CN104258709A - Waste derived fuel burning smoke separation and purifying process - Google Patents

Waste derived fuel burning smoke separation and purifying process Download PDF

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CN104258709A
CN104258709A CN201410501011.8A CN201410501011A CN104258709A CN 104258709 A CN104258709 A CN 104258709A CN 201410501011 A CN201410501011 A CN 201410501011A CN 104258709 A CN104258709 A CN 104258709A
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flue gas
waste
derived fuel
activated carbon
incinerator
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CN104258709B (en
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潘志成
彭玉梅
赵媛
邱小丽
刘璐
袁欣
刘纪景
陈丹丹
范晓阳
章仁忠
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Sichuan University of Science and Engineering
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CHENGDU CER (GROUP) Co Ltd
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Abstract

本发明涉及一种废物衍生燃料焚烧烟气分离净化工艺,包括依次进行的步骤:焚烧炉焚烧产生的烟气在焚烧炉内充足氧用氨水脱硫脱硝,干冰急冷塔急速降温防止二恶英生成,旋风除尘器内用螯合剂吸附重金属,半干式脱酸塔内通熟石灰浆脱酸,活性炭喷射器中用活性炭吸附杂质颗粒,袋式除尘器中通过薄膜滤料过滤烟尘颗粒,中空纤维微孔膜过滤罐内通过吸收液吸收二氧化碳,加热炉加热至250℃-350℃,各项指标检测合格后,经由引风机通过高烟囱排入大气。本发明提供的一种废物衍生燃料焚烧烟气分离净化工艺,将废物衍生燃料焚烧烟气中的有害物质有效分离净化。

The invention relates to a process for separating and purifying flue gas from waste-derived fuel incineration, which includes the following steps: the flue gas produced by incineration in an incinerator is sufficiently oxygenated in the incinerator to desulfurize and denitrify with ammonia water, and the dry ice quenching tower is rapidly cooled to prevent the formation of dioxins, The chelating agent is used to adsorb heavy metals in the cyclone dust collector, the slaked lime slurry is deacidified in the semi-dry deacidification tower, the activated carbon is used to absorb impurity particles in the activated carbon injector, and the dust particles are filtered through the film filter material in the bag filter, and the hollow fiber microporous The carbon dioxide is absorbed in the membrane filter tank through the absorption liquid, and the heating furnace is heated to 250°C-350°C. After passing the inspection of all indicators, it is discharged into the atmosphere through the high chimney through the induced draft fan. The invention provides a waste-derived fuel incineration flue gas separation and purification process, which effectively separates and purifies harmful substances in the waste-derived fuel incineration flue gas.

Description

一种废物衍生燃料焚烧烟气分离净化工艺A waste-derived fuel incineration flue gas separation and purification process

技术领域 technical field

本发明涉及烟气分离净化工艺,具体是指一种废物衍生燃料焚烧烟气分离净化工艺。 The invention relates to a flue gas separation and purification process, in particular to a waste-derived fuel incineration flue gas separation and purification process.

背景技术 Background technique

废物衍生燃料焚烧具有热值高、回收利用率高等优点而得到广泛应用。然而,焚烧过程中产生的烟气还是含有许多有害物质,可能造成环境的二次污染。烟气中有害物质主要成分包括烟尘飞灰、酸性气体(一氧化碳、二氧化碳、二氧化硫、三氧化硫、氮氧化物、氟化氢、氯化氢等)、颗粒物、重金属、二恶英等。如何将废物衍生燃料焚烧的烟气进行有效分离净化,以保证污染物含量降至标准限值以下再安全排放,成为设计垃圾焚烧烟气处理系统时需要解决的难题。 Waste-derived fuel incineration has been widely used due to its advantages of high calorific value and high recycling rate. However, the flue gas produced during the incineration process still contains many harmful substances, which may cause secondary pollution to the environment. The main components of harmful substances in flue gas include soot and fly ash, acid gases (carbon monoxide, carbon dioxide, sulfur dioxide, sulfur trioxide, nitrogen oxides, hydrogen fluoride, hydrogen chloride, etc.), particulate matter, heavy metals, dioxins, etc. How to effectively separate and purify the flue gas from waste-derived fuel incineration so as to ensure that the pollutant content falls below the standard limit before safe discharge has become a problem that needs to be solved when designing a waste incineration flue gas treatment system.

发明内容 Contents of the invention

本发明的目的在于提供一种废物衍生燃料焚烧烟气分离净化工艺,将废物衍生燃料焚烧烟气中的有害物质有效分离净化。 The object of the present invention is to provide a waste-derived fuel incineration flue gas separation and purification process, which can effectively separate and purify harmful substances in the waste-derived fuel incineration flue gas.

本发明通过下述技术方案实现:一种废物衍生燃料焚烧烟气分离净化工艺,其工艺流程包括以下依次进行的步骤: The present invention is realized through the following technical scheme: a waste-derived fuel incineration flue gas separation and purification process, the process flow includes the following steps in sequence:

A脱硫脱硝;废物衍生燃料进入焚烧炉进行焚烧,焚烧炉内控制温度维持在850℃以上,焚烧炉内腔出口端的温度保持在850℃-1050℃,烟气在焚烧炉内腔出口端停留时间2S以上,同时,焚烧炉内腔出口端的顶部通过氨水喷淋装置不间断喷淋氨水并配有环向助燃氧气,生成的氨肥落入底部的传送带; A desulfurization and denitrification; waste-derived fuel enters the incinerator for incineration, the temperature in the incinerator is maintained above 850°C, the temperature at the outlet end of the incinerator cavity is maintained at 850°C-1050°C, and the residence time of the flue gas at the outlet end of the incinerator cavity At the same time, the top of the outlet end of the incinerator cavity is continuously sprayed with ammonia water through the ammonia water spray device and equipped with circular combustion-supporting oxygen, and the generated ammonia fertilizer falls into the conveyor belt at the bottom;

