CN104263250A - Environment-friendly rubber silicate adhesive - Google Patents
Environment-friendly rubber silicate adhesive Download PDFInfo
- Publication number
- CN104263250A CN104263250A CN201410478272.2A CN201410478272A CN104263250A CN 104263250 A CN104263250 A CN 104263250A CN 201410478272 A CN201410478272 A CN 201410478272A CN 104263250 A CN104263250 A CN 104263250A
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- China
- Prior art keywords
- silicate
- environment
- adhesive
- environmental protection
- silicate adhesive
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Abstract
The invention provides an environment-friendly rubber silicate adhesive with high performance. The environment-friendly rubber silicate adhesive is characterized by comprising the following components according to weight proportions: 100-500g of silicate, 1-5g of butyl acrylate, 0.5-3g of polyacrylamide, 6-30g of silane coupling agent, 0.1-2g of tackifier, 0.1-1g of plasticizers, 0.1-1g of water-proofing agent and 0.1-0.5g of corrosion remover. The environment-friendly rubber silicate adhesive, which is prepared by using multiple organics as modifiers under the premise of avoiding adding any inorganic filler, has the characteristics of high bonding strength, high water resisting property, high heat resisting property, low curing temperature, high corrosion-prevention protection function and the like; meanwhile, the environment-friendly adhesive has no harmful component such as formaldehyde and the like; therefore, the adhesive is environment-friendly.
Description
Technical field
The invention belongs to technical field of adhesive, be specifically related to a kind of tackiness agent, particularly relate to a kind of environmental protection silicate adhesive.
Background technology
Usual tackiness agent is divided into organic type cementing agent and inorganic type cementing agent, wherein typical organic type tackiness agent is as resol, high owing to itself there is cohesive strength, water-fast, heat-resisting, wear-resisting and good chemical stability, because organic adhesion agent has superior adhesiveproperties, thus in a lot of fields in be used widely, as being applied to timber, plastics industry, but it is higher that it also exists cost, the shortcomings such as solidification value is high and grow set time, also there is temperature tolerance difference in most of organic adhesion agent simultaneously, large and the high in cost of production shortcoming of toxicity, limit its range of application.But inorganic adhesive raw material sources are wide, cheap, manufacture and easy construction day. range of application is comparatively wide, is day by day subject to people's attention.Current existing inorganic adhesive mainly contains silicate and phosphoric acid salt two large system, wherein phosphate adhesive non-refractory, and sizing material fragility is large, be not suitable for plane adhesion, therefore the application of silicate adhesive is more extensive.Silicate adhesive has the features such as bonding strength is relatively large, temperature tolerance is relatively better, has been widely used in pottery, glass, wrapping material, material of construction, metal and the various material such as nonmetal; But traditional silicate adhesive still exists that bonding strength is low, poor water resistance and the shortcoming such as condition of cure is high.
Summary of the invention
For the problem of above-mentioned silicate cement mixture; the object of this invention is the environmental protection silicate adhesive providing a kind of excellent property; this tackiness agent has that bonding strength is higher, water tolerance is better, thermotolerance is splendid, solidification value is lower and the more excellent feature of corrosionproof protection effect to steel, has a good application prospect.
The present invention is achieved through the following technical solutions: a kind of environmental protection silicate adhesive, is characterized in that, its component is made up of following weight:
Described silicate is water glass, potassium silicate, lithium silicate, ammonium silicate, and its formula of is M
2o.nSiO
2, wherein the value of n is 1.5 ~ 4.
Described softening agent is dioctyl phthalate (DOP) and dimixo-octyl phthalate, wherein any one.
Described tackifier are Walocel MT 20.000PV.
Described water-resisting agent is epoxy resin or hydroxyl silicono acid esters, wherein any one.
Described sanitas is p-hydroxybenzoic acid or aethyl parabenum, wherein any one.
Environmental protection silicate adhesive provided by the invention obtains through the following steps: take a certain amount of water glass, under 50 DEG C of constant temperatures, add butyl acrylate, polyacrylamide and silane coupling agent while stirring, be warming up to 60 ~ 70 DEG C, stir after 2 ~ 3h, add tackifier afterwards again, softening agent, water-resisting agent, sanitas obtain water white tackiness agent.
The present invention is under the prerequisite of not adding any mineral filler; using gas chromatography as properties-correcting agent; the silicate adhesive made has that bonding strength is higher, water tolerance is better, thermotolerance is splendid, solidification value is lower and the more excellent feature of corrosionproof protection effect; this environment-friendly adhesive is not containing objectionable constituent such as formaldehyde simultaneously; cost is low, belongs to environmentally friendly tackiness agent.
Embodiment
Below embodiments of the invention are elaborated: the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1: a kind of environmental protection silicate adhesive, by following batching:
Embodiment 2: a kind of environmental protection silicate adhesive, by following batching:
Embodiment 3: a kind of environmental protection silicate adhesive, by following batching:
Environmental protection silicate prepared by above-described embodiment realizes in the steps below: by batching described above, take quantitative silicate, under 50 DEG C of constant temperatures, add butyl acrylate, polyacrylamide and silane coupling agent while stirring, be warming up to 60 ~ 70 DEG C, after stirring 2 ~ 3h, add correspondingly tackifier, softening agent, water-resisting agent, sanitas afterwards again and obtain water white tackiness agent.
