CN104245265B - For collecting the method and system of thermoplastic resin - Google Patents
For collecting the method and system of thermoplastic resin Download PDFInfo
- Publication number
- CN104245265B CN104245265B CN201280072547.1A CN201280072547A CN104245265B CN 104245265 B CN104245265 B CN 104245265B CN 201280072547 A CN201280072547 A CN 201280072547A CN 104245265 B CN104245265 B CN 104245265B
- Authority
- CN
- China
- Prior art keywords
- thermoplastic resin
- hollow mould
- heat
- arresting structure
- mould
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0203—Separating plastics from plastics
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
- B29B2017/0213—Specific separating techniques
- B29B2017/0255—Specific separating techniques using different melting or softening temperatures of the materials to be separated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
For collecting the system of thermoplastic resin, it includes heating arrangements, and this heating arrangements is configured to heat described thermoplastic resin, to control its viscoelasticity；Pressing mechanism, this pressing mechanism is configured to apply pressure reduction to the surface of described thermoplastic resin；And arresting structure, this arresting structure is constructed for capturing a part for described thermoplastic resin.
Description
Technical field
It relates to for the method and system collecting thermoplastic resin.
Background technology
Along with the use of durable consumer goods is more and more universal, use High performance plastic resin, its kind the most more
Class also will be more, it is therefore desirable to toughness and mouldability according to resin collect these high-performance thermoplastic trees subtly
Fat, for recycling, forms higher-quality thermoplastic resin.Particularly more come in household wares and Automobile Products
Use high performance thermoplastic resin manyly.Especially, when using high property in optical element and high-strength parts
During energy thermoplastic resin, processing technique is extremely complex, and raw material is the most costly；Accordingly, it would be desirable to these are high
The thermoplastic resin of performance can recycle to be more nearly the quality level of the quality level of original product.
The most generally the method collecting thermoplastic resin of employing is by means of proportion and/or charge characteristic, even now
Method is very simple, but is but unsuitable for collecting high performance thermoplastic resin subtly.Such as, because should different
In with, (television set, automobile etc.) expects that high performance thermoplastic resin has different thermostabilitys and mouldability, because of
These needs carry out different adjustment according to different application scenarios, including changing molecular weight, being doped with different molecular weight
Polymer, the different monomer of copolymerization, and add functional group, and in some cases, also can mix different
Polymer, thus form polymer alloy.By such adjustment, can be as required by the organic composite of limited quantity
Thing (monomer) makes the thermoplastic resin of various characteristic.But, such adjustment is without making high-performance thermoplastic tree
Fat has proportion and the charge characteristic of inequality；Therefore, these high-performance heat is collected by proportion and/or charge characteristic
Plastic resin is relatively difficult.
Additionally, in the case of being adjusted according to molecular weight, even if carrying out the spectrum analysis of such as infrared analysis,
It is also impossible to be collected.For copolymer, polymer mixture and polymeric alloy, to a certain extent
Identification in addition can be carried out by spectrum analysis, but hardly possible accurately identification and be collected in thermoplastic resin intermixture
In miscellaneous thermoplastic resin of containing with different weight percentage.
In order to reclaim be more nearly the quality level of original product by quality level in the way of, need to receive more subtly
Collection thermoplastic resin.Specifically, not only will according to title material (such as ABS, cyclenes, polyimides etc.),
But also to collect thermoplastic resin according to the characteristic of their molecular weight and such as thermostability or mouldability.Heat-resisting
Property determined by the material that used, and mouldability is determined by the requirement of product.Poor mouldability can make product have
Flaw, thus the quality of product can be greatly affected.
For thermoplastic resin, directly affecting of the softening point that thermostability is represented by Tg (vitrifying point),
And mouldability is affected by the storage modulus in the temperature range (caoutchouc elasticity scope) from vitrifying point to melting point.
On the whole, such characteristic is normally referred to as rheological behavior (kinetics viscoelasticity).Some thermoplastic resins have phase
As main chain (backbone), thus Tg is of substantially equal, but has different characteristic (examples in the range of caoutchouc elasticity
As, the difference such as storage modulus).Because the purpose being adjusted such thermoplastic resin is primarily to improve it
Mouldability, thus preferably separate these thermoplastic resins, and to by the product with original this thermoplastic resin of use
The thermoplastic resin that as category, the thermoplastic resin of these in product is made is recycled.
Accompanying drawing explanation
Fig. 1 shows the partial sectional view of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 2 shows the partial sectional view of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 3 shows the partial sectional view of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 4 shows the partial sectional view of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 5 shows the rheological behavior of different thermoplastic resin.
Fig. 6 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 7 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 8 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Fig. 9 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Figure 10 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Figure 11 shows the schematic perspective view of the hollow mould according to embodiment of the present disclosure.
Figure 12 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Figure 13 shows the schematic diagram of the system for collecting thermoplastic resin according to embodiment of the present disclosure.
Detailed description of the invention
The advantage of the disclosure is, thermoplastic resin has the rheological behavior of uniqueness, thus can be based on them from softening
Put the difference of scope (caoutchouc elasticity scope) the interior rheological behavior between melting point and collect thermoplastic resin.Due to
Storage modulus in the range of caoutchouc elasticity is proportional to the power needed for deformation, thus can be determined by thermoplastic resin and exist
Deformation extent under uniform temperature, certain pressure and measure storage modulus.When determining the deformation extent of thermoplastic resin,
Certain pressure can be applied at a certain temperature poor to the surface of thermoplastic resin.
Such as, can be by applying the malleation higher than atmospheric pressure to the specific region on the surface of thermoplastic resin, and simultaneously
Atmospheric pressure is applied to the region in addition to this specific region on the surface of this thermoplastic resin；Or to this thermoplastic resin
The specific region on the surface of fat applies the negative pressure lower than atmospheric pressure, and simultaneously should to removing of the surface of this thermoplastic resin
Region outside specific region applies atmospheric pressure；Or, such as by the given zone on the surface of this thermoplastic resin
Territory applies the malleation higher than atmospheric pressure, and executes to the region in addition to this specific region on the surface of this thermoplastic resin
Than adding the negative pressure that atmospheric pressure is low, thus apply specific pressure differential to the surface of thermoplastic resin.