B防二恶英;热烟气从干冰急冷塔的上部进入,顺着内嵌干冰的塔壁从上往下流动,烟气与喷入的雾化急冷水顺流接触,由于冷水和干冰的迅速气化,热烟气在0.5S内冷却至200℃以下; B anti-dioxin; the hot flue gas enters from the upper part of the dry ice quenching tower, flows from top to bottom along the tower wall embedded with dry ice, and the flue gas contacts the sprayed atomized quenching water downstream, due to the combination of cold water and dry ice Rapid gasification, the hot flue gas is cooled to below 200°C within 0.5S;

C除重金属;经急冷的烟气从干冰急冷塔的下部进入旋风除尘器,烟气温度维持在150℃-200℃,旋风除尘器顶端喷淋螯合剂溶液,螯合剂加压喷洒与烟气中的重金属充分混合形成颗粒物,颗粒物掉至颗粒传送带; C removal of heavy metals; the quenched flue gas enters the cyclone dust collector from the lower part of the dry ice quenching tower, the temperature of the flue gas is maintained at 150°C-200°C, the top of the cyclone dust collector is sprayed with a chelating agent solution, and the chelating agent is sprayed into the flue gas under pressure The heavy metals are fully mixed to form particles, and the particles fall to the particle conveyor belt;

D半干式脱酸;烟气从半干式脱酸塔下部进入,半干式脱酸塔底部旋转喷雾器向下喷洒熟石灰浆,熟石灰浆溶液与上升的烟气逆流,与烟气中的酸性物质反应生成干态粉末状物质,粉末掉落至颗粒传送带,烟气温度降至130℃以下; D Semi-dry deacidification; the flue gas enters from the lower part of the semi-dry deacidification tower, and the rotary sprayer at the bottom of the semi-dry deacidification tower sprays slaked lime slurry downwards, and the slaked lime slurry solution and the rising flue gas flow countercurrently, and the acidity in the flue gas The substance reacts to form a dry powder substance, the powder falls to the particle conveyor belt, and the temperature of the flue gas drops below 130°C;

E除颗粒物;烟气进入半干式脱酸塔和袋式除尘器之间的活性炭喷射器,由活性炭喷射器向烟气管道中喷射粉状活性炭,吸附杂质的活性炭颗粒从活性炭喷射器下端掉落至颗粒传送带; E Removal of particulate matter; the flue gas enters the activated carbon injector between the semi-dry deacidification tower and the bag filter, and the activated carbon injector sprays powdered activated carbon into the flue gas pipeline, and the activated carbon particles adsorbing impurities fall from the lower end of the activated carbon injector Fall to the pellet conveyor belt;

F吸附烟尘;烟气从袋式除尘器下部进入,温度控制在60℃以上,经过袋式除尘器内薄膜滤料进行过滤; F absorbs smoke and dust; the flue gas enters from the lower part of the bag filter, the temperature is controlled above 60°C, and is filtered through the film filter material in the bag filter;

G除二氧化碳;弱酸性气体进入中空纤维微孔膜过滤罐,温度控制在40℃-50℃,弱酸性气体在中空纤维微孔膜元件之间流动,中空纤维微孔膜元件表面的吸收液与二氧化碳反应,形成一种弱联结化合物; G removes carbon dioxide; weakly acidic gas enters the hollow fiber microporous membrane filter tank, the temperature is controlled at 40°C-50°C, the weakly acidic gas flows between the hollow fiber microporous membrane elements, the absorption liquid on the surface of the hollow fiber microporous membrane elements and Carbon dioxide reacts to form a weakly linked compound;

H排放气体;烟气进入二次加热炉,加热至250℃-350℃,再经由引风机通过高烟囱排入大气。 H exhaust gas; the flue gas enters the secondary heating furnace, is heated to 250°C-350°C, and then is discharged into the atmosphere through the high chimney through the induced draft fan.

废物衍生燃料焚烧产生的高温烟气在焚烧炉内腔出口端脱硫脱硝,通过烟道进入干冰急冷塔急速降温,进入旋风除尘器去除重金属、粒径较大的颗粒物,进入半干式脱酸塔中脱酸,进入活性炭喷射器吸附颗粒物,进入袋式除尘器吸附烟尘,进入中空纤维微孔膜过滤罐除二氧化碳,最后气体经由引风机、二次加热炉、高烟囱排入大气,过程中集取的飞灰、重金属、颗粒物固化处理,集取的铵盐再处理成为氨肥,集取的二氧化碳循环利用。 The high-temperature flue gas produced by the incineration of waste-derived fuels is desulfurized and denitrified at the outlet of the incinerator cavity, and enters the dry ice quenching tower through the flue for rapid cooling, enters the cyclone dust collector to remove heavy metals and larger particles, and enters the semi-dry deacidification tower The acid is deacidified in the medium, enters the activated carbon injector to absorb particulate matter, enters the bag filter to absorb dust, enters the hollow fiber microporous membrane filter tank to remove carbon dioxide, and finally the gas is discharged into the atmosphere through the induced draft fan, the secondary heating furnace, and the high chimney. The collected fly ash, heavy metals, and particles are solidified, the collected ammonium salt is reprocessed into ammonia fertilizer, and the collected carbon dioxide is recycled.

步骤A,脱硫脱硝。废物衍生燃料焚烧产生的烟气在焚烧炉内腔出口端停留2S以上,温度保持在850℃-1050℃,避免二恶英类物质生成。同时,焚烧炉内腔出口端的顶部通过氨水喷淋装置不间断喷淋氨水并配有环向助燃氧气,氧气、氨水和烟气中的酸性物质发生了多个反应,主要反应方程式如下: Step A, desulfurization and denitrification. The flue gas produced by the incineration of waste-derived fuel stays at the outlet of the incinerator for more than 2 seconds, and the temperature is kept at 850°C-1050°C to avoid the formation of dioxins. At the same time, the top of the outlet end of the incinerator cavity is continuously sprayed with ammonia water and equipped with circular combustion-supporting oxygen through the ammonia water spray device. Multiple reactions have occurred between oxygen, ammonia water and the acidic substances in the flue gas. The main reaction equation is as follows:

CO + O2 = CO2 CO + O2 = CO2

CO2 + 2NH3·H2O = CO(NH2)2 + H2O CO 2 + 2NH 3 H 2 O = CO(NH 2 ) 2 + H 2 O

SO2 + O2 = SO3 SO 2 + O 2 = SO 3

SO+ 2NH3·H2O = (NH4)2SO3 + H2O SO 2 + 2NH 3 H 2 O = (NH 4 ) 2 SO 3 + H 2 O

SO+ NH3·H2O = NH4HSO3 SO 2 + NH 3 H 2 O = NH 4 HSO 3

SO+ 2NH3·H2O = (NH4)2SO4 SO 3 + 2NH 3 H 2 O = (NH 4 ) 2 SO 4

2NO + O2 = 2NO2 2NO + O 2 = 2NO 2

6NO + 4NH3·H2O = 5N2 + 5H2O 6NO + 4NH 3 H 2 O = 5N 2 + 5H 2 O

2NO+ 2NH3·H2O = NH4NO3 + NH4NO2 + H2O 2NO 2 + 2NH 3 H 2 O = NH 4 NO 3 + NH 4 NO 2 + H 2 O

HF+ NH3·H2O = NH4F + H2O HF+ NH 3 H 2 O = NH 4 F + H 2 O

HCL+ NH3·H2O = NH4CL + H2O HCL+ NH 3 H 2 O = NH 4 CL + H 2 O

反应生成多种铵盐,由于此步骤是在高温环境中,水被迅速蒸发而不产生废水,生成的铵盐落入底部传送带,可进一步加工成氨肥。氨水浓度、氧气充入量根据烟气成分及流量大小调整。此步骤可在焚烧炉内腔进行脱硫脱硝,充分利用焚烧产生的热量,也无需添加催化剂,结构紧凑,节约成本、效果显著。 The reaction produces various ammonium salts. Since this step is in a high-temperature environment, the water is evaporated quickly without producing waste water. The ammonium salts generated fall into the bottom conveyor belt and can be further processed into ammonia fertilizer. The concentration of ammonia water and the filling amount of oxygen are adjusted according to the composition of flue gas and the flow rate. This step can carry out desulfurization and denitrification in the inner cavity of the incinerator, making full use of the heat generated by incineration, and does not need to add catalysts. It has a compact structure, saves costs, and has remarkable effects.

步骤B,防二恶英。由于冷水和干冰的迅速气化,热烟气在0.5S内冷却至200℃以下,避开了二恶英类前提物再次生成二恶英的条件。干冰急冷器除降温外,还有除尘作用。在烟气急冷的过程中,急冷水和干冰全部气化,使烟气降温、体积变小,同时也脱除一部分飞灰从急冷器下部排出至飞灰传送带,待后续工艺固化处理。 Step B, anti-dioxin. Due to the rapid gasification of cold water and dry ice, the hot flue gas is cooled to below 200°C within 0.5S, which avoids the conditions for the dioxin-like precursors to regenerate dioxins. In addition to cooling, the dry ice quencher also has the function of dust removal. During the quenching process of the flue gas, the quenching water and dry ice are all vaporized to cool down the flue gas and reduce its volume. At the same time, part of the fly ash is removed and discharged from the lower part of the quencher to the fly ash conveyor belt for solidification in the subsequent process.

步骤C,除重金属。旋风除尘器顶端喷淋的螯合剂溶液加压后与含有重金属的烟气充分混合,螯合剂与重金属离子强力螯合,使烟气中的重金属离子析出。螯合剂适用的PH值条件范围宽且受离子浓度影响小,可以与废气中铜、铅、锌、铁、钴、镍、锰、镉、汞、钨、钼、金、银等重金属离子螯合后形成颗粒。由于水在高温下气化,螯合形成的颗粒落入飞灰传送带,待后续工艺固化处理。步骤C反应温度优选150℃-200℃,此温度范围内无需对反应物加热,同时螯合剂与重金属离子螯合形成颗粒的粒径较大,且水可迅速气化,利于颗粒的脱落分离。 Step C, removing heavy metals. The chelating agent solution sprayed on the top of the cyclone dust collector is pressurized and fully mixed with the flue gas containing heavy metals. The chelating agent is strongly chelated with the heavy metal ions to precipitate the heavy metal ions in the flue gas. The chelating agent is suitable for a wide range of pH values and is less affected by ion concentration. It can chelate heavy metal ions such as copper, lead, zinc, iron, cobalt, nickel, manganese, cadmium, mercury, tungsten, molybdenum, gold, and silver in exhaust gas. Then particles are formed. Due to the gasification of water at high temperature, the particles formed by chelation fall into the fly ash conveyor belt and are to be solidified in the subsequent process. The reaction temperature of step C is preferably 150°C-200°C. In this temperature range, there is no need to heat the reactants. At the same time, the chelating agent and the heavy metal ion chelate to form particles with a large particle size, and the water can be quickly vaporized, which is conducive to the separation of the particles.

步骤D,半干式脱酸。烟气经旋风除尘器脱除掉粒径较大的颗粒物后进入半干式脱酸塔下部,塔顶通过喷嘴喷洒出的雾化熟石灰浆与上升的烟气逆流而充分接触,完成对烟气酸性污染物的吸收净化。半干式脱酸采用熟石灰浆与烟气中的酸性气体反应,可有效去除氢氟酸、氯化氢及部分二氧化碳。其主要反应方程式为: Step D, semi-dry deacidification. The flue gas enters the lower part of the semi-dry deacidification tower after being removed by the cyclone dust collector to remove the larger particles. Absorption and purification of acid pollutants. Semi-dry deacidification uses slaked lime slurry to react with acid gas in flue gas, which can effectively remove hydrofluoric acid, hydrogen chloride and part of carbon dioxide. Its main reaction equation is:

2HF+ Ca(OH)2 = CaF2 + 2H2O 2HF+ Ca(OH) 2 = CaF 2 + 2H 2 O

2HCl+ Ca(OH)2 = CaCl2 + 2H2O 2HCl + Ca(OH) 2 = CaCl 2 + 2H 2 O

CO2+ Ca(OH)2 = CaCO3 + H2O CO2 + Ca(OH) 2 = CaCO 3 + H 2 O

在半干式脱酸塔内,熟石灰浆中的水分在高温烟气作用下完全蒸发,无多余的废水生成,同时也使烟气温度降至130℃以下。反应后的生成物呈干态粉末状,除部分连同飞灰从半干式脱酸塔底部的飞灰传送带排出至后续工艺固化外,其余随烟气从脱酸塔上部通过抽风泵抽出。 In the semi-dry deacidification tower, the water in the slaked lime slurry is completely evaporated under the action of high-temperature flue gas, no redundant waste water is generated, and the temperature of the flue gas is also reduced to below 130°C. The product after the reaction is in the form of dry powder, except that some fly ash is discharged from the fly ash conveyor belt at the bottom of the semi-dry deacidification tower to be solidified in the subsequent process, and the rest is drawn out from the upper part of the deacidification tower with the flue gas through the exhaust pump.

步骤E,除颗粒物。由于活性炭表面多孔结构,可进一步吸附烟气中的重金属、粒径较小颗粒、灰飞及二恶英。吸附了污染物的活性炭颗粒在袋式除尘器中被薄膜滤料拦截,从烟气中分离出来,因而进一步去除烟气中的重金属、粒径较小颗粒、灰飞及二恶英。没有吸附污染物的活性炭颗粒在薄膜滤料表面形成滤饼,可继续吸附烟气残留的重金属、粒径较小颗粒、灰飞及二恶英。 Step E, remove particulate matter. Due to the porous structure on the surface of activated carbon, it can further absorb heavy metals, small particles, ash and dioxins in the flue gas. The activated carbon particles adsorbed pollutants are intercepted by the film filter material in the bag filter and separated from the flue gas, thus further removing heavy metals, small particles, ash and dioxins in the flue gas. Activated carbon particles that do not adsorb pollutants form a filter cake on the surface of the membrane filter material, which can continue to adsorb heavy metals, small particles, ash and dioxins remaining in the flue gas.

步骤F,吸附烟尘。烟气从袋式除尘器下部进入,温度控制在60℃以上,经过袋式除尘器内聚四氟乙烯薄膜滤料进行过滤。烟气的酸露点会影响滤料的可靠性和使用寿命。当烟气温度低于酸露点时,结露所产生的酸液将腐蚀除尘器或在滤料上形成烟尘粘结而影响过滤效果。经过上述步骤分离净化后,烟气酸露点为45℃-55℃,因此,此步骤温度控制在60℃以上,既无需另行加热烟气,有能减少酸性气体对设备的腐蚀。进一步,采用四氟乙烯薄膜滤料进行过滤,增强滤料抗腐蚀性并防止堵塞。 Step F, absorbing smoke and dust. The flue gas enters from the lower part of the bag filter, the temperature is controlled above 60°C, and is filtered through the polytetrafluoroethylene film filter material in the bag filter. The acid dew point of the flue gas will affect the reliability and service life of the filter material. When the flue gas temperature is lower than the acid dew point, the acid liquid produced by condensation will corrode the dust collector or form soot adhesion on the filter material, which will affect the filtering effect. After the separation and purification of the above steps, the acid dew point of the flue gas is 45°C-55°C. Therefore, the temperature in this step is controlled above 60°C. There is no need to heat the flue gas separately, and it can reduce the corrosion of the equipment by the acid gas. Further, the tetrafluoroethylene film filter material is used for filtration to enhance the corrosion resistance of the filter material and prevent clogging.

步骤G,除二氧化碳。烟气经过半干式脱酸塔除酸、袋式除尘器滤尘后,焚烧后的烟气已烟气分离,气体基本纯净仅含有少量残余的二氧化碳使气体呈弱酸性。弱酸性气体加压进入中空纤维微孔膜过滤罐,在中空纤维微孔膜元件之间流动,而吸收液逆向流动,二氧化碳在浓度梯度作用下层层渗入,中空纤维微孔膜元件表面的吸收液与二氧化碳充分接触,并反应生成一种弱联结化合物。处理后的气体经过二次加热炉再次加热并检测合格后,从高烟囱排入大气。富集二氧化碳后的吸收液经过液泵抽离中空纤维微孔膜元件表面,在热交换机中与未吸收二氧化碳的吸收液进行热交换后,再进入再生塔中解吸再生。 Step G, removing carbon dioxide. After the flue gas is deacidified by the semi-dry deacidification tower and filtered by the bag filter, the flue gas after incineration has been separated from the flue gas. The gas is basically pure and only contains a small amount of residual carbon dioxide, which makes the gas weakly acidic. Weak acid gas is pressurized into the hollow fiber microporous membrane filter tank, flows between the hollow fiber microporous membrane elements, while the absorption liquid flows in the opposite direction, carbon dioxide infiltrates layer by layer under the action of the concentration gradient, and the absorption liquid on the surface of the hollow fiber microporous membrane elements In full contact with carbon dioxide, it reacts to form a weakly linked compound. The treated gas is reheated by the secondary heating furnace and tested to be qualified, and then discharged into the atmosphere from the high chimney. The absorption liquid enriched with carbon dioxide is pumped away from the surface of the hollow fiber microporous membrane element through a liquid pump, and after heat exchange with the absorption liquid that has not absorbed carbon dioxide in the heat exchanger, it enters the regeneration tower for desorption and regeneration.

步骤H,排放气体。气体进入内腔洁净的二次加热炉加热至250℃-350℃,并通过各项指标检测均达标后,通过高烟囱排入大气。 Step H, discharging gas. The gas enters the secondary heating furnace with a clean inner cavity and is heated to 250°C-350°C, and after all indicators are up to standard, it is discharged into the atmosphere through a high chimney.

进一步地,所述废物衍生燃料焚烧烟气分离净化工艺流程采用计算机自动控制系统进行控制,所述计算机自动控制系统还包括检测系统、数据存储器和运行显示屏。 Further, the waste-derived fuel incineration flue gas separation and purification process flow is controlled by a computer automatic control system, and the computer automatic control system also includes a detection system, a data storage and an operation display screen.

