CN104310988B - 一种低介电常数微波介电陶瓷Ba3In2Zn7O13及其制备方法 - Google Patents

一种低介电常数微波介电陶瓷Ba3In2Zn7O13及其制备方法 Download PDF

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CN104310988B
CN104310988B CN201410574287.9A CN201410574287A CN104310988B CN 104310988 B CN104310988 B CN 104310988B CN 201410574287 A CN201410574287 A CN 201410574287A CN 104310988 B CN104310988 B CN 104310988B
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罗昊
李纯纯
苏和平
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Linquan Extraordinary Advertising Media Co ltd
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Abstract

本发明公开了一种温度稳定型低介电常数微波介电陶瓷Ba3In2Zn7O13及其制备方法。（1）将纯度为99.9%（重量百分比）以上的BaCO3、In2O3和ZnO的原始粉末按Ba3In2Zn7O13的组成称量配料；（2）将步骤（1）原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1200℃大气气氛中预烧6小时；（3）在步骤（2）制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1250~1300℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5%的聚乙烯醇溶液，聚乙烯醇的添加量占粉末总质量的3%。本发明制备的陶瓷烧结良好，介电常数达到29.1～30.5，其品质因数Qf值高达68000‑87000GHz，谐振频率温度系数小，在工业上有着极大的应用价值。

Description

一种低介电常数微波介电陶瓷Ba3In2Zn7O13及其制备方法
技术领域
本发明涉及介电陶瓷材料，特别是涉及用于制造微波频率使用的陶瓷谐振器与滤波器等微波元器件的介电陶瓷材料及其制备方法。
背景技术
微波介电陶瓷是指应用于微波频段（主要是UHF和SHF频段）电路中作为介质材料并完成一种或多种功能的陶瓷，在现代通讯中被广泛用作谐振器、滤波器、介质基片和介质导波回路等元器件，是现代通信技术的关键基础材料，已在便携式移动电话、汽车电话、无绳电话、电视卫星接受器和军事雷达等方面有着十分重要的应用，在现代通讯工具的小型化、集成化过程中正发挥着越来越大的作用。
应用于微波频段的介电陶瓷，应满足如下介电特性的要求：（1）系列化介电常数εr以适应不同频率及不同应用场合的要求;（2）高的品质因数Q值或低的介质损耗tanδ以降低噪音，一般要求Qf≥3000 GHz;(3) 谐振频率的温度系数τƒ尽可能小以保证器件具有好的热稳定性，一般要求-10 ppm /℃≤τƒ≤+10 ppm/℃。国际上从20世纪30年代末就有人尝试将电介质材料应用于微波技术, 并制备出TiO2微波介质滤波器，但其谐振频率温度系数τƒ太大而无法实用化。上世纪70年代以来，开始了大规模的对介质陶瓷材料的开发工作, 根据相对介电常数εr的大小与使用频段的不同，通常可将已被开发和正在开发的微波介质陶瓷分为4类。
（1）超低介电常数微波介电陶瓷，主要代表是Al2O3-TiO2、Y2BaCuO5、MgAl2O4和Mg2SiO4等，其εr≤20，品质因数Q×f≥50000GHz，τƒ≤10 ppm/°C。主要用于微波基板以及高端微波元器件。
（2）低εr和高Q值的微波介电陶瓷，主要是BaO-MgO-Ta2O5, BaO-ZnO-Ta2O5或BaO-MgO-Nb2O5, BaO-ZnO-Nb2O5系统或它们之间的复合系统MWDC材料。其εr=20～35, Q=(1～2)×104(在f≥10 GHz下), τƒ≈0。主要应用于f≥8 GHz的卫星直播等微波通信机中作为介质谐振器件。
（3）中等εr和Q值的微波介电陶瓷，主要是以BaTi4O9、Ba2Ti9O20和（Zr、Sn）TiO4等为基的MWDC材料,其εr＝35~45，Q=（6～9）×103（在f=3～－4GHz下），τƒ≤5 ppm/°C。主要用于4～8 GHz 频率范围内的微波军用雷达及通信系统中作为介质谐振器件。
（4）高εr而Q值较低的微波介电陶瓷，主要用于0.8～4GHz 频率范围内民用移动通讯系统，这也是微波介电陶瓷研究的重点。80年代以来，Kolar、Kato等人相继发现并研究了类钙钛矿钨青铜型BaO—Ln2O3—TiO2系列(Ln=La、 Sm、 Nd或Pr等,简称BLT系)、复合钙钛矿结构CaO—Li2O—Ln2O3—TiO2系列、铅基系列材料、Ca1-xLn2x/3TiO3系等高εr微波介电陶瓷，其中BLT体系的BaO—Nd2O3—TiO2材料介电常数达到90，铅基系列 (Pb,Ca)ZrO3介电常数达到105。
由于微波介电陶瓷的三个性能指标（εr与Q·f 和τƒ）之间是相互制约的关系（见文献：微波介质陶瓷材料介电性能间的制约关系，朱建华，梁飞，汪小红，吕文中，电子元件与材料，2005年3月第3期），满足三个性能要求的单相微波介质陶瓷非常少，主要是它们的谐振频率温度系数通常过大或者品质因数偏低而无法实际应用要求。目前对微波介质陶瓷的研究大部分是通过大量实验而得出的经验总结,却没有完整的理论来阐述微观结构与介电性能的关系，因此，在理论上还无法从化合物的组成与结构上预测其谐振频率温度系数和品质因数等微波介电性能，探索与开发近零谐振频率温度系数（-10 ppm /℃≤τƒ≤+10ppm/℃）与较高品质因数的系列不同介电常数微波介电陶瓷是本领域技术人员一直渴望解决但始终难以获得成功的难题，这在很大程度上限制了微波介电陶瓷与器件的发展。
发明内容
本发明的目的是提供一种具有良好的热稳定性与低损耗的低介电常数微波介电陶瓷材料及其制备方法。
本发明的微波介电陶瓷材料的化学组成为Ba3In2Zn7O13。
本微波介电陶瓷材料的制备方法步骤为：
（1）将纯度为99.9%（重量百分比）以上的BaCO3、In2O3和ZnO的原始粉末按Ba3In2Zn7O13的组成称量配料。
（2）将步骤（1）原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1200℃大气气氛中预烧6小时。
（3）在步骤（2）制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1250~1300℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5%的聚乙烯醇溶液，聚乙烯醇添加量占粉末总质量的3%。
本发明的优点：Ba3In2Zn7O13陶瓷介电常数达到29.1～30.5，其谐振频率的温度系数τƒ小，温度稳定性好；品质因数Qf值高达68000-87000GHz，可广泛用于各种介质谐振器和滤波器等微波器件的制造，可满足低温共烧技术及微波多层器件的技术需要，在工业上有着极大的应用价值。
具体实施方式
实施例：
表1示出了构成本发明的不同烧结温度的3个具体实施例及其微波介电性能。其制备方法如上所述，用圆柱介质谐振器法进行微波介电性能的评价。
本陶瓷可广泛用于各种介质基板等微波器件的制造，可满足移动通信和卫星通信等系统的技术需要。
表1：

