CN104278289B - Electrolysis electrode equipment and the electrolytic water generating device for possessing the electrolysis electrode equipment - Google Patents
Electrolysis electrode equipment and the electrolytic water generating device for possessing the electrolysis electrode equipment Download PDFInfo
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- CN104278289B CN104278289B CN201410283359.4A CN201410283359A CN104278289B CN 104278289 B CN104278289 B CN 104278289B CN 201410283359 A CN201410283359 A CN 201410283359A CN 104278289 B CN104278289 B CN 104278289B
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Abstract
Electrolysis electrode equipment is provided and possesses the electrolytic water generating device of the electrolysis electrode equipment.Electrolysis electrode equipment (10) is configured to so that mode of the conductive film (13) between adjacent electrode (11,14) is laminated and conductive film (13) is contacted with least a portion at the interface (27A, 27B) of electrode (11,14) with water, electrolysis processing is carried out to the water supplied from receiving surface (1A), the water after carrying out the electrolysis processing is sent out from the receiving surface (1A).And, in the state of from stacked direction (Z) between conductive film (13) and the conductive film (13) and electrode (11,14) at equitant region (R) place of electrode (11,14), formed with water flowing road (14d, 13d).
Description
Technical field
The present invention relates to a kind of electrolysis electrode equipment and possesses the electrolytic water generating device of the electrolysis electrode equipment.
Background technology
In the past, as electrolytic water generating device, it is known that following device：As Japanese Unexamined Patent Publication 2000-169989 publications are (following
Be expressed as patent document 1) it is disclosed as, there is the electrolysis electrode equipment being made of anode, conductive film and cathode, profit
Ozone Water (electrolysis water) is obtained with electrolysis electrode equipment generation ozone (electrolytically generated thing).
In the patent document 1, by by the anode electrode being made of platinum woven wire, be used as the ion of conductive film
Exchange membrane, the cathode electrode of woven wire are wrapped on cylindric axis body to form electrolysis electrode equipment successively.Then, along circle
The axial water flowing of column axis body, thus comes in the boundary of anode electrode and amberplex generation ozone (electrolytically generated thing)
To Ozone Water (electrolysis water).
The content of the invention
Inventors above-mentioned amberplex (conductive film) is attentively studied repeatedly as a result, specify that ion exchange
Film (conductive film) is according to its moisture content and the resistance of film, i.e. electric conductivity change.
Moreover, under water flowing A-stage, not by water flowing in usual electrolysis electrode equipment.
Thus, there are following worry：Within the specified time limit after water flowing starts, with the change of the moisture content of conductive film
Dynamic, the conductivity of conductive film changes.As a result, action initial stage for example there is be difficult to generate Ozone Water (electrolysis water) or
The concentration of person's ozone (electrolytically generated thing) becomes unstable worry, and the generative capacity of ozone (electrolytically generated thing) is possible to produce
Raw deviation.In this way, in above-mentioned conventional technology, the concentration of electrolytically generated thing can not rapidly be controlled.
The present invention is used to solve above-mentioned conventional problem, and its object is to obtain more quickly controlling electrolytically generated thing
Concentration electrolysis electrode equipment and possess the electrolytic water generating device of the electrolysis electrode equipment.
In order to solve upper above-mentioned conventional problem, electrolysis electrode equipment of the invention is configured to so that conductive film is between adjacent
Electrode between mode be laminated and above-mentioned conductive film is contacted with least a portion at the interface of above-mentioned electrode with water, it is right
Electrolysis processing is carried out from the water of receiving surface supply, the water after carrying out the electrolysis processing is sent out from the receiving surface.Moreover, from stacking
Above-mentioned conductive film and the above-mentioned conductive film at the equitant region of above-mentioned electrode and above-mentioned electrode in the state of the observation of direction
Between, formed with water flowing road.
Thus, when supplying water to electrolysis electrode equipment, conductive film can be easily supplied into by water flowing road Jiang Shui,
Conductive film can be made more quickly to become moisture state.Concentration as a result, it is possible to make electrolytically generated thing more quickly becomes
Stable state.
Brief description of the drawings
Fig. 1 is the sectional view for schematically showing the electrolytic water generating device involved by an embodiment of the invention.
Fig. 2 is schematically shown in the pipe arrangement of the electrolytic water generating device involved by an embodiment of the invention
The sectional view of the streamline of water.
Fig. 3 is the decomposition of the electrolysis electrode equipment in the electrolytic water generating device involved by an embodiment of the invention
Stereogram.
Fig. 4 is the variation for schematically showing the electrolytic water generating device involved by an embodiment of the invention
Sectional view.
Fig. 5 is plate-like cathodes, conductive film, plate-shaped anode and the electrode for representing the electrolytic water generating device shown in Fig. 4
The top view of pallet.
Fig. 6 is the figure for schematically showing the plate-like cathodes involved by an embodiment of the invention, and (a) is to overlook
Figure, (b) is front view.
Fig. 7 is the front view in the C portions that amplification shows Fig. 6 (b).
Fig. 8 is the figure for schematically showing the electrolysis electrode equipment involved by an embodiment of the invention, is to represent
Electrolysis electrode equipment is not by the stereogram of the state of water flowing.
Fig. 9 is the figure for schematically showing the electrolysis electrode equipment involved by an embodiment of the invention, is to represent
Electrolysis electrode equipment is by the stereogram of the state of abundant water flowing.
Figure 10 is the variation for schematically showing the electrolysis electrode equipment involved by an embodiment of the invention
Figure, is to represent electrolysis electrode equipment not by the stereogram of the state of water flowing.
Figure 11 is the variation for schematically showing the electrolysis electrode equipment involved by an embodiment of the invention
Figure, is to represent electrolysis electrode equipment by the stereogram of the state of abundant water flowing.