所述计算机自动控制系统,能对废物衍生燃料焚烧烟气分离净化工艺所涉及的装置实行顺序自动启停,运行参数自动检测和储存,关键参数实行自动调节,使烟气净化装置实现自动化控制。计算机自动控制系统采用集散型控制结构,主要由工业控制计算机系统、PLC控制系统、现场控制系统、数据通讯网络等组成。引风机采用变频控制,根据燃料的特性及负荷变化情况进行调节。脉冲袋式除尘器清灰控制采用PLC控制装置,控制方式为定时、定阻,并设有温度、压力、流量、料位、滤袋破损的检测,实现对系统的监督和控制。 The computer automatic control system can automatically start and stop the devices involved in the waste-derived fuel incineration flue gas separation and purification process in sequence, automatically detect and store operating parameters, and automatically adjust key parameters, so as to realize automatic control of the flue gas purification device. The computer automatic control system adopts a distributed control structure, which is mainly composed of an industrial control computer system, a PLC control system, a field control system, and a data communication network. The induced draft fan adopts frequency conversion control, which is adjusted according to the characteristics of the fuel and the change of the load. The dust removal control of pulse bag filter adopts PLC control device, the control mode is timing and constant resistance, and it is equipped with detection of temperature, pressure, flow, material level and filter bag damage to realize the supervision and control of the system.

所述检测系统,用于每一个步骤重要控制点的检测以及最终排放气体各项指标的检测;所述数据存储器,用于整个系统运行数据的记录存储;所述运行显示屏,用于配合系统动画,实时查看工艺流程各个步骤的进度情况。进一步地,所述步骤A中,供氨设备包括氨水存储罐和氨水流量阀。氨水存储罐通过氨水流量阀控制向焚烧炉内氨水喷淋装置供氨。 The detection system is used for the detection of important control points in each step and the detection of various indicators of the final exhaust gas; the data storage is used for recording and storing the operation data of the entire system; the operation display screen is used to cooperate with the system Animation, real-time viewing of the progress of each step of the process. Further, in the step A, the ammonia supply equipment includes an ammonia water storage tank and an ammonia water flow valve. The ammonia water storage tank is controlled to supply ammonia to the ammonia water spraying device in the incinerator through the ammonia water flow valve.

进一步地,所述步骤B中,干冰急冷塔的塔壁为中空结构,中空层内部填充干冰碎块,中空层顶部连接二氧化碳收集器。收集的二氧化碳可回收循环利用。 Further, in the step B, the wall of the dry ice quenching tower is a hollow structure, the hollow layer is filled with dry ice pieces, and the top of the hollow layer is connected to a carbon dioxide collector. The collected carbon dioxide can be recovered and recycled.

进一步地,所述步骤D中,熟石灰浆由储存在熟石灰仓中的熟石灰经过下料器进入搅拌装置与水充分搅拌,再由熟石灰乳储槽至压力泵进入旋转喷雾器,由旋转喷雾器控制流量。 Further, in the step D, the slaked lime slurry is stored in the slaked lime bin through the feeder and enters the stirring device to be fully stirred with water, and then enters the rotary sprayer from the slaked lime milk storage tank to the pressure pump, and the flow rate is controlled by the rotary sprayer.

进一步地,所述步骤E中,活性炭储存在活性炭仓、经过给料器、鼓风机,通过活性炭喷嘴向烟气管道喷射粉状活性炭。粉状活性炭扩大接触面积,利用吸收。 Further, in the step E, the activated carbon is stored in the activated carbon bin, passes through the feeder, the blower, and sprays the powdered activated carbon to the flue gas pipe through the activated carbon nozzle. Powdered activated carbon expands the contact area and utilizes absorption.

进一步地,所述步骤F中,薄膜滤料采用PTFE复合滤料。PTFE复合滤料具有耐高温,耐腐蚀,过滤精度高等性能。 Further, in the step F, the film filter material adopts PTFE composite filter material. PTFE composite filter material has the properties of high temperature resistance, corrosion resistance and high filtration precision.

进一步地,所述步骤G中的中空纤维微孔膜元件采用聚丙烯材料;吸收液采用氨基酸钾溶液;吸收液温度为40℃-50℃。 Further, the hollow fiber microporous membrane element in the step G is made of polypropylene material; the absorbing liquid is made of amino acid potassium solution; the temperature of the absorbing liquid is 40°C-50°C.

所述步骤G中的中空纤维微孔膜元件采用聚丙烯材料;吸收液采用氨基酸钾溶液;吸收液温度为40℃-50℃。从加工成本及工艺稳定性方面考虑,中空纤维微孔膜元件的材料优选聚丙烯,吸收液优选氨基酸钾溶液。由于氨基酸钾溶液在40℃-50℃时对二氧化碳的吸收率最高,因此,要求中空纤维微孔膜过滤罐内反应温度控制在40℃-50℃。因反应过程产生的热量与损失的热量相当,因此要求进入中空纤维微孔膜过滤罐的气体温度和吸收液温度均维持在40℃-50℃。 The hollow fiber microporous membrane element in the step G is made of polypropylene material; the absorption liquid is amino acid potassium solution; the temperature of the absorption liquid is 40°C-50°C. Considering processing cost and process stability, the material of the hollow fiber microporous membrane element is preferably polypropylene, and the absorption liquid is preferably amino acid potassium solution. Since the amino acid potassium solution has the highest absorption rate of carbon dioxide at 40°C-50°C, the reaction temperature in the hollow fiber microporous membrane filter tank is required to be controlled at 40°C-50°C. Because the heat generated in the reaction process is equivalent to the heat lost, it is required that the temperature of the gas entering the hollow fiber microporous membrane filter tank and the temperature of the absorbing liquid be maintained at 40°C-50°C.

