CN104231527A - Antistatic flame-retardant ABS plastic - Google Patents
Antistatic flame-retardant ABS plastic Download PDFInfo
- Publication number
- CN104231527A CN104231527A CN201410430624.7A CN201410430624A CN104231527A CN 104231527 A CN104231527 A CN 104231527A CN 201410430624 A CN201410430624 A CN 201410430624A CN 104231527 A CN104231527 A CN 104231527A
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- CN
- China
- Prior art keywords
- percent
- fire retardant
- abs plastic
- electrostatic fire
- retardant abs
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 48
- 239000003063 flame retardant Substances 0.000 title claims abstract description 47
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 12
- 238000001746 injection moulding Methods 0.000 claims abstract description 16
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 9
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 8
- 238000005469 granulation Methods 0.000 claims abstract description 8
- 230000003179 granulation Effects 0.000 claims abstract description 8
- 239000010452 phosphate Substances 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 239000003112 inhibitor Substances 0.000 claims description 9
- 230000003068 static effect Effects 0.000 claims description 9
- 239000003292 glue Substances 0.000 claims description 8
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- -1 phosphate ester Chemical class 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 5
- ZVGLLLKDNYVIAE-UHFFFAOYSA-N 1-bromopiperazine Chemical compound BrN1CCNCC1 ZVGLLLKDNYVIAE-UHFFFAOYSA-N 0.000 claims description 3
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000002216 antistatic agent Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 239000003607 modifier Substances 0.000 abstract 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The antistatic flame-retardant ABS plastic comprises the following components: 66.4 percent of ABS resin, 10 percent of antistatic agent, 3 percent of compatilizer, 7 percent of high rubber powder, 10 percent of flame retardant, 3 percent of antimony trioxide, 0.2 percent of flow modifier, 0.3 percent of phosphate flame retardant CFP-2202 percent, 0.1 percent of antioxidant and 70.1 percent of anti-dripping agent. The preparation process comprises the following steps: adding the ABS resin and various additives into a high-speed mixer according to the proportion for premixing, then putting into a double-screw extruder for granulation, and adding into an injection molding machine for injection molding. The invention has the beneficial effects that: the UL94 flame retardant grade of the material reaches V-0 grade, the oxygen index is 26 percent, and the material has good flame retardant effect. Permanent antistatic agent is added to make surface resistivity reach 1010Europeanism procumbens, is not influenced by ambient humidity, and has permanent antistatic performance.
Description
Technical field
The present invention relates to polymeric material field, particularly relate to a kind of ABS plastic of anti-electrostatic fire retardant.
Background technology
Acrylonitrile-butadiene-styrene copolymer (ABS) has good physicals and use properties, can be widely used in each field, but ABS resin itself exists some shortcomings, as high-insulativity, inflammableness, significantly limit its application.In order to overcome the shortcoming of ABS resin itself, expanding it should have scope, and people add different additives to ABS resin, as fire retardant, static inhibitor etc., makes it have more excellent performance.The ABS plastic that the fire retardant that the present invention adds, static inhibitor obtain has permanent antistatic performance and flame retardant effect.
Summary of the invention
The object of this invention is to provide a kind of anti-electrostatic fire retardant ABS plastic.
The present invention is achieved through the following technical solutions:
A kind of anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, fire retardant 10%, antimonous oxide S-05N3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.
Further, described fire retardant is any one in TDE, brominated epoxy, tetrabromo-bisphenol, bromo piperazine, wherein preferred TDE.
A kind of preparation technology of anti-electrostatic fire retardant ABS plastic: according to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch, at 80 degree of dry 2-3 hour, adds injection moulding machine injection moulding and obtains anti-electrostatic fire retardant ABS plastic.
Further, described twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim.
Beneficial effect of the present invention is: a kind of anti-electrostatic fire retardant ABS plastic, select the good ABS resin of rigidity as base material, good toughness is obtained by adding high glue powder, but the interpolation of high glue powder reduces the fluidity of molten of material, improving the mobility of material by adding phosphate flame retardant, improving processing characteristics.With TDE for optimum flame-retardant system, make the UL94 flame retardant rating of material reach V-0 level, oxygen index is 26%, has good flame retardant effect.The permanent anti-static agent MH3070 added, makes surface resistivity reach 10
10europe is female, and not by the impact of ambient moisture, has permanent antistatic performance.Well solving the compatibility problem of static inhibitor and ABS by adding compatilizer, making anti-electrostatic fire retardant ABS plastic have excellent physical and mechanical properties.