So, under particular pressure differential and specified temp, the thermoplastic resin that rheological behavior is in particular range just occurs
Deformation, and under this particular pressure differential and specified temp, rheological behavior is just in the thermoplastic resin outside this particular range
Do not deform.The collection of thermoplastic resin can be carried out based on rheological behavior.
According to the disclosure, even with having similar proportion, the thermoplasticity of similar charge characteristic owing to main chain is similar to
Resin, it is possible to rheological behaviors based on them and finely collect, and, can be similar to having based on rheological behavior
The thermoplastic resin group of thermostability carries out finer collection.Therefore, can collect subtly be difficult to traditionally by than
The thermoplastic resin that weight and/or charge characteristic are collected, such as, have different molecular weight or different the gathering of content accounting
Compound, copolymer mixture and there is the polymer alloy of different blending ratio, thus can provide uniform quality and
Thus the recovery resin that can easily recycle in the product similar with primary products.
By with reference to the accompanying drawing constituting a disclosure part in the following detailed description.In accompanying drawing, except as otherwise noted, phase
With reference be commonly referred to as identical parts.And, the effect of accompanying drawing indicates that, and be not necessarily according to
Ratio is drawn.Exemplary embodiment, accompanying drawing and claim in detailed description is not determinate.Can adopt
Use other embodiments, it is possible to making other and change, these are all without departing from the spirit or scope of this paper theme.Can be easy
It is understood by, generally herein upper disclosure each side that describe and illustrated in the accompanying drawings, may be adjusted, replace,
Combining, separate, design, thus form multiple different structure, all these structures contain the most definitely in herein.
Fig. 1 shows the partial cutaway of the system 10 for collecting thermoplastic resin 50 according to embodiment of the present disclosure
View.System 10 can be provided with hollow mould 20, transmission band 30, and pressure roller 40.Hollow mould 20 and pressure roller
40 both sides that can be arranged on transmission band 30 opposite each otherly.Can be by transmission band 30 at hollow mould 20 and pressure roller
Thermoplastic resin 50 is transported between 40.Hollow mould 20 can arrange at least one hole 22, to catch on its surface 21
Obtain a part for thermoplastic resin 50.At least one hole 22 described may pass through the inner side and outer side of hollow mould 20.
The size at least one hole 22 described can be about a few tenths of of thermoplastic resin 50 size.Hollow mould 20 exists
The coating of low-surface-energy it is coated with on surface 21 in addition at least one hole 22 described.
Pressure roller 40 may be configured as applying uniform pressure to thermoplastic resin 50.Extruding towards thermoplastic resin 50
During hollow mould 20, system 10 can apply to be higher than to the contact area between thermoplastic resin 50 and hollow mould 20
The malleation of atmospheric pressure, meanwhile, by least one hole 22 described to thermoplastic resin 50 and hollow mould
Non-contact area between 20 applies atmospheric pressure.So, just surface to thermoplastic resin 50 is applied with certain
Pressure differential.
As it is shown in figure 1, towards thermoplastic resin 50 extruded hollow mould 20 and simultaneously to thermoplastic resin 50
When heating is to control its viscoelasticity, the thermoplastic resin 50 that rheological behavior falls within a certain range just deforms,
In so the thermoplastic resin 50 of some enters at least one hole 22 described.Then, rheological behavior falls into this
Thermoplastic resin 50 in particular range is just captured in hollow mould 20.In this article, hollow mould 20
Arrive the effect of arresting structure, its part being configured to capture thermoplastic resin 50.
In contrast, as in figure 2 it is shown, towards thermoplastic resin 50 extruded hollow mould 20 and simultaneously
When heating thermoplastic resin 50 to control its viscoelasticity, rheological behavior is positioned at the thermoplasticity outside this particular range
Resin 50 does not deforms, and a part for thermoplastic resin 50 does not enter at least one hole 22 described.This
Sample, rheological behavior is positioned at the thermoplastic resin 50 outside this particular range and would not be captured by hollow mould 20.
Optionally, as it is shown on figure 3, system 10 can be provided with vacuum draw unit 90.Towards 50 extruded hollow
During mould 20, system 10 can seal connecing between thermoplastic resin 50 and hollow mould 20 applying predetermined pressure
Touch while region, utilize vacuum draw unit 90, by least one hole 22 described to thermoplastic resin 50
And the contact area between hollow mould 20 applies the negative pressure of subatmospheric power.So, can be to thermoplastic resin 50
Surface apply certain pressure reduction.Thus thermoplastic resin can be collected based on identical aforementioned principles based on rheological behavior
Fat.
Optionally, as shown in Figure 4, system 10 uses mould 23 rather than hollow mould 20.This mould 23
At least one recess 25 can be provided with, to capture a part for thermoplastic resin 50 on its surface 24.Recess 25
Size is about a few tenths of of thermoplastic resin 50 size.Removing at least one recess 25 described of mould 23
Surface can be coated with the coating of low-surface-energy.Mould 23 may be configured to the surface of extrusion of thermoplastic resin 50.When to
When thermoplastic resin 50 extrusion die 23, system 10 is just to contacting between thermoplastic resin 50 with mould 23
Region applies the malleation of superatmospheric power, meanwhile by recess 25 to thermoplastic resin 50 and hollow mould
Non-contact area between 23 applies atmospheric pressure.So, just surface to thermoplastic resin 50 is applied with certain
Pressure reduction.Thermoplastic resin can be collected based on rheological behavior based on identical aforementioned principles.With hollow mould 20 class
As be that mould 23 serves the effect of arresting structure, consist of capture thermoplastic resin 50 a part.
In a non-restrictive version of the disclosure, heat and pressure differential can be applied to multiple thermoplastic resin 50, can
At least capture one of which thermoplastic resin 50.Can select to execute based on the softening point of thermoplastic resin 50 to be captured
The heat added.And, executing of selection pressure difference can be carried out based on the desirable pressure making thermoplastic resin 50 to be captured distort
Dosage.
