CN104342077A - Water-based adhesive used in ocean engineering for electrostatic flocking of stainless steel coated plates - Google Patents
Water-based adhesive used in ocean engineering for electrostatic flocking of stainless steel coated plates Download PDFInfo
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- CN104342077A CN104342077A CN201310350293.1A CN201310350293A CN104342077A CN 104342077 A CN104342077 A CN 104342077A CN 201310350293 A CN201310350293 A CN 201310350293A CN 104342077 A CN104342077 A CN 104342077A
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Abstract
The invention provides a water-based adhesive used in ocean engineering for electrostatic flocking of stainless steel coated plates. The water-based adhesive is characterized by comprising the following components in parts by weight: 140 parts of acrylic modified polyurethane emulsion, 10-27 parts of carbon black, 0.5-1.5 parts of mineral oil, 0.03-0.07 part of isothiazolinone bactericides, 0.3-2.8 parts of sodium alkyl benzene sulfonate, 0.8-4.5 parts of organic bentonite and 10-22 parts of water-based tackifying resin. The adhesive for stainless steel plate flocking is obtained by adding the acrylic modified polyurethane emulsion and carbon black to a mixed reaction kettle, adding the mineral oil, the isothiazolinone bactericides, sodium alkyl benzene sulfonate and organic bentonite while stirring, continuously stirring the components, reducing the stirring speed and adding the water-based tackifying resin. The adhesive has high adhesive strength and good water resistance, flexibility, corrosion resistance and oxidation resistance and has stable properties even if the adhesive is used in the ocean environment for a long term.
Description
Technical field
The present invention relates to a kind of aqueous-based adhesive being applied to metal sheet surface flocking, in particular for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering.
Background technology
The high performance material that flocking steel plate is a kind of continuous enforcement static flocking on starting material coiled material and makes.Flocking steel plate, as a kind of comparatively novel implanted article, has unique excellent performance.Flocking steel plate stainless steel plate makees substrate, any decorative pattern wanted on villous surface can also be planted.Produce this flocking stainless steel plate, have many requirements: first to tackiness agent, adhesive therefor must have remarkable base plate bonding power, and can not peel off as the bonding mode of porous plastics and glass fibre propping material; The second, require that tackiness agent can meet wearing quality and the long-term safety of flocking stainless steel plate; 3rd, flocking stainless steel plate needs to stand the multiple process operations such as rolling forming processing, punch process, screw processing, plasma cutting, seam be folding in the course of processing, and this just requires that tackiness agent can have good snappiness.In addition, for meeting the life-time service of flocking stainless steel plate production and construction, tackiness agent need have certain fungicidal properties and package stability, and meets the environmental requirement of modern society.
Because flocking stainless steel plate is type material, present domestic market does not have professional production for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, in ocean environment, air is rainy, high temperature, high wind stream and concentration of saline fog are high, commercially available Flock Adhesive, on the stainless steel coating plate static flocking being used in oceanographic engineering, solidity to corrosion, erosion wear resistance, humidity resistance, binding strength, water resistance and antioxidant property are not good.
Summary of the invention
The present invention is directed to the problems referred to above, be provided for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, meet shelf-stable, bonding firmly, the over-all properties such as Anti-erosion, anti-oxidant, wet-heat resisting and processing characteristics be good.
According to technical scheme provided by the invention, for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, feature is: comprise following component, its component ratio by mass number meter:
Acrylic acid modified polyurethane emulsion 140 parts, carbon black 10 ~ 27 parts, 0.5 ~ 1.5 part, mineral oil, isothiazolinone biocide agent 0.03 ~ 0.07 part, alkyl benzene sulphonate (ABS) sodium salt 0.3 ~ 2.8 part, organobentonite 0.8 ~ 4.5 part, water-based solvent misture 10 ~ 22 parts.
