CN104291512B - Electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant - Google Patents

Electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant Download PDF

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Publication number
CN104291512B
CN104291512B CN201410600646.3A CN201410600646A CN104291512B CN 104291512 B CN104291512 B CN 104291512B CN 201410600646 A CN201410600646 A CN 201410600646A CN 104291512 B CN104291512 B CN 104291512B
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housing
sewage
water inlet
flow straightener
sterilization device
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CN104291512A (en
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李伟东
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Ji'nan Tai Reed Environmental Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/487Treatment of water, waste water, or sewage with magnetic or electric fields using high frequency electromagnetic fields, e.g. pulsed electromagnetic fields
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/46125Electrical variables
    • C02F2201/4614Current
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/10Photocatalysts

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  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Physical Water Treatments (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Catalysts (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

Electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant, including base, water pipe it is installed on base, water inlet pipe connects with pulse electromagnetic field sterilizer, the tube wall periphery of water inlet pipe arranges magnetic sleeve pipe, and pulse electromagnetic field sterilizer connects with Photocatalyst sterilization device, installs ultraviolet lamp tube and photocatalysis rod in Photocatalyst sterilization device, Photocatalyst sterilization device connects with electrolysis flow straightener, and electrolysis flow straightener arranges outlet pipe.Mass disposal organic wastewater is achieved by the technological means of pure physics, thoroughly solve chemical treatment means and inevitably produce secondary pollution, the problem repeating corrosion and the threat that cause healthy to operating personnel, simultaneously the present invention also have that operating cost is low, volume is little, can the advantage such as continuous processing sewage.

