CN104231704B - Environmental protection UV coating - Google Patents
Environmental protection UV coating Download PDFInfo
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- CN104231704B CN104231704B CN201410451703.6A CN201410451703A CN104231704B CN 104231704 B CN104231704 B CN 104231704B CN 201410451703 A CN201410451703 A CN 201410451703A CN 104231704 B CN104231704 B CN 104231704B
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Abstract
The invention discloses a kind of environmental protection UV coating; including following components in parts by weight: tripropylene glycol diacrylate 40 60 parts; 2 methyl 2 acrylic acid 2 hydroxyethyl ester phosphates 6 10 parts; urethane acrylate 35 45 parts; aliphatic urethane acrylate 24 parts, 2,4; 6 trimethylbenzoyl phenyl phosphinic acid ethyl esters 48 parts, organosilicon levelling agent 0.2 0.4 parts.The environmental protection UV coating of the present invention, has preferable wear-resisting scratch-resisting, chemical proofing, and has good adhesive force.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of environmental protection UV coating.
Background technology
UV is coating material solidified is that the new coating kind on the ground such as America and Europe, Japan is popular at twentieth century end.
Being applied to the external coating process of furniture, floor, mobile phone, walkman shell the earliest, its application is existing
Further expand to household appliance technical field and motorcycle and the Lacquer finish etc. such as cosmetics containers, television set and computer
Other field.
UV is exactly the English abbreviation of ultraviolet (Ultra-VioletRay). and industrial UV wavelength is with 200nm
It is its range of application to 450nm.The processing procedure irradiating " UV irradiates hardenable material " with UV and make it harden,
We term it " UVCuringProcess ".Environmental protection UV coating can pass through dip-coating, showering, paint be coated with,
After the method coatings such as spin coating, even vacuum painting, then irradiate and film-forming through UV photons.Gu Mingsi
Justice, the solidification of environmental protection UV coating is inseparable with the irradiation of UV light.This technique functions comes from 70 years
The international coatings market in generation, is a kind of brand-new green technology.Utilize the ultraviolet light polymerization that this technology produces
Coating, is called for short UV coating.In 20 end of the centurys, UV is coating material solidified to come into vogue in the ground such as west, Japan, is
A kind of coating variety representing fashion.It is applied to the earliest at the external coating of mobile phone, DVD, walkman shell
Reason, its application now further expanded to the household appliance technical field such as cosmetics, television set and computer later.
UV photocureable coating has without VOC (VOC), and environmental pollution is little, solidification
Speed is fast, saves the energy, cured product performance is good, be suitable for the advantages such as high-speed automated production.And pass
System coating is volatile, curing rate slow, is unfavorable for environmental protection.Therefore, UV coating is traditional coating
Main substitute.
Compared with general solvent based coating, the feature of UV coating is as follows:
UV coating solidifies (UV quartz burner) under UV photons irradiates, generally only need about 1 second or
Shorter time, can carry out quick and continuous operation, be greatly improved production efficiency.
Conventional oligomer in UV coating, such as epoxy acrylate, urethane acrylate, polyester acrylic
The resins such as ester, polyether acrylate, acroleic acid esterification polyacrylic resin and insatiable hunger polyester, and various
The simple function group of acrylate or polyfunctional monomer, all can be by freely under the effect of UV photons
Base causes polymerized at room temperature and crosslinking, thus be particularly conducive to heat sensitive base material (as timber, paper and
Plastics) covering with paint.
UV coating need not heat drying, thus can save energy when construction than conventional heated drying coating
Source 75%-90%.
The various coating equipments of UV coating are compact, are not required to drying tunnel, simple and efficient to handle, it is easy to accomplish produce
Automation, thus it is greatly saved occupation area of equipment, and reduce working space.
UV coating is solvent-free or the most solvent-free a kind of coating, and in film forming procedure, VOC free evaporate into air
In, environment is not polluted, it is easy to meet the environmental regulation of government or legislative bodies.
UV coating realizes the cross-linked polymeric between component under the effect of UV photons, and liquid is quickly solid
Chemical conversion film, and has tridimensional network, thus coating surface performance can be made to be improved, as hardness,
Pliability, wear-resisting scratch-resisting, chemical proofing, high gloss, durability etc..
Summary of the invention
For above-mentioned deficiency present in prior art, the technical problem to be solved is to provide one
Plant environmental protection UV coating.
A kind of environmental protection UV coating, including following components in parts by weight: tripropylene glycol diacrylate
40-60 part, 2-methyl-2-2-hydroxyethyl acrylate phosphate 6-10 part, urethane acrylate
35-45 part, aliphatic urethane acrylate 2-4 part, 2,4,6-trimethylbenzoyl phenyl phosphonic acids
Ethyl ester 4-8 part, organosilicon levelling agent 0.2-0.4 part.
A kind of environmental protection UV coating, including following components in parts by weight: tripropylene glycol diacrylate
40-60 part, 2-methyl-2-2-hydroxyethyl acrylate phosphate 6-10 part, urethane acrylate
35-45 part, aliphatic urethane acrylate 2-4 part, 2,4,6-trimethylbenzoyl phenyl phosphonic acids
Ethyl ester 4-8 part, organosilicon levelling agent 0.2-0.4 part, bactericide 0.2-0.4 part.
Described bactericide is N-(4,6-dimethyl pyrimidine-2-base) aniline and/or Enestroburin.Preferably,
Described bactericide is by N-(4,6-dimethyl pyrimidine-2-base) aniline of 10-30wt% and the alkene of 70-90wt%
Trifloxystrobin mixes.The present invention is pioneeringly by N-(4,6-dimethyl pyrimidine-2-base) aniline or alkene
Trifloxystrobin, in coating, serves preferable effect.
Tripropylene glycol diacrylate, also known as tri (propylene glycol) diacrylate, CAS No.:
42978-66-5.2-methyl-2-2-hydroxyethyl acrylate phosphate, CAS accession number: 52628-03-2.
2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl esters, No. CAS: 84434-11-7.
N-(4,6-dimethyl pyrimidine-2-base) aniline, CAS:53112-28-0.Enestroburin, CAS:
238410-11-2。
The environmental protection UV coating of the present invention uses industry universal method to be prepared from.
The environmental protection UV coating of the present invention, has preferable wear-resisting scratch-resisting, chemical proofing, and
And there is good adhesive force.
Detailed description of the invention
Embodiment 1-4
Weigh each component according to embodiment 1-4 data corresponding in table 1, use industry universal method system
Standby, obtain the environmental protection UV coating of the present invention.
Table 1: the environmental protection UV formulation for coating material list position of embodiment 1-4: kilogram
Test case 1
The environmental protection UV coating of embodiment 1-4 is carried out performance test, testing standard and test result see
Table 2.
Table 2: the environmental protection UV coating property test table of embodiment 1-4
The performance of the environmental protection UV coating of embodiment 1-4 is tested, found that embodiment 1-4
The environmental protection UV coating key property prepared is good, meets relevant regulations index.
Test case 2
Antibacterial test standard: HG/T 3950-2007 " antibiotic paint ".Detect with bacterium: ETEC.
Coating antibacterium performance test: test result is shown in Table 3.
Table 3: coating antibacterium performance test table
| Antibacterium rate (ETEC), % | |
| Embodiment 1 | 99.2 |
| Embodiment 2 | 87.2 |
| Embodiment 3 | 88.6 |
| Embodiment 4 | 12.4 |
Coating antibacterium endurance quality is tested:
Use 1 30W, wavelength 253.7nm uviol lamp, antibiotic paint test plate (panel) distance uviol lamp 0.9m,
Irradiate 100 hours, re-test antibacterium performance.Test result is shown in Table 24.
Table 4: coating antibacterium endurance quality test table
| Antibacterium rate (ETEC), % | |
| Embodiment 1 | 95.3 |
| Embodiment 2 | 81.6 |
| Embodiment 3 | 82.5 |
| Embodiment 4 | 10.6 |
Claims (1)
1. an environmental protection UV coating, it is characterised in that include following components in parts by weight: 3 third
Omega-diol diacrylate 40-60 part, 2-methyl-2-2-hydroxyethyl acrylate phosphate 6-10 part is poly-
Urethane acrylate 35-45 part, aliphatic urethane acrylate 2-4 part, 2,4,6-trimethylbenzene first
Aminosulfonylphenyl phosphinic acid ethyl ester 4-8 part, organosilicon levelling agent 0.2-0.4 part, bactericide 0.2-0.4 part；
Described bactericide is by N-(4,6-dimethyl pyrimidine-2-base) aniline of 10-30wt% and 70-90wt%
Enestroburin mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410451703.6A CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410451703.6A CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104231704A CN104231704A (en) | 2014-12-24 |
| CN104231704B true CN104231704B (en) | 2016-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410451703.6A Active CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
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| Country | Link |
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| CN (1) | CN104231704B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312418A (en) * | 2017-07-16 | 2017-11-03 | 长沙善道新材料科技有限公司 | A kind of antimicrobial UV coating and its manufacture craft |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275054A (en) * | 2007-03-29 | 2008-10-01 | 比亚迪股份有限公司 | Ultraviolet cured paint composition and preparation thereof |
| CN101294011A (en) * | 2007-04-28 | 2008-10-29 | 佛山市顺德区汉达精密电子科技有限公司 | UV paint |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103525270A (en) * | 2013-09-24 | 2014-01-22 | 浙江佑谦特种材料有限公司 | UV (ultraviolet) coating for heat transfer printing on metal material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100725249B1 (en) * | 2005-12-20 | 2007-06-04 | (주)디피아이 홀딩스 | Ultraviolet curable paint for steels coating |
-
2014
- 2014-09-05 CN CN201410451703.6A patent/CN104231704B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101275054A (en) * | 2007-03-29 | 2008-10-01 | 比亚迪股份有限公司 | Ultraviolet cured paint composition and preparation thereof |
| CN101294011A (en) * | 2007-04-28 | 2008-10-29 | 佛山市顺德区汉达精密电子科技有限公司 | UV paint |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103525270A (en) * | 2013-09-24 | 2014-01-22 | 浙江佑谦特种材料有限公司 | UV (ultraviolet) coating for heat transfer printing on metal material |
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| CN104231704A (en) | 2014-12-24 |
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Inventor after: Sheng Qinghua Inventor before: Huang Meirong |
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Effective date of registration: 20180411 Address after: 322000, Zhejiang, Jinhua province Yiwu City Yi Town Road 71 Patentee after: YIWU DINGSHENG PRINTING Co.,Ltd. Address before: Room 4, building 411-45-4, science and technology building, No. 599, Jiangnan Road, hi tech Zone, Ningbo, Zhejiang, China Patentee before: NINGBO HIGH-TECH ZONE BAYI NEW MATERIAL TECHNOLOGY CO.,LTD. |
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Effective date of registration: 20230912 Address after: No. 3 Longyin Road, Longyou Economic Development Zone, Donghua Street, Longyou County, Quzhou City, Zhejiang Province, 324499 Patentee after: Quzhou Dingsheng New Materials Co.,Ltd. Address before: 322000 No. 71 Xiangyi Road, Yiting Town, Yiwu City, Jinhua City, Zhejiang Province Patentee before: YIWU DINGSHENG PRINTING Co.,Ltd. |