CN104313911A - Anti-oxidation penetrating agent for leather and preparation method of anti-oxidation penetrating agent - Google Patents
Anti-oxidation penetrating agent for leather and preparation method of anti-oxidation penetrating agent Download PDFInfo
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- CN104313911A CN104313911A CN201410575540.2A CN201410575540A CN104313911A CN 104313911 A CN104313911 A CN 104313911A CN 201410575540 A CN201410575540 A CN 201410575540A CN 104313911 A CN104313911 A CN 104313911A
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Abstract
The invention discloses an anti-oxidation penetrating agent for leather and a preparation method of the anti-oxidation penetrating agent. The anti-oxidation penetrating agent for leather is prepared from the following raw materials in parts by weight: 42-45 parts of oleic acid polyoxyethylene ester, 6-8 parts of dodecanoyl monoethanolamine sulphate sodium salt, 2-4 parts of polyglycerol fatty acid ester, 4-5 parts of zinc acetate, 8-10 parts of dicumyl peroxide, 3-4 parts of disodium hydrogen phosphate, 6-8 parts of sodium potassium tartrate tetrahydrate, 1-3 parts of ascorbic acid, 2-4 parts of ethyl orthosilicate, 3-5 parts of dioctyl sebacate, 8-10 parts of modified moss and 45-50 parts of water. The anti-oxidation penetrating agent for leather is economical, practical and low in cost, can be used for effectively preventing the leather from being damaged, is high in oxidation resistance and long in service cycle, does no damage to the leather and also has good frictional characteristic and wear resistance; meanwhile, by virtue of the modified moss, the overall performance of the penetrating agent can be effectively improved, the level dyeing property is excellent, and the penetration performance of leather dye can be obviously improved.
Description
Technical field
The present invention relates to textile printing and dyeing technology, be specifically related to a kind of non-oxidizability leather bleeding agent and preparation method thereof.
Background technology
Bleeding agent, belongs to non-ionic surface active agent, can do textile dyeing bath and arrange the penetrant of bathing, playing osmosis, be also have fixing hydrophilic and oleophilic group, align, and can make the material that surface tension significantly declines in the surface energy of solution; But because existing bleeding agent can only tolerate the temperature of 150 DEG C, be only 80g/L containing NaOH concentration in tolerant dye liquor when dyeing and finishing, this non-refractory, also not alkaline-resisting characteristic, easily makes dyeing liquor layering, affects Color in dyeing course.
Summary of the invention
The object of the present invention is to provide a kind of non-oxidizability leather bleeding agent and preparation method thereof.
The present invention adopts following technical scheme to achieve these goals:
Non-oxidizability leather bleeding agent, the weight portion of its constitutive material is: polyoxyethylene oleic acid ester 42-45, lauric monoethanolamide sodium sulphate 6-8, polyglyceryl fatty acid ester 2-4, zinc acetate 4-5, cumyl peroxide 8-10, sodium hydrogen phosphate 3-4, sodium potassium tartrate tetrahydrate 6-8, ascorbic acid 1-3, ethyl orthosilicate 2-4, di-n-octyl sebacate 3-5, modification moss 8-10 and water 45-50.
Non-oxidizability leather bleeding agent, the weight portion of its constitutive material is: polyoxyethylene oleic acid ester 45, lauric monoethanolamide sodium sulphate 7, polyglyceryl fatty acid ester 3, zinc acetate 4.5, cumyl peroxide 9, sodium hydrogen phosphate 3.5, sodium potassium tartrate tetrahydrate 7, ascorbic acid 2, ethyl orthosilicate 3, di-n-octyl sebacate 4, modification moss 9 and water 48.
The preparation method of non-oxidizability leather bleeding agent, comprises the following steps:
(1) preparation of modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate again, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven;
(2) the modification moss of step (1) is ground, then add in the mixed solution of sodium potassium tartrate tetrahydrate and ascorbic acid, soak 2-4 days, for subsequent use;
(3) each raw material is taken by the weight portion of constitutive material, polyoxyethylene oleic acid ester, lauric monoethanolamide sodium sulphate and polyglyceryl fatty acid ester is added in water, be heated to 85-90 DEG C, then standby material and other residue constitutive materials of step (2) is added wherein, be uniformly mixed 20-30 minute, regulate Ph to 5-8 after cooling, to obtain final product.
Beneficial effect of the present invention:
Bleeding agent of the present invention is economical and practical, cost is low, and can effectively prevent leather impaired, oxidation resistance be high, and life cycle is long, and to leather without any damage, has good frictional behavior, abrasion performance simultaneously; And modification moss of the present invention effectively can improve the combination property of bleeding agent, levelling excellent performance, obviously can increase the permeance property of leather dye.
Detailed description of the invention
Embodiment 1: non-oxidizability leather bleeding agent, the weight portion (kg) of its constitutive material is: polyoxyethylene oleic acid ester 45, lauric monoethanolamide sodium sulphate 7, polyglyceryl fatty acid ester 3, zinc acetate 4.5, cumyl peroxide 9, sodium hydrogen phosphate 3.5, sodium potassium tartrate tetrahydrate 7, ascorbic acid 2, ethyl orthosilicate 3, di-n-octyl sebacate 4, modification moss 9 and water 48.
The preparation method of non-oxidizability leather bleeding agent, comprises the following steps:
(1) preparation of modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 5% acrylic acid, 2.5% ammonium persulfate again, stir 3-4h at 85 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2 times amount, after mixing, be placed on 105 DEG C of oven dry 35min in baking oven;
(2) the modification moss of step (1) is ground, then add in the mixed solution of sodium potassium tartrate tetrahydrate and ascorbic acid, soak 3 days, for subsequent use;
(3) each raw material is taken by the weight portion of constitutive material, polyoxyethylene oleic acid ester, lauric monoethanolamide sodium sulphate and polyglyceryl fatty acid ester is added in water, be heated to 85 DEG C, then standby material and other residue constitutive materials of step (2) is added wherein, be uniformly mixed 25 minutes, regulate Ph to 5-8 after cooling, to obtain final product.
