CN104237327A - Device and method for detecting in-vehicle air quality - Google Patents

Device and method for detecting in-vehicle air quality Download PDF

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CN104237327A
CN104237327A CN201410384662.3A CN201410384662A CN104237327A CN 104237327 A CN104237327 A CN 104237327A CN 201410384662 A CN201410384662 A CN 201410384662A CN 104237327 A CN104237327 A CN 104237327A
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controller
air quality
gas
snr
sensitization film
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CN104237327B (en
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富军
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Abstract

The invention discloses a device and a method for detecting the in-vehicle air quality. The method comprises the steps of detecting the concentrations of all harmful gases in a vehicle respectively by all gas sensitive films, and calculating the average value of all response signals such as I (t) 1, I (t) 2,...and I (t) m by a controller to obtain a detection signal I (t); carrying out a series of data processing by the detection signal to obtain signal noise ratio (SNR) corresponding to the I (t); and when the SNR is more than SNRW, judging that the air quality does not reach the standard by the controller, displaying the information that air quality does not reach the standard in a display device by the controller, and enabling an alarm device to send out alarm information. After the device and the method are adopted, the in-vehicle air quality can be comprehensively evaluated, and the concentrations of all the harmful gases can be monitored; the alarm information can be sent out in time, so that a powerful support is provided for health of people.

Description

In-car air quality pick-up unit and detection method
Technical field
The present invention relates to automobile technical field, especially relate to one can fast, accurately, air quality in automatic detection vehicle, and in-car air quality is made to in-car air quality pick-up unit and the detection method of comprehensive evaluation.
Background technology
Current vehicle air quality condition is very troubling, and the existence of harmful gas has had a strong impact on the healthy of occupant; The testing process more complicated of current in-car air quality pick-up unit, needs manual operations mostly, cannot automatically detect.Further, common pick-up unit can only detect single gas and to exceed standard situation, cannot make comprehensive evaluation to overall air quality in car.
Chinese patent mandate publication number: CN203443895U, authorize publication date on February 19th, 2014, disclose a kind of determining instrument of indoor air quality, it comprises casing, detector body, detector body is arranged on box house, described detector body is provided with gauge tap, time controller, air pump, described gauge tap tie-time controller, time controller connects several air pumps be arranged in parallel, and series connection is provided with individual event gas detect switch on each air pump, individual event gas detect pilot lamp, described air pump is connected with spectrophotometric display screen, spectrophotometric display screen connects mini-printer.The weak point of this invention is, function singleness, complicated operation, cannot automatically detect in-car air quality.
Summary of the invention
Goal of the invention of the present invention is the testing process more complicated in order to overcome pick-up unit of the prior art, need manual operations, automatically the deficiency detected cannot be carried out, provide one can fast, accurately, air quality in automatic detection vehicle, and in-car air quality is made to in-car air quality pick-up unit and the detection method of comprehensive evaluation.
To achieve these goals, the present invention is by the following technical solutions:
A kind of in-car air quality pick-up unit, comprises the controller be located on the instrument desk of automobile, storer, pick-up unit, alarm, display and gauge tap; Described pick-up unit comprises housing, is located at the cylindrical shell of the lower ending opening of housing upper, cylindrical shell be located at being connected for the motor driving cylindrical shell to horizontally rotate in housing, the gas outlet being provided with draft tube in described cylindrical shell and being connected with draft tube, lower housing portion is provided with exhausr port, exhausr port is provided with the first solenoid valve, draft tube is provided with air pump and the second solenoid valve, and draft tube is stretched out outside cylindrical shell, and gas outlet is provided with the venthole of several arrangements;
Being provided with head tank, operational amplifier and data collecting card that clean air is housed in housing, being provided with m in the housing below gas outlet for detecting the gas sensitization film of gas with various; Head tank is connected with draft tube by purge pipe, purge pipe is provided with the 3rd solenoid valve, each gas sensitization film is electrically connected with the input end of operational amplifier respectively, the output terminal of operational amplifier is electrically connected with data collecting card, and controller is electrically connected with the first solenoid valve, the second solenoid valve, the 3rd solenoid valve, motor, data collecting card, alarm, storer, display, air pump and gauge tap respectively.
Clean air in head tank of the present invention is used for cleaning each gas sensitization film, thus makes each gas sensitization film remain reliable susceptibility; Each gas sensitization film is respectively used to the concentration of various harmful gas in inspection vehicle; The present invention calculates each response signal I (t) 1, I (t) 2..., I (t) mmean value, thus obtain detection signal I (t), utilize detection signal to carry out a series of data processing, thus obtain the SNR corresponding with I (t); As SNR > SNR wtime, then air quality judgement not up to standard made by controller, and controller shows air quality information not up to standard in the display, and alarm sends warning message.
When gauge tap is opened, first controller controls to clean gas sensitization film, thus ensure the accuracy detecting data, then automatically control to detect air in car, and automatically data processing is carried out to detection signal I (t) obtained, when air quality is not up to standard, controller shows air quality information not up to standard in the display, and alarm sends warning message.
After obtaining in-car air quality information not up to standard, the personnel that the personnel ridden maybe will ride can open vehicle window venting or adopt other device to take a breath; Thus effectively avoid harmful gas to the injury of human body.
Therefore, the present invention has simple to operate, and testing process, data processing and the deterministic process that exceeds standard are carries out automatically; Can overall assessment be carried out to the air quality in car and send warning message in time, for the healthy of people provides the feature provided powerful support for.
As preferably, described draft tube comprises ring pipe, the transverse tube be connected with ring pipe and vertical tube; Gas outlet ringwise, draft tube is positioned at above gas outlet, and draft tube is connected with gas outlet by vertical tube, and transverse tube stretches out outside cylindrical shell, each venthole at exhaust pipe lower part circumferentially, is less than the aperture of the vent port away from vertical tube near the aperture of the vent port of vertical tube.
As preferably, the cylindrical shell between draft tube and gas outlet is provided with circular baffle plate, and baffle edge embeds to be located in the annular groove of cylinder inboard wall, and chute downside is provided with leakage-proof ring, and vertical tube is through baffle plate.
As preferably, described m is the gas sensitization film that 10,10 gas sensitization films are respectively for detecting sulfide, hydrogen, alcohol, toluene, dimethylbenzene, carbon monoxide, carbon dioxide, methane, propane and oxides of nitrogen.
As preferably, described gas sensitization film is the cylindrical shape of both ends open, resistive heater is provided with in the cavity of gas sensitization film, resistive heater two ends are connected with power electric respectively by heating pin, gas sensitization film is provided with two and detects pins and two fixing pins, and two are detected pin and are electrically connected with the in-phase input end of operational amplifier and inverting input respectively.
The resistive heater arranged in the cavity of gas sensitization film is used for heating to gas sensitization film.The structure of gas sensitization film of the present invention contributes to improving gas detect precision, in working order, gas sensitization film is by Resistant heating to 300 ~ 480 DEG C, when tested gas is carried into sensor sensing film surface, gas molecule is oxidized under the effect of high temperature, oxidation product is attached to gas sensitization film surface, and cause the change of gas sensitization film resistance, the change according to this resistance value can realize the sign of gas concentration.Gas with various sensitive membrane of the present invention adopts different materials preparation, and often kind of gas sensitization film is only responsive to specific gas, and namely gas sensitization film has specificity.
As preferably, operational amplifier is UPC4570 low noise computing paster amplifier, and data collecting card is the low-power-consumption embedded data collecting card based on MSP430F5438, and controller is the low-power-consumption embedded MCU of MSP430F149.
A detection method for in-car air quality pick-up unit, comprises the steps:
(7-1) air quality threshold SNR is preset with in controller w, be provided with one deck accidental resonance model in storer:
wherein, V (x, t) is potential function, and x (t) is Brownian movement Particles Moving lopcus function, and a, b are the constant of setting, and ξ (t) is external noise, and D is external noise intensity, and N (t) grasps noise in being, for periodic sinusoidal signal, A is signal amplitude, and f is signal frequency, and t is run duration, for phase place,
(7-2) gas sensitization film is cleaned:
When gauge tap is opened, controller control the first, the 3rd solenoid valve is opened and is cleaned the gas sensitization film in housing with clean air; Clean air under pressure, enters in housing by draft tube and gas outlet, discharges outside housing by exhausr port;
(7-3) Detection of Air Quality:
After cleaning, controller controls the first, the 3rd closed electromagnetic valve, and the second solenoid valve is opened; And controlling motor and air pump work, driven by motor cylindrical shell horizontally rotates, and the gas in compartment enters in draft tube and detects, and after detection, controller controls the second closed electromagnetic valve;
In testing process, gas contacts with each gas sensitization film, and each gas sensitization film produces response signal I (t) respectively 1, I (t) 2..., I (t) m, controller calculates the average signal of each response signal, and average signal is defined as detection signal I (t);
(7-4) data processing:
(7-4-1) detection signal I (t) inputs in one deck accidental resonance model by controller, controller calculates V (x, t) for first order derivative and the second derivative of x (t), and make equation equal 0, obtain two layers of accidental resonance model:
setting noise intensity D=0, i (t)=0, N (t)=0; The critical value calculating A is
(7-4-2) critical value of A is substituted in one deck accidental resonance model, and set X 0(t)=0, sn 0=0, with quadravalence jade for asking rain Ge Kuta Algorithm for Solving one deck accidental resonance model, obtain x n + 1 ( t ) = x n ( t ) + 1 / 6 [ ( k 1 ) n + ( 2 - 2 ) ( k 2 ) n + ( 2 + 2 ) ( k 3 ) n + ( k 4 ) n ] ; And calculate ( k 1 ) n = 4 ( a x n - 1 ( t ) - b x n - 1 3 ( t ) + s n n - 1 ) , ( k 2 ) n = 4 [ a ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) - b ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) 3 + sn n - 1 ] , ( k 3 ) n = 4 [ a ( x n - 1 ( t ) + ( k 2 ) n - 1 2 ) - b ( x n - 1 ( t ) + 2 - 1 2 ( k 1 ) n - 1 + 2 - 2 2 ( k 2 ) n - 1 ) 3 + s n n + 1 ] , ( k 4 ) n = 4 [ a ( x n - 1 ( t ) + ( k 3 ) n - 1 ) - b ( x n - 1 ( t ) - 2 2 ( k 2 ) n - 1 + 2 + 2 2 ( k 3 ) n - 1 ) 3 + s n n + 1 ] ;
Wherein, x nt n order derivative that () is x (t), sn n-1the value of n-1 order derivative at t=0 place of S (t), sn n+1the value of n+1 order derivative at t=0 place of S (t), n=0,1 ..., N-1; Obtain x 1(t), x 2(t) ..., x n+1the value of (t);
(7-4-3) controller is to x 1(t), x 2(t) ..., x n+1t () carries out integration, obtain the x (t) determined, and obtains x (t) produces accidental resonance moment position x in the double-deck stochastic system of one deck accidental resonance model and two layers of accidental resonance model composition mvalue and x mcorresponding resonance moment t 1and and t 1corresponding noise D 1, D 1for the value of in D;
(7-4-4) controller utilizes formula calculate the signal to noise ratio (S/N ratio) that double-deck stochastic resonance system exports; Wherein, Δ U=a 2/ 4b; Obtain output signal-to-noise ratio SNR;
(7-5) comprehensive descision is made:
If SNR > is SNR w, then air quality judgement not up to standard made by controller, and controller shows air quality information not up to standard in the display, and alarm sends warning message;
If SNR≤SNR w, then air quality judgement up to standard made by controller, and controller shows air quality information up to standard in the display, and controller controls gauge tap and cuts out.
As preferably, also comprise the steps:
(8-1) the gaseous mass threshold value SNR corresponding with each gas sensitization film is preset with in controller p1, SNR p2..., SNR pm; Controller is by I (t) 1, I (t) 2..., I (t) msuccessively in input step (7-4), obtain m output signal-to-noise ratio SNR 1, SNR 2..., SNR m;
If (8-2) SNR i> SNR pi, i=1 ..., m; , i is the sequence number of gas sensitization film, then the judgement that the gas corresponding to i-th gas sensitization film exceeds standard made by controller, and controller demonstrates the information that this kind of gas exceeds standard in the display, and alarm sends warning message.
As preferably, the time that cleaning course continues is 30 seconds to 2 minutes; The time that testing process continues is 30 to 120 seconds.
As preferably, in car, gas is by the speed suction casing of 360mL/min to 570mL/min.
Therefore, the present invention has following beneficial effect:
(1) simple to operate, testing process, data processing and the deterministic process that exceeds standard are carries out automatically; ;
(2) both overall assessment can be carried out to the air quality in car, also concentration monitor can be carried out to various harmful gas;
(3) warning message can be sent in time, for healthy the providing of people provides powerful support for and can detect.
Accompanying drawing explanation
Fig. 1 is a kind of theory diagram of the present invention;
Fig. 2 is a kind of structural drawing of the present invention;
Fig. 3 is a kind of structural drawing of draft tube of the present invention and gas outlet;
Fig. 4 is a kind of structural representation of gas sensitization film of the present invention;
Fig. 5 is a kind of process flow diagram of embodiments of the invention.
In figure: controller 1, storer 2, alarm 3, display 4, gauge tap 5, housing 6, cylindrical shell 7, motor 8, draft tube 9, gas outlet 10, exhausr port 11, first solenoid valve 12, air pump 13, second solenoid valve 14, operational amplifier 15, data collecting card 16, gas sensitization film 17, the 3rd solenoid valve 18, transverse tube 19, vertical tube 20, crossbeam 21, insulating circuit board 22, cross 23, heating pin 24, detection pin 25, fixing pin 26.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention will be further described.
Embodiment 1
Embodiment is as shown in Figure 1 and Figure 2 a kind of in-car air quality pick-up unit, comprises the controller 1 be located on the instrument desk of automobile, storer 2, pick-up unit, alarm 3, display 4 and gauge tap 5; Pick-up unit comprises housing 6, is located at the cylindrical shell 7 of the lower ending opening of housing upper, as shown in Figure 3, the gas outlet 10 being provided with draft tube 9 in cylindrical shell and being connected with draft tube, gas outlet is provided with cross 23, housing is provided with crossbeam 21, crossbeam is provided with motor 8, cross is connected with the rotating shaft of motor by column, lower housing portion is provided with exhausr port 11, exhausr port is provided with the first solenoid valve 12, draft tube is provided with air pump 13 and the second solenoid valve 14, and draft tube is stretched out outside cylindrical shell, and gas outlet is provided with the venthole of arrangement;
Be provided with head tank, operational amplifier 15 and data collecting card 16 that clean air is housed in housing, be provided with insulating circuit board 22 in the housing below gas outlet, as shown in Figure 4, insulating circuit board is provided with 10 for detecting the gas sensitization film 17 of gas with various; Head tank is connected with draft tube by purge pipe, purge pipe is provided with the 3rd solenoid valve 18, each gas sensitization film is electrically connected with the input end of operational amplifier respectively, as shown in Figure 1, the output terminal of operational amplifier is electrically connected with data collecting card, and controller is electrically connected with the first solenoid valve, the second solenoid valve, the 3rd solenoid valve, motor, data collecting card, alarm, storer, display, air pump and gauge tap respectively.
As shown in Figure 3, draft tube comprises ring pipe, the transverse tube 19 be connected with ring pipe and vertical tube 20; Gas outlet ringwise, draft tube is positioned at above gas outlet, and draft tube is connected with gas outlet by vertical tube, and transverse tube stretches out outside cylindrical shell, each venthole at exhaust pipe lower part circumferentially, is less than the aperture of the vent port away from vertical tube near the aperture of the vent port of vertical tube.
Cylindrical shell between draft tube and gas outlet is provided with circular baffle plate, and baffle edge embeds to be located in the annular groove of cylinder inboard wall, and chute downside is provided with leakage-proof ring, and vertical tube is through baffle plate.
10 gas sensitization films are respectively the gas sensitization film for detecting sulfide, hydrogen, alcohol, toluene, dimethylbenzene, carbon monoxide, carbon dioxide, methane, propane and oxides of nitrogen.
As shown in Figure 4, gas sensitization film is the cylindrical shape of both ends open, resistive heater is provided with in the cavity of gas sensitization film, resistive heater two ends are connected with power electric respectively by heating pin 24, gas sensitization film is provided with two and detects pins 25 and two fixing pins 26, two being connected with insulating circuit board 22 and detect pin and be electrically connected with the in-phase input end of operational amplifier and inverting input respectively.
Operational amplifier is UPC4570 low noise computing paster amplifier, and data collecting card is the low-power-consumption embedded data collecting card based on MSP430F5438, and controller is the low-power-consumption embedded MCU of MSP430F149.In head tank, the pressure of clean air is 3 atmospheric pressure.
SNR wutilize method of the present invention to detect by the air that any one concentration comprised in sulfide, hydrogen, alcohol, toluene, dimethylbenzene, carbon monoxide, carbon dioxide, methane, propane and oxides of nitrogen just exceeded standard, and the air comprising the gas that wherein any number of concentration has just exceeded standard is detected, be averaging detecting the snr value that obtains and the SNR that obtains w.
As shown in Figure 5, a kind of detection method of in-car air quality pick-up unit, comprises the steps:
Air quality threshold SNR is preset with in controller w, be provided with one deck accidental resonance model in storer:
wherein, V (x, t) is potential function, and x (t) is Brownian movement Particles Moving lopcus function, and a, b are the constant of setting, and ξ (t) is external noise, and D is external noise intensity, and N (t) grasps noise in being, for periodic sinusoidal signal, A is signal amplitude, and f is signal frequency, and t is run duration, for phase place,
Step 100, gas sensitization film is cleaned:
When gauge tap is opened, controller controls the first, the 3rd solenoid valve and opens, with clean air to the gas sensitization Membrane cleaning in housing 50 seconds; Clean air under pressure, enters in housing by draft tube and gas outlet, discharges outside housing by exhausr port;
Step 200, Detection of Air Quality:
After cleaning, controller controls the first, the 3rd closed electromagnetic valve, and the second solenoid valve is opened; And controlling motor and air pump work, driven by motor cylindrical shell horizontally rotates, and the gas in compartment enters in draft tube with the speed of 400mL/min and detects 1 minute, and after detection, controller controls the second closed electromagnetic valve;
In testing process, gas contacts with each gas sensitization film, and each gas sensitization film produces response signal I (t) respectively 1, I (t) 2..., I (t) m, controller calculates the average signal of each response signal, and average signal is defined as detection signal I (t);
Step 300, data processing:
Step 310, detection signal I (t) inputs in one deck accidental resonance model by controller, and controller calculates V (x, t) for the first order derivative of x (t) and second derivative, and make equation equal 0, obtain two layers of accidental resonance model:
setting noise intensity D=0, i (t)=0, N (t)=0; The critical value calculating A is
Step 320, substitutes into the critical value of A in one deck accidental resonance model, and sets X 0(t)=0, sn 0=0, with quadravalence jade for asking rain Ge Kuta Algorithm for Solving one deck accidental resonance model, obtain x n + 1 ( t ) = x n ( t ) + 1 / 6 [ ( k 1 ) n + ( 2 - 2 ) ( k 2 ) n + ( 2 + 2 ) ( k 3 ) n + ( k 4 ) n ] ; And calculate ( k 1 ) n = 4 ( a x n - 1 ( t ) - b x n - 1 3 ( t ) + s n n - 1 ) , ( k 2 ) n = 4 [ a ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) - b ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) 3 + sn n - 1 ] , ( k 3 ) n = 4 [ a ( x n - 1 ( t ) + ( k 2 ) n - 1 2 ) - b ( x n - 1 ( t ) + 2 - 1 2 ( k 1 ) n - 1 + 2 - 2 2 ( k 2 ) n - 1 ) 3 + s n n + 1 ] , ( k 4 ) n = 4 [ a ( x n - 1 ( t ) + ( k 3 ) n - 1 ) - b ( x n - 1 ( t ) - 2 2 ( k 2 ) n - 1 + 2 + 2 2 ( k 3 ) n - 1 ) 3 + s n n + 1 ] ;
Wherein, x nt n order derivative that () is x (t), sn n-1the value of n-1 order derivative at t=0 place of S (t), sn n+1the value of n+1 order derivative at t=0 place of S (t), n=0,1 ..., N-1; Obtain x 1(t), x 2(t) ..., x n+1the value of (t);
Step 330, controller is to x 1(t), x 2(t) ..., x n+1t () carries out integration, obtain the x (t) determined, and obtains x (t) produces accidental resonance moment position x in the double-deck stochastic system of one deck accidental resonance model and two layers of accidental resonance model composition mvalue and x mcorresponding resonance moment t 1and and t 1corresponding noise D 1, D 1for the value of in D;
Step 340, controller utilizes formula calculate the signal to noise ratio (S/N ratio) that double-deck stochastic resonance system exports; Wherein, Δ U=a 2/ 4b; Obtain output signal-to-noise ratio SNR;
Step 400, make comprehensive descision:
If SNR > is SNR w, then air quality judgement not up to standard made by controller, and controller shows air quality information not up to standard in the display, and alarm sends warning message;
If SNR≤SNR w, then air quality judgement up to standard made by controller, and controller shows air quality information up to standard in the display, and controller controls gauge tap and cuts out.
Embodiment 2
Also comprise the steps:
The gaseous mass threshold value SNR corresponding with each gas sensitization film is preset with in controller p1, SNR p2..., SNR pm; Controller is by I (t) 1, I (t) 2..., I (t) msuccessively in input step (7-4), obtain m output signal-to-noise ratio SNR 1, SNR 2..., SNR m;
If SNR i> SNR pi, i=1 ..., m; , i is the sequence number of gas sensitization film, then the judgement that the gas corresponding to i-th gas sensitization film exceeds standard made by controller, and controller demonstrates the information that this kind of gas exceeds standard in the display, and alarm sends warning message.
Other structure in embodiment 2 and step part in the same manner as in Example 1.
SNR p1, SNR p2..., SNR pmin any one be all that corresponding gas by concentration known just having been exceeded standard utilizes method of the present invention to carry out the numerical value detected and data processing obtains, and repeatedly detect repeatedly, the mean value calculating repeatedly numerical value obtains.
Should be understood that the present embodiment is only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.

Claims (10)

1. an in-car air quality pick-up unit, it is characterized in that, comprise the controller (1) be located on the instrument desk of automobile, storer (2), pick-up unit, alarm (3), display (4) and gauge tap (5); Described pick-up unit comprises housing (6), is located at the cylindrical shell (7) of the lower ending opening of housing upper, cylindrical shell be located at being connected for the motor (8) driving cylindrical shell to horizontally rotate in housing, the gas outlet (10) being provided with draft tube (9) in described cylindrical shell and being connected with draft tube, lower housing portion is provided with exhausr port (11), exhausr port is provided with the first solenoid valve (12), draft tube is provided with air pump (13) and the second solenoid valve (14), draft tube is stretched out outside cylindrical shell, and gas outlet is provided with the venthole of several arrangements;
Being provided with head tank, operational amplifier (15) and data collecting card (16) that clean air is housed in housing, being provided with m in the housing below gas outlet for detecting the gas sensitization film (17) of gas with various; Head tank is connected with draft tube by purge pipe, purge pipe is provided with the 3rd solenoid valve (18), each gas sensitization film is electrically connected with the input end of operational amplifier respectively, the output terminal of operational amplifier is electrically connected with data collecting card, and controller is electrically connected with the first solenoid valve, the second solenoid valve, the 3rd solenoid valve, motor, data collecting card, alarm, storer, display, air pump and gauge tap respectively.
2. in-car air quality pick-up unit according to claim 1, is characterized in that, described draft tube comprises ring pipe, the transverse tube (19) be connected with ring pipe and vertical tube (20); Gas outlet ringwise, draft tube is positioned at above gas outlet, and draft tube is connected with gas outlet by vertical tube, and transverse tube stretches out outside cylindrical shell, each venthole at exhaust pipe lower part circumferentially, is less than the aperture of the vent port away from vertical tube near the aperture of the vent port of vertical tube.
3. in-car air quality pick-up unit according to claim 2, it is characterized in that, the cylindrical shell between draft tube and gas outlet is provided with circular baffle plate, and baffle edge embeds to be located in the annular groove of cylinder inboard wall, chute downside is provided with leakage-proof ring, and vertical tube is through baffle plate.
4. in-car air quality pick-up unit according to claim 1, it is characterized in that, described m is the gas sensitization film that 10,10 gas sensitization films are respectively for detecting sulfide, hydrogen, alcohol, toluene, dimethylbenzene, carbon monoxide, carbon dioxide, methane, propane and oxides of nitrogen.
5. in-car air quality pick-up unit according to claim 1, it is characterized in that, described gas sensitization film is the cylindrical shape of both ends open, resistive heater is provided with in the cavity of gas sensitization film, resistive heater two ends are connected with power electric respectively by heating pin (24), gas sensitization film is provided with two and detects pin (25) and two fixing pins (26), and two detection pins are electrically connected with the in-phase input end of operational amplifier and inverting input respectively.
6. the in-car air quality pick-up unit according to claim 1 or 2 or 3 or 5, it is characterized in that, operational amplifier is UPC4570 low noise computing paster amplifier, data collecting card is the low-power-consumption embedded data collecting card based on MSP430F5438, and controller is the low-power-consumption embedded MCU of MSP430F149.
7. be applicable to a detection method for in-car air quality pick-up unit according to claim 1, it is characterized in that, comprise the steps:
(7-1) air quality threshold SNR is preset with in controller w, be provided with one deck accidental resonance model in storer:
wherein, V (x, t) is potential function, and x (t) is Brownian movement Particles Moving lopcus function, and a, b are the constant of setting, and ξ (t) is external noise, and D is external noise intensity, and N (t) grasps noise in being, for periodic sinusoidal signal, A is signal amplitude, and f is signal frequency, and t is run duration, for phase place;
(7-2) gas sensitization film is cleaned:
When gauge tap is opened, controller control the first, the 3rd solenoid valve is opened and is cleaned the gas sensitization film in housing with clean air; Clean air under pressure, enters in housing by draft tube and gas outlet, discharges outside housing by exhausr port;
(7-3) Detection of Air Quality:
After cleaning, controller controls the first, the 3rd closed electromagnetic valve, and the second solenoid valve is opened; And controlling motor and air pump work, driven by motor cylindrical shell horizontally rotates, and the gas in compartment enters in draft tube and detects, and after detection, controller controls the second closed electromagnetic valve;
In testing process, gas contacts with each gas sensitization film, and each gas sensitization film produces response signal I (t) respectively 1, I (t) 2..., I (t) m, controller calculates the average signal of each response signal, and average signal is defined as detection signal I (t);
(7-4) data processing:
(7-4-1) detection signal I (t) inputs in one deck accidental resonance model by controller, controller calculates V (x, t) for first order derivative and the second derivative of x (t), and make equation equal 0, obtain two layers of accidental resonance model:
setting noise intensity D=0, i (t)=0, N (t)=0; The critical value calculating A is
(7-4-2) critical value of A is substituted in one deck accidental resonance model, and set X 0(t)=0, sn 0=0, with quadravalence jade for asking rain Ge Kuta Algorithm for Solving one deck accidental resonance model, obtain x n + 1 ( t ) = x n ( t ) + 1 / 6 [ ( k 1 ) n + ( 2 - 2 ) ( k 2 ) n + ( 2 + 2 ) ( k 3 ) n + ( k 4 ) n ] ; And calculate ( k 1 ) n = 4 ( a x n - 1 ( t ) - b x n - 1 3 ( t ) + s n n - 1 ) , ( k 2 ) n = 4 [ a ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) - b ( x n - 1 ( t ) + ( k 1 ) n - 1 2 ) 3 + sn n - 1 ] , ( k 3 ) n = 4 [ a ( x n - 1 ( t ) + ( k 2 ) n - 1 2 ) - b ( x n - 1 ( t ) + 2 - 1 2 ( k 1 ) n - 1 + 2 - 2 2 ( k 2 ) n - 1 ) 3 + s n n + 1 ] , ( k 4 ) n = 4 [ a ( x n - 1 ( t ) + ( k 3 ) n - 1 ) - b ( x n - 1 ( t ) - 2 2 ( k 2 ) n - 1 + 2 + 2 2 ( k 3 ) n - 1 ) 3 + s n n + 1 ] ;
Wherein, x nt n order derivative that () is x (t), sn n-1the value of n-1 order derivative at t=0 place of S (t), sn n+1the value of n+1 order derivative at t=0 place of S (t), n=0,1 ..., N-1; Obtain x 1(t), x 2(t) ..., x n+1the value of (t);
(7-4-3) controller is to x 1(t), x 2(t) ..., x n+1t () carries out integration, obtain the x (t) determined, and obtains x (t) produces accidental resonance moment position x in the double-deck stochastic system of one deck accidental resonance model and two layers of accidental resonance model composition mvalue and x mcorresponding resonance moment t 1and and t 1corresponding noise D 1, D 1for the value of in D;
(7-4-4) controller utilizes formula calculate the signal to noise ratio (S/N ratio) that double-deck stochastic resonance system exports; Wherein, Δ U=a 2/ 4b; Obtain output signal-to-noise ratio SNR;
(7-5) comprehensive descision is made:
If SNR > is SNR w, then air quality judgement not up to standard made by controller, and controller shows air quality information not up to standard in the display, and alarm sends warning message;
If SNR≤SNR w, then air quality judgement up to standard made by controller, and controller shows air quality information up to standard in the display, and controller controls gauge tap and cuts out.
8. the detection method of in-car air quality pick-up unit according to claim 7, is characterized in that, also comprise the steps:
(8-1) the gaseous mass threshold value SNR corresponding with each gas sensitization film is preset with in controller p1, SNR p2..., SNR pm; Controller is by I (t) 1, I (t) 2..., I (t) msuccessively in input step (7-4), obtain m output signal-to-noise ratio SNR 1, SNR 2..., SNR m;
If (8-2) SNR i> SNR pi, i=1 ..., m; , i is the sequence number of gas sensitization film, then the judgement that the gas corresponding to i-th gas sensitization film exceeds standard made by controller, and controller demonstrates the information that this kind of gas exceeds standard in the display, and alarm sends warning message.
9. the detection method of in-car air quality pick-up unit according to claim 7, is characterized in that, the time that cleaning course continues is 30 seconds to 2 minutes; The time that testing process continues is 30 to 120 seconds.
10. the detection method of the in-car air quality pick-up unit according to claim 6 or 7 or 8, is characterized in that, in car, gas is by with in the speed suction casing of 360mL/min to 570mL/min.
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