CN104232330A - Washing powder with bactericidal effect - Google Patents
Washing powder with bactericidal effect Download PDFInfo
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- CN104232330A CN104232330A CN201410455962.6A CN201410455962A CN104232330A CN 104232330 A CN104232330 A CN 104232330A CN 201410455962 A CN201410455962 A CN 201410455962A CN 104232330 A CN104232330 A CN 104232330A
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- washing powder
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- germicidal action
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Abstract
The invention belongs to the field of washing products and provides washing powder with a bactericidal effect. The washing powder comprises the following components: antibacterial zeolite, C14-C18 methyl ester sulfonate, sodium dodecyl benzene sulfonate, sodium silicate, anhydrous sodium sulphate, and an assistant, wherein the antibacterial zeolite is 4A zeolite loaded with nano TiO2. The antibacterial zeolite with the bacterial effect is added to the washing powder, so that the washing powder has a high-efficient sterilization effect, and has the characteristics of being strong in soil removability, non-toxic, and low in price.
Description
Technical field
The invention belongs to articles for washing field, relate to a kind of washing powder, particularly a kind of washing powder with germicidal action.
Background technology
Washing powder, as conventional decontamination washing product, is widely used, and current washing powder generally only has soil removability, does not possess sterilizing function, can not meet the requirement of comprehensive cleaning clothes.In recent years, some washing powder with disinfecting and sterilizing functions occur in succession, mainly by adding chemical bactericide to realize in washing powder formula, such as: application publication number is that the Chinese patent of CN103865671A discloses a kind of bactericidal washing powder that with the addition of except mite agent, can effectively press down mite to go out mite; Application publication number is that the Chinese patent of CN103184115A with the addition of boric acid to reach germicidal action and anti-bacteria refresh function in washing powder formula; Application publication number is that the Chinese patent of CN103289834A with the addition of clorox as sterilant in washing powder, the bacterium effectively above removing clothes.In addition, also have and add the relevant report that biological bactericide reaches sterilization and disinfection effect in washing powder, it is the washing powder of sterilant that a kind of bactericidal washing powder (Authorization Notice No. CN101508940B) of Chinese patent discloses a kind of subtilis LD-8 fermentation broth extract that adopts.Above-mentioned research directs the exploitation of washing powder kind with high content of technology, related products has certain sterilization effect, but also there are problems in the application, such as chemical bactericide is poisonous, life-time service easily damages human body, biological bactericide or Chinese medicinal materials sterilant expensive, is unfavorable for reducing production cost, so good, that soil removability is strong, nontoxic, the inexpensive washing powder of exploitation sterilization effect is most important.
Summary of the invention
The object of the invention is to the defect overcoming prior art, provide a kind of washing powder with germicidal action, this washing powder has the advantage that sterilization effect is good, soil removability is strong, nontoxic, inexpensive.
To achieve these goals, the technical solution adopted for the present invention to solve the technical problems is:
There is a washing powder for germicidal action, it is characterized in that: each component of described washing powder and mass fraction thereof are:
Sterilization zeolite 10 ~ 35%,
C14 ~ C18 methyl sodiosul foaliphatate 1 ~ 10%,
Sodium dodecylbenzene sulfonate 5 ~ 20%,
Water glass 5 ~ 30%,
Sodium sulfate anhydrous.min(99) 20 ~ 50%,
Auxiliary agent 1 ~ 15%.
Preferably, each component of wherein said washing powder and mass fraction thereof are:
Sterilization zeolite 15 ~ 30%,
C14 ~ C18 methyl sodiosul foaliphatate 2 ~ 5%,
Sodium dodecylbenzene sulfonate 5 ~ 15%,
Water glass 10 ~ 20%,
Sodium sulfate anhydrous.min(99) 35 ~ 45%,
Auxiliary agent 5 ~ 10%.
Preferably, described sterilization zeolite is load nano-TiO
24A zeolite, the preparation process of described sterilization zeolite comprises: be first presoma with butyl (tetra) titanate, ethanol is solvent, preparation TiO
2precursor sol, then immerses TiO by 4A zeolite
2in precursor sol, finally pyroprocessing 4A zeolite 2h at 450 DEG C, obtains sterilization zeolite.
Preferably, described auxiliary agent is at least one of zymin, SYNTHETIC OPTICAL WHITNER, anti redeposition agent, white dyes, softening agent, static inhibitor, essence.
