CN104262828A - Oil-resistant cable material and preparation method thereof - Google Patents

Oil-resistant cable material and preparation method thereof Download PDF

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Publication number
CN104262828A
CN104262828A CN201410456700.1A CN201410456700A CN104262828A CN 104262828 A CN104262828 A CN 104262828A CN 201410456700 A CN201410456700 A CN 201410456700A CN 104262828 A CN104262828 A CN 104262828A
Authority
CN
China
Prior art keywords
parts
cable material
resistant cable
polyvinyl chloride
polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410456700.1A
Other languages
Chinese (zh)
Inventor
季娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHENJIANG ZHONGJIA ELECTRICAL APPLIANCE Co Ltd
Original Assignee
ZHENJIANG ZHONGJIA ELECTRICAL APPLIANCE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHENJIANG ZHONGJIA ELECTRICAL APPLIANCE Co Ltd filed Critical ZHENJIANG ZHONGJIA ELECTRICAL APPLIANCE Co Ltd
Priority to CN201410456700.1A priority Critical patent/CN104262828A/en
Publication of CN104262828A publication Critical patent/CN104262828A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses an oil-resistant cable material. The preparation method comprises the following steps: mixing polyvinyl chloride, active light calcium carbonate and polyethylene (PE) into a mixing machine, adding a polyester plasticizer, a stabilizer, antimony trioxide (Sb2O3) and high-polymer organic calcium when the temperature reaches 90 DEC, and uniformly mixing at normal temperature; and discharging the mixture into a discharging section, compounding in a double screw extruder, extruding and granulating. The cable material can keep the original physical properties constant in various oil stain environments on the premise of ensuring various physical property indexes in the conventional environment.

Description

A kind of oil resistant cable material and preparation method thereof
Technical field
The present invention relates to a kind of high polymers CABLE MATERIALS.
Background technology
Electric wire refers to the material for electric power, communication and associated transport purposes.Along with the development of society, electric wire is more and more widely used in every field, as transport, communication, building etc., therefore, also more and more higher to the requirement of the professional domain of electric wire.Traditional polyvinyl chloride cable material, formula is: polyvinyl chloride 100 parts, dioctyl phthalate (DOP) 50-60 part, one package stabilizer 6-10 part, lubricant 1-3 part, calcene 20-30 part, above-mentioned materials CABLE MATERIALS can only solve conventional indoor and outdoor environmental demand, some special trade is needed to the equipment of operation in a variety of greasy dirt, normal cable then can not meet its environmental requirement.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of oil resistant cable material, and this CABLE MATERIALS is guaranteeing that the every physical index in conventional environment also keeps original physical property constant in various oil pollution environment outward.
A kind of oil resistant cable material, wherein, its moiety is made up of the raw material of following weight part:
Above-mentioned a kind of oil resistant cable material, wherein, preferably, its moiety is made up of the raw material of following weight part:
A preparation method for oil resistant cable material, wherein, preparation process is as follows: by polyvinyl chloride, calcene and polyethylene (PE) are put into mixing machine and are mixed, when temperature reaches 90 degree, add polyester plasticizer, stablizer, antimonous oxide (SB 2o 3), polymer organic calcium, mixes under normal temperature state; The material mixed is discharged into unloading part, then joins in twin-screw extruder mixing, extrude, granulation.
Above-mentioned a kind of oil resistant cable material, compared with prior art, tool has the following advantages in the present invention:
1, by improving production formula and additive, cable jacket and heart yearn is made to have stronger oil rub resistance performance.
2, polyester plasticizer well compatible requirement of anti-adverse environment while guaranteeing conventional physical property, especially motor transformer oils.
3, light specific gravity, plasticizing rate are high, and heatproof reaches 40 DEG C ~ 105 DEG C, and indeformable not embrittlement is aging, possesses superior product performance, range of application and field more extensive;
4, under 136 DEG C of thermal ageing 168h conditions, the velocity of variation of mechanical property (tensile strength, elongation at break) is within ± 20%, and oxygen index is greater than 38, therefore, has good over-all properties.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Polyvinyl chloride of the present invention is high molecular weight pvc (HMWPV ±), also known as polychloroethylene with high polymerization degree, refers to the polyvinyl chloride resin of the polymerization degree more than 1300.Stablizer is calcium zinc (Ca-Zn) one package stabilizer.
Embodiment one:
By 100 parts of polyvinyl chloride, 30 parts of calcenes and 1 part of polyethylene (PE) are put into mixing machine and are mixed, when temperature reaches 90 degree, add 50 parts of polyester plasticizers, 10 parts of calcium zinc (Ca-Zn) one package stabilizers, 10 parts of antimonous oxide (SB 2o 3), 5 parts of polymer organic calciums, mix under normal temperature state; The material mixed is discharged into unloading part, then joins in twin-screw extruder mixing, extrude, granulation.
The performance data of the oil resistant cable material obtained by table 1 embodiment 1
Embodiment two:
By 100 parts of polyvinyl chloride, 30 parts of calcenes and 1 part of polyethylene (PE) are put into mixing machine and are mixed, when temperature reaches 90 degree, add 48 parts of polyester plasticizers, 8.5 parts of calcium zinc (Ca-Zn) one package stabilizers, 9 parts of antimonous oxide (SB 2o 3), 5 parts of polymer organic calciums, mix under normal temperature state; The material mixed is discharged into unloading part, then joins in twin-screw extruder mixing, extrude, granulation.
The performance data of the oil resistant cable material obtained by table 1 embodiment 1
Embodiment one:
By 100 parts of polyvinyl chloride, 30 parts of calcenes and 1 part of polyethylene (PE) are put into mixing machine and are mixed, when temperature reaches 90 degree, add 53 parts of polyester plasticizers, 9.5 parts of calcium zinc (Ca-Zn) one package stabilizers, 9.5 parts of antimonous oxide (SB 2o 3), 5 parts of polymer organic calciums, mix under normal temperature state; The material mixed is discharged into unloading part, then joins in twin-screw extruder mixing, extrude, granulation.
The performance data of the oil resistant cable material obtained by table 1 embodiment 1

