CN104261502B - Containing organic solvent method of wastewater treatment and device thereof - Google Patents
Containing organic solvent method of wastewater treatment and device thereof Download PDFInfo
- Publication number
- CN104261502B CN104261502B CN201410499097.5A CN201410499097A CN104261502B CN 104261502 B CN104261502 B CN 104261502B CN 201410499097 A CN201410499097 A CN 201410499097A CN 104261502 B CN104261502 B CN 104261502B
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- CN
- China
- Prior art keywords
- packed tower
- organic solvent
- spray liquid
- cooled condenser
- water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
The present invention relates to containing organic solvent method of wastewater treatment and device thereof, method is to utilize to be dried the waste water that gas stripping contains organic solvent, water and organic solvent is made to exist in the form of a vapor, it is then passed through hydrophobic adsorption device absorbing organic solvent, remove moisture through dehydrating unit again, utilize blower fan to make to be dried gas and circulate between said apparatus.The device of foundation method manufacture is for including packed tower, dehydrating unit, adsorbent equipment and air circulation duct;Packed tower is made up of spray liquid distributor, filler, spray liquid pool and feeding spraying pump, dehydrating unit is made up of refrigeration compressor, air-cooled condenser, water-cooled condenser, refrigeration expansion valve and refrigerating evaporator, and it being connected into cooling cycle system, air circulation duct is sequentially connected with packed tower gas outlet, adsorbent equipment, refrigerating evaporator, air-cooled condenser, circulating fan, packed tower are dried gas feed.The present invention reclaims organic solvent relative energy-saving more than 70% with utilizing conventional distillation.
Description
Technical field
The present invention relates to the sewage treatment equipment containing organic solvent, specifically containing organic solvent method of wastewater treatment and device thereof.
Background technology
Wet spinning, hollow-fibre membrane manufacture process all can produce substantial amounts of containing dimethyl acetylamide (DMAc) or the organic wastewater of dimethylformamide (DMF).Directly on the one hand the discharge waste water containing organic solvent cause environmental pollution, still further aspect to also result in the wasting of resources.
From the waste water containing organic solvent, reclaim organic solvent be probably the most economical technological means solving the contaminated wastewater containing organic solvent.
DMAc or DMF boiling point is higher than the boiling point of water, when DMAc or DMF is about 20% in waste water, the way of distillation is taked to process these waste water reclamation organic solvents, owing to water evaporation latent heat is big, therefore, utilize the way of distillation to reclaim organic solvent and there is the defect that energy resource consumption is big.
Summary of the invention
Present invention aims to the problem and shortage of above-mentioned existence, there is provided one utilize hydrophobicity adsorbent equipment and heat pump class dehydrating unit associated working, with utilize conventional distillation reclaim organic solvent relative energy-saving more than 70% containing organic solvent method of wastewater treatment and device thereof.
The above-mentioned purpose of the present invention is to be achieved by the following technical programs:
Containing organic solvent method of wastewater treatment, utilize and be dried the waste water that gas stripping contains organic solvent, water and organic solvent is made to exist in the form of a vapor, it is then passed through hydrophobic adsorption device absorbing organic solvent, remove moisture through dehydrating unit again, utilize blower fan to make gas circulate between said apparatus.
Containing organic solvent wastewater treatment equipment, including packed tower, dehydrating unit, adsorbent equipment and air circulation duct;
Packed tower is made up of spray liquid distributor, filler, spray liquid pool and feeding spraying pump, spray liquid pool and wastewater outlet is located at bottom packed tower, packed tower bottom is provided with dry gas feed, packing area it is provided with in the middle part of packed tower, packing area is built with filler, top, packing area is equipped with spray liquid distributor, packed tower top is provided with gas outlet, and wastewater outlet pipeline is by feeding spraying pump and water-cooled condenser connection spray liquid distributor.
Dehydrating unit is made up of refrigeration compressor, air-cooled condenser, water-cooled condenser, refrigeration expansion valve and refrigerating evaporator, and is connected into cooling cycle system.
Air circulation duct is sequentially connected with packed tower gas outlet, adsorbent equipment, refrigerating evaporator, air-cooled condenser, circulating fan, packed tower are dried gas feed.
Between water-cooled condenser and spray liquid distributor, pipeline is provided with the loop being back to spray liquid pool, is respectively equipped with Water flow adjusting valve door between water-cooled condenser and spray liquid distributor on pipeline and loop.Water flow adjusting valve door, its function is exactly the discharge ratio that regulation is delivered to spray liquid distributor and is returned directly to spray liquid pool.
