talcum;
4, SO 3: be anhydrite, desulfurated plaster, phosphogypsum or fluorgypsum.
In a word, starting material are selected first to require, as far as possible not containing harmful heavy metal, secondly closely may gather materials on the spot, finally calculate its comprehensive cost.
The moderate-element composite fertilizer of this energy increasing yield and improving quality, its manufacture method comprises the steps:
Step one: batching, by SiO 2: 32% ~ 42%; CaO: 30% ~ 40%; MgO:20% ~ 30% and SO 3: 2.5% ~ 3.5% accurately takes raw mineral materials, and it is joined heat and determines according to kiln type: general by 750Kcal/kg grog ~ 950kcal/kg grog, shaft kiln capping, and rotary kiln removes the limit;
Step 2: prepared by raw material, by step one proportioned material grinding to crossing 4900 hole sizers, its screen over-size is no more than 5%;
Step 3: raw material homogenizing, by step 2 gained raw material pneumatic blending storehouse or many storehouses collocation, machinery fall storehouse make it homogenizing, SiO 2,the Aggregate Feeding Error of CaO, MgO is no more than 1%, SO 3aggregate Feeding Error be no more than 0.5%, join Thermal Error and be no more than 1%;
Step 4: clinker burning, above-mentioned material is calcined 1-8 hour in the stove of 1250 DEG C ~ 1350 DEG C, rotary kiln capping, boiler-turbine CCS removes the limit, and after gained clinker cooling, homogenizing is stand-by;
Step 5: make, is milled to 4900 hole square hole sieve screen over-sizes and is no more than 5% by step 4 gained chamotte powder, pack warehouse-in after the assay was approved through cooling, homogenizing.
In the present invention, the principle of material each composition by weight percent proportioning is as follows:
1, SiO 2content 32% ~ 42%, be preferably 34% ~ 40%; Work as SiO 2content more than 40% time, generate CaSiO 3, cause the solvability of fertilizer to reduce; Work as SiO 2content when being less than 34%, generate C 3s, lumps after causing fertilizer to apply field and solidifies, thus reduces activity and fertilizer efficiency significantly;
2, the content 30% ~ 40% of CaO, is preferably 32% ~ 38%, generates insoluble CaSiO when CaO content is less than 32% 3, cause the solvability of fertilizer to reduce; When CaO content more than 38% time one be possible generate C 3s, and cause luming, solidifying, reduce fertilizer efficiency; One is do not have the aluminum oxide in the f-CaO activating soil of complete reaction, thus the absorption Al causing crop too much 2o 3make agricultural-food seriously defective;
3, the content 20% ~ 30% of MgO, is preferably 22% ~ 28%, when the content of MgO is less than 22% because generating MgSiO 3and have a strong impact on the solvability of fertilizer; When MgO content more than 28% time, likely make batching time CaO, SiO 2ratio reduce, thus make sintering reaction insufficient, thus affect fertilizer efficiency;
4, SO 3content 2% ~ 4%, be preferably 2.5% ~ 3.5%, work as SO 3content when being less than 2.5%, its mineralization reduces, unfavorable good quality and high output low consumption; Work as SO 3content more than 3.5% time, easy to form bulk during sintering, seriously affects the operation factor of equipment, have impact on quality on the contrary and adds cost.
In a word, compared with prior art, the present invention not only starting material can suit measures to local conditions to gather materials on the spot, and to the silicon in supplementary soil, calcium, magnesium elements, phosphorus in activating soil and element silicon, the harmful heavy metals such as the cadmium in passivation soil, arsenic, chromium, mercury, lead have significant effect, and the farmland that particularly heavy metal is polluted possesses good repairing effect.
Embodiment
Below by embodiment, the present invention is further described
Embodiment one:
Will containing SiO 2caO MgO SO 3mineral press 34:36.5:27:2.5 percentage batching, join hot 800kcal/kg grog, cross 4900 hole square hole sieve screen over-sizes through raw mill grinding and be not more than 5%, when sintering 1 after homogenizing is qualified in the rotary kiln of 1300 DEG C, then cool grinding to 4900 hole square hole sieve surplus and be no more than 5% warehouse-in, homogenizing is up to the standards packaging warehouse-in.
Embodiment two:
Will containing SiO 2caO MgO SO 3mineral press 40:33:23.5:3.5 percentage batching, join hot 900kcal/kg grog, 4900 hole square hole sieves are crossed through raw mill grinding, screen over-size is not more than 5%, in the shaft kiln of 1350 DEG C, 7 hours are sintered after homogenizing is qualified, then cool grinding to 4900 hole square hole sieve surplus and be no more than 5% warehouse-in, homogenizing is up to the standards packaging warehouse-in.
Can be verified by above two examples, the present invention not only can utilize common siliceous, calcium, magnesium, sulphur mineral to suit measures to local conditions to produce moderate-element composite fertilizer, and may be used for live phosphorus, silicon of living, heavy metal particularly significantly in passivation soil, guarantees to increase production, increases income, improves quality of agricultural product;
Above embodiment has been described in detail essence of the present invention; but can not limit protection scope of the present invention with this; all do according to the essence of the present invention simple modifications, modification or equivalent transformation, all drop within claims of the present invention.