Claims (1)

1.一种温度稳定型低介电常数微波介电陶瓷，其介电常数为29.1～30.5，其特征在于所述微波介电陶瓷的化学组成为：Ba3In2Zn7O13；
所述微波介电陶瓷的制备方法具体步骤为：
（1）将纯度为99.9%（重量百分比）以上的BaCO3、In2O3和ZnO的原始粉末按Ba3In2Zn7O13的组成称量配料；
（2）将步骤（1）原料湿式球磨混合12小时，球磨介质为蒸馏水，烘干后在1200℃大气气氛中预烧6小时；
（3）在步骤（2）制得的粉末中添加粘结剂并造粒后，再压制成型，最后在1250~1300℃大气气氛中烧结4小时；所述的粘结剂采用质量浓度为5%的聚乙烯醇溶液，聚乙烯醇添加量占粉末总质量的3%。
CN201410574287.9A 2014-10-24 2014-10-24 一种低介电常数微波介电陶瓷Ba3In2Zn7O13及其制备方法 Expired - Fee Related CN104310988B (zh)

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Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Photofield effect and photoresponse properties of the transparent oxide-based BaInZnO thin-film transistors;Si Joon Kim et al.,;《Sensors and Actuators A:Physical》;20130111;第193卷;第1-12页 *
The formation of InZnO lattices incorporating Ba for thin-film transistors using a solution process;Si Joon Kim et al.,;《Journal of Crystal Growth》;20110202;第326卷;第163-165页 *

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