First 200 ~ 300 parts of adipic acid type polyester diol (molecular weight is 1800 ~ 2000), 60 ~ 70 parts of isophorone diisocyanates and 0.05 ~ 0.2 part of dibutyl tin dilaurate are added in pyroreaction tank, mix and blend is also heated to 80 ~ 100 DEG C, react 1.8 ~ 2.2 hours, stirring velocity is 1200 ~ 2000 revs/min, makes polyester polyols alcohol mixture.
Polyester polyols alcohol mixture is added in cooling retort, be cooled to 68 ~ 80 DEG C, add 8 ~ 10 parts of dimethylol propionic acids and 7 ~ 10 parts of N-Methyl pyrrolidone, react 3.8 ~ 4.5 hours under temperature 70 ~ 90 DEG C, stirring velocity are the condition of 1200 ~ 2000 revs/min; Be cooled to 35 ~ 45 DEG C, add 6 ~ 8 parts of triethylamines, low whipping speed is react 20 ~ 40 minutes under the condition of 1200 ~ 2000 revs/min; Add 500 ~ 600 parts of deionized waters again, low whipping speed is high speed dispersion emulsification 0.8 ~ 1.2 hour under the condition of 3000 ~ 4000 revs/min; Finally add 6 ~ 9 parts of isophorone diamines, low whipping speed is react 50 ~ 90 minutes under the condition of 1200 ~ 2000 revs/min, obtains base polyurethane prepolymer for use as.
40 ~ 60 parts of methyl methacrylates and 500 ~ 600 parts of base polyurethane prepolymer for use as are joined in high-speed stirring still, dispersed with stirring 0.8 ~ 1 hour under the condition of temperature 68 ~ 80 DEG C, stirring velocity is 4000 ~ 4600 revs/min, then in 1.6 ~ 2 hours, 0.4 ~ 0.6 part of Diisopropyl azodicarboxylate is dripped, stir while dripping, stirring velocity is 4000 ~ 4800 revs/min, be warming up to 80 ~ 90 DEG C after being added dropwise to complete to continue to react 2.5 ~ 3.5 hours under the condition stirred, stirring velocity is 4000 ~ 5000 revs/min, discharging when temperature is down to 45 ~ 60 DEG C, namely described acrylic acid modified polyurethane emulsion is obtained.
140 parts of acrylic acid modified polyurethane emulsions and 10 ~ 27 parts of carbon blacks are added in hybrid reactor, stirring velocity is 2000 ~ 2500 revs/min, stir after 20 ~ 40 minutes, 0.5 ~ 1.5 part of mineral oil is added while stirring, 0.03 ~ 0.07 part of isothiazolinone biocide agent, 0.3 ~ 2.8 part of alkyl benzene sulphonate (ABS) sodium salt and 0.8 ~ 4.5 part of organobentonite, continue stirring 15 ~ 30 minutes, stirring velocity is 900 ~ 1200 revs/min, reduce stirring velocity to 300 ~ 600 rev/min, and add 10 ~ 22 parts of water-based solvent misture, utilize water-based solvent misture as viscosity increaser, stir 10 ~ 30 minutes, namely the described stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering is obtained.
Stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering of the present invention, have the shelf lives long, the normal temperature sealed storage phase is more than 1 year; Cohesive strength is high, stainless steel coating plate and fine hair is all had to the cohesive force of high strength; Water resistance is good, rainy at air stable with long-term use properties in the ocean environment of high wind stream; Snappiness is moderate, while guarantee flocking stainless steel coating plate Joint strength, can meet various processing request again; Solidity to corrosion is good, stainless steel coating plate can be protected not to be corroded, can ensure lasting cohesive strength and antioxidant property again in the ocean environment that concentration of saline fog is high in long-term use.
Embodiment:
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment one: for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, its preparation process is as follows, its component ratio by mass number meter:
(1) polyester polyols alcohol mixture is prepared: add in pyroreaction tank by 200 parts of adipic acid type polyester diol (molecular weight is 1800 ~ 2000), 60 parts of isophorone diisocyanates and 0.05 ~ 0.2 part of dibutyl tin dilaurate, mix and blend is also heated to 80 DEG C, react 1.8 hours, stirring velocity is 1200 revs/min, makes polyester polyols alcohol mixture.