Hydrophobic adsorption device can optionally absorbing organic solvent from air.Adsorbent equipment can be to utilize hydrophobic molecular to sieve the molecular sieve concentration runner that is fabricated by, or utilizes the fixed adsorbent bed that the molecular sieve of hydrophobic is fabricated by.After adsorbent equipment adsorbs a number of organic solvent, by heating, organic solvent can be made to regenerate from adsorbent equipment, and the organic solvent contained in regeneration air can realize condensation by cooling and reclaim.
The cold-producing medium discharged from refrigeration compressor first passes through after air-cooled condenser cools down again through water-cooled condenser cooling.The cooling medium of cooling condenser is exactly to need the waste water containing organic solvent to be processed, and the function of water-cooled condenser is to make cold-producing medium also make while cooling down to heat by the waste water containing organic solvent to be processed.
Feeding spraying pump has two functions, one of function makes the water in spray liquid pool make refrigeration system cool down through water-cooled condenser exactly, and another one function is exactly to make to need the waste water containing organic solvent to be processed to be uniformly distributed in filler from spray liquid distributor in spray liquid pool.
Water section through water-cooled condenser sprays on the filler of packed tower through spray liquid distributor as spray liquid, and part directly sends spray liquid pool back to.
The function of circulating fan is exactly to circulate air through packed tower, the adsorbent equipment of hydrophobic, the refrigerating evaporator of refrigeration system and the air-cooled condenser of refrigeration system, finally sends packed tower back to.
The present invention is designed by above-mentioned structure, dry gas is utilized to carry the waste water containing organic solvent by packed tower equivalent, water and organic solvent is made to exist in the form of a vapor, recycling hydrophobicity adsorbent equipment and heat pump class dehydrating unit associated working, first with hydrophobic adsorption device absorbing organic solvent, then utilize dehydrating unit to remove moisture, reclaim organic solvent relative energy-saving more than 70% with utilizing conventional distillation.
The present invention is further illustrated below in conjunction with the accompanying drawings.
Accompanying drawing explanation
Fig. 1 is a kind of structural representation of the present invention.
Detailed description of the invention
As it is shown in figure 1, the wastewater treatment equipment Han organic solvent, including packed tower 1, dehydrating unit, adsorbent equipment 2 and air circulation duct;
Packed tower 1 is made up of spray liquid distributor 12, filler 13, spray liquid pool 14 and feeding spraying pump 9, spray liquid pool 14 and wastewater outlet is located at bottom packed tower 1, packed tower 1 bottom is provided with dry gas feed, it is provided with packing area in the middle part of packed tower 1, packing area is built with filler 13, top, packing area is equipped with spray liquid distributor 12, packed tower 1 top is provided with gas outlet, and wastewater outlet pipeline connects spray liquid distributor 12 by feeding spraying pump 9 and water-cooled condenser 7
Dehydrating unit is made up of refrigeration compressor 6, air-cooled condenser 4, water-cooled condenser 7, refrigeration expansion valve 8 and refrigerating evaporator 3, and is connected into cooling cycle system,
Air circulation duct is sequentially connected with packed tower 1 gas outlet, adsorbent equipment 2, refrigerating evaporator 3, air-cooled condenser 4, circulating fan 5, packed tower 1 are dried gas feed.
Between water-cooled condenser 7 and spray liquid distributor 12, pipeline is provided with the loop being back to spray liquid pool 14, and pipeline is provided with Water flow adjusting valve door 11, and loop is provided with Water flow adjusting valve door 10.
In the present invention, refrigeration system can be multiple, flows according to vertical direction it addition, packed tower can also be cross-current type, i.e. hydrojet, and air prolongs horizontal direction flowing.
Above-described embodiment is the present invention preferably embodiment; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modify, substitute, combine, simplify; all should be the substitute mode of equivalence, within being included in protection scope of the present invention.
