CN104233282B - A kind of Co-based alloy powder repaired for wheel disc of turbocharger of internal combustion engine - Google Patents
A kind of Co-based alloy powder repaired for wheel disc of turbocharger of internal combustion engine Download PDFInfo
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- CN104233282B CN104233282B CN201310244909.7A CN201310244909A CN104233282B CN 104233282 B CN104233282 B CN 104233282B CN 201310244909 A CN201310244909 A CN 201310244909A CN 104233282 B CN104233282 B CN 104233282B
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- alloy powder
- turbocharger
- wheel disc
- combustion engine
- internal combustion
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Abstract
A kind of Co-based alloy powder repaired for wheel disc of turbocharger of internal combustion engine, its composition includes Cr, Mo, Ni, Y2O3, Hf, be characterized in also including W, Si, Mn, Co, Fe, the mass percent of the most each component is: C:0.1 ~ 0.5%;Cr:9 ~ 11%;Mo:16 ~ 20%;W:5 ~ 7%;Ti:3 ~ 7%;Al:1 ~ 3%;B:0.3 ~ 0.7%;Si:0.4 ~ 0.6%;Y2O3: 0.3 ~ 0.5%;Ce:0.2 ~ 0.4%;Ni: surplus.The present invention solves and improves alloy powder crack resistance in laser cladding layer, mouldability, technology stability and homogeneity of ingredients, meets that remanufactured component is anti-corrosion to cladding layer, wear-resisting, the combination property requirement of endurance and moderate hardness etc..
Description
Technical field
The present invention relates to a kind of alloy powder material being suitable for laser melting coating, particularly relate to a kind of for internal combustion engine whirlpool
The Co-based alloy powder that wheel supercharger wheel disc is repaired, belongs to C23C24/10 (2006.01) the I skill in IPC International Patent Classification (IPC)
Art field.
Background technology
Turbocharger be a kind of in hot environment ultrahigh speed rotate machinery, its parts turbine disk working speed up to
10000~20000 revs/min, the machinery of such high speed rotating often causes damage because installing and using improper, makes user suffer
Certain economic loss.May cause because of vibration when high speed rotating owing to there is gap when the blade on the turbine disk assembles
Accident, so for fixing blade, often after blade assembles, on the falcon tooth of both sides, riveter point is to fasten blade, but riveting point usually can
Cause stress to concentrate when high speed rotating, thus cause wheel disc to lose efficacy, there is crackle and accidents caused in tenon tooth.Therefore, it is necessary to adopt
Take certain mode to carry out riveting point restoring maintenance.
The Electric Welding Buttering Technique mode used at present, all can inevitably produce big thermal deformation, height this for the turbine disk
Precise part all can not bear.
Therefore, suitable turbocharger wheel disc restorative procedure is selected, it is ensured that adding of the turbocharger wheel disc after reparation
Work error is little, thermal deformation is little, standardization is strong, repair after wheel disc performance good, be problem the most urgently to be resolved hurrily.
Laser melting coating recovery technique, as the re-manufacturing technology of a kind of advanced person, has obtained rapid popularization in recent years and extensively should
With.
At present, corrosion-inhibiting coating both domestic and external uses the traditional handicrafts such as spraying, surfacing to prepare, and these traditional handicrafts prepare
Corrosion-inhibiting coating has some to be difficult to the problem overcome.Such as: anticorrosive coat actual functional capability layer is the thinnest;Manufacture in coating procedure and be easily generated gas
Hole, the defect such as it is mingled with;Coating and mother metal faying face are non-metallurgical binding, and problems such as coming off easily occurs in coating.And use laser to melt
Coating technique manufactures corrosion-inhibiting coating then can effectively solve problem above, and the process conditions greatly reducing manufacture corrosion-inhibiting coating are wanted
Ask, reduce cost simultaneously.
Laser melting coating is as the re-manufacturing technology of a kind of advanced person, along with improving constantly of laser power and stability,
Rapid popularization and extensively application are arrived.Laser melting coating is to obtain in metal surface to be combined with matrix strong metallurgical, and pore-free, splits
The advanced re-manufacturing technology of the high performance surface coating of the defects such as stricture of vagina, it can be by dystectic alloy material cladding in low melting point
Substrate surface, it is also possible on low-cost substrates, prepare high performance face coat, with replace the most senior, high performance
Integral material, saves precious metal, reduces parts cost.Laser melting coating solves many conventional methods and is difficult to processing or cannot
The problem of processing, provides a kind of technology effective method unique, advanced for product remanufacturing.