(2) base polyurethane prepolymer for use as is prepared: added by above-mentioned polyester polyols alcohol mixture in cooling retort, be cooled to 68 DEG C, add 8 parts of dimethylol propionic acids and 7 parts of N-Methyl pyrrolidone, react 3.8 hours under temperature 70 C, stirring velocity are the condition of 1200 revs/min; Be cooled to 35 DEG C, add 6 parts of triethylamines, low whipping speed is react 20 minutes under the condition of 1200 revs/min; Add 500 parts of deionized waters again, low whipping speed is high speed dispersion emulsification 0.8 hour under the condition of 3000 revs/min; Finally add 6 parts of isophorone diamines, low whipping speed is react 50 minutes under the condition of 1200 revs/min, obtains base polyurethane prepolymer for use as.
(3) acrylic acid synthesizing modified polyurethane emulsion: 40 parts of methyl methacrylates and 500 parts of base polyurethane prepolymer for use as are joined in high-speed stirring still, dispersed with stirring 0.8 hour under the condition of temperature 68 DEG C, stirring velocity is 4000 revs/min, then in 1.6 hours, 0.4 part of Diisopropyl azodicarboxylate is dripped, stir while dripping, stirring velocity is 4000 revs/min, be warming up to 80 DEG C after being added dropwise to complete to continue to react 2.5 hours under the condition stirred, stirring velocity is 4000 revs/min, discharging when temperature is down to 45 DEG C, namely described acrylic acid modified polyurethane emulsion is obtained.
(4) preparation of stainless steel plate flocking aqueous-based adhesive: 140 parts of acrylic acid modified polyurethane emulsions and 10 parts of carbon blacks are added in hybrid reactor, stirring velocity is 2000 revs/min, add carbon black, to improve the optics of tackiness agent, physicals, increase the hardness of tackiness agent, and reach the effect hiding substrate, stir after 20 minutes, 0.5 part of mineral oil is added while stirring, 0.03 part of isothiazolinone biocide agent, 0.3 part of alkyl benzene sulphonate (ABS) sodium salt and 0.8 part of organobentonite, add mineral oil and eliminate the bubble that may exist in tackiness agent, prevent the blank spot occurring non-gluing in coating procedure, add isothiazolinone biocide agent, prevent tackiness agent and flocking stainless steel plate from occurring going mouldy in placement or use procedure, add alkyl benzene sulphonate (ABS) sodium salt, to promote tackiness agent sprawling on stainless steel plate surface, improve the coating homogeneity of tackiness agent on stainless steel plate surface, add organobentonite, in order to improve system viscosity, system is made to keep uniform and stable suspended state or milkiness state, or formation gel, there is thickening, suspend, emulsification, stablize and wait several functions, continue stirring 15 minutes, stirring velocity is 900 revs/min, reduce stirring velocity to 300 rev/min, and add 10 parts of water-based solvent misture, utilize water-based solvent misture as viscosity increaser, not only can be adjusted to suitable viscosity but also can be well compatible with emulsion, stir 10 minutes, namely the described stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering is obtained.
With 0.25mm stainless steel plate for substrate, length 2.5mm polypropylene fibre as fine hair, tackiness agent coated weight 25g/m
2.
As shown in table 1 to embodiment one preparation-obtained tackiness agent flocking performance evaluation project, test conditions and result.
The flocking performance evaluation project of table 1 tackiness agent, test conditions and result
Embodiment two: for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, its preparation process is as follows, its component ratio by mass number meter:
(1) polyester polyols alcohol mixture is prepared: add in pyroreaction tank 1 by 300 parts of adipic acid type polyester diol (molecular weight is 1800 ~ 2000), 70 parts of isophorone diisocyanates and 0.2 part of dibutyl tin dilaurate, mix and blend is also heated to 100 DEG C, react 2.2 hours, stirring velocity is 2000 revs/min, makes polyester polyols alcohol mixture.
