CN104230603A - Environment-friendly organic and inorganic fertilizer prepared with molasses alcohol waste mash used as raw material - Google Patents

Environment-friendly organic and inorganic fertilizer prepared with molasses alcohol waste mash used as raw material Download PDF

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Publication number
CN104230603A
CN104230603A CN201410480402.6A CN201410480402A CN104230603A CN 104230603 A CN104230603 A CN 104230603A CN 201410480402 A CN201410480402 A CN 201410480402A CN 104230603 A CN104230603 A CN 104230603A
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molasses alcohol
alcohol waste
waste mash
organic
fertilizer
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陈作军
王修海
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Guangxi Di Yuan Zhi Benfei Industry Co Ltd
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Guangxi Di Yuan Zhi Benfei Industry Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The invention discloses environment-friendly organic and inorganic fertilizer prepared with molasses alcohol waste mash used as a raw material. High-temperature condensed bacilli are inoculated in just-discharged high-temperature molasses alcohol waste mash for fermentation, a metal complexing agent is added, then the molasses alcohol waste mash is kept to be evaporated at the high temperature for a period; the molasses alcohol waste mash is led into an anaerobic fermentation pool for anaerobic fermentation after being naturally cooled; then aerobic bacteria are added into the molasses alcohol waste mash, the mixture is mixed with organic filler and inorganic fertilizer in a certain proportion for fermentation for 12-36 hours, the fermented molasses alcohol waste mash is subjected to degumming treatment and slurry-spraying granulation, then beneficial bacteria are added, and a finished product is obtained. According to the environment-friendly organic and inorganic fertilizer, other bacteria are removed through the high temperature, the metal complexing agent is added to remove heavy metals, bacterium fermentation effects at all phases are improved, the finished product has no obvious stink, the added organic filler is rich in inorganic nutrients and microelements such as N, P, K and the like, the production cost is saved, and the product quality is improved.

Description

A kind of environmentally-friendly organic inorganic being prepared by raw material with molasses alcohol waste mash is fertile
Technical field
The present invention relates to composite fertilizer's technical field, particularly a kind of take molasses alcohol waste mash as the composite fertilizer that raw material is made.
Background technology
The technological innovation of Guangxi Region in recent years sugar enterprise and development, Guangxi sugaring industry progressively defines with the industrial chain of " sugar material sugarcane → machine sugar → molasses → alcohol → molasses alcohol waste mash → production fertilizer ".In this industrial chain, the alcohol fermentation liquid produced due to sugaring industry causes the problem of environmental pollution also to become clear day by day, the alcohol fermentation liquid that Guangxi sugar enterprise produces is in 2012 up to more than 3,500,000 tons, and the funds needing to take out more than 500,000,000 yuan are every year for the innoxious governance of alcohol fermentation liquid.Because the protein content of alcohol fermentation liquid is high, there is very high chemical oxygen demand and biological oxygen demand (BOD), hydrobiont mortality can be caused if entered in a large number in water, and produce strong foul smell, cause water resources and atmospheric pollution.Alcohol slops is to the harm of environment, and mainly its ionic concn is large and containing large amount of organic.According to analysis, containing organism 6% ~ 8% in waste liquid; Simultaneously containing a large amount of n-p-k elements.Be discharged in water and pollute the environment, cause eutrophication, and due to chemical oxygen demand (COD) and biological oxygen demand (BOD) (BOD) too high and hydrobiont may be made to be choked to death.And these are all the nutritive substances needed for farm crop, when being condensed into it containing organism more than 35%, simultaneously containing higher N-P-K content, be exactly a kind of manure resources of preciousness.Therefore, how carrying out harmless treatment to alcohol fermentation liquid and effectively utilizing is break the most key ring of Guangxi sugaring industry development bottleneck, release Guangxi sugaring industry potential, utilizing the byproduct molasses alcohol waste mash of sugaring to produce alcohol, Methionin, yeast etc. is the important channel that sugarcane fully utilizes, but because the technical scheme of comprehensive utilization fails to solve well always, most molasses alcohol waste mash is for a long time caused to be taken as discharging of waste liquid, not only fail to utilize this resource very well, cause serious environmental pollution on the contrary.
