Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
The thickening mechanism of cellulose thickener be hydrophobic main chain and surrounding water molecules by hydrogen bond association, improve the fluid volume of polymkeric substance itself, decrease the space of Particle free activity, thus improve system viscosity.Also can be realized the raising of viscosity by the winding of molecular chain, showing as and have high viscosity at static and low sheraing, is low-viscosity under high shear.This is because when static state or low shearing speed, cellulose molecular chain is in state of disarray and makes system present high viscosity; And when high shear rates, molecule is parallel to flow direction and makes ordered arrangement, be easy to mutual slip, so system viscosity degradation.Cellulose thickener, attapulgite and auxiliary agent are mixed by a certain percentage, can obtain use under neutral environment, have good thickening adhesive effect, the binding agent of not metal ion, be applicable in Building Ceramics Industry and need to be fixed with in bonding operation frit particle.
Preparation-the embodiment 1 of frit granule agglomerant
The preparation of frit granule agglomerant: the component of every 100kg frit granule agglomerant: Natvosol (purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.) 5.0kg, attapulgite 2.5kg, polymethyl siloxane 1.1kg, organic-silicon-modified sodium phosphate 1.7kg, surplus is water.
The preparation method of above-mentioned frit granule agglomerant, comprises the following steps: a) that Natvosol is soluble in water, stirs; B) add polymethyl siloxane and organic-silicon-modified sodium phosphate, stir; C) add attapulgite and residue water solvent, stir and obtain frit granule agglomerant, surveying its flow velocity is 26.8s (30 DEG C, be coated with-4 glasss).It should be noted that, organic-silicon-modified sodium phosphate can use sodium polyacrylate or Sodium hexametaphosphate 99 to replace as dispersion agent also can realize this programme.
Dumb light under glazed throws the preparation-embodiment 1-1 of glazed brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick; The requirement of adobe relatively goodly can present decalcomania, therefore needs to adopt the higher finished product adobe of whiteness as end brick;
(2), end brick stamp; The mode of four look spray ink Printings is adopted to form full-color decalcomania;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray the frit granule agglomerant that last layer is obtained by embodiment 1 again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 1-1 selects is sprawled in sintering process, printed layer is formed ice crystal textured pattern, frit particle can be bought by colour glaze company and obtain, the frit such as, used in the present embodiment is the great Hong colour glaze company limited from Sanshui District of Foshan City, the present embodiment firing temperature is 1000 DEG C, and the time is 1.5 hours.
Comparative example 1-2
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick (identical with embodiment 1-1);
(2), end brick stamp; (identical with embodiment 1-1)
(3), frit layer: figuratum frit layer on covering again on the brick of printed pattern, and then sprays last layer methylcellulose gum aqueous slurry;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents; (identical with embodiment 1-1)
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Though comparative example obtains the dumb light under glazed with ice crystal textured pattern and throws glazed brick finished product, there is the visible pin hole of a small amount of naked eyes in texture, the continuity of ice crystal texture is not strong.
Can be compared by embodiment 1-1 and the ornamental brick final product quality of comparative example 1-2 and draw and on the clear frit granular layer with ice crystal effect, sprayed frit granule agglomerant of the present invention in embodiment 1-1, make pebble frit particles stick in glaze paint, and do not affect by lower negative pressure in the preheating zone through kiln, glaze paint retains preferably and is not absorbed.In order to illustrate further, the frit granule agglomerant providing embodiment 1-1 to obtain below compares with the kinematic viscosity value μ of the viscosity aqueous slurry used in comparative example 1-2, and experimental data is in table 1.
Kinematic viscosity value μ: be coated with-4 glasss measure at 30 DEG C liquid to flow out from the hole of predetermined hole diameter needed for time obtain flow velocity t, and convert by t=0.223 μ+6.0 and draw kinematic viscosity value μ.
Contrast experiment's data of table 1 embodiment 1-1 and comparative example 1-2
Numbering |
Flow velocity/s |
Kinematic viscosity value/(mm
2/s)
|
Embodiment 1-1 |
26.8 |
85.19 |
Comparative example 1-2 |
7.4 |
8.05 |
Can obtain from table 1, its kinematic viscosity value of frit granule agglomerant in embodiment 1-1 uses the kinematic viscosity of the viscosity aqueous slurry be mixed with by methylcellulose gum to be worth 10 times more than in comparative example 1-2, when the lower negative pressure of kiln preheating zone, can better be bonding frit particle, make it remain not to be sucked away, improve integrity and smoothness that the texture of rear surface is burnt till in adobe greatly, the pin hole problems may leaving over generation because frit particle is sucked away disappearance can be avoided.