(2) base polyurethane prepolymer for use as is prepared: added by above-mentioned polyester polyols alcohol mixture in cooling retort 2, be cooled to 80 DEG C, add 10 parts of dimethylol propionic acids and 10 parts of N-Methyl pyrrolidone, react 4.5 hours under temperature 90 DEG C, stirring velocity are the condition of 2000 revs/min; Be cooled to 45 DEG C, add 8 parts of triethylamines, low whipping speed is react 40 minutes under the condition of 2000 revs/min; Add 600 parts of deionized waters again, low whipping speed is high speed dispersion emulsification 1.2 hours under the condition of 4000 revs/min; Finally add 9 parts of isophorone diamines, low whipping speed is react 90 minutes under the condition of 2000 revs/min, obtains base polyurethane prepolymer for use as.
(3) acrylic acid synthesizing modified polyurethane emulsion: 60 parts of methyl methacrylates and 600 parts of base polyurethane prepolymer for use as are joined in high-speed stirring still, dispersed with stirring 1 hour under the condition of temperature 80 DEG C, stirring velocity is 4600 revs/min, then in 2 hours, 0.6 part of Diisopropyl azodicarboxylate is dripped, stir while dripping, stirring velocity is 4800 revs/min, be warming up to 90 DEG C after being added dropwise to complete to continue to react 3.5 hours under the condition stirred, stirring velocity is 5000 revs/min, discharging when temperature is down to 60 DEG C, namely described acrylic acid modified polyurethane emulsion is obtained.
(4) preparation of stainless steel plate flocking aqueous-based adhesive: 140 parts of acrylic acid modified polyurethane emulsions and 27 parts of carbon blacks are added in hybrid reactor, stirring velocity is 2500 revs/min, add carbon black, to improve the optics of tackiness agent, physicals, increase the hardness of tackiness agent, and reach the effect hiding substrate, stir after 40 minutes, 1.5 parts of mineral oil are added while stirring, 0.07 part of isothiazolinone biocide agent, 2.8 parts of alkyl benzene sulphonate (ABS) sodium salts and 4.5 parts of organobentonites, add mineral oil and eliminate the bubble that may exist in tackiness agent, prevent the blank spot occurring non-gluing in coating procedure, add isothiazolinone biocide agent, prevent tackiness agent and flocking stainless steel plate from occurring going mouldy in placement or use procedure, add alkyl benzene sulphonate (ABS) sodium salt, to promote tackiness agent sprawling on stainless steel plate surface, improve the coating homogeneity of tackiness agent on stainless steel plate surface, add organobentonite, in order to improve system viscosity, system is made to keep uniform and stable suspended state or milkiness state, or formation gel, there is thickening, suspend, emulsification, stablize and wait several functions, continue stirring 30 minutes, stirring velocity is 1200 revs/min, reduce stirring velocity to 600 rev/min, and add 22 parts of water-based solvent misture, utilize water-based solvent misture as viscosity increaser, not only can be adjusted to suitable viscosity but also can be well compatible with emulsion, stir 30 minutes, namely the described stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering is obtained.
Embodiment three: for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, comprise the following steps, its component ratio by mass number meter:
(1) polyester polyols alcohol mixture is prepared: add in pyroreaction tank by 250 parts of adipic acid type polyester diol (molecular weight is 1800 ~ 2000), 65 parts of isophorone diisocyanates and 0.1 part of dibutyl tin dilaurate, mix and blend is also heated to 90 DEG C, react 2.0 hours, stirring velocity is 1500 revs/min, makes polyester polyols alcohol mixture.