Since 20 century 70s, just there is patent literature about molasses alcohol waste mash as fertilizer, before 2008, technical scheme still rest on adopt molasses alcohol waste mash or molasses alcohol waste mash concentrated solution directly as Term Fertilization in field, because it not easily transporting, using rear needs using ground overlay film, therefore never introduced to the market on a large scale.After 2008, molasses alcohol waste mash carries out studying as solid composite fertilizer and starts to enter a new field, as Li Yangrui, Guangxi Academy of Agricultural Sciences, Fei Ye limited liability company of Germany and Britain of Nanning City have made more research and contribution.As the patent application that Chinese Patent Application No. is 201110308137.X and 201210499085.3, the thinking of technical scheme mainly by adding biological inoculum, biologic packing material carries out fermenting, remove colloid or be bonded together colloid, add the mineral manure of solubization with rice bran, obtains solid composite fertilizer after oven dry.But do not remove the processing step of heavy metal, likely cause that the effect of fermenting process is unstable, quality product cannot be effectively controlled, two is the technical schemes not removing the miscellaneous bacteria in molasses alcohol waste mash in time, and a large amount of peculiar smell may be had in production process to produce.
As patent application of the present invention closest to prior art, Chinese patent application 201310122086 is that the problem solving molasses alcohol waste mash stench proposes a solution.But following 3 aspect technical problems still fail to solve preferably: one is the situation of heavy metals exceeding standard, and heavy metals exceeding standard may affect the situation of the activity of biological inoculum, cause likely existing in follow-up each fermenting process that ferment effect is bad, quality product is not up to standard; Two is do not keep temperature to cause corrupt miscellaneous bacteria likely ineffective technical scheme removed after prior art proposes to drop into high temperature Bacillus coagulans at high operating temperatures, likely Yin Wendu declines and causes the fermentation of high temperature Bacillus coagulans and molasses alcohol waste mash insufficient, the situation such as cause deodorizing effect not good; Three is the pH value not regulating molasses alcohol waste mash before anaerobically fermenting in time, may cause the situation of anaerobically fermenting poor effect.
Summary of the invention
For existing take molasses alcohol waste mash as the above-mentioned defect existed during the biological organic fertilizer of raw material is produced, the technical problem to be solved in the present invention is: 1. solving molasses alcohol waste mash is the various influence factors of stink that raw material production biological organic fertilizer finished product produces, and required link is few, the finished product and production process environmental protection; 2. adopt multi-stage type fermentation, improve ferment effect, reduce production cost; 3. improve KNP and the content of humic acid of molasses alcohol waste mash, improve product quality.
The solution of the present invention is by realizing like this: a kind of environmentally-friendly organic inorganic being prepared by raw material with molasses alcohol waste mash is fertile, it is characterized in that, is prepared from by following steps:
1) high temperature Bacillus coagulans is inoculated in the molasses alcohol waste mash fermentation of just discharging;
2) pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging is measured, add metal chelating agent, then molasses alcohol waste mash is maintained the temperature 30-360 minute of 90 DEG C-100 DEG C, being concentrated into containing organism 35-95%, surplus is the molasses alcohol waste mash of water;
3) drop into pH value regulator, the pH value of molasses alcohol waste mash is adjusted between 7-8, then is introduced into anaerobically fermenting pond, and add anaerobic bacterial fermentation 12-48 hour;
4) molasses alcohol waste mash is added aerobic bacteria more by a certain percentage with organic stopping composition, mineral manure mixing secondary fermentation 12-36 hour;
5) obtained finished product after adding beneficial organism flora after the molasses alcohol waste mash fermented being carried out degumming process, spray granulating.
Further: the molasses alcohol waste mash leavening temperature of described firm discharge is >=90 DEG C.
Further: described molasses alcohol waste mash: organic stopping composition: the ratio of mineral manure is 1-2.5:1:1.
Further: described probiotics is one or more in root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus, and described beneficial organism flora reaches 0.1-10 hundred million/gram.
Further: described mineral manure is at least one in water-soluble nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, described water-soluble nitrogenous fertilizer is at least one in ammonium sulfate, ammonium chloride or urea; Described water soluble phosphorous fertilizer is primary ammonium phosphate or potassium primary phosphate; Described water soluble potassic fertilizer is Repone K, potassium sulfate or saltpetre.
Further: described metal chelating agent is TMT organosulfur, EDTA, citric acid, Padil, one or more in ammoniacal liquor.