But, the alloy powder that laser melting coating is special in the market is actually rare, and the traditional handicraft such as surfacing, spraying institute
The alloy powder used, is to be allocated by different proportion, and various Ni-based, the cobalt needed for the form preparation of powder mixing machine
Base, iron(-)base powder.These hybrid alloys powder exist such as mix uneven, granularity difference is big, fusing point is different, composition
Deviation, the coefficient of expansion not parity problem, causes in actual cladding uncontrollable crackle, pore, segregation, performance is unstable, be difficult to
The defects such as machine adds.
People alloy powder material side needed for research and utilization laser melting and coating technique carries out part of appliance reparation in recent years
Face has made some progress, such as.
" a kind of mobile laser cladding scene processing that the Chinese invention patent application of Publication No. CN1854317 is given
Alloy powder material ", this alloy powder material utilizes following elemental composition to strengthen nickel-base alloy: Cr, W, Mo, Al, Ti, Co, also
Can add Co, C, N, Nb, Cu, B, Si and trace rare-earth element, wherein, rare earth element can be Ce, Y, Hf.
The Chinese invention patent application of Publication No. CN101381868 be given " a kind of laser melting coating high rigidity is stainless
Steel alloy powder and preparation technology ", this alloy powder each Ingredient Wt percentage ratio is: C:0.5-0.8%;Cr:18-24%;
Ni:11-17%;B:2.0-5.5%;Si:2.0-6.0%;Mo:4-9%; CeO2: 1-5%;Fe surplus.Alloy powder
Preparation technology includes: dispensing, melting, slag making are collected with composition detection, sieve in six steps with deoxidation, powder by atomization, powder.
The Chinese invention patent application of Publication No. CN101381869 be given " laser melting coating is high hard without splitting ferrous alloy
Special metals powder ", the formula of this special metals powder, weight percentage: carbon (C): 0.3-0.5;Silicon (Si): 1.2-2.0;
Boron (B): 0.4-1.0;Nickel (Ni): 1.5-2.5;Chromium (Cr): 1.0-1.5;Manganese (Mn): 1.0-1.5;Molybdenum (Mo): 1.5-2.5;
Vanadium (V): 0.15-0.7;Niobium (Nb): 0.15-0.7 surplus is ferrum (Fe), its weight sum is 100%.
" a kind of laser melting coating conductive rollers cobalt-based that the Chinese invention patent application of Publication No. CN101187022 is given
Alloy powder ", the percentage by weight of the chemical composition of this alloy powder is: Cr:24~30%;W:6~10%;Mo:3~6%;
Ni:6~12%;Fe:2~10%;Mn:0.5~2%;Si:0.2~2%;V:0.1~0.6%;B:0.3~1.5%;C:
0.5~2.5%;Y2O3: 0~0.5%;Hf:0~0.5%;La2O3: 0~0.5%;Ce:0~0.5%;Surplus is Co.
Though technique scheme be given these for laser melting coating alloy powder can repair specific part of appliance
The technique effect that upper acquirement is certain, but owing to having self technology characteristics, be not met by and be applicable to other specific base material swashing
The technological requirement of light cladding, particularly can not meet alloy powder crack resistance in laser cladding layer, mouldability, process stabilizing
The requirement of the antiseptic property to cladding layer is also satisfied while property and homogeneity of ingredients.
Therefore, what research and development made new advances has antiseptic power, the stable performance Ni-based conjunction of laser melting coating corrosion-inhibiting coating
Bronze end, is the key subjects in described technical field, retrieves verification through the applicant: there is no the relevant report of this respect both at home and abroad
Road.
Summary of the invention
It is an object of the invention to provide and a kind of there is antiseptic power, stable performance laser melting coating corrosion-inhibiting coating nickel
Base alloy powder, manufactures corrosion-inhibiting coating for the method using laser melting coating.This Co-based alloy powder is at existing Ni-Cr-Mo
On the basis of alloy, at least add trace rare-earth element Y2O3A kind of that carry out matrix intercrystalline strengthening, particularly also with in Hf element
At least add the one in W, Co, Si, Mn element and carry out alloy substrate strengthening, thus solve and improve alloy powder at laser
Crack resistance, mouldability, technology stability and homogeneity of ingredients in cladding layer, meets remanufactured component anti-corrosion to cladding layer, resistance to
The combination property requirement of mill, endurance and moderate hardness etc..