Embodiment
Embodiments of the present invention are a kind of electrolysis electrode equipment, be configured to so that conductive film between adjacent electrode it
Between mode be laminated and above-mentioned conductive film is contacted with least a portion at the interface of above-mentioned electrode with water, to from receiving surface
The water of supply carries out electrolysis processing, sends out the water carried out after the electrolysis processing from the receiving surface, and the electrolysis electrode equipment is from layer
Above-mentioned conductive film and the above-mentioned conductive film at the equitant region of above-mentioned electrode and above-mentioned electricity in the state of folded direction observation
Between pole, formed with water flowing road.
Electrolysis electrode equipment thereby, it is possible to the concentration for obtaining more quickly controlling electrolytically generated thing.
In addition, the above-mentioned water flowing road of above-mentioned electrolysis electrode equipment is formed at above-mentioned electrode side.
Thereby, it is possible to suppress the shape distortion on water flowing road, electrolysis performance can be maintained to longer-term.
In addition, the above-mentioned water flowing road of above-mentioned electrolysis electrode equipment is formed at above-mentioned conductive film side.
Thus, water flowing road is formed at conductive film in itself, therefore just can without being processed to other components such as electrode
Obtain the electrolysis electrode equipment with water flowing road.
In addition, above-mentioned conductive film has touching for seamed edge (edge) shape with above-mentioned water flowing road in above-mentioned electrolysis electrode equipment
Point.
Thereby, it is possible to conductive film is more reliably contacted with electrode.
In addition, the above-mentioned conductive film and above-mentioned electrode of above-mentioned electrolysis electrode equipment are configured to load and unload.
Thereby, it is possible to more easily carry out the maintenance of conductive film, electrode.
In addition, the electrolytic water generating device of embodiments of the present invention possesses：Above-mentioned electrolysis electrode equipment；And pipe arrangement,
Its flow path formed with the water for supplying the object handled by above-mentioned electrolysis electrode equipment as electrolysis, above-mentioned electrolysis electrode are set
It is standby to be embedded in the pipe arrangement.
Electrolysis thereby, it is possible to the electrolysis electrode equipment for obtaining possessing the concentration that can more quickly control electrolytically generated thing
Water generating device.
In addition, in above-mentioned electrolytic water generating device, so that above-mentioned water flowing curb and the water of the flowing water in above-mentioned flow path
The above-mentioned electrolysis electrode equipment of mode of roughly the same direction extension in stream direction is embedded in above-mentioned pipe arrangement.
Thereby, it is possible to more quickly make the resistance stabilization of conductive film, it can more quickly make the concentration of electrolytically generated thing
Stablize.
In the following, embodiments of the present invention are described in detail with reference to the attached drawings.In the following, as electrolytic water generating device, illustrate
The ozone water generating device of Ozone Water is generated by producing ozone (electrolytically generated thing) and the ozone is dissolved into water.This
Outside, Ozone Water decomposes sterilization, organic matter effective, therefore is used in water treatment field and food, medical domain extensively, has nothing
Residual, do not generate the advantages of secondary product is so.In addition, the extending direction of flow path is set to water (flow) direction (anteroposterior direction) X,
The width of flow path is set to width Y, the direction that electrode, conductive film are laminated is set to stacked direction (upper and lower
To) Z, to illustrate.
In addition, following embodiment and its variation include same structural element.Therefore, it is same to these below
Structural element adds common mark, and the repetitive description thereof will be omitted.
As shown in Figure 1, the ozone water generating device (electrolytic water generating device) 100 involved by present embodiment possesses electrolysis
Electrode equipment 1, pipe arrangement 2, power supply unit 3 and control unit 30.100 pairs of water of ozone water generating device (electrolytic water generating device) into
Row causes the electrolysis of electrochemical reaction to handle, to generate the Ozone Water (electrolysis water) for having dissolved ozone (electrolytically generated thing).
In ozone water generating device (electrolytic water generating device) 100, water with pipe portion 21 and water from by flowing into side line portion 22
The opening 2a of the pipe arrangement 2 of formation is flowed into.Then, flowed from the opening 2a of pipe arrangement 2 water flowed into along streamline as shown in Figure 2, quilt
Electrolysis electrode equipment 1 carries out electrolysis processing.Then, processed water is electrolysed from by with pipe portion 21 and water by electrolysis electrode equipment 1
Flow out the opening 2b outflows for the pipe arrangement 2 that side line portion 23 is formed.
As shown in Figure 1, form the electricity by being laminated by the order of plate-shaped anode 11, conductive film 13, plate-like cathodes 14
Solve electrode equipment 1.In this way, in the present embodiment, electrolysis electrode equipment 1 so that conductive film 13 between adjacent electrode (plate
Shape anode 11 and plate-like cathodes 14) between mode be laminated.
Also, in the present embodiment, electrolysis electrode equipment 1 is configured to conductive film 13 and the interface of plate-shaped anode 11
At least a portion is contacted with water.In the configuration example shown in Fig. 1, side 13b and plate-like cathodes by conductive film 13 are formd
14 side 14b becomes side 28a and becomes the groove portion 28 of bottom 28b by upper surface (surface) 11a of plate-shaped anode 11.Should
Groove portion 28 is formed as the substantially rectangular parallelepiped of 14 side of plate-like cathodes (being in Fig. 1 the top of above-below direction Z) opening (with reference to figure
3).By forming this groove portion 28 so that the plate-shaped anode 11 for being configured at the lower part of groove portion 28 can be with water contact free.
In addition, as long as groove portion 28 at least forms one, in the present embodiment, multiple groove portions 28 are formed as one
Row.
By forming this groove portion 28, interface (conductive film and the electrode of conductive film 13 and plate-shaped anode 11 can be made
Interface) at least a portion of 27A is exposed to groove portion 28.In addition, conductive film 13 and the interface (conductive film of plate-like cathodes 14
With the interface of electrode) at least a portion of 27B can also be exposed to groove portion 28.
