CN104312501A - Jelly glue and preparation method thereof - Google Patents
Jelly glue and preparation method thereof Download PDFInfo
- Publication number
- CN104312501A CN104312501A CN201410584836.0A CN201410584836A CN104312501A CN 104312501 A CN104312501 A CN 104312501A CN 201410584836 A CN201410584836 A CN 201410584836A CN 104312501 A CN104312501 A CN 104312501A
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- CN
- China
- Prior art keywords
- minutes
- stirring
- agent
- normal temperature
- gel glue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003292 glue Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 235000015110 jellies Nutrition 0.000 title abstract 6
- 239000008274 jelly Substances 0.000 title abstract 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 55
- 238000003756 stirring Methods 0.000 claims abstract description 49
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 15
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- 229920002521 macromolecule Polymers 0.000 claims description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 17
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 15
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 15
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 15
- 239000001488 sodium phosphate Substances 0.000 claims description 13
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 13
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 13
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 13
- IPGANOYOHAODGA-UHFFFAOYSA-N dilithium;dimagnesium;dioxido(oxo)silane Chemical compound [Li+].[Li+].[Mg+2].[Mg+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IPGANOYOHAODGA-UHFFFAOYSA-N 0.000 claims description 12
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 9
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 6
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 6
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 2
- 239000003638 chemical reducing agent Substances 0.000 abstract 3
- 238000007710 freezing Methods 0.000 abstract 2
- 239000002952 polymeric resin Substances 0.000 abstract 2
- 229920003002 synthetic resin Polymers 0.000 abstract 2
- 239000000499 gel Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 231100000331 toxic Toxicity 0.000 abstract 1
- 230000002588 toxic effect Effects 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- 239000004836 Glue Stick Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to jelly glue which is characterized by comprising the following raw materials in percentage by weight: 1-15% of high polymer resin, 3-12% of gelata, 0.1-5% of viscosity reducer, 1-10% of anti-freezing agent and the balance of water. The preparation method of the jelly glue comprises the following steps: (1) preparing raw materials; (2) adding the viscosity reducer and water into a stirring kettle, and stirring for 5-10 minutes at normal temperature until the viscosity reducer is completely dissolved; (3) adding the gelata into the stirring kettle, and stirring for 10-40 minutes at normal temperature; (4) adding the anti-freezing agent and the high polymer resin into the stirring kettle, and stirring for 30-90 minutes at normal temperature until the resin is completely dissolved; and (5) filling and packaging the liquid mixture obtained in the step (4), and standing for 12-36 hours to obtain the jelly glue. The jelly glue disclosed by the invention does not contain toxic and harmful substances, is extremely easy to flush, and is very suitable to serve as a student supply and an office supply; the production process is finished at normal temperature, the process is simple, and the production cycle is short; and the jelly glue is a liquid with good fluidity after production is finished, is easy to fill and shows the shape of gel after standing.
Description
Technical field
The present invention relates to a kind of stationery, specifically a kind of gel glue and preparation method thereof.
Background technology
Current stationery class sizing agent mainly PVA liquid glue and solid glue stick.
But PVA liquid glue production cost is lower to be needed to add formaldehyde reaction mostly, and formaldehyde has toxicity, all has certain harm to the producer and user, especially concerning the producer of Long Term Contact, hazardness is larger.In addition, PVA liquid glue is in use difficult to well control flow, is often coated with out a lot of rate of drying very slow; In carrying and using, the outflow that PVA liquid glue is easily unnecessary from bottle, brings worry to user.
Although solid gums relative liquid glue uses and carries more convenient, relate to a lot of reacting by heating process in producing, complex process power consumption is comparatively large, runs counter to the theory of energy-conserving and environment-protective, Sustainable development; And solid gums is not easy to filling.
Summary of the invention
Technical problem to be solved by this invention is for above-mentioned prior art present situation, and provide formula simple, produce easy, nontoxic a kind of gel glue, its preparation method completes at normal temperatures, and technique is simple, with short production cycle, easily filling.