Thermoplastic resin 50 can include, but are not limited to: vinyl chloride, polypropylene, polyethylene, Merlon, nylon,
Acrylonitrile butadiene styrene polymer, acrylic acid, polystyrene, pi, polyamide, polyvinyl acetate,
Polybutylene terephthalate (PBT), polyethylene terephthalate, polyether sulfone, polysulfones, polyphenylene sulfide, acrylonitrile
-SAN, ethylene-vinyl acetate copolymer, acrylonitritrile-styrene resin, acrylonitrile-benzene
Ethylene-acrylic acid resin copolymer, acrylonitrile ethylene styrene copolymer, acrylonitrile-chloride polyethylene-styrene copolymerized
Thing, ethylene-vinyl alcohol copolymer, MBS, styrene-butadiene-benzene
Ethylene block copolymer, styrene-ethylene-butylene-styrene block copolymer, and ethylene/propylene/diene ternary
Copolymer.
The principle collecting thermoplastic resin based on rheological behavior it is described more fully hereinafter with reference to Fig. 5 to Fig. 9.Figure
5 rheological behaviors showing different thermoplastic resin a, b, c and d.Its represent the most respectively temperature and
Pressure.The operation that system 10 according to the disclosure is carried out has uniqueness based on thermoplastic resin a, b, c and d
Rheological behavior.Such as, consider collect have rheological behavior as shown in Figure 5 thermoplastic resin a, b, c and
During d, can be collected by procedure below.
First, as shown in Figure 6, temperature can be set as T1, this temperature T1 is higher than thermoplastic resin a's and b
Tg, but is below the Tg (Tg (a)=Tg (b) < T1 < Tg (c) < Tg (d)) of thermoplastic resin c and d.
Here, Tg (a), Tg (b), Tg (c) and Tg (d) represent thermoplastic resin a, b, c and d respectively
Tg.At temperature T1, only thermoplastic resin a and b enters caoutchouc elasticity state, and their storage modulus
It is about the one thousandth that temperature is storage modulus during Tg or following.Therefore, towards thermoplasticity at temperature T1
During resin a, b, c and d extruded hollow mould 20, only there is areal deformation in thermoplastic resin a and b.
The Stress control can being applied on pressure roller 40 and be set as P1 (r1 (a) < P1 < r1 (b)), it is higher than r1
(a) (=thermoplastic resin a storage modulus E1 (a)/(required strain fm) at temperature T1), and be less than
R1 (b) (=thermoplastic resin b storage modulus E1 (b)/(required strain fm) at temperature T1), wherein
Fm represents being partly at least one hole 22 described and being attached to the surface of hollow mould 20 of thermoplastic resin
Minimum strain required on 21.By identical mould, the thermoplastic resin with known features being carried out process can be true
This value fixed.Storage modulus E2 of thermoplastic resin b is more than E1 (E1 < E2), and P1 < r1 (b) (=thermoplastic resin
Fat b storage modulus E2/ (required strain fm) at temperature T1).Therefore, even at thermoplastic resin b
In the case of contacting with hollow mould 20 under pressure P1, the surface of thermoplastic resin b also will not occur enough
Deformation.Then, hollow mould 20 only captures thermoplastic resin a, thus can be from remaining thermoplastic resin b, c
With d isolates thermoplastic resin a.
Then, as it is shown in fig. 7, in the case of maintaining temperature to be T1, can be by boost in pressure to P2, it is more than r1
(b) (=thermoplastic resin b storage modulus E1 (b)/(required strain fm) at temperature T1), and repeat
Identical process.In the case, in the group of remaining thermoplastic resin b, c and d, only thermoplastic resin
There is sufficiently deformation in b, thus is captured by hollow mould 20.So, can be from remaining thermoplastic resin c and d
In be separately separated out thermoplastic resin b.
Such as, as shown in Figure 8, temperature can be brought up to T2, this value is positioned at Tg (c) and the heat of thermoplastic resin c
Between the Tg (d) of plastic resin d, and pressure is set to P1.At temperature T2, thermoplastic resin c is in
Caoutchouc elasticity state, but r2 (c)=(=thermoplastic resin c storage modulus E2 (c)/(institute at temperature T2
The strain fm needed)) more than P1 (P1 < r2 (c)).Therefore, the surface of thermoplastic resin c does not deforms, therefore
Thermoplastic resin c is not captured by hollow mould 20.
As it is shown in figure 9, owing to pressure being further increased to P2 and having carried out identical operation, thus by r2 (c)
It is set smaller than P2 (r2 (c) < P2).Therefore, there is sufficiently deformation in thermoplastic resin c, and by hollow mould
20 captures.So, thermoplastic resin c can be isolated from remaining thermoplastic resin d.By such operation weight
Change temperature and pressure again, such as, by raising temperature and pressure the most from low to high, can be by their stream
Become characteristic and collect different thermoplastic resin a, b, c and d subtly.
Hereinafter this process is summed up.First design temperature.Then, while maintaining temperature, change step by step
Pressure changeable.Finally, separate and collect rheological behavior thermoplastic resin in given range.Such as, warmed-up heat
The temperature of plastic resin a, b, c and d can be about 35 degrees Celsius to about 200 degrees Celsius.Pressure applied is poor
Can be about 0.01MPa to about 10MPa.Such as, if the one in thermoplastic resin a, b, c and d is glass
Transition point be about from 96 degrees Celsius to about 105 degrees Celsius and its storage modulus at 130 degrees Celsius time be about 5MPa's
ABS resin, then, under 130 degrees Celsius, the pressure reduction being applied in ABS resin is about 1MPa to about 10MPa.
And, if the one in thermoplastic resin a, b, c and d is glass transition point is about 135 degrees Celsius and energy storage mould
Amount is about the cycloolefin copolymer resins of 0.13MPa when 170 degrees Celsius, then, under 170 degrees Celsius, be applied to
Pressure reduction on cycloolefin copolymer resins is about 0.05MPa to about 0.5MPa.
Table 1
| Temperature | Pressure | Resin in mixture | The resin separated | Remaining resin |
| T1 | P1 | a,b,c,d | a | b,c,d |
| T1 | P2 | b,c,d | b | c,d |
| T2 | P1 | c,d | Non | c,d |
| T2 | P2 | c,d | c | d |
By repeat above procedure, by processing repeatedly above under identical temperature and pressure, can improve by
The purity of the thermoplastic resin of empty mould 20 capture.