(2) base polyurethane prepolymer for use as is prepared: added by above-mentioned polyester polyols alcohol mixture in cooling retort, be cooled to 75 DEG C, add 9 parts of dimethylol propionic acids and 8 parts of N-Methyl pyrrolidone, react 4.2 hours under temperature 80 DEG C, stirring velocity are the condition of 1500 revs/min; Be cooled to 40 DEG C, add 7 parts of triethylamines, low whipping speed is react 30 minutes under the condition of 1500 revs/min; Add 550 parts of deionized waters again, low whipping speed is high speed dispersion emulsification 1.0 hours under the condition of 3500 revs/min; Finally add 8 parts of isophorone diamines, low whipping speed is react 60 minutes under the condition of 1500 revs/min, obtains base polyurethane prepolymer for use as.
(3) acrylic acid synthesizing modified polyurethane emulsion: 50 parts of methyl methacrylates and 550 parts of base polyurethane prepolymer for use as are joined in high-speed stirring still, dispersed with stirring 0.9 hour under the condition of temperature 70 C, stirring velocity is 4300 revs/min, then in 1.8 hours, 0.5 part of Diisopropyl azodicarboxylate is dripped, stir while dripping, stirring velocity is 440 revs/min, be warming up to 85 DEG C after being added dropwise to complete to continue to react 3.0 hours under the condition stirred, stirring velocity is 4500 revs/min, discharging when temperature is down to 50 DEG C, namely described acrylic acid modified polyurethane emulsion is obtained.
(4) preparation of stainless steel plate flocking aqueous-based adhesive: 140 parts of acrylic acid modified polyurethane emulsions and 19 parts of carbon blacks are added in hybrid reactor, stirring velocity is 2250 revs/min, add carbon black, to improve the optics of tackiness agent, physicals, increase the hardness of tackiness agent, and reach the effect hiding substrate, stir after 30 minutes, 1 part of mineral oil is added while stirring, 0.05 part of isothiazolinone biocide agent, 1.5 parts of alkyl benzene sulphonate (ABS) sodium salts and 2.2 parts of organobentonites, add mineral oil and eliminate the bubble that may exist in tackiness agent, prevent the blank spot occurring non-gluing in coating procedure, add isothiazolinone biocide agent, prevent tackiness agent and flocking stainless steel plate from occurring going mouldy in placement or use procedure, add alkyl benzene sulphonate (ABS) sodium salt, to promote tackiness agent sprawling on stainless steel plate surface, improve the coating homogeneity of tackiness agent on stainless steel plate surface, add organobentonite, in order to improve system viscosity, system is made to keep uniform and stable suspended state or milkiness state, or formation gel, there is thickening, suspend, emulsification, stablize and wait several functions, continue stirring 20 minutes, stirring velocity is 1000 revs/min, reduce stirring velocity to 500 rev/min, and add 16 parts of water-based solvent misture, utilize water-based solvent misture as viscosity increaser, not only can be adjusted to suitable viscosity but also can be well compatible with emulsion, stir 20 minutes, namely the described stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering is obtained.
As can be seen here, the stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering of the present invention, have the shelf lives long, the normal temperature sealed storage phase is more than 1 year; Cohesive strength is high, stainless steel coating plate and fine hair is all had to the cohesive force of high strength; Water resistance is good, rainy at air stable with long-term use properties in the ocean environment of high wind stream; Snappiness is moderate, while guarantee flocking stainless steel coating plate Joint strength, can meet various processing request again; Solidity to corrosion is good, stainless steel coating plate can be protected not to be corroded, can ensure lasting cohesive strength and antioxidant property again in the ocean environment that concentration of saline fog is high in long-term use.
Claims (1)
1. for the stainless steel coating plate static flocking aqueous-based adhesive of oceanographic engineering, feature is: comprise following component, its component ratio by mass number meter:
Acrylic acid modified polyurethane emulsion 140 parts, carbon black 10 ~ 27 parts, 0.5 ~ 1.5 part, mineral oil, isothiazolinone biocide agent 0.03 ~ 0.07 part, alkyl benzene sulphonate (ABS) sodium salt 0.3 ~ 2.8 part, organobentonite 0.8 ~ 4.5 part, water-based solvent misture 10 ~ 22 parts.