Claims (2)

1. a moderate-element composite fertilizer for energy increasing yield and improving quality, is characterized in that: the weight percent of this each raw material of moderate-element composite fertilizer is:
SiO 2 ：32%～42%；CaO ：30%～40%；MgO ：20%～30%; SO 3：2%～4%。
2. a manufacture method for the moderate-element composite fertilizer of energy increasing yield and improving quality, is characterized in that: the method comprises the following steps:
Step one: batching, by SiO 2: 32% ~ 42%, CaO: 30% ~ 40%, MgO:20% ~ 30% and SO 3: 2% ~ 4% accurately takes raw mineral materials, and it is joined heat and determines according to kiln type: general by 750Kcal/kg grog ~ 950kcal/kg grog, shaft kiln capping, and rotary kiln removes the limit;
Step 2: prepared by raw material, by step one proportioned material grinding to crossing 4900 hole sizers, its screen over-size is no more than 5%;
Step 3: raw material homogenizing, by step 2 gained raw material pneumatic blending storehouse or many storehouses collocation, machinery fall storehouse make it homogenizing, SiO 2,the Aggregate Feeding Error of CaO, MgO is no more than 1%, SO 3aggregate Feeding Error be no more than 0.5%, join Thermal Error and be no more than 1%;
Step 4: clinker burning, above-mentioned material is calcined 1-8 hour in the stove of 1250 DEG C ~ 1350 DEG C, rotary kiln capping, boiler-turbine CCS removes the limit, and after gained clinker cooling, homogenizing is stand-by;
Step 5: make, is milled to 4900 its screen over-sizes of hole square hole sieve and is no more than 5% by step 4 gained chamotte powder, pack warehouse-in after the assay was approved through cooling, homogenizing.
CN201410611723.5A 2014-11-04 2014-11-04 Secondary element composite fertilizer capable of increasing yield and improving quality and preparation method of secondary element composite fertilizer Pending CN104355934A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861983A (en) * 2015-05-07 2015-08-26 环保桥（湖南）生态环境修复有限公司 Farmland soil conditioner and preparation method thereof
CN105199737A (en) * 2015-10-28 2015-12-30 雷志刚 Soil conditioner used for treating heavy metal pollution
CN106831144A (en) * 2017-02-24 2017-06-13 史丹利农业集团股份有限公司 A kind of industrial crops Special basal fertilizer and preparation method thereof
CN108395287A (en) * 2018-06-06 2018-08-14 大连环球矿产股份有限公司 A kind of silico-calcium magnesium mineral siliceous fertilizer produced using wollastonite（Soil conditioner）And preparation method thereof
CN108586142A (en) * 2018-06-06 2018-09-28 大连环球矿产股份有限公司 It is a kind of to prepare potassium silicon magnesium calcium mineral soil conditioner and preparation method thereof using potassium albite
CN109369221A (en) * 2018-11-15 2019-02-22 北京璞域环保科技有限公司 A method of secondary nutrients are produced using rotary kiln calcining serpentine
CN109486496A (en) * 2018-12-22 2019-03-19 浙江中地净土科技有限公司 A kind of renovation agent and preparation method thereof for thallium metallic pollution soil
CN109504387A (en) * 2018-12-22 2019-03-22 浙江中地净土科技有限公司 A kind of renovation agent and preparation method thereof for beryllium metallic pollution soil
CN109735341A (en) * 2018-12-22 2019-05-10 浙江中地净土科技有限公司 A kind of mineral microencapsulation material and preparation method thereof for soil remediation
CN109943339A (en) * 2019-04-18 2019-06-28 江苏爱佳福如土壤修复有限公司 A kind of soil conditioner of Silicon-rich and the preparation method and application thereof
CN110079332A (en) * 2019-05-09 2019-08-02 上杭鑫昌龙实业有限公司 Soil conditioner and preparation method thereof and application method
CN110194956A (en) * 2019-05-10 2019-09-03 湖南泰谷生态工程有限公司 Organic type cadmium arsenic combined pollution renovation agent and the preparation method and application thereof
CN110257076A (en) * 2019-06-20 2019-09-20 湖南双红农科生态工程有限公司 A kind of cadmium soil conditioner
CN115677407A (en) * 2022-10-26 2023-02-03 湖南省辰河生态农业科技股份有限公司 Rice cadmium-reducing organic fertilizer and preparation method thereof