Comparative example 1-3
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick (identical with embodiment 1-1);
(2), end brick stamp; (identical with embodiment 1-1)
(3), frit layer: figuratum frit layer on covering again on the brick of printed pattern, and then sprays last layer glue;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents; (identical with embodiment 1-1)
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Though comparative example obtains the dumb light under glazed with ice crystal textured pattern and throws glazed brick finished product, there is the visible pin hole of a small amount of naked eyes in texture, the continuity of ice crystal texture is not strong.
Can be compared by embodiment 1-1 and the ornamental brick final product quality of comparative example 1-3 and draw and on the clear frit granular layer with ice crystal effect, sprayed frit granule agglomerant of the present invention in embodiment 1-1, make pebble frit particles stick in glaze paint, and do not affect by lower negative pressure in the preheating zone through kiln, glaze paint retains preferably and is not absorbed.In order to illustrate further, the frit granule agglomerant providing embodiment 1-1 to obtain below compares with the kinematic viscosity value μ of the glue used in comparative example 1-3, and experimental data is in table 2.
Kinematic viscosity value μ: be coated with-4 glasss measure at 30 DEG C liquid to flow out from the hole of predetermined hole diameter needed for time obtain flow velocity t, and convert by t=0.223 μ+6.0 and draw kinematic viscosity value μ.
Contrast experiment's data of table 2 embodiment 1-1 and comparative example 1-3
Numbering |
Flow velocity/s |
Kinematic viscosity value/(mm
2/s)
|
Embodiment 1-1 |
26.8 |
85.19 |
Comparative example 1-3 |
6.8 |
7.75 |
Can obtain from table 2, its kinematic viscosity value of frit granule agglomerant in embodiment 1-1 uses the kinematic viscosity of glue to be worth 10 times more than in comparative example 1-3, when the lower negative pressure of kiln preheating zone, can better be bonding frit particle, make it remain not to be sucked away, improve integrity and smoothness that the texture of rear surface is burnt till in adobe greatly, the pin hole problems may leaving over generation because frit particle is sucked away disappearance can be avoided.
Preparation-the embodiment 2 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with enforcement 1, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose (Dezhou Kang Rong Chemical Co., Ltd.) 5.5kg, attapulgite 3.0kg, polymethyl siloxane 1.4kg, Sodium hexametaphosphate 99 2.1kg, surplus is ethanol.
Preparation-embodiment the 2-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 2 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 2-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 980 DEG C, and the time is 2 hours.The frit particles stick agent flow velocity that the present embodiment obtains is 25.7s (30 DEG C, is coated with-4 glasss), and kinematic viscosity value is 84.56mm
2/ s.
Preparation-the embodiment 3 of frit granule agglomerant
Preparation method and the embodiment 1 of the present embodiment are basically identical, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: Vltra tears (Dezhou Kang Rong Chemical Co., Ltd.) 6.0kg, attapulgite 2.6kg, polymethyl siloxane 1.2kg, Sodium hexametaphosphate 99 1.8kg, surplus is ethylene glycol.
Preparation-embodiment the 3-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 3 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 3-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 995 DEG C, and the time is 1.8 hours.The present embodiment use the agent of frit particles stick flow velocity for 25.2s (30 DEG C, be coated with-4 glasss), kinematic viscosity value is 84.98mm2/s.
Preparation-the embodiment 4 of frit granule agglomerant
Preparation method and the embodiment 1 of the present embodiment are basically identical, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: Vltra tears (Dezhou Kang Rong Chemical Co., Ltd.) 3.0kg, Natvosol 2.4kg, attapulgite 2.7kg, polymethyl siloxane 1.3kg, sodium polyacrylate 1.9kg, surplus is water and ethylene glycol.
Preparation-embodiment the 4-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 4 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 4-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 997 DEG C, and the time is 1.8 hours.The frit particles stick agent flow velocity that the present embodiment obtains is 26.4s (30 DEG C, is coated with-4 glasss), and kinematic viscosity value is 86.28mm
2/ s.