Claims (6)
1. an environmental protection silicate adhesive, is characterized in that, its component is made up of following weight:
。
2. a kind of environmental protection silicate adhesive according to claim 1, is characterized in that, described silicate is water glass, potassium silicate, lithium silicate, ammonium silicate, and its formula of is M
2.nSiO
2, wherein the value of n is 1.5 ~ 4.
3. a kind of environmental protection silicate adhesive according to claim 1, is characterized in that, described softening agent is dioctyl phthalate (DOP) and dimixo-octyl phthalate, wherein any one.
4. a kind of environmental protection silicate adhesive according to claim 1, is characterized in that, described tackifier are Walocel MT 20.000PV.
5. a kind of environmental protection silicate adhesive according to claim 1, is characterized in that, described water-resisting agent is epoxy resin or hydroxyl silicono acid esters, wherein any one.
6. a kind of environmental protection silicate adhesive according to claim 1, is characterized in that, described sanitas is p-hydroxybenzoic acid or aethyl parabenum, wherein any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410478272.2A CN104263250B (en) | 2014-09-18 | 2014-09-18 | A kind of environment-friendlyadhesive adhesive silicate adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410478272.2A CN104263250B (en) | 2014-09-18 | 2014-09-18 | A kind of environment-friendlyadhesive adhesive silicate adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104263250A true CN104263250A (en) | 2015-01-07 |
| CN104263250B CN104263250B (en) | 2016-06-29 |
Family
ID=52154841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410478272.2A Expired - Fee Related CN104263250B (en) | 2014-09-18 | 2014-09-18 | A kind of environment-friendlyadhesive adhesive silicate adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104263250B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861879A (en) * | 2015-05-14 | 2015-08-26 | 李凤令 | Glue for building and decoration and preparation method of glue |
| CN106366946A (en) * | 2016-08-26 | 2017-02-01 | 北京斯霖垦科技有限公司 | Method for preparing lithium-containing sodium silicate adhesive |
| CN108587490A (en) * | 2018-03-22 | 2018-09-28 | 孙立恒 | Novel aqueous special gelatin |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1288921A (en) * | 2000-10-24 | 2001-03-28 | 华东理工大学 | Self-curing inorganic heat-conducting daub |
| CN103013353A (en) * | 2011-09-26 | 2013-04-03 | 陈银凤 | Preparation method of neutral weatherproof glass cement |
| CN103146344A (en) * | 2013-03-25 | 2013-06-12 | 曹大庆 | Aqueous inorganic and fireproof foam adhesive |
-
2014
- 2014-09-18 CN CN201410478272.2A patent/CN104263250B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1288921A (en) * | 2000-10-24 | 2001-03-28 | 华东理工大学 | Self-curing inorganic heat-conducting daub |
| CN103013353A (en) * | 2011-09-26 | 2013-04-03 | 陈银凤 | Preparation method of neutral weatherproof glass cement |
| CN103146344A (en) * | 2013-03-25 | 2013-06-12 | 曹大庆 | Aqueous inorganic and fireproof foam adhesive |
Non-Patent Citations (1)
| Title |
|---|
| 张琴等: "改性硅酸盐胶粘剂的制备与性能研究", 《中国胶粘剂》, vol. 20, no. 10, 31 October 2011 (2011-10-31), pages 41 - 44 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861879A (en) * | 2015-05-14 | 2015-08-26 | 李凤令 | Glue for building and decoration and preparation method of glue |
| CN106366946A (en) * | 2016-08-26 | 2017-02-01 | 北京斯霖垦科技有限公司 | Method for preparing lithium-containing sodium silicate adhesive |
| CN108587490A (en) * | 2018-03-22 | 2018-09-28 | 孙立恒 | Novel aqueous special gelatin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104263250B (en) | 2016-06-29 |
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| C14 | Grant of patent or utility model | ||
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190527 Address after: 300 000 Heercun, Shuangkou Town, Beichen District, Tianjin (in Zhongtian United Hospital) Patentee after: TIANJIN HESHENGYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. Address before: 300 000 Heercun, Shuangkou Town, Beichen District, Tianjin (West of Jintong Highway) Patentee before: ZHONGTIAN JOINT ENERGY SAVING CONSTRUCTION DEVELOPMENT (TIANJIN) Co.,Ltd. |
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| TR01 | Transfer of patent right |
Effective date of registration: 20191203 Address after: 300400 Xian he Er Cun, Shuangkou Town, Beichen District, Tianjin (West of Jintang highway) Patentee after: ZHONGTIAN JOINT ENERGY SAVING CONSTRUCTION DEVELOPMENT (TIANJIN) Co.,Ltd. Address before: 300 000 Heercun, Shuangkou Town, Beichen District, Tianjin (in Zhongtian United Hospital) Patentee before: TIANJIN HESHENGYUAN NEW MATERIAL TECHNOLOGY CO.,LTD. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160629 |