CN104312455A - Anti-fading ultraviolet curing decorative adhesive and preparation method thereof - Google Patents
Anti-fading ultraviolet curing decorative adhesive and preparation method thereof Download PDFInfo
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- CN104312455A CN104312455A CN201410584861.9A CN201410584861A CN104312455A CN 104312455 A CN104312455 A CN 104312455A CN 201410584861 A CN201410584861 A CN 201410584861A CN 104312455 A CN104312455 A CN 104312455A
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- ultraviolet light
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Abstract
The invention relates to the technical field of decorative adhesives and particularly relates to an anti-fading ultraviolet curing decorative adhesive and a preparation method thereof. The anti-fading ultraviolet curing decorative adhesive is prepared from the following raw materials in parts by weight: 50-60 parts of glycidyl ether epoxy resin and epoxidized oil acrylate mixture, 1-2 parts of pigment, 2-5 parts of photopolymerization initiator, 10-20 parts of reactive diluent, 1-2 parts of leveling agent and 1-2 parts of defoaming agent. The formula in the invention is an organic formula to prevent the pigment in the curing agent from ageing, so as to prevent the ultraviolet curing adhesive from yellowing after long-time use, and the anti-fading ultraviolet curing decorative adhesive is environment-friendly and is non-toxic, thereby generating no influence on human or animals touching the product and meeting the national monitoring requirements on product quality safety.
Description
Technical field
The present invention relates to decorating glue technical field, particularly relate to a kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof.
Background technology
At present, UV-curing technology is that the industries such as building provide a kind of new technique, and this technology utilization is coated on the ultraviolet cured adhesive on base material and issues in the initiation of UV-light and be biochemically cross-linked curing molding.This technique is almost carry out at normal temperatures and pressures, avoids the High Temperature High Pressure of injection moulding.
And extrude ultraviolet cured adhesive by point gum machine, can on base material height of formation different, the three-dimensional pattern of various colors and word, and can possess different colors and special-effect, therefore ultraviolet cured adhesive is applied gradually at advertisement field and is promoted.
But ultraviolet cured adhesive easily turns to be yellow after Dryly use for some time, overall color is caused to lose efficacy.And along with era development, the continuous lifting of standard requirement, has higher requirement to the fade-proof of ultraviolet cured adhesive, and demand is a kind of more friendly to environment, to the product of the low evil of human body low toxicity.
Summary of the invention
The object of the invention is to address the deficiencies of the prior art, a kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof is provided.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
A kind of fade-proof ultraviolet light polymerization decorating glue, is characterized in that: count by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 50 ~ 60 parts;
Pigment: 1 ~ 2 part;
Photoepolymerizationinitiater initiater: 2 ~ 5 parts;
Reactive thinner: 10 ~ 20 parts;
Flow agent: 1 ~ 2 part;
Defoamer: 1 ~ 2 part.
Further, the fade-proof ultraviolet light polymerization decorating glue of described one is counted by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 55 parts;
Pigment: 1 part;
Photoepolymerizationinitiater initiater: 5 parts;
Reactive thinner: 15 parts;
Flow agent: 1 part;
Defoamer: 1 part.
Further, described reactive thinner is methacrylic acid undecyl ester and diacrylate ester mixture.
Further, described Photoepolymerizationinitiater initiater is cyanuric chloride, ethoxybenzoin or said mixture.
Further, described defoamer is tributyl phosphate.
Present invention also offers a kind of making method of above-mentioned a kind of fade-proof ultraviolet light polymerization decorating glue, comprise the following steps: by glyceryl ether epoxy resin and epoxidized oil acrylate mixture, pigment, reactive thinner, flow agent, defoamer, abundant mixing is also heated to 40 ~ 50 DEG C of stirring 10 ~ 30min, add Photoepolymerizationinitiater initiater again, stir, then leave standstill cooling and get final product.
The invention provides a kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof, beneficial effect is as follows:
A kind of fade-proof ultraviolet light polymerization decorating glue of the present invention and preparation method thereof, by improving traditional ultraviolet cured adhesive, glyceryl ether epoxy resin and epoxidized oil acrylate mixture and methacrylic acid undecyl ester and diacrylate ester mixture is adopted to carry out organic proportioning, prevent the pigment in solidifying agent aging, thus ultraviolet cured adhesive can not be turned to be yellow after a long time use, and environment-protecting asepsis evil, can not impact the human or animal of contact product, meet the monitoring requirement of country to Product quality and safety.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
The fade-proof ultraviolet light polymerization decorating glue of described one is counted by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 60 parts;
Pigment: 1.5 parts;
Cyanuric chloride: 4 parts;
Methacrylic acid undecyl ester and diacrylate ester mixture: 15 parts;
Flow agent: 1.5 parts;
Tributyl phosphate: 1 part.
