CN104293216A - Acrylic ester adhesive composition - Google Patents
Acrylic ester adhesive composition Download PDFInfo
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- CN104293216A CN104293216A CN201410625059.XA CN201410625059A CN104293216A CN 104293216 A CN104293216 A CN 104293216A CN 201410625059 A CN201410625059 A CN 201410625059A CN 104293216 A CN104293216 A CN 104293216A
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- sizing composition
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Abstract
The invention discloses an acrylic ester adhesive composition. The acrylic ester adhesive composition comprises the following components in parts by weight: 42-60 parts of acrylic acid monomer, 1-10 parts of epoxy resin, 1-5 parts of a curing agent, 12-28 parts of a thickening agent, 1-4 parts of a stabilizing agent, 1-4 parts of an oxidizing agent, 1-2 parts of a reducing agent and 1-10 parts of aids. The adhesive composition is reasonable in structural collocation, and is particularly suitable for the field of ocean ships, the decomposition volatility is not high under long-term illumination, and the volatile gas irritation of the adhesive composition is lower than that of an existing product. Moreover, the adhesive composition touches water, the viscosity is improved to a certain extent, and the temporary plugging effect is remarkable.
Description
Technical field
The present invention relates to ship domain adhesive field, relate in particular to a kind of acrylate sizing composition.
Background technology
Ship domain is very high to the requirement of coating and tackiness agent when safeguarding marine surface, because the difference of the Working environment of boats and ships and traditional field, under the irradiation of high density seawater and daylight, low-quality viscose glue can produce strong sharp aroma, and after it meets water, bounding force can decline to a great extent.
Summary of the invention
Goal of the invention: the object of this invention is to provide a kind of volatile flavor do not stimulate, meet water after a kind of acrylate sizing composition of being strengthened within a certain period of time of bounding force.
Technical scheme: in order to realize foregoing invention object, a kind of acrylate sizing composition of the present invention, comprises following raw material by mass fraction: acrylic monomer 42 ~ 60 parts; Epoxy resin 1 ~ 10 part; 1 ~ 5 part, solidifying agent; Thickening material 12 ~ 28 parts; Stablizer 1 ~ 4 part; 1 ~ 4 part, oxygenant; Reductive agent 1 ~ 2 part; Auxiliary agent 1 ~ 10 part.
Described acrylic monomer comprises two or more mixing in tetrahydrofuran methyl acrylate, phenoxyethyl methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, lauryl methacrylate, methacrylic acid tetradecyl ester, methacrylic acid cetyl ester, polyethyleneglycol diacrylate, Triethylene glycol diacrylate, Propenoic acid, 2-methyl, isobutyl ester, hydroxyethyl methylacrylate, Rocryl 410.
Described epoxy resin comprises bisphenol epoxy, novolac epoxy.
Described solidifying agent is acid anhydrides type or phenol aldehyde type or polythiol type epoxy hardener.
Described tackifier comprise ABS resin or paracril or both combinations.
Described stablizer comprises 2,6 di tert butyl 4 methyl phenol, Resorcinol, Resorcinol, para benzoquinone, p-ten.-butylcatechol any one or multiple combination.
Described superoxide comprises diacyl peroxide or hydroperoxide.
Described reductive agent is triethylamine.
Described auxiliary agent comprises methacrylic acid or toxilic acid.
Preferably, described sizing composition is made up of following mass fraction by mass fraction: tetrahydrofuran methyl acrylate 20 parts, lauryl methacrylate 30 parts, bisphenol epoxy 10 parts, anhydride type curing agent 3 parts, ABS resin 3 parts, Resorcinol 1 part, Resorcinol 1 part, hydrogen peroxide 1 part, triethylamine 1 part, methacrylic acid 2 parts.
Beneficial effect: sizing composition structure matching of the present invention is reasonable, is particularly suitable for marine ship field, it is not high to decompose volatility under long-term illumination, and institute's volatilization gas pungency is lower than currently available products.And after this product chance water, viscosity obtains certain lifting on the contrary, remarkable for interim plugging effect.