Figure 10 shows the schematic diagram of the system 10 according to one aspect of the disclosure.In addition to the structure shown in Fig. 1,
System 10 can be provided with pressing mechanism 60 and heating arrangements 70.This pressing mechanism 60 may be configured to thermoplastic resin 50
Surface apply pressure reduction.Specifically, as shown in Figure 10, pressing mechanism 60 can be provided with arm 62 and pressing creation dress
Put 63.Hollow mould 20 can be provided with bearing bracket stand 61, so that hollow mould 20 rotates.Hollow mould 20 can be
Roll mould.Similarly, pressure roller 40 can be provided with bearing bracket stand 65, so that pressure roller 40 rotates.The first end of wall 62
Being connected to bearing bracket stand 61, hollow mould 20 can rotate relative to this bearing bracket stand.By pressure generation device 63 to
When the second end of arm 62 applies power, arm 62 rotates relative to fulcrum 64, is then attached to the first end of arm 62
Bearing bracket stand 61 move towards pressure roller 40.So, the thermoplastic resin 50 between hollow mould 20 and pressure roller 40
Just by the extruding of hollow mould 20.
The structure of pressing mechanism 60 is not limited to the structure shown in Figure 10.Such as, pressing mechanism 60 may be configured as towards
Thermoplastic resin 50 extrudes pressure roller 40.Optionally, pressing mechanism 60 can be provided with vacuum draw unit 90, such as figure
Shown in 3.
Heating arrangements 70 may be configured to heat thermoplastic resin 50, to control its viscoelasticity.In order to make thermoplastic resin
Fat 50 deforms, and can heat hollow mould 20 or thermoplastic resin 50 selectively.In order to equably by hollow mould
Tool 20 or thermoplastic resin 50 are heated to mutually synthermal, preferably from outside by infrared heating hollow mould 20
Surface, or blow hot-air on thermoplastic resin 50.Such as, by infrared heating hollow mould 20
In the case of, heating arrangements 70 can be configured with infra red heating device.
In order to make thermoplastic resin 50 and hollow mould 20 towards extruding the most equably at the same pressure, can use
Heat resistant rubber makes transport roller 30, and can apply power by the pressure roller 40 of encapsulating fluid from the dorsal part of transmission band 30.
Pressure roller 40 can have the structure similar with automobile tire, i.e. rubber surrounds high-strength by such as steel bundle or Kevlar bundle
The degree thread nuclear core of core.The pressure roller 40 formed by such structure is flexible, and can bear higher pressure.
Pressure roller is used after being sealed air or fluid (such as, water) under elevated pressures (equal to pressure applied)
40.Pressure in pressure roller 40 is equal to making thermoplastic resin 50 deform required pressure under caoutchouc elasticity state and logical
The most about 0.1MPa is to about 0.9MPa, and wherein minima is 0.1 atmospheric pressure (0.01MPa), and maximum is several
Atmospheric pressure (several MPa).According to the difference of desirable pressure (P1, P2) in processing, correspondingly changed by pump etc.
Become internal pressure.
Transmission band 30 can be made up of the material identical with pressure roller 40 so that thermoplastic resin 50 and hollow mould 20
Contact with each other with uniform pressure.Transmission band 30 is similar to that in automobile the structure of the transmission band used, i.e.
Wherein surrounded by the thread nuclear core of high strength core of such as steel bundle, glass fibre or Kevlar bundle by heat-resisting rubber.
The transmission band 30 formed by such structure is flexible, and can bear higher pressure.Available vibratory conveyors
Thermoplastic resin 50 is uniformly supplied to the transmission band 30 for collecting, thus prevents thermoplastic resin 50
Superposed.
Figure 11 shows the schematic perspective view of the hollow mould 20 of a non-restrictive version according to the disclosure.?
In the case of collecting thermoplastic resin 50 based on its rheological behavior, hollow mould 20 is used for making thermoplastic resin 50
Deformation.Hollow mould 20 can be provided with multiple hole 22 on its surface 21.Can be on the whole surface 21 of hollow mould 20
Upper formation diameter is about the hole 22 of 1mm.No matter which kind of material thermoplastic resin 50 uses make, the size in hole 22
It is about a few tenths of of thermoplastic resin 50 size.Such as, if the size of thermoplastic resin 50 is the most several lis
Rice to the most several millimeters, the size in hole 22 can respectively may be about several millimeters to several microns.Because machining can be passed through, swashs
The deep hole that diameter is about 1mm is made in light processing or electronics processing, thus can be easily made such hole 22.Example
As, if being formed without hole 22, then according to the change of thermoplastic resin 50 kind, cause the difference of surface energy, from
And some thermoplastic resins 50 will not may be attached to hollow mould 20 fully.This surface energy effect can reduce
The degree of accuracy of collection based on rheological behavior.If on the contrary, hole 22 is excessive, the most undeformed thermoplastic resin 50
May enter in hole 22, thus reduce collection precision.Sufficiently small by being formed compared with thermoplastic resin 50
Hole 22, only makes the areal deformation of thermoplastic resin 50, and enters in hole 22.By preventing whole thermoplastic resin
Fat 50 enters in hole 22, can carry out Precise collection based on rheological behavior.
In order to prevent the not deformed thermoplastic resin 50 of high viscosity to be attached to mistakenly in hollow mould 20, can in
It is coated with low-surface-energy, low-frictional force or low chemically reactive on the surface 21 in addition to hole 22 of empty mould 20
Material, such as, for the diamond-like carbon of process tool, chromium nitride or titanium nitride, this prevents surface the most not deformed
Resin be attached to mistakenly in hollow mould 20, thus accuracy can be improved.In the crushing step being described below
In the case of in advance thermoplastic resin 50 being formed as a size of tens millimeters in Zhou, the size in hole is that 1mm is sufficient for
?.Hole 21 can be sufficiently small, so that undeformed thermoplastic resin 50 does not enter in hole 22.Hollow mould 20
Can be made up of heat proof material, such as rustless steel, ferrum, nickel, chromium or its alloy, or pottery.Optionally, hollow mould
Tool 20 can be made up of the material that surface energy is relatively low, such as fluororesin.In fluororesin, there is one and there is height
Thermostability, and the most Undec resin.The hollow mould that the relatively low material of surface energy is made
Tool 20 is without the coating of low-surface-energy.
