CN104313561A - Surface treatment phosphatizing agent for building sectional material - Google Patents
Surface treatment phosphatizing agent for building sectional material Download PDFInfo
- Publication number
- CN104313561A CN104313561A CN201410590597.XA CN201410590597A CN104313561A CN 104313561 A CN104313561 A CN 104313561A CN 201410590597 A CN201410590597 A CN 201410590597A CN 104313561 A CN104313561 A CN 104313561A
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- Prior art keywords
- parts
- phosphorization
- surface treatment
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
- C23C22/37—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also hexavalent chromium compounds
- C23C22/38—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also hexavalent chromium compounds containing also phosphates
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
- C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium
Abstract
The invention discloses a surface treatment phosphatizing agent for a building sectional material. The surface treatment phosphatizing agent is prepared from the following raw materials in parts by weight: 10-12 parts of calcium phosphate, 15-18 parts of manganous nitrate, 4-6 parts of phytic acid, 8-10 parts of sodium fluoborate, 2-5 parts of n-butyl acetate, 2.8-3.5 parts of benzoic acid, 1.2-1.8 parts of an active monomer, 0.8-1.2 parts of nickel nitrate, 0.5-0.8 part of barium nitrite, 1.2-2.5 parts of tartaric acid, 0.4-0.8 part of triethanolamine, 1.4-2.5 parts of chromium sulfate, 2.5-3.5 parts of an initiator, 0.5-1.2 parts of a surfactant and 45-50 parts of industrial water. The manganese and calcium serial environment-friendly phosphating solution which can be used at constant temperature, free from surface adjustment step before phosphorization and washing step after phosphorization, simple and convenient to operate, long in service life, excellent in effect and strong in adhesive force can be used for overcoming the problems that conventional phosphorization is complex in process, relatively high in phosphorization temperature, great in consumption of water and phosphate and the like, much in harmful wastewater and the like.
Description
Technical field
The present invention relates to a kind of technical field of Phosphating Solution, particularly relate to a kind of architectural shape surface treatment phosphorization agent.
Background technology
Iron and steel parts all will do antirust treatment, common way is sprayed paint, and in order to increase the bond strength of coating and steel plate before spraying paint, the bonderizing before all will spraying paint to iron and steel parts, make iron and steel parts outside form a kind of similar honeycomb-like tissue, increase cohesive strength.But it is many to there is the residue produced in muddiness, parkerizing process in existing Phosphating Solution, and incidental expenses area is little, and needs temperature high, the shortcomings such as lost labor.
At present, the existing method processed metallic surface, not only complex procedures, labour intensity large (especially processing the hardware got rusty), efficiency are low, and contaminate environment.Particularly after rust cleaning, hardware is faced with again the problem of getting rusty, and needs to carry out antirust treatment or rotproofing again.
Summary of the invention
The object of this invention is to provide a kind of architectural shape surface treatment phosphorization agent, provide a kind ofly to use at normal temperatures, before phosphatization without after surface adjustment operation, phosphatization without washing step, the problem such as easy and simple to handle, the life-span long and effect is good, the manganese calcium system environment-friendly phosphating solution of strong adhesion, and, water higher with the complex process, the phosphatization temperature that overcome conventional phosphatizing and phosphoric acid salt etc. consume greatly, harmful waste water is many.
The technical solution used in the present invention is as follows:
A kind of architectural shape surface treatment phosphorization agent, by weight, be made up of following raw material: 10-12 part calcium phosphate, 15-18 part manganous nitrate, 4-6 part phytic acid, 8-10 part Sodium tetrafluoroborate, 2-5 N-BUTYL ACETATE, 2.8-3.5 phenylformic acid, 1.2-1.8 parts of reactive monomers, 0.8-1.2 part nickelous nitrate, 0.5-0.8 part barium nitrite, 1.2-2.5 part tartrate, 0.4-0.8 part trolamine, 1.4-2.5 part chromium sulphate, 2.5-3.5 initiator, 0.5-1.2 part tensio-active agent, 45-50 part service water; Its concrete preparation method is as follows: above-mentioned raw materials component mixed, stir and be heated to 90-120 DEG C, insulation 2-2.5 hour, be chilled to 30-60 DEG C, insulation 1-2 hour, reheats to 100-120 DEG C, insulation 1-2 hour, is cooled to normal temperature with 20-30 DEG C/h, i.e. obtained finished product phosphorization agent.
Above-mentioned raw materials component is mixed, stirs and be heated to 110 DEG C, be incubated 2.2 hours, be chilled to 45 DEG C, be incubated 1.5 hours, reheat to 110 DEG C, be incubated 1.5 hours, be cooled to normal temperature with 25 DEG C/h, be i.e. obtained finished product phosphorization agent.
The present invention fills a prescription simple and practical, metal works is invaded Phosphating Solution, can use at normal temperatures, before phosphatization without after surface adjustment operation, phosphatization without washing step, the problem such as easy and simple to handle, the life-span long and effect is good, the manganese calcium system environment-friendly phosphating solution of strong adhesion, and, water higher with the complex process, the phosphatization temperature that overcome conventional phosphatizing and phosphoric acid salt etc. consume greatly, harmful waste water is many.