The technical scheme that the present invention is given is: this nickel-base alloy powder repaired for wheel disc of turbocharger of internal combustion engine
End, its composition includes Cr, Mo, Ni, Y2O3, Hf, be characterized in also including W, Si, Mn, Co, Fe, (matter of the most each component
Amount percent) be.
C:0.1 ~ 0.5%;Cr:9 ~ 11%;Mo:16 ~ 20%;W:5 ~ 7%;Ti:3 ~ 7%.
Al:1 ~ 3%;B:0.3 ~ 0.7%;Si:0.4 ~ 0.6%;Y2O3: 0.3 ~ 0.5%;Ce:0.2 ~ 0.4%.
Ni: surplus.
(mass percent) of each component of this preferred Co-based alloy powder that the present invention is given is.
C:0.2%;Cr:10%;Mo:19%;W:5%;Ti:4%;Al:1%.
B:0.5%;Si:0.5%;Y2O3: 0.3%;Ce:0.2%;Ni: surplus.
(mass percent) of each component of this preferred Co-based alloy powder that the present invention is given is.
C:0.3;Cr:11%;Mo:18%;W:6%;Ti:5%;Al:2%.
B:0.6%;Si:0.4%;Y2O3: 0.4%;Ce:0.3%;Ni: surplus.
The present invention is by substantial amounts of test and creative work, selected alloy substrate intensified element, boundary-strengthening element
With dispersoid particle material, and the degree of preferred each component, by multiple strengthening means, reinforced alloys matrix, again
Improve grain boundary quality, make alloy obtain good combination property, it is achieved thereby that alloy has moderate hardness and intensity
While, reduce again alloy melting point, add wear-resisting, corrosion resisting property.Fundamentally solve and improve alloy powder swashing
Crack resistance, mouldability, technology stability and homogeneity of ingredients in light cladding layer, meet remanufactured component anti-corrosion to cladding layer,
The combination property requirement of wear-resisting, endurance and moderate hardness etc..
What the present invention was given has antiseptic power, stable performance anticorrosive coating nickel-based alloy powder for laser cladding is
Meticulously being prepared by operations such as vacuum melting, vacuum aerosolization, screenings, granularity is-100+270 mesh.
What the present invention was given has anticorrosive coating nickel-based alloy powder for laser cladding antiseptic power, stable performance,
5KW CO is used in actual cladding operates2Laser instrument, in the work of dusty material described in wheel disc of turbocharger of internal combustion engine cladding
Skill parameter is: power: 1800 ~ 3800W, focal length: 320 ~ 400mm, spot diameter: 3 ~ 6mm, scanning speed: 240 ~ 600mm/
Min, puts powder thickness: 0.3 ~ 1mm.
The present invention has antiseptic power, stable performance anticorrosive coating nickel-based alloy powder for laser cladding material, main
The laser melting coating corrosion-inhibiting coating of wheel disc of turbocharger of internal combustion engine to be applied to.
Compared with prior art, the invention has the beneficial effects as follows: on the basis of NI-CR-MO alloys, add alloy substrate strengthening
Element, boundary-strengthening element and dispersoid particle material, and adjust the degree of each element.By multiple strengthening means, by force
Alloy matrix, improves again grain boundary quality, makes alloy obtain good combination property.It is achieved thereby that alloy have moderate
Hardness and intensity while, reduce again alloy melting point, add wear-resisting, corrosion resisting property.Fundamentally solve and improve
Alloy powder crack resistance, mouldability, technology stability and homogeneity of ingredients in laser cladding layer, meets remanufactured component pair
Cladding layer is anti-corrosion, the combination property requirement of wear-resisting, endurance and moderate hardness etc..
Detailed description of the invention
Embodiment 1.
Use 5KW CO2Laser instrument, carries out laser melting coating to wheel disc of turbocharger of internal combustion engine.The Co-based alloy powder of design
The mass percent of alloying element is.
C:0.2%;Cr:10%;Mo:19%;W:5%;Ti:4%;Al:1%;B:0.5%;Si:0.5%;Y2O3: 0.3%;Ce:
0.2%;Ni: surplus.