本发明与现有技术相比,具有以下优点及有益效果: Compared with the prior art, the present invention has the following advantages and beneficial effects:

(1)本发明在焚烧炉内脱硫脱硝,利用废物衍生燃料燃烧产生的热量,无需消耗能源再次加热,而且脱硫脱硝过程中产生的铵盐可用于氨肥生产,利用率高。 (1) The present invention desulfurizes and denitrates in the incinerator, uses the heat generated by the combustion of waste-derived fuels, and does not need to consume energy for reheating, and the ammonium salt produced during the desulfurization and denitrification process can be used for ammonia fertilizer production, with high utilization.

(2)本发明通过干冰急冷塔对焚烧炉内产生的高温烟气进行急速降温,避开二恶英等有害气体产生的条件,也降低后续步骤中涉及设备对耐高温性能的要求。 (2) The present invention rapidly cools the high-temperature flue gas generated in the incinerator through the dry ice quenching tower, avoids the conditions for the generation of harmful gases such as dioxins, and also reduces the requirements for high-temperature resistance of equipment involved in subsequent steps.

(3)本发明结构紧凑,避免烟气分离净化过程中二次污染的产生,烟气分离后的物质优化处理。 (3) The present invention has a compact structure, avoids secondary pollution during the separation and purification process of flue gas, and optimizes the treatment of substances after flue gas separation.

(4)本发明工艺有计算机自动控制,减轻工作人员劳动量和工作难度,确保整个系统运行的稳定性。 (4) The process of the present invention is automatically controlled by a computer, which reduces the labor and difficulty of the staff and ensures the stability of the entire system.

附图说明 Description of drawings

图1为本发明的工艺流程示意图。 Fig. 1 is a schematic diagram of the process flow of the present invention.

其中:1—焚烧炉;11—氨水存储罐;12—氨水喷淋装置;2—干冰急冷塔;21—二氧化碳收集器;3—旋风除尘器;4—半干式脱酸塔;41—熟石灰仓;42—下料器;43—搅拌装置;44—压力泵;45—旋转喷雾器;5—活性炭喷射器;51—活性炭仓;52—给料器;53—鼓风机;54—活性炭喷嘴;6—袋式除尘器;7—中空纤维微孔膜过滤罐;8—二次加热炉;9—引风机;10—高烟囱。 Among them: 1—incinerator; 11—ammonia water storage tank; 12—ammonia water spraying device; 2—dry ice quenching tower; 21—carbon dioxide collector; 3—cyclone dust collector; 4—semi-dry deacidification tower; 41—slaked lime warehouse; 42—feeder; 43—stirring device; 44—pressure pump; 45—rotary sprayer; 5—activated carbon injector; 51—activated carbon warehouse; 52—feeder; 53—blower; —bag filter; 7—hollow fiber microporous membrane filter tank; 8—secondary heating furnace; 9—induced fan; 10—high chimney.

具体实施方式 Detailed ways

下面结合实施例对本发明作进一步地详细说明,但本发明的实施方式不限于此。 The present invention will be further described in detail below in conjunction with examples, but the embodiments of the present invention are not limited thereto.

实施例1: Example 1:

本发明通过下述步骤实现:A脱硫脱硝;废物衍生燃料进入焚烧炉1进行焚烧,焚烧炉1内控制温度维持在850℃以上,焚烧炉1内腔出口端的温度保持在850℃-1050℃,烟气在焚烧炉1内腔出口端停留时间2S以上,同时,焚烧炉1内腔出口端的顶部通过氨水喷淋装置不间断喷淋氨水并配有环向助燃氧气,生成的氨肥落入底部的传送带; The present invention is realized through the following steps: A: desulfurization and denitrification; waste-derived fuel enters the incinerator 1 for incineration, the temperature in the incinerator 1 is controlled to be maintained above 850°C, and the temperature at the outlet end of the inner cavity of the incinerator 1 is maintained at 850°C-1050°C, The flue gas stays at the outlet of the inner chamber of the incinerator 1 for more than 2 seconds. At the same time, the top of the outlet of the inner chamber of the incinerator 1 is continuously sprayed with ammonia water and equipped with circular combustion-supporting oxygen through the ammonia water spraying device, and the generated ammonia fertilizer falls to the bottom. conveyor belt;

B防二恶英;热烟气从干冰急冷塔2的上部进入,顺着内嵌干冰的塔壁从上往下流动,烟气与喷入的雾化急冷水顺流接触,由于冷水和干冰的迅速气化,热烟气在0.5S内冷却至200℃以下; B anti-dioxin; hot flue gas enters from the upper part of the dry ice quenching tower 2, flows from top to bottom along the tower wall embedded with dry ice, and the flue gas contacts with the sprayed atomized quenching water downstream, due to the cold water and dry ice Rapid gasification, the hot flue gas is cooled to below 200°C within 0.5S;

C除重金属;经急冷的烟气从干冰急冷塔2的下部进入旋风除尘器3,烟气温度维持在150℃-200℃,旋风除尘器3顶端喷淋螯合剂溶液,螯合剂加压喷洒与烟气中的重金属充分混合形成颗粒物,颗粒物掉至颗粒传送带; C removal of heavy metals; the quenched flue gas enters the cyclone dust collector 3 from the bottom of the dry ice quenching tower 2, the flue gas temperature is maintained at 150°C-200°C, the top of the cyclone dust collector 3 is sprayed with a chelating agent solution, and the chelating agent is sprayed under pressure and The heavy metals in the flue gas are fully mixed to form particles, which fall to the particle conveyor belt;

D半干式脱酸;烟气从半干式脱酸塔4下部进入,半干式脱酸塔4底部旋转喷雾器向下喷洒熟石灰浆,熟石灰浆溶液与上升的烟气逆流,与烟气中的酸性物质反应生成干态粉末状物质,粉末掉落至颗粒传送带,烟气温度降至130℃以下; D Semi-dry deacidification; the flue gas enters from the bottom of the semi-dry deacidification tower 4, and the rotary sprayer at the bottom of the semi-dry deacidification tower 4 sprays slaked lime slurry downwards, and the slaked lime slurry solution and the rising flue gas flow countercurrently, and are mixed with the flue gas The acidic substance reacts to form a dry powder substance, the powder falls to the particle conveyor belt, and the temperature of the flue gas drops below 130°C;