Embodiment
A kind of architectural shape surface treatment phosphorization agent, by weight, be made up of following raw material: 10-12 part calcium phosphate, 15-18 part manganous nitrate, 4-6 part phytic acid, 8-10 part Sodium tetrafluoroborate, 2-5 N-BUTYL ACETATE, 2.8-3.5 phenylformic acid, 1.2-1.8 parts of reactive monomers, 0.8-1.2 part nickelous nitrate, 0.5-0.8 part barium nitrite, 1.2-2.5 part tartrate, 0.4-0.8 part trolamine, 1.4-2.5 part chromium sulphate, 2.5-3.5 initiator, 0.5-1.2 part tensio-active agent, 45-50 part service water; Its concrete preparation method is as follows: above-mentioned raw materials component mixed, stir and be heated to 110 DEG C, be incubated 2.2 hours, be chilled to 45 DEG C, be incubated 1.5 hours, reheat to 110 DEG C, be incubated 1.5 hours, be cooled to normal temperature with 25 DEG C/h, i.e. obtained finished product phosphorization agent.
Claims (2)
1. an architectural shape surface treatment phosphorization agent, by weight, it is characterized in that, be made up of following raw material: 10-12 part calcium phosphate, 15-18 part manganous nitrate, 4-6 part phytic acid, 8-10 part Sodium tetrafluoroborate, 2-5 N-BUTYL ACETATE, 2.8-3.5 phenylformic acid, 1.2-1.8 parts of reactive monomers, 0.8-1.2 part nickelous nitrate, 0.5-0.8 part barium nitrite, 1.2-2.5 part tartrate, 0.4-0.8 part trolamine, 1.4-2.5 part chromium sulphate, 2.5-3.5 initiator, 0.5-1.2 part tensio-active agent, 45-50 part service water; Its concrete preparation method is as follows: above-mentioned raw materials component mixed, stir and be heated to 90-120 DEG C, insulation 2-2.5 hour, be chilled to 30-60 DEG C, insulation 1-2 hour, reheats to 100-120 DEG C, insulation 1-2 hour, is cooled to normal temperature with 20-30 DEG C/h, i.e. obtained finished product phosphorization agent.
2. architectural shape surface treatment phosphorization agent according to claim 1, it is characterized in that, above-mentioned raw materials component is mixed, stirs and be heated to 110 DEG C, be incubated 2.2 hours, be chilled to 45 DEG C, be incubated 1.5 hours, reheat to 110 DEG C, be incubated 1.5 hours, normal temperature is cooled to, i.e. obtained finished product phosphorization agent with 25 DEG C/h.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410590597.XA CN104313561A (en) | 2014-10-29 | 2014-10-29 | Surface treatment phosphatizing agent for building sectional material |
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CN201410590597.XA CN104313561A (en) | 2014-10-29 | 2014-10-29 | Surface treatment phosphatizing agent for building sectional material |
Publications (1)
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CN104313561A true CN104313561A (en) | 2015-01-28 |
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CN201410590597.XA Pending CN104313561A (en) | 2014-10-29 | 2014-10-29 | Surface treatment phosphatizing agent for building sectional material |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105420588A (en) * | 2015-11-03 | 2016-03-23 | 合肥海源机械有限公司 | Preparation method of automobile hub fixed bolt |
CN107287584A (en) * | 2017-05-16 | 2017-10-24 | 合肥市瀚坤机械有限公司 | One kind takes door frame surface conditioning agent |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002024973A2 (en) * | 2000-09-20 | 2002-03-28 | Ge Betz, Inc. | Tri-cation zinc phosphate conversion coating and process of making the same |
CN101109081A (en) * | 2007-04-30 | 2008-01-23 | 余取民 | Normal temperature barium salt modified phosphorizing liquid capable of avoiding water wash after phosphorized |
CN102747356A (en) * | 2012-07-30 | 2012-10-24 | 长沙学院 | Normal temperature calcium-manganese phosphorizing liquid |
CN103352215A (en) * | 2013-06-21 | 2013-10-16 | 安徽省六安市朝晖机械制造有限公司 | Phosphorization anti-rust treatment process for workpiece |
CN103805983A (en) * | 2012-11-08 | 2014-05-21 | 北京中科三环高技术股份有限公司 | Surface treatment method for permanent magnet material by adopting phosphorization agent to carry out phosphorization treatment |
-
2014
- 2014-10-29 CN CN201410590597.XA patent/CN104313561A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002024973A2 (en) * | 2000-09-20 | 2002-03-28 | Ge Betz, Inc. | Tri-cation zinc phosphate conversion coating and process of making the same |
CN101109081A (en) * | 2007-04-30 | 2008-01-23 | 余取民 | Normal temperature barium salt modified phosphorizing liquid capable of avoiding water wash after phosphorized |
CN102747356A (en) * | 2012-07-30 | 2012-10-24 | 长沙学院 | Normal temperature calcium-manganese phosphorizing liquid |
CN103805983A (en) * | 2012-11-08 | 2014-05-21 | 北京中科三环高技术股份有限公司 | Surface treatment method for permanent magnet material by adopting phosphorization agent to carry out phosphorization treatment |
CN103352215A (en) * | 2013-06-21 | 2013-10-16 | 安徽省六安市朝晖机械制造有限公司 | Phosphorization anti-rust treatment process for workpiece |
Non-Patent Citations (1)
Title |
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周代瑚: "多元系中温磷化工艺", 《电镀与涂饰》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105420588A (en) * | 2015-11-03 | 2016-03-23 | 合肥海源机械有限公司 | Preparation method of automobile hub fixed bolt |
CN107287584A (en) * | 2017-05-16 | 2017-10-24 | 合肥市瀚坤机械有限公司 | One kind takes door frame surface conditioning agent |
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Effective date of registration: 20160525 Address after: Luyang District of Hefei City Shouchun road 230001 Anhui province No. 356 merchants International Building room 1407 Applicant after: HEFEI ZHENGTUO DECORATION MATERIALS CO., LTD. Address before: 230011 Luyang Industrial Park, Fuyang North Road, Luyang District, Anhui, Hefei Applicant before: Hefei Huayang Construction Machinery Co.,Ltd. |
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Application publication date: 20150128 |