In this way, in the present embodiment so that at least a portion of the conductive film 13 and interface 27A of plate-shaped anode 11 with
Water contacts and conductive film 13 forms electrolysis with the mode that at least a portion of the interface 27B of plate-like cathodes 14 is contacted with water
Electrode equipment 1.In addition, the conductive film 13 and the interface 27A of plate-shaped anode 11 in present embodiment refer to conductive film 13
The intersection of side 13b and upper surface (surface) 11a of plate-shaped anode 11.In addition, conductive film 13 and plate in present embodiment
The interface 27B of shape cathode 14 refers to the boundary line of the side 14b of plate-like cathodes 14 and the side 13b of conductive film 13.
In addition, the interface contacted with water is not limited to above-mentioned interface, as long as being configured to plate-shaped anode 11 and conductive film
13 interface and plate-like cathodes 14 are contacted with least a portion of any one in the interface of conductive film 13 with water.
In addition, conductive film 13 both can be that formed objects can not also be same with plate-like cathodes 14, but at least need to make
Connected between mutual slit (sheet limbers 13a and limbers 14a), and be necessary to ensure that enough electrical-contact areas.Cause
This, it is contemplated that these situations, preferably conductive film 13 and plate-like cathodes 14 are roughly the same projection size (from stacking
It is roughly the same size in the state of direction Z observations).
In addition, plate-shaped anode 11 both can be that the size identical with conductive film 13, plate-like cathodes 14 can not also be same, but
It is the size preferably when from stacked direction Z more than the degree that all groove portions 28 can be seen.
Moreover, electrolysis electrode equipment 1 is so that the spread configuration direction of multiple groove portions 28 and shape roughly the same anteroposterior direction X
State is embedded into pipe arrangement 2.
In addition, electrolysis electrode equipment 1 is from the water of the receiving surface 1A of water supply to carrying out electrolysis processing, and from the receiving surface
1A sends out the water after having carried out electrolysis processing.At this time, ozone is contained in the water after electrolysis processing, as shown in Fig. 2, this contains ozone
Water when being sent from receiving surface 1A towards water outflow side 2B flow.In addition, the ozone generated is sent from receiving surface 1A
Go out and be dissolved into during being flowed towards water outflow side 2B in water.
Electrolysis electrode equipment 1 receives the ion supply from conductive film 13 and the electric current from power supply unit 3, in tabular sun
The electrolysis for carrying out electrochemically generating ozone at the pole 11 and interface 27A of conductive film 13 is handled.The electrochemical reaction
It is as follows.
Anode-side：3H2O→O3+6H++6e-
2H20→O2+4H++4e-
Cathode side：2H++2e-→H2
Can be by forming conductive gold on the conductive board of width 10mm, the length 50mm formed using niobium or so
Hard rock film, to form plate-shaped anode 11.The conductive diamond film has boron doped conductive.Conductive diamond film is to utilize
Ionomer cvd (chemical vapor deposition：Chemical vapor deposition) method is formed at conduction with 3 μm or so of thickness
On property substrate.In addition, in the present embodiment, the shape of plate-shaped anode 11 and plate-like cathodes 14 is set to tabular, but plate
Shape anode 11, plate-like cathodes 14 can also be membranaceous, mesh-shape, wire.
Conductive film 13 is configured in the plate-shaped anode 11 formed with conductive diamond film.The conductive film 13 is proton
The amberplex of conductivity type, has 100~200 μm or so of thickness.Moreover, on the conductive film 13, as shown in figure 3,
Multiple sheet limbers 13a formed with through-thickness (Z-direction) perforation.In the present embodiment, by each sheet limbers
13a is set to the same shape.In addition, multiple sheet limbers 13a are configured to a row.In addition, the shape of sheet limbers 13a and
Arrangement can also be other manner.
Plate-like cathodes 14 are configured on conductive film 13.Plate-like cathodes 14 are the stainless steel of 1mm or so for example by thickness
Electrode plate is formed.In the plate-like cathodes 14, as shown in figure 3, multiple limbers 14a formed with through-thickness perforation.Should
Limbers 14a has and the same or similar opening shapes of sheet limbers 13a.In addition, limbers 14a with sheet limbers
13a's arranges identical spacing along the direction spread configuration identical with the arrangement of sheet limbers 13a.
Moreover, electrolysis electrode equipment 1 is configured to for conductive film 13 to be placed at the conductive gold to form a film in plate-shaped anode 11
On hard rock film, plate-like cathodes 14 are placed on conductive film 13.
At this time, plate-like cathodes 14 so that the states that are connected with sheet limbers 13a of limbers 14a (by limbers 14a and piece
Shape limbers 13a forms the state of groove portion 28) it is placed on conductive film 13.Thus, electrolysis electrode equipment 1 can by water from
The surface of plate-like cathodes 14 is received in limbers 14a and sheet limbers 13a.In addition, electrolysis electrode equipment 1 will can contain
In sheet limbers, the water for the ozone that the interface of the end of 13a and plate-shaped anode 11 produces is from limbers 14a and sheet water flowing
Hole 13a is sent out.That is, the upper surface of limbers 14a is receiving surface 1A, and electrolysis electrode equipment 1 receives water from receiving surface 1A and send
Go out.
Pipe arrangement 2 is used for the water as the object of electrolysis processing to the supply of electrolysis electrode equipment 1, which forms to have and supply
Water supply line (flow path) P of opening 2a, 2b of feedwater.In the present embodiment, pipe arrangement 2 is by non-conductive using acrylic acid series etc.
The component of the resin of property is formed.In addition, pipe arrangement 2 outer circumferential surface side formed with the width identical with plate-shaped anode 11
Shell portion (opening) 15b of 10mm, length 50mm or so.
Also, pipe arrangement 2 has the opening 2c for being used for accommodating electrolysis electrode equipment 1.Opening 2c flows into side line portion by water
22 and water outflow side line portion 23 formed.Moreover, the water in pipe arrangement 2 is flowed between side line portion 22 and water outflow side line portion 23
Accommodate electrolysis electrode equipment 1.
In addition, pipe arrangement 2 is configured to enable to form the receiving surface 1A that the inner wall of opening 2c includes electrolysis electrode equipment 1.