Claims (3)

1. an oil resistant cable material, is characterized in that, its moiety is made up of the raw material of following weight part:
Polyvinyl chloride 100 parts
Polyester plasticizer 45-55 part
Stablizer 8-10 part
Polymer organic calcium 5 parts
Antimonous oxide (SB 2o 3) 9-10 part
Polyethylene (PE) 1 part
Calcene 30 parts.
2. a kind of oil resistant cable material as claimed in claim 1, is characterized in that, preferably, it is made up of the raw material of following weight part:
Polyvinyl chloride 100 parts
Polyester plasticizer 50 parts
Stablizer 10 parts
Polymer organic calcium 5 parts
Antimonous oxide (SB 2o 3) 10 parts
Polyethylene (PE) 1 part
Calcene 30 parts.
3. a preparation method for oil resistant cable material, is characterized in that, by polyvinyl chloride, calcene and polyethylene (PE) are put into mixing machine and mixed, and when temperature reaches 90 degree, add polyester plasticizer, stablizer, antimonous oxide (SB 2o 3), polymer organic calcium, mixes under normal temperature state; The material mixed is discharged into unloading part, then joins in twin-screw extruder mixing, extrude, granulation.
CN201410456700.1A 2014-09-09 2014-09-09 Oil-resistant cable material and preparation method thereof Pending CN104262828A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410456700.1A CN104262828A (en) 2014-09-09 2014-09-09 Oil-resistant cable material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410456700.1A CN104262828A (en) 2014-09-09 2014-09-09 Oil-resistant cable material and preparation method thereof

Publications (1)

Publication Number Publication Date
CN104262828A true CN104262828A (en) 2015-01-07

Family

ID=52154425

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410456700.1A Pending CN104262828A (en) 2014-09-09 2014-09-09 Oil-resistant cable material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104262828A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251441A (en) * 2018-08-21 2019-01-22 镇江中佳电器有限公司 A kind of waterproof oil resistant cable material
CN112795102A (en) * 2019-11-13 2021-05-14 江苏河阳电气有限公司 Flame-retardant cable for electric vehicle charging system and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109251441A (en) * 2018-08-21 2019-01-22 镇江中佳电器有限公司 A kind of waterproof oil resistant cable material
CN112795102A (en) * 2019-11-13 2021-05-14 江苏河阳电气有限公司 Flame-retardant cable for electric vehicle charging system and preparation method thereof

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PB01 Publication
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150107