Additionally, by forming the hole 22 through hollow mould 20, attachment can be separated by air pressure from the inside in hole 22
Thermoplastic resin 50.So, the separability that thermoplastic resin 50 reduces because of access aperture 22 is improved.
Therefore easily from hollow mould 20 heat of dissociation plastic resin 50, and can prevent from blocking hollow mould 20, and block
Live hollow mould 20 and can reduce efficiency and the accuracy of process.
For the ease of reclaiming the thermoplastic resin 50 being attached to hollow mould 20 in a subsequent step, it is formed about
The hole 22 of 1mm, each hole is from outer thoughtful inner circumferential through hollow mould 20, and described hole is formed so that can be from hollow mould
Air or the liquid of such as water are injected, to remove thermoplastic resin 50 by hole 22 in the inside of tool 20.Such as Figure 12 institute
Showing, system 10 also can have injection mechanism 81, and it is configured by and injects stream from the hollow space of hollow mould 20
Body and get rid of captured thermoplastic resin 50 from hole 22.Injection mechanism 81 is configured from the hollow of sky mould 20
Part injects air (such as, air-spray) or water.Thermoplastic resin 50 can be got rid of from hole 22.Also in can cooling down
Empty mould 20.The thermoplastic resin 50 got rid of is placed in collection container 82.
The device cutting thermoplastic resin 50 in advance can be used.Such as, can use a kind of cutting mechanism, it is configured to
It is the thermoplastic resin part being basically the same by every kind of crushing in described multiple thermoplastic resin 50.
In a non-restrictive version of the disclosure, as shown in Figure 10, single system 10 can be used to represent " to be criticized
Process ", wherein after each step processes, store remaining thermoplastic resin 50, then after a step process terminates
Change temperature and pressure, in order to perform next step and process.
Optionally, in another non-restrictive version of the disclosure, as shown in figure 13, system 10 can be provided with series connection
Multiple subsystem 10A, 10B and 10C of form, thus different subsystem 10A, 10B and 10C capture rheology
Different thermoplastic resin a, b, c that characteristic is different.
Subsystem 10A can be provided with: heating arrangements 70A, and it is configured to multiple thermoplastic resin a, b, c and d
Apply heat, thus control its viscoelasticity；Pressing mechanism 60A, its be configured to described multiple thermoplastic resin a,
Each surface of b, c and d applies pressure reduction；And hollow mould 20A, it is configured to capture the one of thermoplastic resin a
Part.This pressing mechanism 60A can be provided with pressure roller 40A, this pressure roller 40A be configured by facing to thermoplastic resin a,
B, c and d extruded hollow mould 20A and to thermoplastic resin a, b, c and d apply uniform pressure.Select by
Heat that heating arrangements 70A and pressing mechanism 60A applies to described multiple thermoplastic resin a, b, c and d and pressure
The amount of difference, to capture thermoplastic resin a by described hollow mould 20B.
Subsystem 10B can be provided with: heating arrangements 70B, and it is configured at thermoplastic resin a by hollow mould 20A
Capture backward remaining one or more thermoplastic resins b, c and d and apply heat, thus control its viscoelasticity；Add
Press mechanism 60B, it is configured to execute to each surface of described one or more remaining thermoplastic resin b, c and d
Add pressure reduction；And hollow mould 20B, its part being configured to capture thermoplastic resin b.This pressing mechanism 60B
Can be provided with pressure roller 40B, this pressure roller 40B is configured by facing to thermoplastic resin b, c and d extruded hollow mould 20B
And apply uniform pressure to thermoplastic resin b, c and d.Select by heating arrangements 70B and pressing mechanism 60B to
Heat that one or more remaining thermoplastic resin b, c and d described apply and the amount of pressure reduction, with by described
Empty mould 20B captures thermoplastic resin b.
Subsystem 10C is provided with: heating arrangements 70C, and it is configured to be caught by hollow mould 20B at thermoplastic resin b
Obtain backward remaining one or more thermoplastic resins c and d and apply heat, thus control its viscoelasticity；Pressing mechanism
60C, it is configured to apply pressure reduction to each surface of one or more remaining thermoplastic resin c and d described；With
And hollow mould 20C, its part being configured to capture thermoplastic resin c.This pressing mechanism 60C can be provided with pressure roller
40C, this pressure roller 40C are configured by facing to thermoplastic resin c and d extruded hollow mould 20C to thermoplastic resin
Fat c and d applies uniform pressure.Select by heating arrangements 70C and pressing mechanism 60C to described one or more
The heat of remaining thermoplastic resin c and d applying and the amount of pressure reduction, to capture thermoplastic by described hollow mould 20C
Property resin c.
Subsystem 10A, 10B and 10C can use mould 23 as shown in Figure 4, and do not use hollow mould 20A,
20B and 20C.And, as it is shown on figure 3, subsystem 10A, 10B and 10C can be provided with vacuum draw unit
90。
By the disclosure, can collect subtly based on thermostability and there is similar main chain, similar proportion and charge characteristic
Thermoplastic resin, and, forming a team even with the thermoplastic resin with similar thermostability also can be based on its energy storage mould
Measure and collect subtly.System 10 can be used to carry out such collection.
Can collect subtly such as molecular weight is different and/or content accounting is different polymer, mixed polymer and
The thermoplastic resin being generally difficult to collect of the polymer alloy that mixing ratio is different etc.And, thus quality can be provided
Uniformly and thus can easily in the product similar with primary products recycling recovery resin.
Because being collected by hollow mould 20 being applied heat the areal deformation that only makes thermoplastic resin, from
And heat only can affect the surface of thermoplastic resin.Therefore, with wherein make thermoplastic resin fusing and based on its melt
Changing a collection method collected to compare, energy consumption is relatively low, thus cost is relatively low.Reduce the degraded of resin, thus
Collected resin can be reused as high-quality resin.
The following is the working Examples of the disclosure.
In embodiment 1, with glass transition point be 80 degrees Celsius and 100 degrees Celsius of lower storage moduluss as 0.5MPa
Polystyrene resin as the thermoplastic resin a listed in table 1.With glass transition point be 80 degrees Celsius and
100 degrees Celsius of lower storage moduluss are that the pet resin of 5MPa is as the thermoplastic listed in table 1
Property resin b.It it is 130 degrees Celsius and at 150 degrees Celsius of lower storage moduluss cyclenes as 2MPa with glass transition point
Copolymer resin is as the thermoplastic resin c listed in table 1.It it is 160 degrees Celsius and 180 with glass transition point
Degree Celsius lower storage modulus is that the polycarbonate resin of 3MPa is as the thermoplastic resin d listed in table 1.