In present embodiment, electrolysis electrode equipment 1 is so that the upper surface of plate-like cathodes 14 becomes and water inflow side 2A and water outflow side 2B
The mode of the water inner wall substantially the same face that flows into side line portion 22 and water outflow side line portion 23 be embedded in pipe arrangement 2.
In this way, in the present embodiment, pipe arrangement 2 is configured to the receiving surface 1A of electrolysis electrode equipment 1 being embedded into by current
Enter the opening 2c that side line portion 22 and water outflow side line portion 23 are formed.Thus, formed by the receiving surface 1A of electrolysis electrode equipment 1
The part in the face for forming flow path P of pipe arrangement 2.At this time, flow path (water supply stream of the groove portion 28 towards the flowing water in pipe arrangement 2
Road P) opening.
In addition, in the present embodiment, electrolysis electrode equipment 1 is in a manner of making the inner wall that receiving surface 1A is contained in pipe arrangement 2
Fixed by housing 15.The housing 15 is used to accommodate electrolysis electrode equipment 1, by the structure using dielectric resins such as acrylic acid series
Part is formed.
As shown in Figure 1, formed with shell portion (opening) 15b in housing 15, and formed with flange part 15a, with the flange
Formed with seal groove 26 on pipe arrangement face opposite portion 15a.Moreover, seal 25 is provided with seal groove 26.Moreover, using tightly
Firmware 16 fastens flange part 15a and pipe arrangement 2, and thus housing 15 is installed in pipe arrangement 2.
In the present embodiment, by forming this structure, to be configured to handling conductive film 13 and electrode (tabular
Anode 11, plate-like cathodes 14).
Power supply unit 3 is used to make to produce potential difference across conductive film 13 between plate-shaped anode 11 and plate-like cathodes 14.Tabular
Anode 11 via conducting wire 31 be electrically connected to the power supply unit 3+side, plate-like cathodes 14 via conducting wire 32 be electrically connected to power supply unit 3-
Side.Also, power supply unit 3 is electrically connected to control unit 30 via distribution H, enabling passes through the 30 Switching power portion 3 of control unit
On-off changes output.
By forming this structure, as shown in Figure 1, electrolytic water generating device 100 is formed as：The pipe arrangement 2 of water inflow side 2A
Sectional area A1 it is roughly the same with the sectional area A2 of the pipe arrangement 2 of the receiving surface 1A comprising electrolysis electrode equipment 1 of water inflow side 2A.
Similarly, electrolytic water generating device 100 is formed as：The sectional area A4 of pipe arrangement 2 of water outflow side 2B and including for water outflow side 2B
The sectional area A3 of the pipe arrangement 2 of the receiving surface 1A of electrolysis electrode equipment 1 is roughly the same.That is, it is formed as follows electrolysis water generation
Device 100：From the internal face of the water inflow side 2A at the setting unit of electrolysis electrode equipment 1 to the setting unit of electrolysis electrode equipment 1
The internal face of the water outflow side 2B at place, it is roughly the same with the sectional area that water supply line is orthogonal.
It is further possible to form electrolytic water generating device 100A as shown in Figure 4.
Electrolytic water generating device 100A substantially have with 100 same structure of electrolytic water generating device, but
On this point of not forming opening 2c in pipe arrangement 2 is different from electrolytic water generating device 100.
Specifically, the recess 2d of 1 storage of electrolysis electrode equipment is provided with pipe arrangement 2, electrolysis electrode equipment 1 is stored
Into recess 2d.That is, electrolysis electrode equipment 1 is inserted into pipe arrangement 2 and is received into recess by opening 2a, opening 2b from pipe arrangement 2
In 2d.
In addition, the electrolysis electrode equipment 1 being received in the pipe arrangement 2 of electrolytic water generating device 100A is across acrylic acid series tree
The electrode pallet 15A of fat is received in recess 2d (with reference to Fig. 4).In addition, as shown in figure 5, electrode pallet 15A be formed as with
Plate-shaped anode 11, plate-like cathodes 14 and the roughly the same rectangular plate-like of 13 shape of conductive film, in the upper of electrode pallet 15A
Portion, is laminated by the order of plate-shaped anode 11, conductive film 13, plate-like cathodes 14.Formed with utilization on electrode pallet 15A
Screw hole (not shown) of the fastening screw when fixed plate-shaped anode 11, plate-like cathodes 14 and conductive film 13.Also, electrode
Pallet 15A has the function of to strengthen due to stress and curved to avoid plate-shaped anode 11, plate-like cathodes 14, conductive film 13.
In addition, in Fig. 4, exemplified with the situation that conducting wire 31 is connected to plate-shaped anode 11, but can also be configured to as
Lower structure：Electrode pallet 15A is formed using conductive material, and conducting wire 31 is set in electrode pallet 15A, makes electrode pallet
15A integrally becomes power supply body, thus powers to plate-shaped anode 11.
In addition, the method on plate-shaped anode 11, plate-like cathodes 14 and conductive film 13 are attached, except screw
In addition, it is also contemplated that using spring, pressing fixture etc., as long as meeting with electricity/physics mode reliably by conductive film 13 and plate
Shape anode 11 and plate-like cathodes 14 are attached and plate-shaped anode 11 is not short-circuit with plate-like cathodes 14, are not limited to above-mentioned
Means.
Preferably, the electrolysis electrode equipment 1 is stored in a manner of receiving surface 1A is embedded in the inner wall of pipe arrangement 2.Separately
Outside, it is preferred that be configured to handling conductive film 13 and electrode (plate-shaped anode 11, plate-like cathodes 14).
Then, action, the effect of electrolytic water generating device 100,100A for being configured to the structure are illustrated.
First, in order to supply water to electrolysis electrode equipment 1, supply water from the opening 2a of pipe arrangement 2 to pipe arrangement 2.