Preparation-the embodiment 5 of frit granule agglomerant
Preparation method and the embodiment 1 of the present embodiment are basically identical, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: Vltra tears (Dezhou Kang Rong Chemical Co., Ltd.) 2.5kg, hydroxyethylmethyl-cellulose 2.8kg (purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.), attapulgite 2.9kg, polymethyl siloxane 1.2kg, Sodium hexametaphosphate 99 0.8kg, organic-silicon-modified sodium phosphate 1.0kg, surplus is second alcohol and water.
Preparation-embodiment the 5-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 5 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 5-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 985 DEG C, and the time is 1.8 hours.The flow velocity that the present embodiment obtains the agent of frit particles stick is 26.7s (30 DEG C, is coated with-4 glasss), and kinematic viscosity value is 88.13mm
2/ s.
Preparation-the embodiment 6 of frit granule agglomerant
Preparation method and the embodiment 1 of the present embodiment are basically identical, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose (purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.) 3.0kg, Natvosol (purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.), attapulgite 2.8kg, polymethyl siloxane 1.2kg, Sodium hexametaphosphate 99 1.4kg, sodium polyacrylate 0.6kg, surplus is ethylene glycol and ethanol.
Preparation-embodiment the 6-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 6 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 6-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 998 DEG C, and the time is 1.8 hours.The frit particles stick agent flow velocity that the present embodiment obtains is 25.8s (30 DEG C, is coated with-4 glasss), and kinematic viscosity value is 85.45mm
2/ s.
Preparation-the embodiment 7 of frit granule agglomerant
Preparation method and the embodiment 1 of the present embodiment are basically identical, and difference is, in the present embodiment, component and the ratio of employing are different.The component of every 100kg frit granule agglomerant: Natvosol (purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.) 5.7kg, attapulgite 3.0kg, polymethyl siloxane 1.4kg, Sodium hexametaphosphate 99 1.8kg, surplus is ethylene glycol.
Preparation-embodiment the 7-1 of ornamental brick
(1), prepare the end brick: select white water-intake rate lower than 0.5% finished product adobe do end brick;
(2), end brick stamp;
(3), frit layer: first spray one deck hydrophober on the brick of printed pattern, and then cover upper figuratum frit layer, finally spray last layer frit granule agglomerant (adopting embodiment 7 to obtain) again;
(4), fire: the brick of frit layer on printed flower and covering is put into kiln and fires, surperficial frit fuses into transparent vitreum, and the pattern color below frit presents;
(5) polishing: by the product after burning till directly through polishing machine polishing, throws flat by the frit on surface; Described polishing machine, by using elastic module as polishing abrasive tool polishing, using grinding wipe as polishing abrasive tool polishing and use polished section to carry out polishing successively as polishing abrasive tool polishing, makes product surface present matte effect;
(6) final finished product is obtained after the product after above-mentioned polishing being carried out edging, sorting, packaging;
Here the end brick method needing more than explanation to use, formula are conventional formulation well known in the art, and suitably can select according to method condition in practice, this partial content is not inventive point of the present invention.But also it should be noted that, the clear frit particle that the present embodiment 7-1 selects is sprawled in sintering process, and printed layer is formed ice crystal textured pattern, and frit particle can be bought by colour glaze company and obtain.The present embodiment firing temperature is 995 DEG C, and the time is 2 hours.The frit particles stick agent flow velocity that the present embodiment obtains is 25.6s (30 DEG C, is coated with-4 glasss), and kinematic viscosity value is 85.63mm
2/ s.
In addition, this scheme can also be improved in the following way, namely after stamp, sprays one deck hydrophober, and hydrophober can be avoided, when spraying frit particle fixing agent, after solvent penetration wherein, destroying decalcomania and blank strength.Spraying one deck hydrophober after stamp can head it off preferably, such as in one embodiment of the invention, uses organosilicon as hydrophober, after its spraying, makes the base substrate after spray fusing block particle fixing agent in course of conveying, reduce the loss of 3-5%.
Below know-why of the present invention is described in conjunction with specific embodiments.These describe just in order to explain principle of the present invention, and can not be interpreted as limiting the scope of the invention by any way.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present invention, and these modes all will fall within protection scope of the present invention.