Its melting and coating process parameter is: power: 1800~3800W, focal length: 320 ~ 400mm, spot diameter: 3~6mm, scanning
Speed: 240~600mm/min, puts powder thickness: 0.3~1.0mm.
Embodiment 2.
Use 5KW CO2Laser instrument, carries out laser melting coating to wheel disc of turbocharger of internal combustion engine.The Co-based alloy powder of design
The mass percent of alloying element is.
C:0.3;Cr:11%;Mo:18%;W:6%;Ti:5%;Al:2%;B:0.6%;Si:0.4%;Y2O3: 0.4%;Ce:
0.3%;Ni: surplus.
Its melting and coating process parameter is: power: 1800~3800W, focal length: 320 ~ 400mm, spot diameter: 3~6mm, scanning
Speed: 240~600mm/min, puts powder thickness: 0.3~1.0mm.
Claims (1)
1. the Co-based alloy powder repaired for wheel disc of turbocharger of internal combustion engine, it is characterised in that Co-based alloy powder is each
The mass percent of component is:
C:0.2%, Cr:10%, Mo:19%, W:5%, Ti:4%, Al:1%,
B:0.5%, Si:0.5%, Y2O3: 0.3%, Ce:0.2%, Ni: surplus;Or
C:0.3%, Cr:11%, Mo:18%, W:6%, Ti:5%, Al:2%,
B:0.6%, Si:0.4%, Y2O3: 0.4%, Ce:0.3%, Ni: surplus.
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CN201310244909.7A CN104233282B (en) | 2013-06-20 | 2013-06-20 | A kind of Co-based alloy powder repaired for wheel disc of turbocharger of internal combustion engine |
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CN104862693B (en) * | 2015-04-24 | 2018-04-06 | 燕山大学 | A kind of laser melting coating restorative procedure of cone pulley for metal-wire drawing machine |
CN104831123B (en) * | 2015-05-26 | 2017-09-01 | 广东电网有限责任公司电力科学研究院 | Corrosion-inhibiting coating and its powder stock and preparation method and application |
CN106854717B (en) * | 2015-12-08 | 2018-08-28 | 沈阳大陆激光技术有限公司 | A kind of Co-based alloy powder of laser manufacture ejection roller way of continuous casting machine |
CN105506616B (en) * | 2015-12-14 | 2017-05-10 | 西安文理学院 | Laser cladding nickel base alloy powder for repairing damaged blower vane and repair method |
CN106435580B (en) * | 2016-11-25 | 2019-04-23 | 福州大学 | The Ni-based molybdenum disulfide powder of laser melting coating, and preparation method thereof and application method |
CN111250900B (en) * | 2020-02-24 | 2022-11-01 | 江西恒大高新技术股份有限公司 | Preparation method of modified Inconel625 powder surfacing coating |
CN113308629B (en) * | 2021-06-01 | 2022-07-01 | 石家庄铁道大学 | Nickel-based alloy powder for petroleum plunger laser cladding and application method |
CN115351271B (en) * | 2022-08-31 | 2024-01-26 | 国家电投集团江西水电检修安装工程有限公司 | Impeller corrosion-resistant coating powder, impeller corrosion-resistant coating and preparation method thereof |
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JPS5891145A (en) * | 1981-11-24 | 1983-05-31 | Toshiba Tungaloy Co Ltd | Titanium oxide-base colored sintered alloy |
CN102021562B (en) * | 2009-09-17 | 2012-07-11 | 沈阳大陆激光技术有限公司 | Method for repairing damage of wheel disc of turbocharger of internal combustion engine |
CN102031513B (en) * | 2009-09-28 | 2012-07-11 | 沈阳大陆激光技术有限公司 | Restoring method of last-stage blade of steam turbine |
CN101838758B (en) * | 2010-05-24 | 2011-08-10 | 苏州大学 | Cobalt-free nickel-based alloy |
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Effective date of registration: 20230322 Address after: No. 102, Office Building, No. A3, Gucheng North Road, Shijingshan District, Beijing, 100043 Patentee after: BEIJING DALU TIANRUI LASER ENGINEERING TECHNOLOGY Co.,Ltd. Address before: 110136 No. 29 Shen Shen road, Shenbei New Area economic and Moral Development Zone, Liaoning, Shenyang Patentee before: Shenyang Dalu Laser Technology Co.,Ltd. |
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