CN104310956A - Low-temperature heat-resistant ceramic and production process thereof - Google Patents

Low-temperature heat-resistant ceramic and production process thereof Download PDF

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Publication number
CN104310956A
CN104310956A CN201410538158.4A CN201410538158A CN104310956A CN 104310956 A CN104310956 A CN 104310956A CN 201410538158 A CN201410538158 A CN 201410538158A CN 104310956 A CN104310956 A CN 104310956A
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China
Prior art keywords
low
temperature heat
resistant ceramic
raw material
glaze
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CN201410538158.4A
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Chinese (zh)
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CN104310956B (en
Inventor
危连进
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FUJIAN DEHUA WILL CERAMIC Co Ltd
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FUJIAN DEHUA WILL CERAMIC Co Ltd
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Priority to CN201410538158.4A priority Critical patent/CN104310956B/en
Priority to CN201511014149.6A priority patent/CN105645939B/en
Publication of CN104310956A publication Critical patent/CN104310956A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses low-temperature heat-resistant ceramic and a production process thereof. The low-temperature heat-resistant ceramic is prepared from the following raw materials in percentage by mass: 36%-42% of lepidolite, 24%-30% of aluminum oxide, 30%-32% of Longyan kaolin and 2%-4% of bentonite. The production process of the low-temperature heat-resistant ceramic comprises the following steps: pre-pulverizing the raw materials, then using a ball mill to perform wet-process ball milling, magnetically removing iron impurities after screening, molding, fettling and performing biscuit firing; then, performing color painting and spraying bright glaze to perform glaze firing, packaging and warehousing to obtain the low-temperature heat-resistant ceramic. The production process disclosed by the invention adopts the bright glaze, so that the produced low-temperature heat-resistant ceramic has good quality, bright color and luster and stable performances; and moreover, the sintering temperature is low, a great deal of heat is saved, and thus, the energy consumption can be lowered by 30%, not only can the fuel consumption and the fuel cost be lowered, but also great effect can be provided for energy conservation and emission reduction.

Description

A kind of low temperature thermal pottery and production technique thereof
Technical field
The present invention relates to ceramic product technical field, specifically a kind of low temperature thermal pottery and production technique thereof.
Background technology
Refractory ceramics is the important component part of special cermacis, sometimes also as the integral part of high-temperature refractory.Can be used as high-temperature structural material, for many fields such as aerospace, nuclear power, electronic technology, machinery, chemical industry, metallurgy, be the indispensable high temperature engineering materials of modern science and technology, various in style, purposes is very extensive.
Because traditional high temperature ceramic material composition is single, there is obvious deficiency in nature, and high temperature ceramic material exists processing difficulties, heat-shock resistance is poor, not easily carry out boning etc. shortcoming, therefore industry begins one's study novel fire resistant stupalith and low temperature thermal material.This low temperature thermal material is obtained under lower high temperature, but but with its distinctive structure and performance, has resistant to elevated temperatures performance, and therefore low temperature thermal material has very large market outlook, also has very important meaning for field of new.
Summary of the invention
The object of the present invention is to provide a kind of preparation temperature low and the low temperature thermal of superior performance pottery and production technique thereof, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme:
A low temperature thermal pottery, is made up of the raw material of following mass percent: lithionite 36% ~ 42%, aluminum oxide 24% ~ 30%, Longyan kaolin 30% ~ 32%, wilkinite 2% ~ 4%.
A production technique for low temperature thermal pottery, concrete steps are as follows: Longyan kaolin and wilkinite are crushed to the particulate state that diameter is less than 6mm by (1) respectively; (2) raw material lithionite, aluminum oxide, Longyan kaolin and bentonite clay particle is taken according to mass percent; (3) raw material is put into ball mill and is added clear water and grind 25 ~ 30h, and is screened by 220 ~ 300 mesh sieves; (4) magnetic separation is carried out, to remove iron contamination contained in mud raw material; (5) mud raw material is carried out filter-press dehydration, after carry out vacuum pugging and become mud bar, water ratio is less than 22%; (6) mud bar is carried out shaping, repaired biscuit, and burn 800 DEG C, about 4h; (8) after cooling, can under glazed be carried out, execute spray light glaze, at the temperature of 1150 ~ 1200 DEG C, continue glaze firing 8 ~ 10h; (9) also the product after glaze firing can be carried out applique baking, packaging and warehouse-in.
Compared with prior art, the invention has the beneficial effects as follows: production technique of the present invention uses bright glaze, the good product quality produced, bright in color, stable performance; And firing temperature is low, save a large amount of heat energy, therefore energy consumption can reduce by 30%, not only reduces fuel consumption and fuel cost, and has significant role for energy-saving and emission-reduction.
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
A low temperature thermal pottery, is made up of the raw material of following mass percent: lithionite 36%, aluminum oxide 30%, Longyan kaolin 30%, wilkinite 4%.
Embodiment 2
A low temperature thermal pottery, is made up of the raw material of following mass percent: lithionite 39%, aluminum oxide 27%, Longyan kaolin 31%, wilkinite 3%.
Embodiment 3
A low temperature thermal pottery, is made up of the raw material of following mass percent: lithionite 42%, aluminum oxide 24%, Longyan kaolin 32%, wilkinite 2%.
The production technique of above-described embodiment 1, embodiment 2 and the low temperature thermal pottery described in embodiment 3, concrete steps are as follows: Longyan kaolin and wilkinite are crushed to the particulate state that diameter is less than 6mm by (1) respectively; (2) raw material lithionite, aluminum oxide, Longyan kaolin and bentonite clay particle is taken according to mass percent; (3) raw material is put into ball mill and is added clear water and grind 25 ~ 30h, and is screened by 220 ~ 300 mesh sieves; (4) magnetic separation is carried out, to remove iron contamination contained in mud raw material; (5) mud raw material is carried out filter-press dehydration to become mud cake to carry out vacuum pugging to become mud bar, make the water ratio of mud bar be less than 22%; (6) mud bar is carried out shaping, repaired biscuit, and burn 800 DEG C, after about 4h, can under glazed be carried out; (8), after cooling, execute spray light glaze, at the temperature of 1150 DEG C-1200 DEG C, continue glaze firing 8-10h; (9) also the product after glaze firing can be carried out applique baking, packaging and warehouse-in.
Production technique of the present invention uses bright glaze, the good product quality produced, bright in color; And firing temperature is low, save large energy, therefore energy consumption can reduce by 30%, not only reduces fuel consumption and fuel cost, and has significant role for energy-saving and emission-reduction; The waste material waste residue recoverable occurred in operation, reduces the total cost of production, improves economic benefit.
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.