Description

Electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant
Technical field
The present invention relates to a kind of water treatment facilities, specifically a kind of electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant.
Background technology
Oil-field flooding is the waste water that oil is carried out producing in recovery process by oil-extracting and water-injecting oil-extraction method, the fluctuation of its complicated component, water quality and quantity is big, pollutant levels are high and difficult degradation, pollutant mostly is poisonous and hazardous organic matter, and single process technique is extremely difficult to water quality re-injection requirement.Studying efficient, economic, energy-conservation treatment technology, the efficient combination of exploitation different process, is main contents and the developing direction of petrochemical wastewater Processing Technology Research.The heavily contaminated sewage such as existing oil-field flooding can only process by chemical means, but this process means need longer chemical time, the continuous processing of sewage cannot be realized, and large-scale consersion unit need to be equipped with, the repetition etching problem causing the secondary pollution of chemical reaction reagent, equipment being the most also difficult to avoid that, the most also can constitute a threat to the healthy of operating personnel.
Summary of the invention
It is an object of the invention to provide a kind of electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant, it can carry out effective sterilizing, algae removal, purification, scale removal etc. by pure physical means to the sewage that oil-field flooding and other multiple intractability are big and process.
The present invention is for achieving the above object, it is achieved through the following technical solutions: include base, water pipe it is installed on base, water inlet pipe connects with pulse electromagnetic field sterilizer, the tube wall periphery of water inlet pipe arranges magnetic sleeve pipe, and pulse electromagnetic field sterilizer connects with Photocatalyst sterilization device, installs ultraviolet lamp tube and photocatalysis rod in Photocatalyst sterilization device, Photocatalyst sterilization device connects with electrolysis flow straightener, and electrolysis flow straightener arranges outlet pipe.Described pulse electromagnetic field sterilizer includes water inlet end housing and water side housing, between water inlet end housing and water side housing, dividing plate is set, cathode sleeve is installed on dividing plate, cathode sleeve two ends lay respectively in water inlet end housing and water side housing, on cathode sleeve in water inlet end housing, flow inlet is set, arranging water export on cathode sleeve in the housing of water side, the shaft core position in cathode sleeve installs conductive anode rod, and the external diameter of conductive anode rod is less than the internal diameter of cathode sleeve.Described electrolysis flow straightener includes flow straightener housing, flow straightener housing sidewall bottom arranges water inlet and sewage draining exit, and flow straightener housing sidewall top arranges outlet pipe, and flow straightener case top arranges top cover, installing electrode column on top cover, electrode column end is positioned at flow straightener lower housing portion.The housing of described Photocatalyst sterilization device is Horizontal tubular housing, ultraviolet lamp tube and photocatalysis rod all horizontal positioned in the housing of Photocatalyst sterilization device.The water inlet end housing of described pulse electromagnetic field sterilizer and water side housing are the equal horizontal positioned of Horizontal tubular housing, cathode sleeve and conductive anode rod.Magnetic sleeve pipe periphery wall arranges magnetic shield cover.
It is an advantage of the current invention that: achieve mass disposal organic wastewater by the technological means of pure physics, thoroughly solve chemical treatment means and inevitably produce secondary pollution, the problem repeating corrosion and the threat that cause healthy to operating personnel, simultaneously the present invention also have that operating cost is low, volume is little, can the advantage such as continuous processing sewage.
Accompanying drawing explanation
Fig. 1 is present configuration schematic diagram;
Fig. 2 is the A-A section view structure for amplifying schematic diagram of Fig. 1;
Fig. 3 is the B-B section view structure for amplifying schematic diagram of Fig. 1;
Fig. 4 is the C-C section view structure for amplifying schematic diagram of Fig. 1;
Fig. 5 is the left view structural representation of Fig. 4.
Detailed description of the invention
Electromagnetism of the present invention catalysis oxidation oil-field flooding and sewage-treatment plant include base 1, water pipe 2 it is installed on base 1, water inlet pipe 2 connects with pulse electromagnetic field sterilizer 3, the tube wall periphery of water inlet pipe 2 arranges magnetic sleeve pipe 4, pulse electromagnetic field sterilizer 3 connects with Photocatalyst sterilization device 5, installing ultraviolet lamp tube 15 and photocatalysis rod 16 in Photocatalyst sterilization device 5, Photocatalyst sterilization device 5 connects with electrolysis flow straightener 6, and electrolysis flow straightener 6 arranges outlet pipe 7.nullSewage flows through water inlet pipe 2 successively、Pulse electromagnetic field sterilizer 3、Photocatalyst sterilization device 5 and electrolysis flow straightener 6,Finally flow out from outlet pipe 7,When sewage flows through water inlet pipe 2,Electromotive force can be produced,Lattice is made to refine,The i.e. particle diameter of the brilliant particle of the dirt in sewage significantly reduces (after finding in experiment that sewage flows through water inlet pipe 2,Wherein particle diameter can be down to 0.22 micron at the particle diameter of the brilliant particle of dirt of 39 microns,And it is the fastest to have flow velocity,The electromotive force produced is the biggest,The feature that dirty brilliant thinning effect is the best),Thus reach antiscale、Scale removal purpose,Guarantee internal non flouling behaviour in running of the present invention,Ensure system stable operation,Run for follow-up system and provide good running environment,When sewage flows through the magnetic field that magnetic sleeve pipe 4 produces,In sewage, the Premeabilisation of cells pressure of microorganism changes,Microbial cell is made to rupture,Cell stops breeding,Reach sterilization、The effect of algae removal,Hydrone in sewage can also form ordered arrangement under the magnetic fields that magnetic sleeve pipe 4 produces,Produce magnetization,Be conducive to strengthening conductance,And then strengthen the sterilization effect of next step pulse electromagnetic field sterilizer 3;After sewage enters pulse electromagnetic field sterilizer 3, the electric field of pulses generation and magnetic field alternating action, microbial cell membrane permeability in sewage is made to increase, film-strength weakens, material outflow in film, the outer material of film penetrates into, cause organic matter thalline dead, electromagnetic field produces ionization, normal bio chemical reaction and the metabolism of organic matter cell membrane are blocked, organic matter bacterium substance in vivo is made to change, ring-type, polycyclic, backbone