CN104292960B - 一种阳离子表面活性剂油漆清洗剂 - Google Patents
一种阳离子表面活性剂油漆清洗剂 Download PDFInfo
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- 239000003973 paint Substances 0.000 title claims abstract description 24
- 239000003093 cationic surfactant Substances 0.000 title claims abstract description 14
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims abstract description 48
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims abstract description 29
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims abstract description 16
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims abstract description 15
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 28
- 241000234295 Musa Species 0.000 claims description 15
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 14
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 238000005660 chlorination reaction Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 230000001988 toxicity Effects 0.000 abstract description 6
- 231100000419 toxicity Toxicity 0.000 abstract description 6
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract description 3
- 239000002280 amphoteric surfactant Substances 0.000 abstract description 2
- 240000005561 Musa balbisiana Species 0.000 abstract 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002118 epoxides Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 241001116389 Aloe Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-N sodium;hydron;carbonate Chemical compound [Na+].OC(O)=O UIIMBOGNXHQVGW-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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Abstract
本发明涉及一种清洗剂，更具体的讲是一种阳离子表面活性剂油漆清洗剂，其由下述按重量份计的组分组成：香蕉水、碳酸氢钠、十二烷基三甲基氯化铵、十二烷基乙氧基磺基甜菜碱、二氯甲烷、去离子水，本发明使用阳离子表面活性剂十二烷基三甲基氯化铵和两性表面活性剂十二烷基乙氧基磺基甜菜碱相配伍，十二烷基三甲基氯化铵本身具有一定毒性，但是其与十二烷基乙氧基磺基甜菜碱有较好的配伍作用，配伍后不仅仅活性基团活性增加，脱漆效果明显，而且毒性大大降低，而且两者均具有一定的杀菌作用，因此使得本发明清洗剂还具有杀菌作用。
Description
技术领域
本发明涉及一种清洗剂，更具体的讲是一种阳离子表面活性剂油漆清洗剂。
背景技术
目前市场上常用的油漆清洗剂一般分为有机和无机两用，有机清洗剂一般由醇类、芳烃、酮类和醚类等溶剂组合而成，挥发性较高而且易燃易爆且毒性较大，而无机多以酸碱为主，腐蚀性强、清洗速度慢且效果不好，而目前最常用的是采用十二烷基苯磺酸钠为表面活性剂，其为阴离子表面活性剂，由于其生产成本低、性能好而且无毒而被广泛应用，如专利号为201310619748.5的专利申请公开了一种油漆清洗剂，其包括如下重量含量的成分：十二烷基苯磺酸钠3—6份，碳酸氢钠10—15份，甘油1—3份，芦荟提取液6—8份，碳酸钙20—35份，去离子水70—90份，上述发明所公开的油漆清洗剂，利用各成分与油漆的相容性实现物理去污，不含刺激性化学物质，对人体皮肤没有损害，适于清洗蘸到人体皮肤上的油漆，但是本发明中采用去离子水作为溶剂，碳酸钙和碳酸氢钠作为脱漆的主要成分，其主要还是以无机脱漆为主，十二烷基苯磺酸钠仅仅作为添加剂添加，并没有改变无机脱漆的主要缺点，脱漆效果差、效率低而且功能单一。
发明内容