By glyceryl ether epoxy resin and epoxidized oil acrylate mixture, pigment, methacrylic acid undecyl ester and diacrylate ester mixture, flow agent, tributyl phosphate, abundant mixing is also heated to 40 ~ 50 DEG C of stirring 10 ~ 30min, add cyanuric chloride again, stir, then leave standstill cooling and get final product.
Embodiment 2:
The fade-proof ultraviolet light polymerization decorating glue of described one is counted by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 50 parts;
Pigment: 1 part;
Ethoxybenzoin: 3 parts;
Methacrylic acid undecyl ester and diacrylate ester mixture: 12 parts;
Flow agent: 1 part;
Tributyl phosphate: 1 part.
By glyceryl ether epoxy resin and epoxidized oil acrylate mixture, pigment, methacrylic acid undecyl ester and diacrylate ester mixture, flow agent, tributyl phosphate, abundant mixing is also heated to 40 ~ 50 DEG C of stirring 10 ~ 30min, add ethoxybenzoin again, stir, then leave standstill cooling and get final product.
Claims (6)
1. a fade-proof ultraviolet light polymerization decorating glue, is characterized in that: count by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 50 ~ 60 parts;
Pigment: 1 ~ 2 part;
Photoepolymerizationinitiater initiater: 2 ~ 5 parts;
Reactive thinner: 10 ~ 20 parts;
Flow agent: 1 ~ 2 part;
Defoamer: 1 ~ 2 part.
2. the fade-proof ultraviolet light polymerization decorating glue of one according to claim 1, is characterized in that: the fade-proof ultraviolet light polymerization decorating glue of described one is counted by weight, is prepared from by following raw material:
Glyceryl ether epoxy resin and epoxidized oil acrylate mixture: 55 parts;
Pigment: 1 part;
Photoepolymerizationinitiater initiater: 5 parts;
Reactive thinner: 15 parts;
Flow agent: 1 part;
Defoamer: 1 part.
3. the fade-proof ultraviolet light polymerization decorating glue of one according to claim 1, is characterized in that: described reactive thinner is methacrylic acid undecyl ester and diacrylate ester mixture.
4. the fade-proof ultraviolet light polymerization decorating glue of one according to claim 1, is characterized in that: described Photoepolymerizationinitiater initiater is cyanuric chloride, ethoxybenzoin or said mixture.
5. the fade-proof ultraviolet light polymerization decorating glue of one according to claim 1, is characterized in that: described defoamer is tributyl phosphate.
6. the fade-proof ultraviolet light polymerization decorating glue of one according to claim 1, it is characterized in that: the making method of described a kind of fade-proof ultraviolet light polymerization decorating glue, comprise the following steps: by glyceryl ether epoxy resin and epoxidized oil acrylate mixture, pigment, reactive thinner, flow agent, defoamer, abundant mixing is also heated to 40 ~ 50 DEG C of stirring 10 ~ 30min, add Photoepolymerizationinitiater initiater again, stir, then leave standstill cooling and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584861.9A CN104312455B (en) | 2014-10-28 | 2014-10-28 | A kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584861.9A CN104312455B (en) | 2014-10-28 | 2014-10-28 | A kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104312455A true CN104312455A (en) | 2015-01-28 |
| CN104312455B CN104312455B (en) | 2016-03-02 |
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| CN201410584861.9A Active CN104312455B (en) | 2014-10-28 | 2014-10-28 | A kind of fade-proof ultraviolet light polymerization decorating glue and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070293603A1 (en) * | 2006-06-19 | 2007-12-20 | Ashland Licensing And Intellectual Property Llc | Epoxy adhesive composition and use thereof |
| CN102167962A (en) * | 2011-03-22 | 2011-08-31 | 深圳市飞世尔实业有限公司 | Photocuring adhesive used for adhering optic glass lenses and preparation method thereof |
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2014
- 2014-10-28 CN CN201410584861.9A patent/CN104312455B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070293603A1 (en) * | 2006-06-19 | 2007-12-20 | Ashland Licensing And Intellectual Property Llc | Epoxy adhesive composition and use thereof |
| CN102167962A (en) * | 2011-03-22 | 2011-08-31 | 深圳市飞世尔实业有限公司 | Photocuring adhesive used for adhering optic glass lenses and preparation method thereof |
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| Publication number | Publication date |
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| CN104312455B (en) | 2016-03-02 |
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Effective date of registration: 20201127 Address after: 272000 room 2211, Jinchen international building, Linghua South Road, Liuhang street, high tech Zone, Jining City, Shandong Province Patentee after: Jining xinruida Information Technology Co., Ltd Address before: 610000 Shiyang Industrial Park, hi tech Zone, Chengdu, Sichuan Patentee before: CHENGDU NASHUO TECHNOLOGY Co.,Ltd. |