First 200 ~ 300 parts of adipic acid type polyester diol (molecular weight is 1800 ~ 2000), 60 ~ 70 parts of isophorone diisocyanates and 0.05 ~ 0.2 part of dibutyl tin dilaurate are added in pyroreaction tank, mix and blend is also heated to 80 ~ 100 DEG C, react 1.8 ~ 2.2 hours, stirring velocity is 1200 ~ 2000 revs/min, makes polyester polyols alcohol mixture.
Polyester polyols alcohol mixture is added in cooling retort, be cooled to 68 ~ 80 DEG C, add 8 ~ 10 parts of dimethylol propionic acids and 7 ~ 10 parts of N-Methyl pyrrolidone, react 3.8 ~ 4.5 hours under temperature 70 ~ 90 DEG C, stirring velocity are the condition of 1200 ~ 2000 revs/min; Be cooled to 35 ~ 45 DEG C, add 6 ~ 8 parts of triethylamines, low whipping speed is react 20 ~ 40 minutes under the condition of 1200 ~ 2000 revs/min; Add 500 ~ 600 parts of deionized waters again, low whipping speed is high speed dispersion emulsification 0.8 ~ 1.2 hour under the condition of 3000 ~ 4000 revs/min; Finally add 6 ~ 9 parts of isophorone diamines, low whipping speed is react 50 ~ 90 minutes under the condition of 1200 ~ 2000 revs/min, obtains base polyurethane prepolymer for use as.
40 ~ 60 parts of methyl methacrylates and 500 ~ 600 parts of base polyurethane prepolymer for use as are joined in high-speed stirring still, dispersed with stirring 0.8 ~ 1 hour under the condition of temperature 68 ~ 80 DEG C, stirring velocity is 4000 ~ 4600 revs/min, then in 1.6 ~ 2 hours, 0.4 ~ 0.6 part of Diisopropyl azodicarboxylate is dripped, stir while dripping, stirring velocity is 4000 ~ 4800 revs/min, be warming up to 80 ~ 90 DEG C after being added dropwise to complete to continue to react 2.5 ~ 3.5 hours under the condition stirred, stirring velocity is 4000 ~ 5000 revs/min, discharging when temperature is down to 45 ~ 60 DEG C, namely described acrylic acid modified polyurethane emulsion is obtained.
140 parts of acrylic acid modified polyurethane emulsions and 10 ~ 27 parts of carbon blacks are added in hybrid reactor, stirring velocity is 2000 ~ 2500 revs/min, stir after 20 ~ 40 minutes, 0.5 ~ 1.5 part of mineral oil is added while stirring, 0.03 ~ 0.07 part of isothiazolinone biocide agent, 0.3 ~ 2.8 part of alkyl benzene sulphonate (ABS) sodium salt and 0.8 ~ 4.5 part of organobentonite, continue stirring 15 ~ 30 minutes, stirring velocity is 900 ~ 1200 revs/min, reduce stirring velocity to 300 ~ 600 rev/min, and add 10 ~ 22 parts of water-based solvent misture, utilize water-based solvent misture as viscosity increaser, stir 10 ~ 30 minutes, namely the described stainless steel coating plate static flocking aqueous-based adhesive for oceanographic engineering is obtained.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310350293.1A CN104342077A (en) | 2013-08-07 | 2013-08-07 | Water-based adhesive used in ocean engineering for electrostatic flocking of stainless steel coated plates |
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| CN201310350293.1A CN104342077A (en) | 2013-08-07 | 2013-08-07 | Water-based adhesive used in ocean engineering for electrostatic flocking of stainless steel coated plates |
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| CN104342077A true CN104342077A (en) | 2015-02-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
-
2013
- 2013-08-07 CN CN201310350293.1A patent/CN104342077A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105602494A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Organosilicone modified waterborne acrylate electrostatic flocking formaldehyde-free adhesive and preparation method thereof |
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Application publication date: 20150211 |