Then, the water inflow side 2A for being fed into water from the water inflow side line portion 22 of electrolysis electrode equipment 1 is flowed into electricity
The receiving surface 1A of electrode equipment 1 is solved, groove portion 28 is flowed into from receiving surface 1A.Then, via the electrolysis electrode equipment 1 of generation ozone
Surface (conductive film 13 in groove portion 28 and the interface 27A of plate-shaped anode 11) flowed from the receiving surface 1A of electrolysis electrode equipment 1
Go out.Then, from the water that the receiving surface 1A of electrolysis electrode equipment 1 flows out via water outflow side line portion 23 water outflow side 2B from
The opening 2b of pipe 2 is discharged.
When making power supply unit 3 under the state (utilizing supplied water to make 1 water-immersed state of electrolysis electrode equipment)
Connect come when utilizing the power supply unit 3 to apply voltage between the plate-shaped anode 11 and plate-like cathodes 14 of electrolysis electrode equipment 1, in tabular
Between anode 11 and plate-like cathodes 14 potential difference is produced across conductive film 13.In this way, by making plate-shaped anode 11 cloudy with tabular
Potential difference is produced between pole 14, plate-shaped anode 11, conductive film 13 and plate-like cathodes 14 are powered, in electrolysis electrode equipment 1
Electrolysis processing is carried out in water in sheet limbers 13a and limbers 14a, in conductive film 13 and the interface of plate-shaped anode 11
27A nearby produces ozone.
The voltage applied at this time is several~tens volts of volts, and the yield of voltage higher (current value is higher) then ozone is bigger.
Then, the ozone that is produced near the interface 27A of conductive film 13 and plate-shaped anode 11 is while flowing with dampening
And the downstream of flow path P is transported to while being dissolved into water.Dissolved ozone is generated by making ozone be dissolved into water like this
Water (Ozone Water).
In addition, inventors attentively studying to above-mentioned conductive film 13 as a result, specify that conductive film 13 repeatedly
According to its moisture content, the resistance of film, i.e. electric conductivity change.
Moreover, under water flowing A-stage, not by water flowing in usual electrolysis electrode equipment.
Thus, there are following worry：Within the specified time limit after water flowing starts, with the change of the moisture content of conductive film 13
It is dynamic and the conductivity of conductive film 13 changes.As a result, at action initial stage, for example there is be difficult to generate Ozone Water (electrolysis
Water) or the concentration of ozone (electrolytically generated thing) become unstable worry, the generative capacity of ozone (electrolytically generated thing) has can
It can produce deviation.In this way, in conventional structure, the concentration of ozone (electrolytically generated thing) can not rapidly be controlled.
Therefore, in the present embodiment, enabling more quickly control the ozone (electricity generated by electrolysis electrode equipment 1
Solution product) concentration (be controlled such that quickly generation as defined in concentration dissolved ozone water).
Specifically, conductive film 13 overlaps with plate-like cathodes (electrode) 14 in the state of from stacked direction Z
Region R at conductive film 13 and plate-like cathodes (electrode) 14 between, formed with water flowing road 14d.
In the present embodiment, as shown in figure 8, mutually opposing conductive film 13 upper surface 13c and plate-like cathodes
In the lower surface 14c of (electrode) 14, plate-like cathodes (electrode) 14 lower surface 14c (electrode side) form water flowing road 14d.It is logical
Cross and form water flowing road 14d in the lower surface 14c (electrode side) of plate-like cathodes (electrode) 14 like this, water flowing road 14d can be suppressed
Shape distortion, so as to longer-term maintain electrolysis performance.
In the present embodiment, conductive film 13 and plate-like cathodes (electrode) 14 in the state of from stacked direction Z
Lower surface 14c Formation cross-sections substantially U-shaped and linear groove at equitant region R, and it is layered in conductive film 13
On, it is consequently formed section substantially U-shaped and linear water flowing road 14d.Water flowing road 14d is equal for a side side and the opposing party side
The access of opening, in the width direction Y be disposed with multiple.
Also, in the present embodiment, as shown in Figure 6 and Figure 7, water flowing road 14d is formed at plate-like cathodes (electrode) 14
The outer rim 14e and position 14f across groove portion 28 and groove portion 28.
By forming water flowing road 14d like this, following structure is formed：Electric conductivity in the state of from stacked direction Z
Film 13 and 14 equitant region R of plate-like cathodes (electrode) possesses small bumps.
In addition it is also possible to as shown in Figure 10, in the upper surface 13c and plate-like cathodes of mutually opposing conductive film 13
In the lower surface 14c of (electrode) 14, conductive film 13 upper surface 13c (conductive film side) forms water flowing road 13d.If picture
Water flowing road 13d so is formed in the upper surface 13c (conductive film side) of conductive film 13, then water flowing road 13d is formed at electric conductivity
Film 13 itself, therefore without being processed the electrolysis electrode equipment 1 that can just obtain that there is water flowing road to other components such as electrode.
That is, by using the conductive film 13 formed with water flowing road 13d, the electrolysis electrode equipment with water flowing road can be readily derived
1。
In addition, also can be in the upper surface 13c of mutually opposing conductive film 13 and the following table of plate-like cathodes (electrode) 14
14c this two side in face forms water flowing road.At this time it is also possible to the water flowing road on the water flowing road of conductive film side and electrode side is configured to
Both ends overlap.That is, can also be formed by the water flowing road of conductive film side and the water flowing road of electrode side generally cylindrical logical
Water route.Alternatively, it is also possible to which the water flowing road on the water flowing road of conductive film side and electrode side is configured to what is staggered in the direction of the width
State.At this time, both can be a part of overlapping in the state of from stacked direction Z, can not also be overlapping.
Moreover, electrolysis electrode equipment 1 is with water flowing road 14d edges and the water (flow) direction (front and back of the flowing water in flow path P
To) mode that extends of roughly the same directions of X is embedded in pipe arrangement 2.
By forming the structure, when supplying water to electrolysis electrode equipment 1, water flowing road 14d, water flowing road can be passed through
Water is easily supplied into conductive film 13 by 13d, so as to make conductive film 13 more quickly become moisture state.
It is as discussed above, in the present embodiment, the conductive film 13 in the state of from stacked direction Z
Between the conductive film 13 at 14 equitant region R of plate-like cathodes (electrode) and plate-like cathodes (electrode) 14, formed with logical
Water route 14d, water flowing road 13d.