Further: step 4) described in organic stopping composition be waste material after fish processing, the waste material after the processing of described fish: feces of livestock and poultry: the ratio of wooden chaff is 1:1:1.
Further: described pH value regulator is liquefied ammonia, borate.
Further: the metal ion in the waste water after described process is 1:1.5 ~ 5 with the mass content ratio of metal chelating agent.
Further: the bacterial content of described high temperature Bacillus coagulans bacterium liquid is >1 × 10 7/ ml is 1:100 with the portion rate being inoculated in molasses alcohol waste mash.
The invention has the beneficial effects as follows:
1. simple compared with prior art processes, required fermentation time is short.
2. add metal chelating agent, complexation heavy metal ion, because heavy metal has very strong killing action to some probiotics, dispelling heavy metal affects larger for later stage multi-stage type ferment effect.
3. high temperature molasses alcohol waste mash maintains more than 90 DEG C 30-360 minute, kills corrupt miscellaneous bacteria, and adds high temperature Bacillus coagulans and ferment, and the liquid obtained after fermenting tank for fermentation is without obvious stink.
4. serviceability is high, sporeformer, EM bacterium, yield increasing fungus, enzymatic microorganism, zymophyte and antibiotic bacteria is arranged in pairs or groups, and effectively improves the syneryistic effect of biological inoculum.
5. the biologic packing material added is the fish offal after fish processing, it is rich in amino acid, humic acid and other trace elements, through with the aerobic fermentation of molasses alcohol waste mash after, the effect of synergy can be played with his material, also a saving the injected volume of part inorganic fertilizer, reduce production cost.
6., before anaerobically fermenting link, drop into pH value regulator, the pH value of molasses alcohol waste mash is adjusted between 7-8, the effect of anaerobically fermenting can be strengthened.
Molasses alcohol waste mash odorless after multi-stage type fermentation, reaches the effect of environmental protection, becomes the organic bacteria liquid fertilizer that vast farmers is welcome.Through the use identification in Duo Jia sugar refinery, at least can replace fertilizer application amount over half, and improve soil, increase the active fertility of rhizosphere, reduce disease and pest.
Embodiment
Detailed reference example, in description detailed below, proposes some specific detail, to allow those skilled in the art have more thorough understanding to the present invention.But those skilled in the art it will be clear that realization of the present invention not only can be limited to these specific details.In the other cases, known technical scheme is not described in detail, to avoid the correlative detail ambiguous of following examples.
Embodiment 1
After the molasses alcohol waste mash of temperature (>=90 DEG C) is discharged, molasses alcohol waste mash is introduced heating bath and maintain the temperature at 90 DEG C, measure pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging, then by 1 part of high temperature Bacillus coagulans bacterium liquid (bacterial content >1 × 10 7/ ml) devote 100 parts of molasses alcohol waste mash fermentations of just having discharged, add the solution of metal chelating agent EDTA=0.05mol/L concentration, the metal ion in molasses alcohol waste mash is made to be 2:1 with the mass content ratio of metal chelating agent EDTA, molasses alcohol waste mash is maintained the temperature 360 minutes of 90 DEG C, being concentrated into containing organism 75%, surplus is the molasses alcohol waste mash of water.Drop into liquefied ammonia as pH value regulator, the pH value of molasses alcohol waste mash is adjusted to 7, then is introduced into anaerobically fermenting pond, and add anaerobic bacterial fermentation 12 hours; In molasses alcohol waste mash, add aerobic bacteria, molasses alcohol waste mash, fish processing waste material, ammonium sulfate are mixed secondary fermentation 12 hours in the ratio of 2.5:1:1; The mixed bacteria liquid of root nodule bacterium, root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus is added, obtained finished product after making every gram of composite organic-inorganic fertilizer contain 500,000,000/gram of beneficial organism floras after the molasses alcohol waste mash fermented is carried out degumming process, spray granulating.