The present invention solves the problems of the technologies described above adopted technical scheme:
A kind of gel glue, the weight percent of each raw material is: macromolecule resin 1% to 15%, gelifying agent 3% to 12%, viscosity-depression agent 0.1% to 5%, antifreezing agent 1% to 10%, and all the other are water.
For optimizing technique scheme, the measure taked also comprises:
Above-mentioned macromolecule resin is the one in polyvinylpyrrolidone and polyvinyl alcohol, or both mixtures.
Above-mentioned polyvinylpyrrolidone be molecular weight 10000000 to 13000000 polyvinylpyrrolidonepowder powder; In embodiment, polyvinyl alcohol to be the trade mark be 1788 pva powder.
Above-mentioned gelifying agent is the one in lithium magnesium silicate and neusilin, or both mixtures.
Above-mentioned viscosity-depression agent is one or more mixtures in Sodium hexametaphosphate 99, trisodium phosphate and sodium polyphosphate.
Above-mentioned antifreezing agent is one or more mixtures in ethylene glycol, propylene glycol, glycerol.
A kind of preparation method of gel glue: comprise the following steps:
Step one, preparation raw material;
Step 2, join in stirring tank by viscosity-depression agent and water, stirring at normal temperature 5 minutes to 10 minutes is to dissolving completely;
Step 3, in stirring tank, add gelifying agent, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, in stirring tank, add antifreezing agent and macromolecule resin, and stirring at normal temperature is dissolved completely for 30 minutes to 90 minutes to resin;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gel glue.
Compared with prior art, the invention has the advantages that, the advantages of nontoxic raw materials of this gel glue is harmless, high safety.This gel glue only need stir at normal temperatures when producing and make raw material fully dissolve and mix, and technique is simple, with short production cycle; Be the liquid of good fluidity when having produced, be easy to filling, in gel after leaving standstill, no longer there is mobility, can effectively prevent from carrying and unnecessary outflow in use procedure.
In addition, gel glue of the present invention, without hazardous and noxious substances, very easily rinses, and is suitable as very much student stationery and office appliance.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
A kind of gel glue, the weight percent of each raw material is: macromolecule resin 1% to 15%, gelifying agent 3% to 12%, viscosity-depression agent 0.1% to 5%, antifreezing agent 1% to 10%, and all the other are water.
In embodiment, macromolecule resin is the one in polyvinylpyrrolidone and polyvinyl alcohol, or both mixtures.
In embodiment, polyvinylpyrrolidone be molecular weight 10000000 to 13000000 polyvinylpyrrolidonepowder powder; In embodiment, polyvinyl alcohol to be the trade mark be 1788 pva powder.
In embodiment, gelifying agent is the one in lithium magnesium silicate and neusilin, or both mixtures.
In embodiment, viscosity-depression agent is one or more mixtures in Sodium hexametaphosphate 99, trisodium phosphate and sodium polyphosphate.
In embodiment, antifreezing agent is one or more mixtures in ethylene glycol, propylene glycol, glycerol.
A kind of preparation method of gel glue: comprise the following steps:
Step one, preparation raw material;
Step 2, join in stirring tank by viscosity-depression agent and water, stirring at normal temperature 5 minutes to 10 minutes is to dissolving completely;
Step 3, in stirring tank, add gelifying agent, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, in stirring tank, add antifreezing agent and macromolecule resin, and stirring at normal temperature is dissolved completely for 30 minutes to 90 minutes to resin;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gel glue.
Embodiment one:
Step one, prepare raw material according to following weight percent:
Macromolecule resin: polyvinylpyrrolidone 5%
Viscosity-depression agent: trisodium phosphate 0.8%
Gelifying agent: lithium magnesium silicate 6%
Antifreezing agent: propylene glycol 5%
All the other are water.
Step 2, add in stirring tank by trisodium phosphate and water, stirring at normal temperature 5 minutes to 10 minutes is to dissolving completely;
Step 3, in stirring tank, add lithium magnesium silicate, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, in stirring tank, add propylene glycol and polyvinylpyrrolidone, and stirring at normal temperature is dissolved completely for 30 minutes to 90 minutes to resin;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gelatinous gel glue.