In the mixture of thermoplastic resin a, b, c and d, temperature be 100 degrees Celsius, pressure be under 1MP
Thermoplastic resin a is isolated from remaining thermoplastic resin b, c and d.Then, temperature be 100 degrees Celsius,
Pressure is to isolate thermoplastic resin b from remaining thermoplastic resin c and d under 10MP.But, in temperature it is
150 degrees Celsius, pressure be under 1MP, it is impossible to from remaining thermoplastic resin c and d, isolate thermoplastic resin.
Finally, temperature be 150 degrees Celsius, pressure be under 10MP, isolate thermoplasticity from remaining thermoplastic resin d
Resin c.
In example 2, with glass transition point be 100 degrees Celsius and at one hundred and twenty degrees centigrade storage modulus be
The acrylate of 0.1MPa is as the thermoplastic resin a listed in table 1.With glass transition point be 100 degrees Celsius,
And storage modulus is that the acrylate of 2MPa is as the thermoplastic resin listed in table 1 at one hundred and twenty degrees centigrade
b.It it is 130 degrees Celsius and in the cyclenes copolymerization as 1MPa of 160 degrees Celsius of lower storage moduluss with glass transition point
Resin is as the thermoplastic resin c listed in table 1.It is 250 degrees Celsius with glass transition point and takes the photograph 280
Under family name's degree, storage modulus is that the thermoplastic polyamide resin of 5MPa is as the thermoplastic resin d listed in table 1.
In the mixture of thermoplastic resin a, b, c and d, temperature be 120 degrees Celsius, pressure be 0.2MP
Under from remaining thermoplastic resin b, c and d, isolate thermoplastic resin a.Then, it is 120 Celsius in temperature
Degree, pressure are to isolate thermoplastic resin b from remaining thermoplastic resin c and d under 5MP.But, in temperature
Degree is 160 degrees Celsius, pressure is under 0.2MPa, it is impossible to isolate thermoplasticity from remaining thermoplastic resin c and d
Resin.Finally, temperature be 160 degrees Celsius, pressure be under 5MPa, isolate from remaining thermoplastic resin d
Thermoplastic resin c.
Although the embodiment with reference to limited quantity describes the disclosure, it will be understood, however, that general in this area
Logical technical staff is under the enlightenment of the disclosure, it is contemplated that go out other embodiment, and this sends out without departing from disclosed herein
Bright scope.Therefore, the scope of the present invention is defined by the appended claims.
Claims (31)
1., for collecting a system for thermoplastic resin, this system includes:
Heating arrangements, this heating arrangements is configured to multiple thermoplastic resin is applied heat, to control described multiple thermoplastic
The viscoelasticity of property resin；
Pressing mechanism, this pressing mechanism is configured to apply pressure reduction to the surface of described multiple thermoplastic resin；And
Arresting structure, this arresting structure is constructed for capturing at least one thermoplasticity in described multiple thermoplastic resin
A part for resin,
Wherein said arresting structure includes mould, and this mould includes arranging in its surface, described in capture at least one
Plant at least one recess of the described part of thermoplastic resin,
The surface-coated in addition at least one recess described of wherein said mould has low-surface-energy coating,
Wherein said pressing mechanism is configured by and extrudes described mould facing at least one thermoplastic resin described and execute
Add described pressure reduction, and
Wherein said mould is hollow mould, and at least one recess wherein said is by through described hollow mould extremely
A few hole is formed.
System the most according to claim 1, wherein, based at least one thermoplastic resin described in be captured
Softening point select the amount of heat that applies.
System the most according to claim 1, wherein, according at least one thermoplastic resin described in be captured
The required pressure that is distorted selects the amount of applied pressure reduction.
System the most according to claim 1, wherein, the amount selecting the heat applied and the pressure applied
The amount of difference so that at least one thermoplastic resin described to be captured described in be partially into that described at least one is recessed
Portion.
System the most according to claim 1, wherein, described mould by ferrum, nickel, iron or they alloy,
Or pottery is made.
System the most according to claim 1, wherein, described low-surface-energy coating is by diamond-like-carbon, nitrogen
Change chromium or titanium nitride is made.
System the most according to claim 1, this system also includes injection mechanism, and this injection mechanism is configured to lead to
Cross the hollow space injecting fluid from described hollow mould and get rid of from least one hole described captured described in
Few a kind of thermoplastic resin.
System the most according to claim 1, this system also include crush mechanism, this crushing mechanism be configured to by
All crush the multiple thermoplastic resin parts for being basically the same each of in described multiple thermoplastic resin.
System the most according to claim 1, wherein, described heating arrangements is configured by the described capture of heating
Structure and to described multiple thermoplastic resin apply heat.
System the most according to claim 1, wherein, described pressing mechanism includes pressure roller, and this pressure roller is configured to
Apply uniformly to described multiple thermoplastic resin by extruding described arresting structure facing to described multiple thermoplastic resin
Pressure.
11. systems according to claim 1, this system also includes transporting band, and this transport band is configured to transport institute
State multiple thermoplastic resin.