Claims (2)

1. a low temperature thermal pottery, is characterized in that, is made up of the raw material of following mass percent: lithionite 36% ~ 42%, aluminum oxide 24% ~ 30%, Longyan kaolin 30% ~ 32%, wilkinite 2% ~ 4%.
2. a production technique for low temperature thermal pottery as claimed in claim 1, it is characterized in that, concrete steps are as follows: Longyan kaolin and wilkinite are crushed to the particulate state that diameter is less than 6mm by (1) respectively; (2) raw material lithionite, aluminum oxide, Longyan kaolin and bentonite clay particle is taken according to mass percent; (3) put into ball mill and add clear water grinding 25 ~ 30h, and screened by 220 ~ 300 mesh sieves; (4) magnetic separation is carried out, to remove iron contamination contained in mud raw material; (5) mud raw material is carried out filter-press dehydration and become mud cake, make the water ratio of mud cake be less than 22%, carry out vacuum pugging and become mud bar; (6) undertaken shaping by mud bar, repaired biscuit also burns 800 DEG C, about 4h; (8) after cooling, can under glazed be carried out, execute spray light glaze, at the temperature of 1150 ~ 1200 DEG C, continue glaze firing 8 ~ 10h; (9) also the product after glaze firing can be carried out applique baking, packaging and warehouse-in.
CN201410538158.4A 2014-10-14 2014-10-14 A kind of low temperature thermal pottery and production technique thereof Active CN104310956B (en)

Priority Applications (2)

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CN201410538158.4A CN104310956B (en) 2014-10-14 2014-10-14 A kind of low temperature thermal pottery and production technique thereof
CN201511014149.6A CN105645939B (en) 2014-10-14 2014-10-14 A kind of low temperature thermal ceramics

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020528A (en) * 2018-09-17 2018-12-18 泉州市陶瓷科学技术研究所 A kind of full porcelain of low temperature high heat resistance and preparation method thereof
CN109574645A (en) * 2019-01-16 2019-04-05 福建省威尔陶瓷股份有限公司 A kind of middle temperature heat-stable ceramic product and preparation method thereof
CN109678458A (en) * 2019-01-21 2019-04-26 福建省威尔陶瓷股份有限公司 A kind of highly heat-conductive carbon/ceramic ceramic products and preparation method thereof
CN110256042A (en) * 2019-06-26 2019-09-20 福建省德化县邦威陶瓷有限公司 The anti-folding heatproof and shockproof ceramic blank of one kind, anti-folding heatproof and shockproof ceramic product and preparation method thereof
CN112174696A (en) * 2019-07-02 2021-01-05 Oppo广东移动通信有限公司 Ceramic structural member, glaze for surface decoration of ceramic structural member, preparation method of ceramic structural member and electronic equipment

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1907908A (en) * 2006-08-17 2007-02-07 钟旭东 Method of producing polishing brick by low-temperature sintering
CN102040374A (en) * 2009-10-19 2011-05-04 泉州坤达礼品有限公司 Lithium-magnesium ceramic fired at low temperature and manufacturing method thereof
CN102786298A (en) * 2012-08-22 2012-11-21 湖南仙凤瓷业有限公司 Magnesian ceramic blank, magnesian ceramic and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1907908A (en) * 2006-08-17 2007-02-07 钟旭东 Method of producing polishing brick by low-temperature sintering
CN102040374A (en) * 2009-10-19 2011-05-04 泉州坤达礼品有限公司 Lithium-magnesium ceramic fired at low temperature and manufacturing method thereof
CN102786298A (en) * 2012-08-22 2012-11-21 湖南仙凤瓷业有限公司 Magnesian ceramic blank, magnesian ceramic and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020528A (en) * 2018-09-17 2018-12-18 泉州市陶瓷科学技术研究所 A kind of full porcelain of low temperature high heat resistance and preparation method thereof
CN109574645A (en) * 2019-01-16 2019-04-05 福建省威尔陶瓷股份有限公司 A kind of middle temperature heat-stable ceramic product and preparation method thereof
CN109678458A (en) * 2019-01-21 2019-04-26 福建省威尔陶瓷股份有限公司 A kind of highly heat-conductive carbon/ceramic ceramic products and preparation method thereof
CN110256042A (en) * 2019-06-26 2019-09-20 福建省德化县邦威陶瓷有限公司 The anti-folding heatproof and shockproof ceramic blank of one kind, anti-folding heatproof and shockproof ceramic product and preparation method thereof
CN112174696A (en) * 2019-07-02 2021-01-05 Oppo广东移动通信有限公司 Ceramic structural member, glaze for surface decoration of ceramic structural member, preparation method of ceramic structural member and electronic equipment

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