Embodiment two:
Step one, prepare raw material according to following weight percent:
Macromolecule resin: polyvinyl alcohol 1,788 8%
Viscosity-depression agent: trisodium phosphate 0.8%
Gelifying agent: lithium magnesium silicate 6%
Antifreezing agent: ethylene glycol 6%
All the other are water.
Step 2, add in stirring tank by trisodium phosphate and water, stirring at normal temperature 5 minutes to 10 minutes is to dissolving completely;
Step 3, in stirring tank, add lithium magnesium silicate, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, in stirring tank, add ethylene glycol and polyvinyl alcohol 1788, and stirring at normal temperature is dissolved completely for 30 minutes to 90 minutes to resin;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gelatinous gel glue.
Embodiment three,
Step one, prepare raw material according to following weight percent:
Macromolecule resin: polyvinyl alcohol 1,788 8%
Polyvinylpyrrolidone 2%
Viscosity-depression agent: Sodium hexametaphosphate 99 0.2%
Trisodium phosphate 1%
Gelifying agent: neusilin 8%
Antifreezing agent: glycerol 7%
All the other are water.
Step 2, viscosity-depression agent Sodium hexametaphosphate 99 and trisodium phosphate mixed add in stirring tank together with water, and stirring at normal temperature is extremely dissolved for 5 minutes to 10 minutes completely;
Step 3, in stirring tank, add neusilin, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, the macromolecule resin adding glycerol and mixed by polyvinyl alcohol 1788 and polyvinylpyrrolidone in stirring tank, and stirring at normal temperature is dissolved to 90 minutes to resin for 30 minutes completely;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gelatinous gel glue.
Embodiment four:
Step one, prepare raw material according to following weight percent:
Macromolecule resin: polyvinyl alcohol 1,788 1%
Polyvinylpyrrolidone 5%
Viscosity-depression agent: sodium polyphosphate 0.5%
Trisodium phosphate 0.5%
Gelifying agent: neusilin 3%
Lithium magnesium silicate 3%
Antifreezing agent: ethylene glycol 2%
Propylene glycol 4%
All the other are water.
Step 2, viscosity-depression agent sodium polyphosphate and trisodium phosphate mixed add in stirring tank together with water, and stirring at normal temperature is extremely dissolved for 5 minutes to 10 minutes completely;
Step 3, in stirring tank, add the gelifying agent mixed by neusilin and lithium magnesium silicate, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, to add in stirring tank by the antifreezing agent of ethylene glycol and mixed with propylene glycol and the macromolecule resin that mixed by polyvinyl alcohol 1788 and polyvinylpyrrolidone, and stirring at normal temperature is dissolved to 90 minutes to resin for 30 minutes completely;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gelatinous gel glue.
Embodiment five:
Gel glue in the present embodiment, composed as follows according to weight percent raw material:
Macromolecule resin: polyvinylpyrrolidone 8%
Viscosity-depression agent: trisodium phosphate 1.2%
Gelifying agent: neusilin 2%
Lithium magnesium silicate 5%
Antifreezing agent: glycerol 7%
All the other are water.
Embodiment six:
Gel glue in the present embodiment, composed as follows according to weight percent raw material:
Macromolecule resin: polyvinylpyrrolidone 10%
Viscosity-depression agent: trisodium phosphate 0.3%
Sodium polyphosphate 0.5%
Sodium hexametaphosphate 99 0.2%
Gelifying agent: neusilin 2%
Lithium magnesium silicate 5%
Antifreezing agent: propylene glycol 10%
All the other are water.
Embodiment seven:
Gel glue in the present embodiment, composed as follows according to weight percent raw material:
Macromolecule resin: polyvinyl alcohol 1,788 1%
Polyvinylpyrrolidone 5%
Gelifying agent: sodium polyphosphate 1.5%
Gelifying agent: lithium magnesium silicate 3%
Antifreezing agent: ethylene glycol 3%
Propylene glycol 3%
Glycerol 4%
All the other are water.
