CN104231704A - Green and environment-friendly UV (ultraviolet) coating - Google Patents
Green and environment-friendly UV (ultraviolet) coating Download PDFInfo
- Publication number
- CN104231704A CN104231704A CN201410451703.6A CN201410451703A CN104231704A CN 104231704 A CN104231704 A CN 104231704A CN 201410451703 A CN201410451703 A CN 201410451703A CN 104231704 A CN104231704 A CN 104231704A
- Authority
- CN
- China
- Prior art keywords
- coating
- environmental protection
- urethane acrylate
- parts
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a green and environment-friendly UV (ultraviolet) coating. The green and environment-friendly UV coating comprises the following components in parts by weight: 40-60 parts of tripropylene glycol diacrylate, 6-10 parts of 2-methyl-2-acrylate-2-hydroxyethyl phosphate, 35-45 parts of urethane acrylate, 2-4 parts of aliphatic urethane acrylate, 4-8 parts of ethyl (2, 4, 6-trimethylbenzoyl) phenylphosphinate and 0.2-0.4 part of organic silicon leveling agent. The green and environment-friendly UV coating disclosed by the invention has relatively good wear and scratch resistance, resistance to chemicals and good adhesion.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of environmental protection UV coating.
Background technology
UV is coating material solidified is that the new coating kind on the ground such as America and Europe, Japan is popular at twentieth century end.Be applied to the external coating process of furniture, floor, mobile phone, walkman shell the earliest, its Application Areas now further expands to household appliance technical field and the other fields such as motorcycle and Lacquer finish such as cosmetics containers, televisor and computer.
UV is exactly the English abbreviation of ultraviolet (Ultra-VioletRay). and industrial UV wavelength is its range of application with 200nm to 450nm.Irradiate " UV irradiates hardenable material " with UV and the processing procedure making it harden, we are referred to as " UVCuringProcess ".Environmental protection UV coating is coated with by dip-coating, showering, paint, spin coating, even after the coating of the method such as vacuum painting, then irradiates and film-forming through UV photons.As its name suggests, the solidification of environmental protection UV coating is inseparable with the irradiation of UV light.This technique functions comes from the international coatings market of the seventies, is a kind of brand-new green technology.Utilize the ultraviolet-curing paint that this technology is produced, be called for short UV coating.In 20 end of the centurys, UV is coating material solidified to come into vogue in the ground such as west, Japan, is a kind of coating variety representing fashion.Be applied to the external coating process of mobile phone, DVD, walkman shell the earliest, its Application Areas now further expanded to the household appliance technical field such as makeup, televisor and computer afterwards.
UV photo-cured coating has containing volatile organic compounds (VOC), and environmental pollution is little, and curing speed is fast, save the energy, cured product performance good, be suitable for the advantages such as high-speed automated production.And traditional coating is volatile, curing speed slow, be unfavorable for environment protection.Therefore, UV coating is the main substitute of traditional coating.
Compared with general solvent based coating, the feature of UV coating is as follows:
UV coating is solidification (UV quartz burner) under UV photons irradiates, and usually only needs about 1 second or shorter time, can carry out quick and continuous operation, greatly enhance productivity.
Conventional oligopolymer in UV coating, as resins such as epoxy acrylate, urethane acrylate, polyester acrylate, polyether acrylate, acroleic acid esterification polyacrylic resin and insatiable hunger polyester, and the simple function group of various acrylate or polyfunctional monomer, all can under the effect of UV photons, cause polymerized at room temperature by free radical and be cross-linked, thus be particularly conducive to the covering with paint to heat sensitive base material (as timber, paper and plastics).
UV coating does not need heat drying, thus can save energy 75%-90% when constructing than the heated drying coating of routine.
The various coating equipments of UV coating are compact, do not need drying tunnel, simple and efficient to handle, are easy to realize the production automation, thus greatly save occupation area of equipment, and reduce working space.
UV coating is a kind of solvent-free or substantially solvent-free coating, and in film process, VOC free evaporate in air, does not pollute environment, the environmental regulation of be content with very little government or legislative bodies.
UV coating realizes the crosslinking polymerization between component under the effect of UV photons, by liquid fast setting film forming, and there is tridimensional network, coating surface performance thus can be made to improve, as hardness, snappiness, wear-resisting scratch-resisting, chemical proofing, high glossiness, wearing quality etc.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of environmental protection UV coating.
A kind of environmental protection UV coating; comprise the component of following weight parts: tripropylene glycol diacrylate 40-60 part; 2-methyl-2-2-hydroxyethyl acrylate phosphoric acid ester 6-10 part; urethane acrylate 35-45 part; aliphatic urethane acrylate 2-4 part, 2,4; 6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 4-8 part, organosilicon flow agent 0.2-0.4 part.
A kind of environmental protection UV coating; comprise the component of following weight parts: tripropylene glycol diacrylate 40-60 part; 2-methyl-2-2-hydroxyethyl acrylate phosphoric acid ester 6-10 part; urethane acrylate 35-45 part, aliphatic urethane acrylate 2-4 part, 2; 4; 6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 4-8 part, organosilicon flow agent 0.2-0.4 part, sterilant 0.2-0.4 part.
Described sterilant is N-(4,6-dimethyl pyrimidine-2-base) aniline and/or enostroburin.Preferably, described sterilant is mixed by N-(4, the 6-dimethyl pyrimidine-2-base) aniline of 10-30wt% and the enostroburin of 70-90wt%.N-(4,6-dimethyl pyrimidine-2-base) aniline or enostroburin are used for, in coating, serving good effect by the present invention pioneeringly.
Tripropylene glycol diacrylate, also known as tri (propylene glycol) diacrylate, CAS No.:42978-66-5.2-methyl-2-2-hydroxyethyl acrylate phosphoric acid ester, CAS accession number: 52628-03-2.2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester, No. CAS: 84434-11-7.
N-(4,6-dimethyl pyrimidine-2-base) aniline, CAS:53112-28-0.Enostroburin, CAS:238410-11-2.
Environmental protection UV coating of the present invention adopts industry universal method to be prepared from.
Environmental protection UV coating of the present invention, has good wear-resisting scratch-resisting, chemical proofing, and has good sticking power.
Embodiment
Embodiment 1-4
Take each component according to embodiment 1-4 data corresponding in table 1, adopt the preparation of industry universal method, obtain environmental protection UV coating of the present invention.
The environmental protection UV formulation for coating material list position of table 1: embodiment 1-4: kilogram
Test case 1
Carry out performance test to the environmental protection UV coating of embodiment 1-4, testing standard and test result are in table 2.
The environmental protection UV coating property test chart of table 2: embodiment 1-4
The performance of the environmental protection UV coating of embodiment 1-4 is tested, found that the environmental protection UV coating fundamental property that embodiment 1-4 obtains is good, meet relevant regulations index.
Test case 2
Antibacterial test standard: HG/T 3950-2007 " antibiotic paint ".Detect with bacterium: colon bacillus.
Coating antibacterium performance test: test result is in table 3.
Table 3: coating antibacterium performance test chart
| ? | Antibacterium rate (colon bacillus), % |
| Embodiment 1 | 99.2 |
| Embodiment 2 | 87.2 |
| Embodiment 3 | 88.6 |
| Embodiment 4 | 12.4 |
Coating antibacterium endurance quality is tested:
Adopt 1 30W, wavelength 253.7nm ultraviolet lamp, antibiotic paint test plate (panel) distance ultraviolet lamp 0.9m, irradiates 100 hours, then testing anti-bacterial performance.Test result is in table 24.
Table 4: coating antibacterium endurance quality test chart
| ? | Antibacterium rate (colon bacillus), % |
| Embodiment 1 | 95.3 |
| Embodiment 2 | 81.6 |
| Embodiment 3 | 82.5 |
| Embodiment 4 | 10.6 |
Claims (5)
1. an environmental protection UV coating, is characterized in that, comprises following component: tripropylene glycol diacrylate, urethane acrylate, aliphatic urethane acrylate and flow agent.
2. an environmental protection UV coating; it is characterized in that; comprise the component of following weight parts: tripropylene glycol diacrylate 40-60 part; 2-methyl-2-2-hydroxyethyl acrylate phosphoric acid ester 6-10 part, urethane acrylate 35-45 part, aliphatic urethane acrylate 2-4 part; 2; 4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 4-8 part, organosilicon flow agent 0.2-0.4 part.
3. an environmental protection UV coating; it is characterized in that; comprise the component of following weight parts: tripropylene glycol diacrylate 40-60 part, 2-methyl-2-2-hydroxyethyl acrylate phosphoric acid ester 6-10 part, urethane acrylate 35-45 part; aliphatic urethane acrylate 2-4 part; 2,4,6-trimethylbenzoyl phenyl phosphinic acid ethyl ester 4-8 part; organosilicon flow agent 0.2-0.4 part, sterilant 0.2-0.4 part.
4. environmental protection UV coating as claimed in claim 3, it is characterized in that, described sterilant is N-(4,6-dimethyl pyrimidine-2-base) aniline and/or enostroburin.
5. environmental protection UV coating as claimed in claim 4, it is characterized in that, described sterilant is mixed by N-(4, the 6-dimethyl pyrimidine-2-base) aniline of 10-30wt% and the enostroburin of 70-90wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410451703.6A CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410451703.6A CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104231704A true CN104231704A (en) | 2014-12-24 |
| CN104231704B CN104231704B (en) | 2016-09-07 |
Family
ID=52220651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410451703.6A Active CN104231704B (en) | 2014-09-05 | 2014-09-05 | Environmental protection UV coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104231704B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312418A (en) * | 2017-07-16 | 2017-11-03 | 长沙善道新材料科技有限公司 | A kind of antimicrobial UV coating and its manufacture craft |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100725249B1 (en) * | 2005-12-20 | 2007-06-04 | (주)디피아이 홀딩스 | Ultraviolet curable paint for steels coating |
| CN101275054A (en) * | 2007-03-29 | 2008-10-01 | 比亚迪股份有限公司 | Ultraviolet cured paint composition and preparation thereof |
| CN101294011A (en) * | 2007-04-28 | 2008-10-29 | 佛山市顺德区汉达精密电子科技有限公司 | UV paint |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103525270A (en) * | 2013-09-24 | 2014-01-22 | 浙江佑谦特种材料有限公司 | UV (ultraviolet) coating for heat transfer printing on metal material |
-
2014
- 2014-09-05 CN CN201410451703.6A patent/CN104231704B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100725249B1 (en) * | 2005-12-20 | 2007-06-04 | (주)디피아이 홀딩스 | Ultraviolet curable paint for steels coating |
| CN101275054A (en) * | 2007-03-29 | 2008-10-01 | 比亚迪股份有限公司 | Ultraviolet cured paint composition and preparation thereof |
| CN101294011A (en) * | 2007-04-28 | 2008-10-29 | 佛山市顺德区汉达精密电子科技有限公司 | UV paint |
| CN102199375A (en) * | 2010-03-26 | 2011-09-28 | 东莞市佩琦涂料有限公司 | Ultraviolet (UV) paint solidified by ultraviolet light |
| CN103525270A (en) * | 2013-09-24 | 2014-01-22 | 浙江佑谦特种材料有限公司 | UV (ultraviolet) coating for heat transfer printing on metal material |
Non-Patent Citations (3)
| Title |
|---|
| 大森英三: "《功能性丙烯酸树脂》", 31 December 1993, article "11.37丙烯酸羟乙基酯的磷酸酯", pages: 211 * |
| 王基铭 等: "《石油化工技术进展》", 30 April 2002, article "4.9.1涂料助剂种类", pages: 583 * |
| 胡飞燕 等: "《涂料基础配方与工艺》", 30 June 2013, article "2.防污剂、防腐剂和防霉剂", pages: 39 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312418A (en) * | 2017-07-16 | 2017-11-03 | 长沙善道新材料科技有限公司 | A kind of antimicrobial UV coating and its manufacture craft |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104231704B (en) | 2016-09-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100588691C (en) | Coating for UV cured plastic and use | |
| CN102827501A (en) | Double-curing varnish paint | |
| CN104087063A (en) | UV (ultraviolet) photo-curable dip-coating and coloring printing ink and preparation method thereof | |
| CN103865376A (en) | UV spraying frosted paint | |
| CN112300684A (en) | Aerosol paint and preparation method thereof | |
| CN110621746B (en) | Ultraviolet-curable coating composition | |
| CN104152007A (en) | Solvent-free UV vacuum spraying priming paint and preparation method thereof | |
| CN106995655A (en) | No-solvent type UV cure coating compositions and coating | |
| CN102898878A (en) | Low-cost high-adhesive-force electron beam radiation curing paint and preparation method thereof | |
| CN104529762B (en) | A kind of quick-dry type double cured resin and preparation method and application | |
| CN102746786B (en) | Ultraviolet-light-cured elastic top varnish and production method thereof | |
| CN114276739B (en) | Vacuum spraying UV (ultraviolet) color-correction finishing paint and preparation method thereof | |
| CN104231704A (en) | Green and environment-friendly UV (ultraviolet) coating | |
| CN110819214A (en) | Preparation method of ultralow-temperature fast-curing powder coating resin for medium-density board | |
| CN107365553B (en) | Thermal transfer printing PET film ultraviolet curing varnish and preparation method thereof | |
| CN110240858B (en) | High-energy and low-energy interactive curing water-based UV (ultraviolet) wood varnish, and preparation method and construction process thereof | |
| CN104231870B (en) | A kind of ultraviolet-curing paint for electromobile shell and preparation method and spraying method | |
| CN110540798B (en) | Spray paint for injection molding and spraying process thereof | |
| CN110845926A (en) | High-hardness high-fullness water-based two-component wood paint | |
| CN112300685A (en) | Aerosol UV coating and preparation method thereof | |
| KR20030078237A (en) | UV curable oriental lacquer coating composition and method for preparing oriental lacquer coating using the same | |
| CN111303693B (en) | Preparation method and application of UV (ultraviolet) ink | |
| CN110903741A (en) | Ultraviolet curing coating | |
| CN108003681A (en) | A kind of household electrical appliances UV Lacquer finish coating and preparation method thereof | |
| CN110511658B (en) | Dual-curing type water-based primer coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sheng Qinghua Inventor before: Huang Meirong |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180411 Address after: 322000, Zhejiang, Jinhua province Yiwu City Yi Town Road 71 Patentee after: YIWU DINGSHENG PRINTING Co.,Ltd. Address before: Room 4, building 411-45-4, science and technology building, No. 599, Jiangnan Road, hi tech Zone, Ningbo, Zhejiang, China Patentee before: NINGBO HIGH-TECH ZONE BAYI NEW MATERIAL TECHNOLOGY CO.,LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20230912 Address after: No. 3 Longyin Road, Longyou Economic Development Zone, Donghua Street, Longyou County, Quzhou City, Zhejiang Province, 324499 Patentee after: Quzhou Dingsheng New Materials Co.,Ltd. Address before: 322000 No. 71 Xiangyi Road, Yiting Town, Yiwu City, Jinhua City, Zhejiang Province Patentee before: YIWU DINGSHENG PRINTING Co.,Ltd. |
|
| TR01 | Transfer of patent right |