Thus, when supplying water to electrolysis electrode equipment 1, the water capacity can be changed places by water flowing road 14d, water flowing road 13d
Conductive film 13 is supplied to, so as to make conductive film 13 more quickly become moisture state.As a result, it is possible to make ozone
The concentration of (electrolytically generated thing) more quickly becomes stable state.
In addition, in the case where conductive film 13 is changed into the state of enough moistenings, as shown in Fig. 9, Figure 11, conductive film 13
Absorb water and expand, the conductive film 13 after expansion enters water flowing road 14d, water flowing road 13d, and water flowing road 14d, water flowing road 13d narrow
Or block.
Moreover, in the case where water flowing road 14d, water flowing road 13d narrow or block, become water in water flowing road 14d, water flowing
The state of flowing is not much in the 13d of road.However, in this case, since conductive film 13 has become the shape of enough moistenings
State and resistance is lower, therefore as the readily flowed state of electric current.Thus, need not be from water flowing road 14d, water flowing road 13d
Supply water to conductive film 13.In addition, in the case where conductive film 13 becomes moisture state, plate-like cathodes (electrode) 14 and conduction
The contact area of property film 13 increase water flowing road 14d, water flowing road 13d area amount, therefore more electric current flowings can be made.
As a result, electrolysis efficiency improves and ozone production efficiency raising, the performance of device can be made more stable.
Also, by forming water flowing road 14d, water flowing road 13d, can using water flowing road 14d, water flowing road 13d come absorb by
In the conductive film 13 that the swelling of conductive film 13 produces and the position offset of plate-like cathodes (electrode) 14.Thus, for example energy
Enough suppress to cause the area of groove portion 28 to diminish since conductive film 13 spills into groove portion 28.Further, it is possible to suppress due to conduction
Property film 13 it is repeatedly dry and the position offset accumulation that moistens and produce is so as to cause the situation that performance is greatly reduced, so as to more
Chronically maintain electrolysis performance.
In addition, there is the contact 13e of seamed edge shape between conductive film 13 and water flowing road 14d, water flowing road 13d, therefore can
Conductive film 13 is more reliably set to be contacted with plate-like cathodes (electrode) 14 by the contact 13e of seamed edge shape.As a result, with it is only single
The structure for making to contact between plane purely is compared, and conductive film 13 and plate-like cathodes (electrode) 14 can more reliably be made by also having
It is electrically connected the advantages of such.
In this way, the electrolysis electrode equipment 1 involved by present embodiment has lot of advantages, but structure is very simple, therefore
Processing cost can be made cheap.
In addition, as described above, in the case where not forming water flowing road 14d, water flowing road 13d, existing rapidly to control
The problem of concentration of ozone (electrolytically generated thing) processed is such, and in order to avoid this problem, such as be contemplated that in the midway of flow path
Position sets cut-off valve to be released or configure force (forcing) pump etc. to avoid water forcibly to apply hydraulic pressure to form moisture state.
If however, being formed as this structure, there are problems with：Device can be maximized, complicated and expend just current cost, but also
Need largely to operate power cost.In addition, it is also possible to consider apply high voltage to promote electrolysis so that ozone concentration is stablized, still
In this approach, can to moisture content is low and the conductive film 13 of state that resistance is high causes very big damage, as a result as dress
The service life put can shorten.
On the other hand, if being configured to form water flowing road 14d, water flowing road 13d as in the present embodiment, can realize
The reduction of cost, and it is capable of the service life reduction of restraining device.
In addition, usually conductive film 13 is using high molecular polymer as base material, therefore under drying regime and moisture state
Change in size (change in size caused by so-called drying/swelling) can be produced the difference of moisture amount.Moreover, work as
When conductive film 13 produces change in size, plate-shaped anode (electrode) 11, plate-like cathodes (electrode) with no generation change in size
Opposite position offset can be produced between 14, energization area will necessarily change, and the electrolysis ability of device can become unstable.
In this way, in the case where not forming water flowing road 14d, water flowing road 13d, the electrolysis ability there are device becomes unstable
Fixed worry.
On the other hand, if being configured to form water flowing road 14d, water flowing road 13d as in the present embodiment, can utilize
Water flowing road 14d, water flowing road 13d carry out the change in size of the conductive film 13 caused by absorption dehydration/swelling, therefore can make device
Electrolysis ability more stableization.
Additionally, there are following worry：Due to conductive film 13 because drying, moistening and stretch repeatedly, gradually in plate-shaped anode
Poor electric contact is produced between (electrode) 11, plate-like cathodes (electrode) 14 and conductive film 13.Moreover, once produce loose contact
Position, it is necessary to carry out man-hour and the cost of following action etc.：Replace conductive film 13；Or in order to ensure thrust and with spiral shell
The fastening such as silk.In addition, also contemplating for adjusting thrust etc. using other structures, but it can become complicated in structure and cause height
Cost.
In this way, in the case where not forming water flowing road 14d, water flowing road 13d, to expend for suppressing in plate-shaped anode (electricity
Pole) 11, man-hour and the cost of poor electric contact are produced between plate-like cathodes (electrode) 14 and conductive film 13.
On the other hand, can be with more if being configured to form water flowing road 14d, water flowing road 13d as in the present embodiment
The change in size of conductive film 13 caused by simple structure absorption dehydration/swelling suppresses at plate-shaped anode (electrode)
11st, poor electric contact is produced between plate-like cathodes (electrode) 14 and conductive film 13.That is, can obtain expending man-hour and into
Change in size can originally be absorbed or suppress the electrolysis electrode equipment 1 of poor electric contact.
In this way, according to the present embodiment, can obtain be easy and promptly controlling the electrolysis electrode of ozone concentration to set
Standby 1 and possess ozone water generating device (electrolytic water generating device) 100, the 100A of the electrolysis electrode equipment 1.