Embodiment 2
After the molasses alcohol waste mash of temperature (>=90 DEG C) is discharged, molasses alcohol waste mash is introduced heating bath and maintain the temperature at about 95 DEG C, measure pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging, then by 1 part of high temperature Bacillus coagulans bacterium liquid (bacterial content >1 × 10 7/ ml) devote 100 parts of molasses alcohol waste mash fermentations of just having discharged, add the solution of metal chelating agent TMT organosulfur=0.05mol/L concentration, the metal ion in molasses alcohol waste mash is made to be 1.5:1 with the mass content ratio of metal chelating agent TMT organosulfur, molasses alcohol waste mash is maintained the temperature 240 minutes of 95 DEG C, being concentrated into containing organism 65%, surplus is the molasses alcohol waste mash of water.Drop into liquefied ammonia as pH value regulator, the pH value of molasses alcohol waste mash is adjusted to about 7.5, then the molasses alcohol waste mash that have adjusted pH value will introduce anaerobically fermenting pond, and add anaerobic bacterial fermentation 36 hours; In molasses alcohol waste mash, add aerobic bacteria, and molasses alcohol waste mash, fish processing waste material, ammonium sulfate are mixed secondary fermentation 36 hours in the ratio of 2.5:1:1; Obtained finished product after adding root nodule bacterium, root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus 0.1 hundred million/gram of beneficial organism floras after the molasses alcohol waste mash fermented is carried out degumming process, spray granulating.
Embodiment 3
After the molasses alcohol waste mash of temperature (>=90 DEG C) is discharged, molasses alcohol waste mash is introduced heating bath and maintain the temperature at 100 DEG C, measure pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging, then by 1 part of high temperature Bacillus coagulans bacterium liquid (bacterial content >1 × 10 7/ ml) devote 100 parts of molasses alcohol waste mash fermentations of just having discharged, add the solution of metal chelating agent Padil=0.05mol/L concentration, the metal ion in molasses alcohol waste mash is made to be 3:1 with the mass content ratio of metal chelating agent Padil, molasses alcohol waste mash is maintained the temperature 30 minutes of 100 DEG C, being concentrated into containing organism 95%, surplus is the molasses alcohol waste mash of water.Drop into liquefied ammonia as pH value regulator, the pH value of molasses alcohol waste mash is adjusted to about 8, then the molasses alcohol waste mash that have adjusted pH value will introduce anaerobically fermenting pond, and add anaerobic bacterial fermentation 12 hours; In molasses alcohol waste mash, add aerobic bacteria, and molasses alcohol waste mash, fish processing waste material, ammonium sulfate are mixed secondary fermentation 12 hours in the ratio of 2.5:1:1; Obtained finished product after adding root nodule bacterium, root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus 1,000,000,000/gram of beneficial organism floras after the molasses alcohol waste mash fermented is carried out degumming process, spray granulating.
Embodiment 4
After the molasses alcohol waste mash of temperature (>=90 DEG C) is discharged, molasses alcohol waste mash is introduced heating bath and maintain the temperature at about 93 DEG C, measure pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging, then by 1 part of high temperature Bacillus coagulans bacterium liquid (bacterial content >1 × 10 7/ ml) devote 100 parts of molasses alcohol waste mash fermentations of just having discharged, add the solution of metal chelating agent citric acid=0.05mol/L concentration, the metal ion in molasses alcohol waste mash is made to be 5:1 with the mass content ratio of metal chelating agent citric acid, molasses alcohol waste mash is maintained the temperature 300 minutes of 93 DEG C, being concentrated into containing organism 80%, surplus is the molasses alcohol waste mash of water.Drop into borate as pH value regulator, the pH value of molasses alcohol waste mash is adjusted to about 7, then the molasses alcohol waste mash that have adjusted pH value will introduce anaerobically fermenting pond, and add anaerobic bacterial fermentation 36 hours; In molasses alcohol waste mash, add aerobic bacteria, and molasses alcohol waste mash, fish processing waste material, ammonium sulfate are mixed secondary fermentation 36 hours in the ratio of 2.5:1:1; Obtained finished product after adding root nodule bacterium, root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus 100,000,000/gram of beneficial organism floras after the molasses alcohol waste mash fermented is carried out degumming process, spray granulating.