Claims (2)
1. the wastewater treatment equipment Han organic solvent, it is characterised in that: include packed tower (1), dehydrating unit, adsorbent equipment (2) and air circulation duct;
Packed tower (1) is made up of spray liquid distributor (12), filler (13), spray liquid pool (14) and feeding spraying pump (9), spray liquid pool (14) and wastewater outlet are located at packed tower (1) bottom, packed tower (1) bottom is provided with dry gas feed, packed tower (1) middle part is provided with packing area, packing area is built with filler (13), top, packing area is equipped with spray liquid distributor (12), packed tower (1) top is provided with gas outlet, wastewater outlet pipeline is by feeding spraying pump (9) and water-cooled condenser (7) connection spray liquid distributor (12)
Dehydrating unit is made up of refrigeration compressor (6), air-cooled condenser (4), water-cooled condenser (7), refrigeration expansion valve (8) and refrigerating evaporator (3), and is connected into refrigerating circulation,
Air circulation duct is sequentially connected with packed tower (1) gas outlet, adsorbent equipment (2), refrigerating evaporator (3), air-cooled condenser (4), circulating fan (5), the dry gas feed of packed tower (1).
Wastewater treatment equipment the most according to claim 1, it is characterized in that: between water-cooled condenser (7) and spray liquid distributor (12), pipeline is provided with the loop being back to spray liquid pool (14), and is respectively equipped with Water flow adjusting valve door on pipeline and loop.
Priority Applications (1)
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CN201410499097.5A CN104261502B (en) | 2014-09-26 | 2014-09-26 | Containing organic solvent method of wastewater treatment and device thereof |
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CN201410499097.5A CN104261502B (en) | 2014-09-26 | 2014-09-26 | Containing organic solvent method of wastewater treatment and device thereof |
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CN104261502A CN104261502A (en) | 2015-01-07 |
CN104261502B true CN104261502B (en) | 2016-08-24 |
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CN105174332A (en) * | 2015-07-16 | 2015-12-23 | 浙江大学 | Method for processing garbage leachate and device thereof |
CN108203374A (en) * | 2016-12-19 | 2018-06-26 | 曾舟华 | Phosphorus pentoxide haze concentrates the method and device of dilute formic acid |
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CN106986486B (en) * | 2017-05-10 | 2020-10-30 | 南京工业大学 | High organic effluent treatment plant that contains salt |
CN111170387B (en) * | 2018-11-13 | 2021-12-17 | 上海景峰制药有限公司 | Drawer type split water organic solvent evaporation device |
CN110407383A (en) * | 2019-07-02 | 2019-11-05 | 太原理工大学 | A kind of device polluted for handling underground water volatile organic matter |
CN111841067A (en) * | 2020-08-14 | 2020-10-30 | 中国华能集团清洁能源技术研究院有限公司 | Low-temperature pentane washing flue gas simultaneous desulfurization and decarburization system and process |
CN113856219A (en) * | 2021-10-20 | 2021-12-31 | 江苏盛勤环境工程有限公司 | Low-temperature normal-pressure evaporation device and evaporation process thereof |
CN117085458B (en) * | 2023-10-20 | 2024-02-13 | 中国华能集团清洁能源技术研究院有限公司 | Combined purifying tower for flue gas cooling and adsorption |
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JPH0214712A (en) * | 1988-06-30 | 1990-01-18 | Toshiba Corp | Gas separation device |
CN101898855A (en) * | 2010-07-16 | 2010-12-01 | 华东理工大学 | Integrated ex-situ repair system for underground water polluted by volatile organic compound |
CN201684526U (en) * | 2009-11-27 | 2010-12-29 | 胜利油田胜利勘察设计研究院有限公司 | CO2 drying device |
CN202376895U (en) * | 2011-12-07 | 2012-08-15 | 上海阿普达实业有限公司 | Zero-gas-consumption compressed air adsorption dry equipment |
CN203235400U (en) * | 2013-03-13 | 2013-10-16 | 漳州震东机械有限公司 | Non-gas-consumption and low-dew-point heat recovery combined dryer |
Family Cites Families (1)
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CN204162460U (en) * | 2014-09-26 | 2015-02-18 | 马军 | Containing organic solvent wastewater treatment equipment |
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Patent Citations (5)
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JPH0214712A (en) * | 1988-06-30 | 1990-01-18 | Toshiba Corp | Gas separation device |
CN201684526U (en) * | 2009-11-27 | 2010-12-29 | 胜利油田胜利勘察设计研究院有限公司 | CO2 drying device |
CN101898855A (en) * | 2010-07-16 | 2010-12-01 | 华东理工大学 | Integrated ex-situ repair system for underground water polluted by volatile organic compound |
CN202376895U (en) * | 2011-12-07 | 2012-08-15 | 上海阿普达实业有限公司 | Zero-gas-consumption compressed air adsorption dry equipment |
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