Embodiment
Embodiment 1
A kind of acrylate sizing composition, comprises following raw material by mass fraction: acrylic monomer 58 parts; Epoxy resin 8 parts; 3 parts, solidifying agent; Thickening material 22 parts; Stablizer 2 parts; 1 part, oxygenant; Reductive agent 1 part; Auxiliary agent 4 parts.
Embodiment 2
A kind of acrylate sizing composition, is made up of following mass fraction by mass fraction: tetrahydrofuran methyl acrylate 30 parts, lauryl methacrylate 30 parts, bisphenol epoxy 10 parts, anhydride type curing agent 5 parts, ABS resin 3 parts, Resorcinol 1 part, Resorcinol 1 part, hydrogen peroxide 1 part, triethylamine 1 part, methacrylic acid 10 parts.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. an acrylate sizing composition, comprises following raw material by mass fraction:
Acrylic monomer 42 ~ 60 parts;
Epoxy resin 1 ~ 10 part;
1 ~ 5 part, solidifying agent;
Thickening material 12 ~ 28 parts;
Stablizer 1 ~ 4 part;
1 ~ 4 part, oxygenant;
Reductive agent 1 ~ 2 part;
Auxiliary agent 1 ~ 10 part.
2. a kind of acrylate sizing composition according to claim 1, is characterized in that: described acrylic monomer comprises two or more mixing in tetrahydrofuran methyl acrylate, phenoxyethyl methacrylate, methoxy poly (ethylene glycol) mono acrylic ester, lauryl methacrylate, methacrylic acid tetradecyl ester, methacrylic acid cetyl ester, polyethyleneglycol diacrylate, Triethylene glycol diacrylate, Propenoic acid, 2-methyl, isobutyl ester, hydroxyethyl methylacrylate, Rocryl 410.
3. a kind of acrylate sizing composition according to claim 1, is characterized in that: described epoxy resin comprises bisphenol epoxy, novolac epoxy.
4. a kind of acrylate sizing composition according to claim 1, is characterized in that: described solidifying agent is acid anhydrides type or phenol aldehyde type or polythiol type epoxy hardener.
5. a kind of acrylate sizing composition according to claim 1, is characterized in that: described tackifier comprise ABS resin or paracril or both combinations.
6. a kind of acrylate sizing composition according to claim 1, it is characterized in that: described stablizer comprises 2,6 di tert butyl 4 methyl phenol, Resorcinol, Resorcinol, para benzoquinone, p-ten.-butylcatechol any one or multiple combination.
7. a kind of acrylate sizing composition according to claim 1, is characterized in that: described superoxide comprises diacyl peroxide or hydroperoxide.
8. a kind of acrylate sizing composition according to claim 1, is characterized in that: described reductive agent is triethylamine.
9. a kind of acrylate sizing composition according to claim 1, is characterized in that: described auxiliary agent comprises methacrylic acid or toxilic acid.
10. a kind of acrylate sizing composition according to claim 1, it is characterized in that, be made up of following mass fraction by mass fraction: tetrahydrofuran methyl acrylate 20 parts, lauryl methacrylate 30 parts, bisphenol epoxy 10 parts, anhydride type curing agent 3 parts, ABS resin 22 parts, Resorcinol 1 part, Resorcinol 1 part, hydrogen peroxide 1 part, triethylamine 1 part, methacrylic acid 2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410625059.XA CN104293216A (en) | 2014-11-07 | 2014-11-07 | Acrylic ester adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410625059.XA CN104293216A (en) | 2014-11-07 | 2014-11-07 | Acrylic ester adhesive composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104293216A true CN104293216A (en) | 2015-01-21 |
Family
ID=52313180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410625059.XA Pending CN104293216A (en) | 2014-11-07 | 2014-11-07 | Acrylic ester adhesive composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104293216A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102556A (en) * | 2017-12-20 | 2018-06-01 | 上海康达新能源材料有限公司 | A kind of double cured adhesives of two-component |
-
2014
- 2014-11-07 CN CN201410625059.XA patent/CN104293216A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102556A (en) * | 2017-12-20 | 2018-06-01 | 上海康达新能源材料有限公司 | A kind of double cured adhesives of two-component |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150121 |