本发明的发明目的在于针对以上现有技术中的不足之处，提供一种脱漆效果好、效率高而且具有一定杀菌效果的油漆清洗剂，本发明不同于现有技术中采用阴离子表面活性剂，本发明使用阳离子表面活性剂十二烷基三甲基氯化铵和两性表面活性剂十二烷基乙氧基磺基甜菜碱相配伍，十二烷基三甲基氯化铵本身具有一定毒性，但是其与十二烷基乙氧基磺基甜菜碱有较好的配伍作用，配伍后不仅仅活性基团活性增加，脱漆效果明显，而且毒性大大降低，而且两者均具有一定的杀菌作用，因此使得本发明清洗剂还具有杀菌作用。
本发明是通过以下技术方案实现的：
一种阳离子表面活性剂油漆清洗剂，由下述按重量份计的组分组成：香蕉水、碳酸氢钠、十二烷基三甲基氯化铵、十二烷基乙氧基磺基甜菜碱、二氯甲烷、去离子水。
上述清洗剂由下述按重量份计的组分组成：香蕉水15-25份、碳酸氢钠20-30份、十二烷基三甲基氯化铵10-20份、十二烷基乙氧基磺基甜菜碱10-20份、二氯甲烷5-15份、去离子水100份。
上述清洗剂由下述按重量份计的组分组成：香蕉水18-23份、碳酸氢钠25-28份、十二烷基三甲基氯化铵12-18份、十二烷基乙氧基磺基甜菜碱12-18份、二氯甲烷8-13份、去离子水100份。
上述清洗剂由下述按重量份计的组分组成：香蕉水22份、碳酸氢钠26份、十二烷基三甲基氯化铵16份、十二烷基乙氧基磺基甜菜碱16份、二氯甲烷12份、去离子水100份。
上述的一种阳离子表面活性剂油漆清洗剂的制备方法，包括如下步骤：首先将去离子水加热到35-45℃；然后将香蕉水、十二烷基三甲基氯化铵、十二烷基乙氧基磺基甜菜碱加入去离子水中进行搅拌，搅拌均匀后静置降温到15-20℃，然后边搅拌边加入二氯甲烷和碳酸氢钠，搅拌均匀即可。
本发明的有益效果是：本发明使用阳离子表面活性剂十二烷基三甲基氯化铵和两性表面活性剂十二烷基乙氧基磺基甜菜碱相配伍，十二烷基三甲基氯化铵本身具有一定毒性，但是其与十二烷基乙氧基磺基甜菜碱有较好的配伍作用，配伍后不仅仅活性基团活性增加，脱漆效果明显，而且毒性大大降低，而且两者均具有一定的杀菌作用，因此使得本发明清洗剂还具有杀菌作用。
具体实施方式
下面结合具体实施例对本发明做进一步说明，以便本领域技术人员可以更好的了解本发明，但并不因此限制本发明。
本发明一种阳离子表面活性剂油漆清洗剂的制备方法，包括如下步骤：首先将去离子水加热到35-45℃；然后将香蕉水、十二烷基三甲基氯化铵、十二烷基乙氧基磺基甜菜碱加入去离子水中进行搅拌，搅拌均匀后静置降温到15-20℃，然后边搅拌边加入二氯甲烷和碳酸氢钠，搅拌均匀即可。
下述实施例均采用上述方法制备。
实施例1
本发明清洗剂由下述按重量份计的组分组成：香蕉水15份、碳酸氢钠20份、十二烷基三甲基氯化铵10份、十二烷基乙氧基磺基甜菜碱10份、二氯甲烷5份、去离子水100份。
实施例2
本发明清洗剂由下述按重量份计的组分组成：香蕉水18份、碳酸氢钠25份、十二烷基三甲基氯化铵12份、十二烷基乙氧基磺基甜菜碱12份、二氯甲烷8份、去离子水100份。
实施例3
本发明清洗剂由下述按重量份计的组分组成：香蕉水22份、碳酸氢钠26份、十二烷基三甲基氯化铵16份、十二烷基乙氧基磺基甜菜碱16份、二氯甲烷12份、去离子水100份。
实施例4
清洗剂由下述按重量份计的组分组成：香蕉水23份、碳酸氢钠28份、十二烷基三甲基氯化铵18份、十二烷基乙氧基磺基甜菜碱18份、二氯甲烷13份、去离子水100份。
实施例5
上述清洗剂由下述按重量份计的组分组成：香蕉水25份、碳酸氢钠30份、十二烷基三甲基氯化铵20份、十二烷基乙氧基磺基甜菜碱20份、二氯甲烷15份、去离子水100份。
采用上述实施例1-5所得清洗剂清洗油漆污染状况相同的油漆污物，清洗效果和清洗速度见下表。
由上表可以看出，本发明在10分钟时基本可以将油漆去除，而且去除率高，同时带有一定的杀菌效果。
Claims (4)
1.一种阳离子表面活性剂油漆清洗剂，由下述按重量份计的组分组成：香蕉水15-25份、碳酸氢钠20-30份、十二烷基三甲基氯化铵10-20份、十二烷基乙氧基磺基甜菜碱10-20份、二氯甲烷5-15份、去离子水100份。
2.根据权利要求1所述的一种阳离子表面活性剂油漆清洗剂，其特征在于：所述清洗剂由下述按重量份计的组分组成：香蕉水18-23份、碳酸氢钠25-28份、十二烷基三甲基氯化铵12-18份、十二烷基乙氧基磺基甜菜碱12-18份、二氯甲烷8-13份、去离子水100份。
3.根据权利要求2所述的一种阳离子表面活性剂油漆清洗剂，其特征在于：所述清洗剂由下述按重量份计的组分组成：香蕉水22份、碳酸氢钠26份、十二烷基三甲基氯化铵16份、十二烷基乙氧基磺基甜菜碱16份、二氯甲烷12份、去离子水100份。
4.根据权利要求1-3中任意一项所述的一种阳离子表面活性剂油漆清洗剂的制备方法，包括如下步骤：首先将去离子水加热到35-45℃；然后将香蕉水、十二烷基三甲基氯化铵、十二烷基乙氧基磺基甜菜碱加入去离子水中进行搅拌，搅拌均匀后静置降温到15-20℃，然后边搅拌边加入二氯甲烷和碳酸氢钠，搅拌均匀即可。
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| CN103351703A (zh) * | 2013-08-05 | 2013-10-16 | 广东山之风环保科技有限公司 | 一种遮蔽漆的环保褪除剂及其制备方法和应用 |
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| CN102850841A (zh) * | 2012-09-17 | 2013-01-02 | 吴江鑫霞纺织有限公司 | 一种油漆剥离清洗剂 |
| CN103351703A (zh) * | 2013-08-05 | 2013-10-16 | 广东山之风环保科技有限公司 | 一种遮蔽漆的环保褪除剂及其制备方法和应用 |
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