Bleeding agent pH value of the present invention is 7.5, cloud point is 41.3 DEG C, water-soluble and the organic solvent of energy, sedimentation time is 49s, and permeability is extremely strong, bleeding agent of the present invention mixes formation dye liquor, in whole dyeing course with water, KOH, dyestuff etc., obvious lamination is there is not, the fabric uniform in color dyed in dye vat.
Claims (3)
1. a non-oxidizability leather bleeding agent, is characterized in that the weight portion of its constitutive material is: polyoxyethylene oleic acid ester 42-45, lauric monoethanolamide sodium sulphate 6-8, polyglyceryl fatty acid ester 2-4, zinc acetate 4-5, cumyl peroxide 8-10, sodium hydrogen phosphate 3-4, sodium potassium tartrate tetrahydrate 6-8, ascorbic acid 1-3, ethyl orthosilicate 2-4, di-n-octyl sebacate 3-5, modification moss 8-10 and water 45-50.
2. non-oxidizability leather bleeding agent according to claim 1, is characterized in that the weight portion of its constitutive material is: polyoxyethylene oleic acid ester 45, lauric monoethanolamide sodium sulphate 7, polyglyceryl fatty acid ester 3, zinc acetate 4.5, cumyl peroxide 9, sodium hydrogen phosphate 3.5, sodium potassium tartrate tetrahydrate 7, ascorbic acid 2, ethyl orthosilicate 3, di-n-octyl sebacate 4, modification moss 9 and water 48.
3. a preparation method for non-oxidizability leather bleeding agent as claimed in claim 1, is characterized in that comprising the following steps:
(1) preparation of modification moss: moss is shone dry grinding, then the hydrochloric acid solution that mass fraction is 10% is put into, 2-3h is left standstill after stirring, cross leaching filter residue, repeatedly rinse several times with deionized water, put in the aqueous solution containing 4-6% acrylic acid, 2-3% ammonium persulfate again, stir 3-4h at 80-90 DEG C of constant temperature; Cross leaching filter residue, then mix with the paraffin wax emulsions of 2-3 times amount, after mixing, be placed on 100-110 DEG C of oven dry 30-40min in baking oven;
(2) the modification moss of step (1) is ground, then add in the mixed solution of sodium potassium tartrate tetrahydrate and ascorbic acid, soak 2-4 days, for subsequent use;
(3) each raw material is taken by the weight portion of constitutive material, polyoxyethylene oleic acid ester, lauric monoethanolamide sodium sulphate and polyglyceryl fatty acid ester is added in water, be heated to 85-90 DEG C, then standby material and other residue constitutive materials of step (2) is added wherein, be uniformly mixed 20-30 minute, regulate Ph to 5-8 after cooling, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575540.2A CN104313911A (en) | 2014-10-25 | 2014-10-25 | Anti-oxidation penetrating agent for leather and preparation method of anti-oxidation penetrating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410575540.2A CN104313911A (en) | 2014-10-25 | 2014-10-25 | Anti-oxidation penetrating agent for leather and preparation method of anti-oxidation penetrating agent |
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| CN104313911A true CN104313911A (en) | 2015-01-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410575540.2A Pending CN104313911A (en) | 2014-10-25 | 2014-10-25 | Anti-oxidation penetrating agent for leather and preparation method of anti-oxidation penetrating agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108774905A (en) * | 2018-05-09 | 2018-11-09 | 嘉兴学院 | From thickening environmental-friendly leather bleeding agent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007308615A (en) * | 2006-05-19 | 2007-11-29 | Dow Corning Toray Co Ltd | Polyethers, manufacturing method thereof, nonionic surfactant, emulsifier, and silicone-oil emulsion composition |
| CN101831815A (en) * | 2009-03-13 | 2010-09-15 | 上海喜若飞精细化工有限公司 | Leather dye uniformly dyeing penetrating agent and preparation method thereof |
| JP2011106038A (en) * | 2009-11-13 | 2011-06-02 | Meisei Kagaku Kogyo Kk | Penetrating agent for water-repelling and oil-repelling processing for polyolefin-based fiber product |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
-
2014
- 2014-10-25 CN CN201410575540.2A patent/CN104313911A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007308615A (en) * | 2006-05-19 | 2007-11-29 | Dow Corning Toray Co Ltd | Polyethers, manufacturing method thereof, nonionic surfactant, emulsifier, and silicone-oil emulsion composition |
| CN101831815A (en) * | 2009-03-13 | 2010-09-15 | 上海喜若飞精细化工有限公司 | Leather dye uniformly dyeing penetrating agent and preparation method thereof |
| JP2011106038A (en) * | 2009-11-13 | 2011-06-02 | Meisei Kagaku Kogyo Kk | Penetrating agent for water-repelling and oil-repelling processing for polyolefin-based fiber product |
| CN103334321A (en) * | 2013-06-24 | 2013-10-02 | 张家港市东方特种染色有限公司 | Cone yarn printing and dyeing penetrating agent and preparation method thereof |
| CN103938438A (en) * | 2013-12-23 | 2014-07-23 | 苏州芳然纺织有限公司 | Osmotic agent used for fabric and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108774905A (en) * | 2018-05-09 | 2018-11-09 | 嘉兴学院 | From thickening environmental-friendly leather bleeding agent and preparation method thereof |
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Application publication date: 20150128 |
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