12. 1 kinds of systems, this system includes:
First heating arrangements, this first heating arrangements is configured to including at least one first thermoplastic resin and at least one
The multiple thermoplastic resin planting the second thermoplastic resin applies heat, thus controls the viscoelastic of described multiple thermoplastic resin
Property；
First pressing mechanism, this first pressing mechanism is configured to apply pressure to each surface of described multiple thermoplastic resin
Difference；
First arresting structure, this first arresting structure is configured to of capture at least one the first thermoplastic resin described
Point；
Second heating arrangements, this second heating arrangements is configured at least one first thermoplastic resin described by described
One arresting structure captures backward one or more thermoplastic resins remaining and applies heat, thus controls described one or many
Plant the viscoelasticity of thermoplastic resin；
Second pressing mechanism, it is every that this second pressing mechanism is configured to remaining one or more thermoplastic resins described
Individual surface applies pressure reduction；And
Second arresting structure, this second arresting structure is configured to of capture at least one the second thermoplastic resin described
Point；
Wherein, select to be applied to described multiple thermoplastic resin by described first heating arrangements and described first pressing mechanism
The amount of heat and the amount of pressure reduction so that described first arresting structure capture at least one the first thermoplastic resin described
Described part,
Wherein, select by described second heating arrangements and described second pressing mechanism to remaining one or more heat described
The amount of heat that plastic resin applies and the amount of pressure reduction so that described second arresting structure capture described at least one second
The described part of thermoplastic resin,
Wherein, described first arresting structure includes the first hollow mould, this first hollow mould include at least one first
Recess, at least one first recess described is formed and quilt by least one first hole through described first hollow mould
It is arranged on the surface of described first hollow mould with the described part of capture at least one the first thermoplastic resin described,
And
Wherein, described second arresting structure includes the second hollow mould, this second hollow mould include at least one second
Recess, at least one second recess described is formed and quilt by least one second hole through described second hollow mould
It is arranged on the surface of described second hollow mould with the described part of capture at least one the second thermoplastic resin described.
13. 1 kinds of methods, the method includes:
To the multiple thermoplastic resin including at least one first thermoplastic resin and at least one the second thermoplastic resin
Fat applies heat, to control the viscoelasticity of described multiple thermoplastic resin；
Pressure reduction is applied to each surface of described multiple thermoplastic resin；
By using the first arresting structure to capture a part at least one the first thermoplastic resin described；
Collect by least one first thermoplastic resin described in described first arresting structure capture；
To remaining one or many after described first arresting structure capture at least one first thermoplastic resin described
Plant thermoplastic resin and apply heat, to control the viscoelasticity of one or more thermoplastic resins described；
Pressure reduction is applied to remaining one or more thermoplastic resins described；
By using the second arresting structure to capture a part at least one the second thermoplastic resin described；And
Collect by least one second thermoplastic resin described in described second arresting structure capture；
Wherein, select to be applied to described multiple thermoplastic resin by described first heating arrangements and described first pressing mechanism
The amount of heat and the amount of pressure reduction so that described first arresting structure capture at least one the first thermoplastic resin described
Described part,
Wherein, select by described second heating arrangements and described second pressing mechanism to remaining one or more heat described
The amount of heat that plastic resin applies and the amount of pressure reduction so that described second arresting structure capture described at least one second
The described part of thermoplastic resin,
Wherein, described first arresting structure includes the first hollow mould, this first hollow mould include at least one first
Recess, at least one first recess described is formed and quilt by least one first hole through described first hollow mould
It is arranged on the surface of described first hollow mould with the described part of capture at least one the first thermoplastic resin described,
And
Wherein, described second arresting structure includes the second hollow mould, this second hollow mould include at least one second
Recess, at least one second recess described is formed and quilt by least one second hole through described second hollow mould
It is arranged on the surface of described second hollow mould with the described part of capture at least one the second thermoplastic resin described.
14. 1 kinds of systems being used for collecting thermoplastic resin, this system includes:
Heating arrangements, this heating arrangements is configured to multiple thermoplastic resin is applied heat, to control described multiple thermoplastic
The viscoelasticity of property resin；
Arresting structure, this arresting structure is constructed for capturing at least one thermoplasticity in described multiple thermoplastic resin
A part for resin, wherein said arresting structure includes hollow mould, and this hollow mould includes at least one recess, institute
State at least one recess and formed and be disposed in described hollow mould by least one hole through described hollow mould
Surface on the described part of capture at least one thermoplastic resin described,
Pressing mechanism, this pressing mechanism is configured to apply pressure reduction to the surface of described multiple thermoplastic resin, wherein said
Pressing mechanism is configured by and extrudes described mould facing at least one thermoplastic resin described and apply described pressure reduction, with
And
Injection mechanism, this injection mechanism is configured by the hollow space injecting fluid from described hollow mould and from described
At least one hole is got rid of the captured described part of at least one thermoplastic resin described.
15. systems according to claim 14, wherein, based at least one thermoplastic resin described in be captured
The softening point of fat selects the amount of heat.
16. systems according to claim 14, wherein, according at least one thermoplastic resin described in be captured
The fat required pressure that is distorted selects the amount of applied pressure reduction.
17. systems according to claim 14, wherein, select the amount of heat that applied and are applied
The amount of pressure reduction so that at least one thermoplastic resin described to be captured described in be partially into that described at least one is recessed
Portion.
18. systems according to claim 14, wherein, described mould by ferrum, nickel, iron or they alloy,
Or pottery is made.
19. systems according to claim 14, wherein, this system also includes crushing mechanism, this crushing mechanism
It is configured to will all crush the multiple thermoplastic resins for being basically the same each of in described multiple thermoplastic resin
Part.
20. systems according to claim 14, wherein, described heating arrangements is configured by described in heating and catches
Obtain structure and described multiple thermoplastic resin is applied heat.
21. systems according to claim 14, wherein, described pressing mechanism includes pressure roller, and this pressure roller constructs
Become and apply all to described multiple thermoplastic resin by extruding described arresting structure facing to described multiple thermoplastic resin
Even pressure.
22. systems according to claim 14, wherein, this system also includes transporting band, and this transport band constructs
Become to transport described multiple thermoplastic resin.
23. 1 kinds of systems being used for collecting thermoplastic resin, this system includes:
Heating arrangements, this heating arrangements is configured to multiple thermoplastic resin is applied heat, to control described multiple thermoplastic
The viscoelasticity of property resin；
Arresting structure, this arresting structure includes hollow mould, and this hollow mould includes at least one hole, described at least one
Individual hole is through described hollow mould and is configured to capture at least one thermoplasticity in described multiple thermoplastic resin
A part for resin, and
Pressing mechanism, this pressing mechanism is configured by least one hole described to the surface of described multiple thermoplastic resin
Apply negative pressure.
24. systems according to claim 23, wherein, based at least one thermoplastic resin described in be captured
The softening point of fat selects the amount of heat.
25. systems according to claim 23, wherein, according at least one thermoplastic resin described in be captured
The fat required pressure that is distorted selects applied negative pressure.
26. systems according to claim 23, wherein, select the amount of heat that applied and are applied
The amount of negative pressure so that at least one thermoplastic resin described to be captured described in be partially into described at least one
Hole.