Embodiment
Of the present inventionly to comprise the following steps:
A kind of preparation technology of anti-electrostatic fire retardant ABS plastic: according to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch, at 80 degree of dry 2-3 hour, adds injection moulding machine injection moulding and obtains anti-electrostatic fire retardant ABS plastic.Described twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim.
Embodiment one:
A kind of anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, TDE 10%, antimonous oxide S-05N 3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.According to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch is at 80 degree of dry 2-3 hour, add injection moulding machine injection moulding and obtain anti-electrostatic fire retardant ABS plastic, twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim, obtain sample 1.
Embodiment two:
A kind of anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, brominated epoxy 10%, antimonous oxide S-05N3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.According to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch is at 80 degree of dry 2-3 hour, add injection moulding machine injection moulding and obtain anti-electrostatic fire retardant ABS plastic, twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim, obtain sample 2.
Embodiment three:
A kind of anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, tetrabromo-bisphenol 10%, antimonous oxide S-05N3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.According to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch is at 80 degree of dry 2-3 hour, add injection moulding machine injection moulding and obtain anti-electrostatic fire retardant ABS plastic, twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim, obtain sample 3.
Embodiment four:
A kind of anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, bromo piperazine 10%, antimonous oxide S-05N3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.According to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch is at 80 degree of dry 2-3 hour, add injection moulding machine injection moulding and obtain anti-electrostatic fire retardant ABS plastic, twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim, obtain sample 4.
Table 1 different flame retardant is on the impact of product performance
Above one embodiment of the present of invention have been described in detail, but described content being only preferred embodiment of the present invention, can not being considered to for limiting practical range of the present invention.All equalizations done according to the present patent application scope change and improve, and all should still belong within patent covering scope of the present invention.
Claims (4)
1. an anti-electrostatic fire retardant ABS plastic comprises following component by percentage to the quality: ABS resin 66.4%, static inhibitor MH307010%, compatilizer SMA7003%, high glue powder ABS60P 7%, fire retardant 10%, antimonous oxide S-05N 3%, flow ability modifying agent BS-38180.2%, phosphate ester flame retardants CFP-2202%, antioxidant 0.3%, anti-dripping agent SN80-SA70.1%.
2. a kind of anti-electrostatic fire retardant ABS plastic according to claim 1, is characterized in that described fire retardant is any one in TDE, brominated epoxy, tetrabromo-bisphenol, bromo piperazine, wherein preferred TDE.
3. the preparation technology of an anti-electrostatic fire retardant ABS plastic: according to the above ratio ABS resin and various auxiliary agent are added high-speed mixer and carry out premix, then premix material is dropped into twin screw extruder granulation, master batch, at 80 degree of dry 2-3 hour, adds injection moulding machine injection moulding and obtains anti-electrostatic fire retardant ABS plastic.
4. the preparation technology of a kind of anti-electrostatic fire retardant ABS plastic according to claim 3, is characterized in that: described twin screw extruder temperature is 160-210 degree, engine speed 1000r/mim, feeding rotating speed 350r/mim.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430624.7A CN104231527A (en) | 2014-08-28 | 2014-08-28 | Antistatic flame-retardant ABS plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410430624.7A CN104231527A (en) | 2014-08-28 | 2014-08-28 | Antistatic flame-retardant ABS plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104231527A true CN104231527A (en) | 2014-12-24 |
Family
ID=52220489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410430624.7A Pending CN104231527A (en) | 2014-08-28 | 2014-08-28 | Antistatic flame-retardant ABS plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104231527A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440894A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of ABS and SMA plastic alloys product |
| GB2574730A (en) * | 2018-06-15 | 2019-12-18 | Hexcel Composites Ltd | Epoxy resin formulations |
| CN114227979A (en) * | 2021-11-26 | 2022-03-25 | 北方华锦化学工业股份有限公司 | Method for modifying antistatic property of ABS (acrylonitrile butadiene styrene) resin by biomass carbon material |
-
2014
- 2014-08-28 CN CN201410430624.7A patent/CN104231527A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108440894A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of ABS and SMA plastic alloys product |
| GB2574730A (en) * | 2018-06-15 | 2019-12-18 | Hexcel Composites Ltd | Epoxy resin formulations |
| GB2574730B (en) * | 2018-06-15 | 2022-10-19 | Hexcel Composites Ltd | Epoxy resin formulations |
| CN114227979A (en) * | 2021-11-26 | 2022-03-25 | 北方华锦化学工业股份有限公司 | Method for modifying antistatic property of ABS (acrylonitrile butadiene styrene) resin by biomass carbon material |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20141224 |
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| WD01 | Invention patent application deemed withdrawn after publication |