Technical characteristics of the present invention is in washing powder, with the addition of the sterilization zeolite with germicidal action, makes washing powder be provided with efficient sterilizing effect.The sterilization zeolite nano-TiO that has been load
24A zeolite, nano-TiO
2be a kind of photocatalyst efficiently, there is significant bactericidal effect, compare with organic bactericide, nano-TiO
2nontoxic, and germicidal action is lasting.The specific surface area of 4A zeolite is large, just can make TiO by simple adsorption process
2colloidal sol uniform loading is on it, then by short annealing process, i.e. obtained load nano-TiO
24A zeolite (sterilization zeolite), preparation technology is simple, and cost is low, can add in a large number in washing powder, reaches the object of efficient sterilizing.
Beneficial effect of the present invention has:
(1) washing powder of the present invention is with sterilization zeolite for sterilization component, gives washing powder good sterilization effect, and has no side effect, cheap, overcomes the hidden danger using organic bactericide to damage the talent;
(2) washing powder of the present invention is using C14 ~ C18 methyl sodiosul foaliphatate and Sodium dodecylbenzene sulfonate as decontamination active ingredient, methyl sodiosul foaliphatate is the anion surfactant obtained for raw material with natural acid methyl esters, there is excellent physical and chemical performance and surfactivity, there is good soil release performance, stability in hard water, extremely low toxicity and excellent biological degradability, washing powder soil removability of the present invention is strong, little to human body pungency, belong to green laundry detergent kind;
(3) washing powder of the present invention is applicable to pure cotton fabric, chemical & blended fabric, BLENDED FABRIC and silk, and use range is wide.
Embodiment
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearly understand, below in conjunction with embodiment, the present invention is further illustrated.Should be appreciated that embodiment described herein only for explaining the present invention, being not intended to limit the present invention.
embodiment 1
A kind of there is the washing powder of germicidal action each component and quality be:
Sterilization zeolite 25 Kg,
C14 ~ C18 methyl sodiosul foaliphatate 3 Kg,
Sodium dodecylbenzene sulfonate 10 Kg,
Water glass 15 Kg,
Sodium sulfate anhydrous.min(99) 40 Kg,
CMC 3 Kg，
Proteolytic enzyme 1 Kg,
White dyes 0.5 Kg,
Static inhibitor 1 Kg,
Essence 1.5 Kg.
Preparation process is as follows:
(1) preparation of sterilization zeolite: be first presoma with butyl (tetra) titanate, ethanol is solvent, preparation TiO2 precursor sol, then immersed in TiO2 precursor sol by 4A zeolite, finally pyroprocessing 4A zeolite 2h at 450 DEG C, obtains sterilization zeolite.
(2) preparation of washing powder:
Precise sterilization zeolite, C14 ~ C18 methyl sodiosul foaliphatate, Sodium dodecylbenzene sulfonate, water glass, Sodium sulfate anhydrous.min(99), CMC, essence, add in mixing device and mix, add water, rising temperature for dissolving, degassed after filtering, evenly, spraying forms dry powder in grinding, finally add proteolytic enzyme, white dyes and static inhibitor, mix.
Washing powder products configuration in embodiment 1 is become the solution of 5% concentration, select intestinal bacteria, Salmonellas, golden yellow common coccus 3 kinds of bacteriums, conventional microbiological is adopted to detect sterilization effect, test-results shows, the sterilization effect of product of the present invention to 3 kinds of bacteriums is all greater than 90%, and sterilization effect is obvious.
embodiment 2
A kind of there is the washing powder of germicidal action each component and quality be:
Sterilization zeolite 28 Kg,
C14 ~ C18 methyl sodiosul foaliphatate 5 Kg,
Sodium dodecylbenzene sulfonate 10 Kg,
Water glass 15 Kg,
Sodium sulfate anhydrous.min(99) 35 Kg,
CMC 3 Kg，
Proteolytic enzyme 1.5 Kg,
White dyes 0.5 Kg,
Essence 2 Kg.
Preparation process is with embodiment 1.
The above, be only preferred embodiment of the present invention, is not intended to limit scope of patent protection of the present invention.
Claims (4)
1. there is a washing powder for germicidal action, it is characterized in that: each component of described washing powder and mass fraction thereof are:
Sterilization zeolite 10 ~ 35%,
C14 ~ C18 methyl sodiosul foaliphatate 1 ~ 10%,
Sodium dodecylbenzene sulfonate 5 ~ 20%,
Water glass 5 ~ 30%,
Sodium sulfate anhydrous.min(99) 20 ~ 50%,
Auxiliary agent 1 ~ 15%.
2. the washing powder with germicidal action according to claim 1, is characterized in that: each component of described washing powder and mass fraction thereof are:
Sterilization zeolite 15 ~ 30%,
C14 ~ C18 methyl sodiosul foaliphatate 2 ~ 5%,
Sodium dodecylbenzene sulfonate 5 ~ 15%,
Water glass 10 ~ 20%,
Sodium sulfate anhydrous.min(99) 35 ~ 45%,
Auxiliary agent 5 ~ 10%.
3. the washing powder with germicidal action according to claim 1 and 2, is characterized in that: described sterilization zeolite is load nano-TiO
24A zeolite, the preparation process of described sterilization zeolite comprises: be first presoma with butyl (tetra) titanate, ethanol is solvent, preparation TiO
2precursor sol, then immerses TiO by 4A zeolite
2in precursor sol, finally pyroprocessing 4A zeolite 2h at 450 DEG C, obtains sterilization zeolite.
4. the washing powder with germicidal action according to claim 1 and 2, is characterized in that: described auxiliary agent is at least one of zymin, SYNTHETIC OPTICAL WHITNER, anti redeposition agent, white dyes, softening agent, static inhibitor, essence.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455962.6A CN104232330A (en) | 2014-09-10 | 2014-09-10 | Washing powder with bactericidal effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455962.6A CN104232330A (en) | 2014-09-10 | 2014-09-10 | Washing powder with bactericidal effect |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104232330A true CN104232330A (en) | 2014-12-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201410455962.6A Pending CN104232330A (en) | 2014-09-10 | 2014-09-10 | Washing powder with bactericidal effect |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505621A (en) * | 2015-12-17 | 2016-04-20 | 广州市浪奇实业股份有限公司 | Neutral peroxide bleacher |
| CN106590945A (en) * | 2017-02-04 | 2017-04-26 | 蒋红梅 | Laundry powder |
| CN115449437A (en) * | 2022-09-06 | 2022-12-09 | 深圳乙奇生物科技有限公司 | Concentrated nano photolysis underwear laundry detergent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1519304A (en) * | 2003-01-24 | 2004-08-11 | 谢家忠 | Nano bactericidal detergent with no phosphor |
| CN102864034A (en) * | 2012-09-05 | 2013-01-09 | 湖南日用化学科学研究所有限公司 | Detergent powder capable of removing stubborn stains |
| CN103695186A (en) * | 2013-12-19 | 2014-04-02 | 广州市浪奇实业股份有限公司 | Detergent composition containing alpha-sulfonated fatty acid alkyl ester salt |
-
2014
- 2014-09-10 CN CN201410455962.6A patent/CN104232330A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1519304A (en) * | 2003-01-24 | 2004-08-11 | 谢家忠 | Nano bactericidal detergent with no phosphor |
| CN102864034A (en) * | 2012-09-05 | 2013-01-09 | 湖南日用化学科学研究所有限公司 | Detergent powder capable of removing stubborn stains |
| CN103695186A (en) * | 2013-12-19 | 2014-04-02 | 广州市浪奇实业股份有限公司 | Detergent composition containing alpha-sulfonated fatty acid alkyl ester salt |
Non-Patent Citations (2)
| Title |
|---|
| 徐志兵等: "TiO2/4A沸石复合光催化剂制备及性能研究", 《中国重要会议论文全文数据库》 * |
| 石建稳: "纳米TiO2光催化剂掺杂改性与负载的研究", 《中国博士学位论文全文数据库（电子期刊）工程科技Ⅰ辑》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505621A (en) * | 2015-12-17 | 2016-04-20 | 广州市浪奇实业股份有限公司 | Neutral peroxide bleacher |
| CN106590945A (en) * | 2017-02-04 | 2017-04-26 | 蒋红梅 | Laundry powder |
| CN115449437A (en) * | 2022-09-06 | 2022-12-09 | 深圳乙奇生物科技有限公司 | Concentrated nano photolysis underwear laundry detergent and preparation method thereof |
| CN115449437B (en) * | 2022-09-06 | 2024-01-19 | 深圳乙奇生物科技有限公司 | Concentrated nano photolysis underwear laundry detergent and preparation method thereof |
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Application publication date: 20141224 |