27. systems according to claim 23, wherein, described mould by ferrum, nickel, iron or they alloy,
Or pottery is made.
28. systems according to claim 23, wherein, this system also includes crushing mechanism, this crushing mechanism
It is configured to will all crush the thermoplastic resin part for being basically the same each of in described multiple thermoplastic resin.
29. systems according to claim 23, wherein, described heating arrangements is configured by described in heating and catches
Obtain structure and described multiple thermoplastic resin is applied heat.
30. systems according to claim 23, wherein, described pressing mechanism includes pressure roller, and this pressure roller constructs
Become and apply all to described multiple thermoplastic resin by extruding described arresting structure facing to described multiple thermoplastic resin
Even pressure.
31. systems according to claim 23, this system also includes transporting band, and this transport band is configured to transport
Described multiple thermoplastic resin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2012/002782 WO2013160931A1 (en) | 2012-04-23 | 2012-04-23 | Methods and systems for collecting thermoplastic resins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104245265A CN104245265A (en) | 2014-12-24 |
| CN104245265B true CN104245265B (en) | 2016-09-28 |
Family
ID=49380351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280072547.1A Expired - Fee Related CN104245265B (en) | 2012-04-23 | 2012-04-23 | For collecting the method and system of thermoplastic resin |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US9409318B2 (en) |
| CN (1) | CN104245265B (en) |
| WO (1) | WO2013160931A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5590789A (en) * | 1992-03-09 | 1997-01-07 | Stricker; Urban | Process and devices for sorting thermoplastic components from a mixed stream |
| WO2003090941A1 (en) * | 2002-04-24 | 2003-11-06 | Salyp Nv | Method and device for picking up particles from a mixture |
| CN101541497A (en) * | 2007-05-01 | 2009-09-23 | 松下电器产业株式会社 | Method of resin segregation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49132868A (en) * | 1973-04-21 | 1974-12-20 | ||
| JP2515302B2 (en) | 1986-08-06 | 1996-07-10 | 株式会社東芝 | Image creation device |
| DE4004300A1 (en) | 1990-02-13 | 1991-08-14 | Refakt Anlagenbau Gmbh | Sepn. of particulate plastic materials of different softening points - by feeding them to a heated moving substrate to which the lower softening point particles adhere, and from which they are then removed |
| DE4220666C2 (en) | 1992-06-24 | 1995-02-09 | Urban Dipl Ing Stricker | Device for sorting thermoplastics from a batch flow |
| JP2002046128A (en) * | 2000-08-01 | 2002-02-12 | Rikogaku Shinkokai | Apparatus and method for selectively recovering plastic pieces |
| JP5331315B2 (en) | 2007-07-04 | 2013-10-30 | 丸善石油化学株式会社 | Thermal imprint method |
| JP4439571B2 (en) | 2007-11-14 | 2010-03-24 | パナソニック株式会社 | Resin separation method |
| US7863409B2 (en) | 2007-11-14 | 2011-01-04 | Panasonic Corporation | Method of separating resin |
-
2012
- 2012-04-23 CN CN201280072547.1A patent/CN104245265B/en not_active Expired - Fee Related
- 2012-04-23 WO PCT/JP2012/002782 patent/WO2013160931A1/en active Application Filing
- 2012-04-23 US US13/640,781 patent/US9409318B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5590789A (en) * | 1992-03-09 | 1997-01-07 | Stricker; Urban | Process and devices for sorting thermoplastic components from a mixed stream |
| WO2003090941A1 (en) * | 2002-04-24 | 2003-11-06 | Salyp Nv | Method and device for picking up particles from a mixture |
| CN101541497A (en) * | 2007-05-01 | 2009-09-23 | 松下电器产业株式会社 | Method of resin segregation |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104245265A (en) | 2014-12-24 |
| WO2013160931A1 (en) | 2013-10-31 |
| US9409318B2 (en) | 2016-08-09 |
| US20130280365A1 (en) | 2013-10-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6207396B2 (en) | Compatible carrier for secondary reinforcement | |
| CN101462391A (en) | Method for preparing carbon nano-tube composite material | |
| CN104411476A (en) | Forming apparatus and method and object thus made | |
| CN103826980A (en) | Heat-resistant food container, and manufacturing method for same | |
| CN110126171A (en) | A kind of polymer particle integration foaming forming technique | |
| CN104245265B (en) | For collecting the method and system of thermoplastic resin | |
| Subramanian | Basics of polymers: fabrication and processing technology | |
| CN103242629A (en) | Starch full-biodegradable resin and continuous preparation method thereof | |
| CN104312112A (en) | Polyester polyethylene alloy plastic pipe and preparation method thereof | |
| CN110240779A (en) | A kind of high-precision is without plug type stalk FDM 3D printing consumptive material and preparation method thereof | |
| CN101417502A (en) | Composite material structure and manufacture method thereof | |
| CN108025463A (en) | Molded part with hole and its manufacture method | |
| Mervine et al. | A review of sustainable materials used in thermoplastic extrusion and powder bed melting additive manufacturing | |
| CN206447795U (en) | The energy saver of dihydric alcohol aqueous solution dehydration by-product monohydric alcohol | |
| CN203413250U (en) | Plastic micro-channel pipeline structure and manufacturing device thereof | |
| CN101735384B (en) | Method for preparing polyacrylonitrile spinning solution and reaction vessel special for same | |
| CN101837628B (en) | Multilayer composite flat-belt forming processing device | |
| CN117550214B (en) | Scratch-resistant nest plate for cycloolefin polymer pre-filled syringe and preparation process thereof | |
| US20160107345A1 (en) | Plastic injection molding and process | |
| CN205529242U (en) | Fiber reinforcement thermoplasticity combined material is with mixing fine yarn | |
| CN102837421A (en) | Composite material structural member manufacturing process and structure | |
| CN216155143U (en) | PET-G sheet production and processing composite device | |
| US20230173716A1 (en) | Macromolecule Forming Mold, Thermosetting Elastomer and Manufacturing Method Therefor | |
| CN206399677U (en) | Pet food palatants quality inspection probe tube | |
| CN110714250A (en) | Yarn |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160928 Termination date: 20200423 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |