CN104233493A - 纺织品中的防臭抗菌织物 - Google Patents

纺织品中的防臭抗菌织物 Download PDF

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CN104233493A
CN104233493A CN201310627477.8A CN201310627477A CN104233493A CN 104233493 A CN104233493 A CN 104233493A CN 201310627477 A CN201310627477 A CN 201310627477A CN 104233493 A CN104233493 A CN 104233493A
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fiber
zinc
textiles
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O·德马勒·卢比奥
D·卡西萨·加拉多
A·瑞博思·考波斯
王晓章
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SUTRAN I MAS D SL
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    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
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    • A41B11/00Hosiery; Panti-hose
    • AHUMAN NECESSITIES
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    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B11/00Hosiery; Panti-hose
    • A41B11/005Hosiery made essentially of a multi-ply construction
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B9/00Undergarments
    • A41B9/001Underpants or briefs
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B9/00Undergarments
    • A41B9/04Knickers for ladies, with or without inserted crotch or seat parts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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Abstract

本发明专利申请包括用于纺织应用中使用的织物,所述织物使用纤维的混合物并在最终制造纺织品之前进行一系列增强织物性质的处理,使得这些物品更加舒适,并且在对抗的细菌的种类数量和该能力有效时间两方面提高其杀菌能力。

Description

纺织品中的防臭抗菌织物
技术领域
本发明专利申请包括纺织应用中使用的织物,所述织物具有对抗臭味和细菌增殖的性质。
背景技术
当前各种材料用于防止臭味产生和同样引起臭味的细菌的增殖。
为获得这些材料,可以将构成织物的纤维在如银和/或铜等金属元素中浸泡,使得所述元素的颗粒附着于纤维,而在将这些物质与人或动物皮肤接触使用时它们可能对一些人引起过敏反应。还有使用锌离子涂覆纤维的浸泡,锌离子具有不会过分地与服装穿着者的皮肤反应的性质。
另一方面,采用这些浸泡的这种织物会迅速失去抗菌元素,这使它们容易再次存在细菌和臭味,因为纤维不保持银和/或铜离子。
因此,有在制成纺织品后利用在使抗菌元素(其会很快失去其效果)附着于其纤维并消除臭味的产品中浸泡而处理的已知织物。并且,作为织物,它们具有由棉和其他已知纤维制成的织物的一般性质,特别是在其吸水能力、织物的触感和硬挺度方面。
发明内容
本发明的目的是获得在人们常用的纺织品中使用的织物,所述织物使这些物品更加舒适,并且在对抗的细菌的种类数量和在该能力有效时间两方面提高其抗菌品质。
因此,本发明采取的是用于优选人用的纺织品中的织物的形式,所述织物由合成和天然纤维以及由纤维素和锌类化合物构成的抗菌纤维的混合物构成。构成丝线的该混合物具有8%~70%的抗菌纤维百分比。
抗菌纤维素纤维具有在其内部的元素锌,使其具有所述锌对抗臭味和细菌增殖的性质。其效果即使洗涤也经时持续,因为其位于纤维内部而不是附着于纤维,后者使其非常容易因洗涤而脱落,从而丧失其特性。
作为此底物,无论其是纤维、丝线还是织物,都也被提供对织物吸水能力具有作用的铝衍生物的浸泡,利用它来提高织物吸水的速度。这符合抗菌纤维所具有的吸水或吸汗(在织物的实际使用中)的能力,产生比现有织物具有更高的吸水能力的织物。
此吸水能力是织物舒适度的衡量标准,因为随着穿着者的汗液消除,吸水越强则提供越舒适的感觉。
铝浸泡也为织物提供了更高的柔软感,提高了所述织物使用者的舒适感。
另一方面,添加至棉、毛或类似纤维的抗菌纤维成为丝线的组成,使得由这些丝线构成的织物与纯粹由棉、毛或类似纤维制成的织物相比较不硬挺。这一较低的硬挺度提高了织物的舒适度,因为织物越不硬挺,则被认为越舒适。
利用作为本专利主题的对于丝线或织物的新处理,所述织物进行了过氧化氢衍生物的添加,这使其可被添加至织物自身的结构,使得更加抗细菌、抗真菌以及抗病毒,并具有避免形成藻类和孢子的性质。
利用与锌的性质加合的此处理,并利用所述锌位于纤维内部的特殊性,我们得到了具有通过所述化合物的作用而增强的抗菌纤维的织物,获得了与具有附着于纤维的金属离子的织物相比对于使用者健康来说安全得多的织物。
该织物以较低的耗水量生产,因为与棉线的生产相比,所使用的抗菌纤维消耗少20倍的水,使环境负荷降低至0.6。
该织物的应用定位于制作优选对应于短袜的物品,当然也可以制作长袜、内衣,和医疗保健物品和家用布料用织物。
以此方式,可获得下述织物,其显著地改善了用于消除臭味的现有织物迄今所提供的特性,因为其由于较高吸水性而更舒适、触感更佳并且丝线较不硬挺,还实现了持续更久的抗菌作用,所有这些都对环境具有较低的负担。
其他细节和特征将随着以下描述的展开而得到阐述,以下描述以说明方式显示了本发明的实际制造,但不限于该用途。
具体实施方式
在本发明的一种优选形式中,我们获得了用于纺织品中的织物,其优选应用于短袜、长袜、内衣、其他保健应用、家用布料等,以防止臭味、可能的细菌,并提高其舒适度。
该织物由纤维的混合物构成,其中通常构成丝线的该混合物具有棉纤维和抗菌纤维,后者的百分比为8%~70%。
该抗菌纤维由纤维素和氧化锌的衍生物构成,其中所述锌通常通过挤出而并入纤维自身结构之中,通过洗涤而以持久的方式释放,可承受高达约75次洗涤,因而可以说,所述纤维的可用性在实用中持续至短袜的整个寿命。
制造织物的这种纤维混合物提供了69cN/%的丝线硬挺度,而棉制的22/1Ne具有78cN/%的硬挺度。
形成织物中的纤维混合物的一部分的抗菌纤维的纤维素组成提高了吸水性,使得对于棉织物而言,在37℃和75%湿度的吸水性测试中结果为7.7%,而对于抗菌纤维的最低值为20%的所述织物而言,其结果为11%。
使用铝衍生物处理的织物使织物比棉织物吸水更迅速,吸收时间减少至少30%。
该织物的硬挺度、其吸水能力和其吸水速度实现了一种优于棉织物的非常舒适的织物,例如,如已经显示的;吸收越强,则舒适感越高。
除其组成和前述铝处理之外,该织物也可以进行下述处理,其中将过氧化氢衍生物添加至其结构,其随织物的使用而释放,获得很高的抗细菌、抗真菌和抗病毒作用,也避免形成藻类和孢子。其发挥所防止的细菌种类拓宽了纤维自身的锌所防止的细菌的种类,其中,有:
-革兰氏阳性菌:金黄色葡萄球菌(Staphilococcus Aureus)、白喉棒状杆菌(Corynebacterium Diptheriae)、单核细胞增多性李斯特菌(ListeriaMonocytogenes)、链球菌(Streptococci)、藤黄微球菌(Micrococcus Luteus)、耐甲氧西林金黄色葡萄球菌(MRSA)和屎肠球菌(Enterococcus Faecium)。
-革兰氏阴性菌:大肠埃希菌(Eschericha Coli)、肺炎克雷伯氏杆菌(KlebsiellaPneumoniae)、绿脓杆菌(Pseudomonas Aeruginosa)、猪霍乱沙门氏菌(Salmonella Choleraesuis)、普通变形杆菌(Proteus Vulgaris)、粘质沙雷氏菌(Serratia Marcescens)、奇异变形杆菌(Proteus Mirabilis)。
利用此处理,真菌族属也被消除,例如:
-黑曲霉(Aspergillus Niger)、枝孢菌(Cladosporium spp)、须癣毛癣菌(Trichophyton mentagrophites)、白色念珠菌(Candida Albicans)、桔青霉(Penicillium Citrinum)、腐皮镰孢菌(Fusarium Solani)、链格孢菌(Alternariaspp)。
除此之外,此处理还避免了一些种类的藻类和孢子的形成,以及具有抵抗如甲型流感(H1N1)病毒、鼻病毒(Rhinovirus)、单纯疱疹病毒(Herpes Simplex)和猫杯状病毒(Feline Calicivirus)等一些病毒的作用。
优选的是,将织物用于制作短袜,当然也可以制作长袜、内衣和医疗保健物品和家用布料用织物。在短袜的制作中,使用的是长度为20mm~100mm且厚度为1分特~8分特的纤维素抗菌纤维。
在充分描述本发明之后,容易发现可以引入任何种类的被认为有必要的修改,只要其不改变本发明的主旨即可,本发明的主旨被总结在以下权利要求中。

Claims (3)

1.一种纺织品用防臭抗菌织物,所述织物由纤维的混合物构成并释放锌以执行防止臭味和消除细菌的功能,其特征在于,所述纤维的混合物具有至少一种由纤维素和锌类化合物构成的抗菌纤维,所述锌在所述纤维的结构的内部,其中,所述织物中的所述纤维的混合物的配比由百分比为8%~70%的抗菌纤维和作为天然和合成纤维的其余部分构成,并且所述纤维用提供到所述纤维的结构的过氧化氢衍生物处理。
2.如权利要求1所述的纺织品用防臭抗菌织物,其特征在于,所述织物含有通过将所述织物进行浸泡而并入的铝。
3.如权利要求1所述的纺织品用防臭抗菌织物,其特征在于,所述织物以制作短袜、长袜、内衣、医疗保健物品和家用布料的方式使用。
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