E除颗粒物;烟气进入半干式脱酸塔4和袋式除尘器6之间的活性炭喷射器5,由活性炭喷嘴54向烟气管道中喷射粉状活性炭,吸附杂质的活性炭颗粒从活性炭喷射器5下端掉落至颗粒传送带; E removal of particulate matter; the flue gas enters the activated carbon injector 5 between the semi-dry deacidification tower 4 and the bag filter 6, and the activated carbon nozzle 54 injects powdered activated carbon into the flue gas pipeline, and the activated carbon particles adsorbing impurities are injected from the activated carbon The lower end of the device 5 falls to the particle conveyor belt;

F吸附烟尘;烟气从袋式除尘器6下部进入,温度控制在60℃以上,经过袋式除尘器6内薄膜滤料进行过滤; F absorbs smoke and dust; the flue gas enters from the lower part of the bag filter 6, the temperature is controlled above 60°C, and is filtered through the film filter material in the bag filter 6;

G除二氧化碳;弱酸性气体进入中空纤维微孔膜过滤罐7,温度控制在40℃-50℃,弱酸性气体在中空纤维微孔膜元件之间流动,中空纤维微孔膜元件表面的吸收液与二氧化碳反应,形成一种弱联结化合物; G removes carbon dioxide; the weak acid gas enters the hollow fiber microporous membrane filter tank 7, the temperature is controlled at 40°C-50°C, the weak acid gas flows between the hollow fiber microporous membrane elements, and the absorption liquid on the surface of the hollow fiber microporous membrane elements Reacts with carbon dioxide to form a weakly linked compound;

H排放气体;烟气进入二次加热炉8,加热至250℃-350℃,再经由引风机9通过高烟囱10排入大气。 H exhaust gas; the flue gas enters the secondary heating furnace 8, is heated to 250°C-350°C, and then is discharged into the atmosphere through the high chimney 10 through the induced draft fan 9.

实施例2: Example 2:

本实施例在上述实施例的基础上进一步优化,进一步地,所述废物衍生燃料焚烧烟气分离净化工艺流程采用计算机自动控制系统进行控制,所述计算机自动控制系统还包括检测系统、数据存储器和运行显示屏。 This embodiment is further optimized on the basis of the above embodiments. Further, the waste-derived fuel incineration flue gas separation and purification process is controlled by a computer automatic control system, and the computer automatic control system also includes a detection system, a data storage and Run the display.

所述焚烧炉1内腔出口端设置温度检测装置和烟道阀门,当检测到焚烧炉1内腔出口端温度低于800℃时,容易产生二恶英等有毒气体,而且不利于无催化剂情况下的脱硫脱硝,故由控制系统发出信号,关闭烟道阀门,直至温度达到工艺要求再开启。 The outlet of the inner cavity of the incinerator 1 is equipped with a temperature detection device and a flue valve. When it is detected that the temperature at the outlet of the inner cavity of the incinerator 1 is lower than 800°C, it is easy to generate toxic gases such as dioxin, which is not conducive to the situation of no catalyst. Therefore, the control system sends a signal to close the flue valve until the temperature reaches the process requirements before opening it.

所述袋式除尘器6中间设有旁路通道,通道两端设置由控制信号触发的阀门,一旦进入除尘器的烟气温度低于60℃,由控制系统发出信号,阀门切换,烟气经旁路通过,延长袋式除尘器6的使用寿命。 There is a bypass channel in the middle of the bag filter 6, and valves triggered by control signals are set at both ends of the channel. Once the temperature of the flue gas entering the dust collector is lower than 60°C, a signal is sent by the control system, the valve is switched, and the flue gas passes through Bypass to prolong the service life of the bag filter 6.

以上所述,仅是本发明的较佳实施例,并非对本发明做任何形式上的限制,凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化,均落入本发明的保护范围之内。 The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention in any form. Any simple modifications and equivalent changes made to the above embodiments according to the technical essence of the present invention all fall within the scope of the present invention. within the scope of protection.

Claims (8)

1.一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于,包括以下步骤: 1. A waste-derived fuel incineration flue gas separation and purification process is characterized in that, comprising the following steps: A脱硫脱硝;废物衍生燃料进入焚烧炉(1)进行焚烧,焚烧炉(1)内控制温度维持在850℃以上,焚烧炉(1)内腔出口端的温度保持在850℃-1050℃,烟气在焚烧炉(1)内腔出口端停留时间2S以上,同时,焚烧炉(1)内腔出口端的顶部通过氨水喷淋装置(12)不间断喷淋氨水并配有环向助燃氧气,生成的氨肥落入底部的传送带; A desulfurization and denitrification; waste-derived fuel enters the incinerator (1) for incineration, the temperature in the incinerator (1) is maintained above 850°C, and the temperature at the outlet of the inner cavity of the incinerator (1) is maintained at 850°C-1050°C, and the flue gas The residence time at the outlet end of the inner cavity of the incinerator (1) is more than 2 seconds. At the same time, the top of the inner cavity outlet end of the incinerator (1) is continuously sprayed with ammonia water and equipped with annular combustion-supporting oxygen through the ammonia water spray device (12), and the generated Ammonia fertilizer falls to the conveyor belt at the bottom; B防二恶英;热烟气从干冰急冷塔(2)的上部进入,顺着内嵌干冰的塔壁从上往下流动,烟气与喷入的雾化急冷水顺流接触,由于冷水和干冰的迅速气化,热烟气在0.5S内冷却至200℃以下; B Anti-dioxin; hot flue gas enters from the upper part of the dry ice quenching tower (2), flows from top to bottom along the tower wall embedded with dry ice, and the flue gas contacts with the sprayed atomized quenching water downstream, due to the cold water With the rapid gasification of dry ice, the hot flue gas is cooled to below 200°C within 0.5S; C除重金属;经急冷的烟气从干冰急冷塔(2)的下部进入旋风除尘器(3),烟气温度维持在150℃-200℃,旋风除尘器(3)顶端喷淋螯合剂溶液,螯合剂加压喷洒与烟气中的重金属充分混合形成颗粒物,颗粒物掉至颗粒传送带; C removal of heavy metals; the quenched flue gas enters the cyclone dust collector (3) from the lower part of the dry ice quenching tower (2), the temperature of the flue gas is maintained at 150°C-200°C, and the top of the cyclone dust collector (3) is sprayed with a chelating agent solution, The chelating agent is sprayed under pressure and fully mixed with the heavy metals in the flue gas to form particles, which fall to the particle conveyor belt; D半干式脱酸;烟气从半干式脱酸塔(4)下部进入,半干式脱酸塔(4)底部旋转喷雾器(45)向下喷洒熟石灰浆,熟石灰浆溶液与上升的烟气逆流,与烟气中的酸性物质反应生成干态粉末状物质,粉末掉落至颗粒传送带,烟气温度降至130℃以下; D Semi-dry deacidification; the flue gas enters from the lower part of the semi-dry deacidification tower (4), and the rotary sprayer (45) at the bottom of the semi-dry deacidification tower (4) sprays slaked lime slurry downward, and the slaked lime slurry solution and the rising smoke The gas flows countercurrently and reacts with the acidic substances in the flue gas to form a dry powdery substance. The powder falls to the particle conveyor belt, and the temperature of the flue gas drops below 130°C; E除颗粒物;烟气进入半干式脱酸塔(4)和袋式除尘器(6)之间的活性炭喷射器(5),由活性炭喷嘴(54)向烟气管道中喷射粉状活性炭,吸附杂质的活性炭颗粒从活性炭喷射器(5)下端掉落至颗粒传送带; E to remove particulate matter; the flue gas enters the activated carbon injector (5) between the semi-dry deacidification tower (4) and the bag filter (6), and the activated carbon nozzle (54) injects powdered activated carbon into the flue gas pipeline, Activated carbon particles that absorb impurities fall from the lower end of the activated carbon injector (5) to the particle conveyor belt; F吸附烟尘;烟气从袋式除尘器(6)下部进入,温度控制在60℃以上,经过袋式除尘器(6)内薄膜滤料进行过滤; F absorbs smoke and dust; the flue gas enters from the lower part of the bag filter (6), the temperature is controlled above 60°C, and is filtered through the inner membrane filter material of the bag filter (6); G除二氧化碳;弱酸性气体进入中空纤维微孔膜过滤罐(7),温度控制在40℃-50℃,弱酸性气体在中空纤维微孔膜元件之间流动,中空纤维微孔膜元件表面的吸收液与二氧化碳反应,形成一种弱联结化合物; G removes carbon dioxide; the weak acid gas enters the hollow fiber microporous membrane filter tank (7), the temperature is controlled at 40°C-50°C, the weak acid gas flows between the hollow fiber microporous membrane elements, and the surface of the hollow fiber microporous membrane elements The absorbing liquid reacts with carbon dioxide to form a weakly linked compound; H排放气体;烟气进入二次加热炉,加热至250℃-350℃,再经由引风机(9)通过高烟囱(10)排入大气。 H exhaust gas; the flue gas enters the secondary heating furnace, is heated to 250°C-350°C, and then is discharged into the atmosphere through the induced draft fan (9) and the high chimney (10). 2.根据权利要求1所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述废物衍生燃料焚烧烟气分离净化工艺流程采用计算机自动控制系统进行控制,所述计算机自动控制系统还包括检测系统、数据存储器和运行显示屏。 2. A waste-derived fuel incineration flue gas separation and purification process according to claim 1, characterized in that: the waste-derived fuel incineration flue gas separation and purification process flow is controlled by a computer automatic control system, and the computer automatic control The system also includes a detection system, a data storage and a running display. 3.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤A中,供氨设备包括氨水存储罐(11)和氨水流量阀,氨水存储罐(11)通过氨水流量阀控制向焚烧炉(1)内氨水喷淋装置(12)供氨。 3. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: in the step A, the ammonia supply equipment includes an ammonia water storage tank (11) and an ammonia water flow valve, and the ammonia water storage The tank (11) supplies ammonia to the ammonia water spraying device (12) in the incinerator (1) through the ammonia water flow valve control. 4.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤B中,干冰急冷塔(2)的塔壁为中空结构,中空层内部填充干冰碎块,中空层顶部连接二氧化碳收集器(21)。 4. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: in the step B, the wall of the dry ice quenching tower (2) is a hollow structure, and the hollow layer is filled with Dry ice pieces, the top of the hollow layer is connected to the carbon dioxide collector (21). 5.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤D中,熟石灰浆由储存在熟石灰仓(41)中的熟石灰经过下料器(42)进入搅拌装置(43)与水充分搅拌,再由熟石灰乳储槽、压力泵(44)进入旋转喷雾器(45),由旋转喷雾器(45)控制流量。 5. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: in the step D, the slaked lime slurry is stored in the slaked lime bin (41) through the feeder (42) Enter the stirring device (43) and fully stir with water, then enter the rotary sprayer (45) from the milk of slaked lime storage tank and pressure pump (44), and the flow rate is controlled by the rotary sprayer (45). 6.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤E中,活性炭储存在活性炭仓(51)、经过给料器(52)、鼓风机(53),通过活性炭喷嘴(54)向烟气管道喷射粉状活性炭。 6. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: in the step E, the activated carbon is stored in the activated carbon bin (51), passes through the feeder (52), The blower (53) sprays powdered activated carbon to the flue gas duct through the activated carbon nozzle (54). 7.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤F中,薄膜滤料采用PTFE复合滤料。 7. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: in the step F, the film filter material is a PTFE composite filter material. 8.根据权利要求1或2所述的一种废物衍生燃料焚烧烟气分离净化工艺,其特征在于:所述步骤G中的中空纤维微孔膜元件采用聚丙烯材料;吸收液采用氨基酸钾溶液;吸收液温度为40℃-50℃。 8. A waste-derived fuel incineration flue gas separation and purification process according to claim 1 or 2, characterized in that: the hollow fiber microporous membrane element in the step G is made of polypropylene material; the absorption liquid is made of potassium amino acid solution ; The temperature of the absorption liquid is 40°C-50°C.
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