In addition, according to the present embodiment, so that water flowing road 14d, water flowing road 13d edge and the water of the flowing water in flow path P
Electrolysis electrode equipment 1 is embedded into pipe arrangement 2 by the mode of direction extension roughly the same stream direction (anteroposterior direction) X.
Thus, conductive film 13 and 14 equitant area of plate-like cathodes (electrode) in the state of from stacked direction Z
Between conductive film 13 and plate-like cathodes (electrode) 14 at the R of domain, it can be formed from the upstream side downstream water flowing road 14d of side, logical
Water route 13d.As a result, in the case that the moisture content of the inferior conductive film 13 of A-stage is non-constant, will can also locate
Water more than reason water is supplied to conductive film 13, can quickly make the moisture content of conductive film 13 constant.Thereby, it is possible to more
Promptly make the resistance stabilization of conductive film 13, ozone concentration can be made more quickly to stablize.
In addition, in the present embodiment, conductive film 13, electrode (plate-shaped anode 11, plate-like cathodes 14) are configured to
Handling, therefore can more easily carry out the maintenance of conductive film 13, electrode (plate-shaped anode 11, plate-like cathodes 14).
Particularly, if fixing receiving electrolysis electrode equipment 1 from the outside of pipe arrangement as electrolytic water generating device 100
Housing 15, the then assembling of electrolytic water generating device 100 can become easy, further can easily carry out conductive film 13,
The maintenance of electrode (plate-shaped anode 11, plate-like cathodes 14).
In addition, if the receiving surface 1A of electrolysis electrode equipment 1 is embedded into the inner wall of pipe arrangement 2, then it can reduce electrolysis electricity
Difference in height near pole equipment 1.If so, the water then supplied to electrolysis electrode equipment 1 can be from the water inflow side 2A of pipe arrangement 2
It is flowed into the receiving surface 1A of electrolysis electrode equipment 1 with not having sinuous flow, can makes the current in pipe arrangement 2 with not producing sinuous flow to electrolysis
1 water flowing of electrode equipment, can avoid being detained near the receiving surface 1A of electrolysis electrode equipment 1.Caused by suppressing
Ozone is grown to bubble, improve the ozone concentration of the Ozone Water from water outflow side 2B outflows.
In addition, if it is substantially same that the plate-like cathodes 14 at the receiving surface 1A of electrolysis electrode equipment 1, which are formed as with pipe arrangement 2,
Simultaneously, then the current in pipe arrangement 2 can be made with not producing sinuous flow to 1 water flowing of electrolysis electrode equipment, therefore the stagnant of water can be suppressed
The generation stayed, to further improve ozone concentration.
Also, if pipe arrangement 2 is configured to and water of the water by the sectional area in the vertical direction in direction from water inflow side 2A
Sectional area A1~A4 is roughly the same untill flowing into the water outflow side line portion 23 in side line portion 22 to water outflow side 2B, then can make
Current in pipe arrangement 2 with not producing sinuous flow to 1 water flowing of electrolysis electrode equipment, therefore the generation of the delay of water can be suppressed, into
One step improves ozone concentration.
The preferred embodiment of the present invention is explained above, but the present invention is not limited to the above embodiment, can
Carry out various modifications.
For example, plate-shaped anode 11 for example also can be by electric conductivity silicon, conductive diamond, titanium, platinum, lead oxide, tantalum oxide
Deng composition, as long as the electrode of the conductive and durability of electrolysis water can be generated, it is possible to use any material.Separately
Outside, in the case where plate-shaped anode 11 is set to diamond electrode, its manufacture method is not limited to the manufacture method using film forming.
In addition, substrate also can be formed using the material beyond metal.
In addition, in the above-described embodiment, Ozone Water is generated exemplified with producing ozone and the ozone is dissolved into water
Ozone water generating device, but the material generated is not limited to ozone, such as can also generate hypochlorous acid and be killed to be used in
Bacterium, water process etc..Alternatively, it is also possible to being the device for generating oxygenated water, hydrogeneous water, chlorinated water, aquae hydrogenii dioxidi etc..
In addition, as long as plate-like cathodes 14 possess the electrode of electric conductivity and durability, for example, also can by platinum, titanium,
Stainless steel, electric conductivity silicon etc. are formed.
In addition, in the above-described embodiment, it is arranged to extend along with current substantially common direction exemplified with by water flowing road
Mode, as long as but water flowing road relative to film surface opening and the structure that can pass water through, then can also along with current
Direction (direction that is vertical, having predetermined angular) extension of intersection, can not also be straight line.Alternatively, it is also possible in conductive film
Water flowing road is formed between anode.In addition, the cross sectional shape on water flowing road may not be U-shaped, for example, can also be V shape,
Curve-like, polygon.
In addition, the specification (shape, size, layout etc.) of pipe arrangement, electrolysis electrode equipment, other detail sections also can be appropriate
Change.
Industrial applicability
As above, caused by electrolysis electrode equipment according to the present invention, electrolytic water generating device can effectively dissolve
Electrolytically generated thing, therefore can also for example be applied to carry out using the Ozone Water as the ozone of electrolytically generated thing has been dissolved net
The purposes such as the water treatment field of change/sterilization, field of food, medical domain, semiconductor applications.
Claims (10)
1. a kind of electrolysis electrode equipment, is configured to be laminated and have in a manner of making conductive film between adjacent electrode
There is the groove portion formed in a manner of making above-mentioned conductive film be contacted with least a portion at the interface of above-mentioned electrode with water, to from connecing
Electrolysis processing is carried out by the water that face supplies, the water after carrying out the electrolysis processing is sent out from the receiving surface, the electrolysis electrode equipment
It is characterized in that,
Above-mentioned conductive film is the film for producing the change in size caused by dry or swelling, above-mentioned groove portion be disposed with it is multiple,
Above-mentioned conductive film and the above-mentioned electric conductivity at the equitant region of above-mentioned electrode in the state of from stacked direction
Between film and above-mentioned electrode, formed with due to above-mentioned electric conductivity in a manner of across above-mentioned groove portion and adjacent other above-mentioned groove portions
The swelling of film and the water flowing road for narrowing or blocking.
2. electrolysis electrode equipment according to claim 1, it is characterised in that
Above-mentioned water flowing curb extends with the direction that above-mentioned groove portion is intersected, and is formed at the outer rim of above-mentioned conductive film or above-mentioned electrode
And across the position of above-mentioned groove portion and adjacent other above-mentioned groove portions.
3. electrolysis electrode equipment according to claim 2, it is characterised in that
Above-mentioned water flowing road is formed at above-mentioned electrode side.
4. the electrolysis electrode equipment according to Claims 2 or 3, it is characterised in that
Above-mentioned water flowing road is formed at above-mentioned conductive film side.
5. the electrolysis electrode equipment according to Claims 2 or 3, it is characterised in that
Above-mentioned conductive film has the contact of seamed edge shape with above-mentioned water flowing road.
6. electrolysis electrode equipment according to claim 4, it is characterised in that
Above-mentioned conductive film has the contact of seamed edge shape with above-mentioned water flowing road.
7. the electrolysis electrode equipment according to Claims 2 or 3, it is characterised in that
Above-mentioned conductive film and above-mentioned electrode are configured to load and unload.
8. electrolysis electrode equipment according to claim 4, it is characterised in that
Above-mentioned conductive film and above-mentioned electrode are configured to load and unload.
9. a kind of electrolytic water generating device, it is characterised in that possess：
Electrolysis electrode equipment according to any one of claim 2~8；And
Pipe arrangement, its flow path formed with the water for supplying the object handled by above-mentioned electrolysis electrode equipment as electrolysis are above-mentioned
Electrolysis electrode equipment is embedded in the pipe arrangement.
10. electrolytic water generating device according to claim 9, it is characterised in that
To make the mode that the above-mentioned water flowing curb direction consistent with the water (flow) direction of the flowing water in above-mentioned flow path extends above-mentioned
Electrolysis electrode equipment is embedded in above-mentioned pipe arrangement.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| JP2013-145158 | 2013-07-11 | ||
| JP2013145158A JP6187861B2 (en) | 2013-07-11 | 2013-07-11 | Electrolytic electrode device and electrolyzed water generating apparatus comprising the electrolytic electrode device |
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| CN104278289B true CN104278289B (en) | 2018-04-27 |
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| CN (1) | CN104278289B (en) |
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| JP6587152B2 (en) * | 2016-03-30 | 2019-10-09 | パナソニックＩｐマネジメント株式会社 | Electrolytic liquid generator |
| US10920408B2 (en) * | 2018-10-24 | 2021-02-16 | Hall Labs Llc | Antimicrobial toilet with electrolyzer |
| CN112875808A (en) * | 2019-11-29 | 2021-06-01 | 无锡小天鹅电器有限公司 | Electrolysis device and clothes treatment equipment |
| CN112875809A (en) * | 2019-11-29 | 2021-06-01 | 无锡小天鹅电器有限公司 | Electrolysis device and clothes treatment equipment |
| JP7228847B2 (en) * | 2020-02-14 | 2023-02-27 | パナソニックＩｐマネジメント株式会社 | Electrolyte liquid generator |
| CN111118527B (en) * | 2020-02-25 | 2023-09-01 | 宁波隆丰电子科技有限公司 | Ozone electrolysis generator and method for cleaning ozone generator |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012206110A (en) * | 2011-03-17 | 2012-10-25 | Masaaki Arai | Electrolytic water production device |
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| DE3401637A1 (en) * | 1984-01-19 | 1985-07-25 | Hoechst Ag, 6230 Frankfurt | METHOD FOR ELECTROLYZING LIQUID ELECTROLYTE |
| JP4394942B2 (en) * | 2003-12-22 | 2010-01-06 | 株式会社Ｉｈｉシバウラ | Electrolytic ozonizer |
| HUP0501204A2 (en) * | 2005-12-23 | 2007-07-30 | Thales Rt | Ozone generating electrolytic cell |
| JP2007283180A (en) * | 2006-04-14 | 2007-11-01 | Ozotech:Kk | Ozone water generator and ozone water generation method |
| JP5133592B2 (en) * | 2007-05-09 | 2013-01-30 | 日科ミクロン株式会社 | Ozone water generator |
| JP5014066B2 (en) * | 2007-11-01 | 2012-08-29 | 三菱電機株式会社 | Electrolysis cell for hydrogen peroxide production |
| JP2009149932A (en) * | 2007-12-19 | 2009-07-09 | Kurita Water Ind Ltd | Electrode for water electrolytic device and water electrolytic device using the same |
| CN101698942B (en) * | 2009-02-11 | 2011-08-10 | 徐名勇 | Ozone generator for use in membrane electrode electrolysis |
| JP5113892B2 (en) * | 2010-04-30 | 2013-01-09 | アクアエコス株式会社 | Membrane-electrode assembly, electrolytic cell using the same, ozone water production apparatus, ozone water production method, sterilization method, and waste water / waste liquid treatment method |
| JP5113891B2 (en) * | 2010-04-30 | 2013-01-09 | アクアエコス株式会社 | Ozone water production apparatus, ozone water production method, sterilization method, and wastewater / waste liquid treatment method |
| JP5427129B2 (en) * | 2010-07-05 | 2014-02-26 | パナソニック株式会社 | Electrolytic electrode unit and electrolyzed water generating apparatus using the same |
| JP2012144778A (en) * | 2011-01-12 | 2012-08-02 | Kobe Steel Ltd | Electrolysis electrode and device for generating ozone using the electrolysis electrode |
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| JP2012206110A (en) * | 2011-03-17 | 2012-10-25 | Masaaki Arai | Electrolytic water production device |
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| JP6187861B2 (en) | 2017-08-30 |
| JP2015017303A (en) | 2015-01-29 |
| TW201506204A (en) | 2015-02-16 |
| TWI546419B (en) | 2016-08-21 |
| CN104278289A (en) | 2015-01-14 |
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