is broken as short chain or even unimolecule structure, Photocatalyst sterilization device 5 for next stage provides excellent running environment, the effect that can make the photochemical catalytic oxidation of photocatalyst is more significantly;After sewage enters Photocatalyst sterilization device 5, owing in water, ring-type, polycyclic, the backbone of residual organic substances thalline have been broken to as short chain or unimolecule structure, therefore the photochemical catalytic oxidation efficiency of photocatalyst system can be promoted compared with existing independent photocatalyst system at double, it is achieved existing the be beyond one's reach sterilizing of photocatalyst sewage disposal device, algae removal efficiency;After sewage enters electrolysis flow straightener 6, current are gradually steady in electrolysis flow straightener 6, and the organic matter in sewage occurs electrochemical reaction to be degraded in electrolysis flow straightener 6, it is achieved dirty water purification.The present invention achieves mass disposal petrochemical industry organic wastewater by the technological means of pure physics, thoroughly solve chemical treatment means and inevitably produce secondary pollution, the problem repeating corrosion and the threat that cause healthy to operating personnel, simultaneously the present invention also have that operating cost is low, volume is little, can the advantage such as continuous processing sewage.For improving sewage treatment capacity further, multistage water inlet pipe 2, pulse electromagnetic field sterilizer 3, Photocatalyst sterilization device 5 and electrolysis flow straightener 6 also can be combined by the way of serial or parallel connection by the present invention, thus reach to further enhance wastewater treatment efficiency, the purpose of raising sewage treating efficiency.
Pulse electromagnetic field sterilizer 3 of the present invention can use various structures, wherein preferably structure is: described pulse electromagnetic field sterilizer 3 includes water inlet end housing 8 and water side housing 9, dividing plate 10 is set between water inlet end housing 8 and water side housing 9, cathode sleeve 11 is installed on dividing plate 10, cathode sleeve 11 two ends lay respectively in water inlet end housing 8 and water side housing 9, on cathode sleeve 11 in water inlet end housing 8, flow inlet 12 is set, on cathode sleeve 11 in water side housing 9, water export 13 is set, shaft core position in cathode sleeve 11 installs conductive anode rod 14, the external diameter of conductive anode rod 14 is less than the internal diameter of cathode sleeve 11.nullDuring use,Pulse electromagnetic field is produced by electric current between cathode sleeve 11 and conductive anode rod 14,Sewage is after water inlet end housing 8 enters pulse electromagnetic field sterilizer 3,Flow inlet 12 from cathode sleeve 11 flows to the water export 13 on cathode sleeve 11,Finally flow out pulse electromagnetic field sterilizer 3 from water side housing 9,Sewage is when flowing through cathode sleeve 11 and being internal,The electric field of pulses generation and magnetic field alternating action,Microbial cell membrane permeability in sewage is made to increase,Film-strength weakens,Material outflow in film,The outer material of film penetrates into,Cause organic matter thalline dead,Electromagnetic field produces ionization,Normal bio chemical reaction and the metabolism of organic matter cell membrane are blocked,Organic matter bacterium substance in vivo is made to change,Ring-type、Polycyclic、Backbone is broken as short chain or even unimolecule structure,Photocatalyst sterilization device 5 for next stage provides excellent running environment,Dividing plate 10 forms obstruct between water inlet end housing 8 and water side housing 9,Prevent sewage from flowing directly out pulse electromagnetic field sterilizer 3 in the case of processing without pulse electromagnetic field.This structure can force whole sewage all to pass through between pulse electromagnetic field, and this structure is easy to arrange multiple water stream channel in pulse electromagnetic field sterilizer 3, many group cathode sleeves 11 and conductive anode rod 14 are i.e. installed in pulse electromagnetic field sterilizer 3, the dispersion that so can realize sewage processes, and sterilization effect is more preferably.In addition, described pulse electromagnetic field sterilizer 3 of the present invention also can use other various structures, such as cathode sleeve can be set in inner walls, conductive anode rod etc. is installed in cathode sleeve, but these structures are all difficult to ensure that when processing sewage whole sewage is all by electromagnetic field effect, also the dispersion that cannot realize sewage processes, it is difficult to reach the sterilization effect of preferred version.
The preferred structure of electrolysis flow straightener 6 of the present invention is: described electrolysis flow straightener 6 includes flow straightener housing 17, flow straightener housing 17 lower sidewall arranges water inlet 18 and sewage draining exit 19, flow straightener housing 17 side wall upper part arranges outlet pipe 7, flow straightener housing 17 top arranges top cover 20, installing electrode column 21 on top cover 20, electrode column 21 end is positioned at flow straightener housing 17 bottom.This structure uses overflow-type water outlet, and after can making electrolytic sewage, the organic matter of residual forms precipitation, can again rise with current and be electrolysed by the electrode column 21 on flow straightener housing 17 top after organic matter precipitation, ensures that wastewater purifying efficiency is excellent, stable.
The housing of Photocatalyst sterilization device 5 of the present invention and the water inlet end housing 8 of pulse electromagnetic field sterilizer 3 and water side housing 9 all preferably employ horizontal type shell, ultraviolet lamp tube 15, photocatalysis rod 16, cathode sleeve 11 and the equal horizontal positioned of conductive anode rod 14, this structure drainage flow resistance is minimum, and equipment cost is minimum.But when the present invention is for the sewage disposal high to salt content, owing to sewage vertical direction concentration difference is bigger, the processing equipment of horizontal type shell and horizontal positioned easily causes the situation that levels sewage disposal is uneven, the phenomenon that electrode burns partially also can be caused when vertical direction concentration difference is excessive, therefore when the sewage disposal high to salt content, the housing of Photocatalyst sterilization device 5 and the water inlet end housing 8 of pulse electromagnetic field sterilizer 3 and water side housing 9 need to use upright shell, simultaneously by ultraviolet lamp tube 15, photocatalysis rod 16, cathode sleeve 11 and conductive anode rod 14 are all vertically arranged, with the negative effect overcoming sewage vertical direction concentration difference to bring, but the flow resistance of equipment cost and sewage can rise therewith.
The present invention is that automatically controlled part and the periphery miscellaneous equipment of the present invention are caused electromagnetic pollution by the magnetic field preventing the outside diffusion of magnetic sleeve pipe 4, can arrange magnetic shield cover 22 at magnetic sleeve pipe 4 periphery wall.

Claims (4)

1. electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant, it is characterized in that: include base (1), water pipe (2) it is installed on base (1), water inlet pipe (2) connects with pulse electromagnetic field sterilizer (3), the tube wall periphery of water inlet pipe (2) arranges magnetic sleeve pipe (4), pulse electromagnetic field sterilizer (3) connects with Photocatalyst sterilization device (5), ultraviolet lamp tube (15) and photocatalysis rod (16) are installed in Photocatalyst sterilization device (5), Photocatalyst sterilization device (5) connects with electrolysis flow straightener (6), and electrolysis flow straightener (6) arranges outlet pipe (7);Described pulse electromagnetic field sterilizer (3) includes water inlet end housing (8) and water side housing (9), dividing plate (10) is set between water inlet end housing (8) and water side housing (9), cathode sleeve (11) is installed on dividing plate (10), cathode sleeve (11) two ends lay respectively in water inlet end housing (8) and water side housing (9), on cathode sleeve (11) in water inlet end housing (8), flow inlet (12) is set, on cathode sleeve (11) in water side housing (9), water export (13) is set, shaft core position in cathode sleeve (11) installs conductive anode rod (14), the external diameter of conductive anode rod (14) is less than the internal diameter of cathode sleeve (11);Described electrolysis flow straightener (6) includes flow straightener housing (17), flow straightener housing (17) lower sidewall arranges water inlet (18) and sewage draining exit (19), flow straightener housing (17) side wall upper part arranges outlet pipe (7), flow straightener housing (17) top arranges top cover (20), installing electrode column (21) on top cover (20), electrode column (21) end is positioned at flow straightener housing (17) bottom.
Electromagnetism the most according to claim 1 catalysis oxidation oil-field flooding and sewage-treatment plant, it is characterized in that: the housing of described Photocatalyst sterilization device (5) is Horizontal tubular housing, ultraviolet lamp tube (15) and photocatalysis rod (16) all horizontal positioned in the housing of Photocatalyst sterilization device (5).
Electromagnetism the most according to claim 1 catalysis oxidation oil-field flooding and sewage-treatment plant, it is characterized in that: the water inlet end housing (8) of described pulse electromagnetic field sterilizer (3) and water side housing (9) are Horizontal tubular housing, cathode sleeve (11) and conductive anode rod (14) all horizontal positioned.
Electromagnetism the most according to claim 1 catalysis oxidation oil-field flooding and sewage-treatment plant, it is characterised in that: magnetic sleeve pipe (4) periphery wall arranges magnetic shield cover (22).
CN201410600646.3A 2014-10-31 2014-10-31 Electromagnetism catalysis oxidation oil-field flooding and sewage-treatment plant Active CN104291512B (en)

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Publication number Priority date Publication date Assignee Title
CN106186504A (en) * 2016-07-28 2016-12-07 大庆凯浮化工产品销售有限公司 The method of compound physical formula sewage sterilization
CN106986509A (en) * 2017-05-26 2017-07-28 佛山市恒芯磁能科技有限公司 A kind of industrial circulating water producing unit and its production method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1741677A1 (en) * 2005-07-06 2007-01-10 Hartmut Schulte Method and device for treating water
CN101033105A (en) * 2007-02-01 2007-09-12 彭云龙 Photoelectromagnetism integrated waste water advanced oxidization method and device thereof
CN101381131A (en) * 2008-10-16 2009-03-11 汪孟金 Sweep frequency electromagnetic field generator
CN103626267A (en) * 2012-08-27 2014-03-12 广州昭合环保科技有限公司 Water purification treatment method for removing microbe
CN104197423A (en) * 2014-08-25 2014-12-10 山东润泰智能电气有限公司 Photo-electromagnetic-ion high-voltage electrostatic air cleaner and cleaning method thereof
CN204162562U (en) * 2014-10-31 2015-02-18 李伟东 The oil-field flooding of electromagnetism catalyzed oxidation and waste disposal plant

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1741677A1 (en) * 2005-07-06 2007-01-10 Hartmut Schulte Method and device for treating water
CN101033105A (en) * 2007-02-01 2007-09-12 彭云龙 Photoelectromagnetism integrated waste water advanced oxidization method and device thereof
CN101381131A (en) * 2008-10-16 2009-03-11 汪孟金 Sweep frequency electromagnetic field generator
CN103626267A (en) * 2012-08-27 2014-03-12 广州昭合环保科技有限公司 Water purification treatment method for removing microbe
CN104197423A (en) * 2014-08-25 2014-12-10 山东润泰智能电气有限公司 Photo-electromagnetic-ion high-voltage electrostatic air cleaner and cleaning method thereof
CN204162562U (en) * 2014-10-31 2015-02-18 李伟东 The oil-field flooding of electromagnetism catalyzed oxidation and waste disposal plant

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