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CN103058792A (en) * 2011-10-20 2013-04-24 吴建中 Production method of high-activity medium element fertilizer
CN103183364A (en) * 2013-04-28 2013-07-03 雷志刚 Method for producing potassium chloride and co-producing calcium, magnesium, phosphorus and silicon composite fertilizer by potassium feldspar
CN103483062A (en) * 2013-09-05 2014-01-01 华南理工大学 Method for producing secondary element fertilizer from micro silicon powder
CN103483039A (en) * 2013-09-05 2014-01-01 华南理工大学 Method for producing secondary element mineral fertilizer by activating wollastonite
CN103771966A (en) * 2013-12-20 2014-05-07 华南理工大学 Method for producing secondary element fertilizer from silica fume
CN103880504A (en) * 2014-03-07 2014-06-25 佛山市健地农业科技有限公司 Silicon-based compound fertilizer and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103058792A (en) * 2011-10-20 2013-04-24 吴建中 Production method of high-activity medium element fertilizer
CN103183364A (en) * 2013-04-28 2013-07-03 雷志刚 Method for producing potassium chloride and co-producing calcium, magnesium, phosphorus and silicon composite fertilizer by potassium feldspar
CN103483062A (en) * 2013-09-05 2014-01-01 华南理工大学 Method for producing secondary element fertilizer from micro silicon powder
CN103483039A (en) * 2013-09-05 2014-01-01 华南理工大学 Method for producing secondary element mineral fertilizer by activating wollastonite
CN103771966A (en) * 2013-12-20 2014-05-07 华南理工大学 Method for producing secondary element fertilizer from silica fume
CN103880504A (en) * 2014-03-07 2014-06-25 佛山市健地农业科技有限公司 Silicon-based compound fertilizer and preparation method thereof

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861983A (en) * 2015-05-07 2015-08-26 环保桥（湖南）生态环境修复有限公司 Farmland soil conditioner and preparation method thereof
CN105199737A (en) * 2015-10-28 2015-12-30 雷志刚 Soil conditioner used for treating heavy metal pollution
CN106831144A (en) * 2017-02-24 2017-06-13 史丹利农业集团股份有限公司 A kind of industrial crops Special basal fertilizer and preparation method thereof
CN108395287A (en) * 2018-06-06 2018-08-14 大连环球矿产股份有限公司 A kind of silico-calcium magnesium mineral siliceous fertilizer produced using wollastonite（Soil conditioner）And preparation method thereof
CN108586142A (en) * 2018-06-06 2018-09-28 大连环球矿产股份有限公司 It is a kind of to prepare potassium silicon magnesium calcium mineral soil conditioner and preparation method thereof using potassium albite
CN109369221A (en) * 2018-11-15 2019-02-22 北京璞域环保科技有限公司 A method of secondary nutrients are produced using rotary kiln calcining serpentine
CN109369221B (en) * 2018-11-15 2021-04-27 北京璞域环保科技有限公司 Method for producing secondary element fertilizer by calcining serpentine in rotary kiln
CN109735341A (en) * 2018-12-22 2019-05-10 浙江中地净土科技有限公司 A kind of mineral microencapsulation material and preparation method thereof for soil remediation
CN109504387A (en) * 2018-12-22 2019-03-22 浙江中地净土科技有限公司 A kind of renovation agent and preparation method thereof for beryllium metallic pollution soil
CN109486496A (en) * 2018-12-22 2019-03-19 浙江中地净土科技有限公司 A kind of renovation agent and preparation method thereof for thallium metallic pollution soil
CN109943339A (en) * 2019-04-18 2019-06-28 江苏爱佳福如土壤修复有限公司 A kind of soil conditioner of Silicon-rich and the preparation method and application thereof
CN110079332A (en) * 2019-05-09 2019-08-02 上杭鑫昌龙实业有限公司 Soil conditioner and preparation method thereof and application method
CN110194956A (en) * 2019-05-10 2019-09-03 湖南泰谷生态工程有限公司 Organic type cadmium arsenic combined pollution renovation agent and the preparation method and application thereof
CN110257076A (en) * 2019-06-20 2019-09-20 湖南双红农科生态工程有限公司 A kind of cadmium soil conditioner
CN115677407A (en) * 2022-10-26 2023-02-03 湖南省辰河生态农业科技股份有限公司 Rice cadmium-reducing organic fertilizer and preparation method thereof
CN115677407B (en) * 2022-10-26 2024-03-22 湖南省辰河生态农业科技股份有限公司 Cadmium-reducing organic fertilizer for rice and preparation method thereof

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Application publication date: 20150218