Most preferred embodiment of the present invention is illustrated, and the various change made by those of ordinary skill in the art or remodeling all can not depart from the scope of the present invention.
Claims (7)
1. a gel glue, is characterized in that: the weight percent of each raw material is: macromolecule resin 1% to 15%, gelifying agent 3% to 12%, viscosity-depression agent 0.1% to 5%, antifreezing agent 1% to 10%, and all the other are water.
2. a kind of gel glue according to claim 1, is characterized in that: described macromolecule resin is the one in polyvinylpyrrolidone and polyvinyl alcohol, or both mixtures.
3. a kind of gel glue according to claim 2, is characterized in that: described polyvinylpyrrolidone be molecular weight 10000000 to 13000000 polyvinylpyrrolidonepowder powder; Described polyvinyl alcohol to be the trade mark be 1788 pva powder.
4. a kind of gel glue according to claim 3, is characterized in that: described gelifying agent is the one in lithium magnesium silicate and neusilin, or both mixtures.
5. a kind of gel glue according to claim 4, is characterized in that: described viscosity-depression agent is one or more mixtures in Sodium hexametaphosphate 99, trisodium phosphate and sodium polyphosphate.
6. a kind of gel glue according to claim 5, is characterized in that: described antifreezing agent is one or more mixtures in ethylene glycol, propylene glycol, glycerol.
7. the preparation method of a kind of gel glue according to claim 1: it is characterized in that: comprise the following steps:
Step one, preparation raw material;
Step 2, join in stirring tank by viscosity-depression agent and water, stirring at normal temperature 5 minutes to 10 minutes is to dissolving completely;
Step 3, in stirring tank, add gelifying agent, stirring at normal temperature 10 minutes to 40 minutes;
Step 4, in stirring tank, add antifreezing agent and macromolecule resin, and stirring at normal temperature is dissolved completely for 30 minutes to 90 minutes to resin;
Step 5, the liquid mixture filling and package will obtained in step 4, leave standstill 12 and littlely after 36 hours, obtain gel glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584836.0A CN104312501B (en) | 2014-10-28 | 2014-10-28 | A kind of preparation method of curry glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584836.0A CN104312501B (en) | 2014-10-28 | 2014-10-28 | A kind of preparation method of curry glue |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104312501A true CN104312501A (en) | 2015-01-28 |
| CN104312501B CN104312501B (en) | 2016-06-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410584836.0A Expired - Fee Related CN104312501B (en) | 2014-10-28 | 2014-10-28 | A kind of preparation method of curry glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104312501B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485597A (en) * | 2018-03-14 | 2018-09-04 | 东莞市东彩印刷包装有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10176153A (en) * | 1996-12-17 | 1998-06-30 | Bunchiyou:Kk | Solid adhesive |
| CN101220252A (en) * | 2008-01-25 | 2008-07-16 | 中北大学 | A kind of solid glue stick and preparation method thereof |
| CN101608103A (en) * | 2008-06-18 | 2009-12-23 | 宁波松鹤文具有限公司 | A kind of allochroic solid adhesive and preparation method thereof |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
-
2014
- 2014-10-28 CN CN201410584836.0A patent/CN104312501B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10176153A (en) * | 1996-12-17 | 1998-06-30 | Bunchiyou:Kk | Solid adhesive |
| CN1192460A (en) * | 1996-12-17 | 1998-09-09 | 株式会社寿 | Solid adhesive |
| CN101220252A (en) * | 2008-01-25 | 2008-07-16 | 中北大学 | A kind of solid glue stick and preparation method thereof |
| CN101608103A (en) * | 2008-06-18 | 2009-12-23 | 宁波松鹤文具有限公司 | A kind of allochroic solid adhesive and preparation method thereof |
| CN102321443A (en) * | 2011-09-15 | 2012-01-18 | 宋仕良 | Environmental protection type transparent solid glue and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108485597A (en) * | 2018-03-14 | 2018-09-04 | 东莞市东彩印刷包装有限公司 | A kind of environmental protection fruit juice gel and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104312501B (en) | 2016-06-29 |
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Granted publication date: 20160629 Termination date: 20171028 |