Embodiment 5
After the molasses alcohol waste mash of temperature (>=90 DEG C) is discharged, molasses alcohol waste mash is introduced heating bath and maintain the temperature at 90 DEG C, measure pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging, then by 1 part of high temperature Bacillus coagulans bacterium liquid (bacterial content >1 × 10 7/ ml) devote 100 parts of molasses alcohol waste mash fermentations of just having discharged, add the solution of metal chelating agent ammoniacal liquor=0.05mol/L concentration, the metal ion in molasses alcohol waste mash is made to be 4:1 with the mass content ratio of metal chelating agent ammoniacal liquor, molasses alcohol waste mash is maintained the temperature 60 minutes of 98 DEG C, being concentrated into containing organism 45%, surplus is the molasses alcohol waste mash of water.Drop into borate as pH value regulator, the pH value of molasses alcohol waste mash is adjusted to about 8, then the molasses alcohol waste mash that have adjusted pH value will introduce anaerobically fermenting pond, and add anaerobic bacterial fermentation 29 hours; In molasses alcohol waste mash, add aerobic bacteria, and molasses alcohol waste mash, fish processing waste material, ammonium sulfate are mixed secondary fermentation 31 hours in the ratio of 2.5:1:1; Obtained finished product after adding root nodule bacterium, root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus 700,000,000/gram of beneficial organism floras after the molasses alcohol waste mash fermented is carried out degumming process, spray granulating.
The finished product make the embodiment of the present invention 1 and the Chemical Mixed Fertilizer A of domestic generic brand, brand import composite fertilizer of Norway B contrast, and carry out on the crimson soil of the sand shale of Nanning City's Wuming County, and experimental cultivar is new No. 22, the platform sugar in sugarcane.For the physicochemical character that examination is unexpected: pH6.5, organic 21.5g/kg, available N 145mg/kg, available P 25mg/kg, active potassic 138mg/kg.Contrast three kinds of fertilizer on the heavy impact of the average single stem of sugarcane, the indexs such as result, the impact on sugarcane productive tiller, the impact on sugarcane yield investigated on sugarcane economical character judge, at N+P 2o 5+ K 2under the condition that O total nutrient is all equal, the embodiment of the present invention 1 is containing higher N element, and the formation for sugarcane productive tiller is favourable; Domestic common Chemical Mixed Fertilizer A (10-10-10) and brand import composite fertilizer of Norway B (15-15-15) are better than to the nutrient supply of sugarcane production.The finished product using the embodiment of the present invention 1 increases production 266.7 kgs/acre, raw material sugarcane than domestic generic brand Chemical Mixed Fertilizer A, volume increase 4,76%, volume increase significant difference; 70 kgs/acre, raw material sugarcane is increased production than brand import composite fertilizer of Norway B, volume increase difference is not remarkable, but in selling price, this product price is only less than 40% of brand import composite fertilizer of Norway B, there is obvious market competition advantage, and 2013,2014 spring ploughing during market sale in achieve successfully.
Last it is noted that obviously, above-described embodiment is only used to example of the present invention is clearly described, and not to the restriction implemented.For the those of ordinary skill in described field, can also make other changes in different forms on the basis of the above description.Here without the need to also cannot to all embodiments with exhaustive.And thus the apparent change of amplifying out or variation be still among protection scope of the present invention.

Claims (10)

1. one kind is that environmentally-friendly organic inorganic prepared by raw material is fertile with molasses alcohol waste mash, it is characterized in that, is prepared from by following steps:
1) high temperature Bacillus coagulans is inoculated in the molasses alcohol waste mash fermentation of just discharging;
2) pH value and the concentration of metal ions of the molasses alcohol waste mash of just discharging is measured, add metal chelating agent, then molasses alcohol waste mash is maintained the temperature 30-360 minute of 90 DEG C-100 DEG C, being concentrated into containing organism 35-95%, surplus is the molasses alcohol waste mash of water;
3) drop into pH value regulator, the pH value of molasses alcohol waste mash is adjusted between 7-8, then is introduced into anaerobically fermenting pond, and add anaerobic bacterial fermentation 12-48 hour;
4) molasses alcohol waste mash is added aerobic bacteria more by a certain percentage with organic stopping composition, mineral manure mixing secondary fermentation 12-36 hour;
5) obtained finished product after adding beneficial organism flora after the molasses alcohol waste mash fermented being carried out degumming process, spray granulating.
2. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: the molasses alcohol waste mash leavening temperature of described firm discharge is >=90 DEG C.
3. organic and inorganic fertilizer as claimed in claim 1, it is characterized in that: described molasses alcohol waste mash adds in aerobic bacteria and organic stopping composition, mineral manure mixed fermentation step, molasses alcohol waste mash: organic stopping composition: the ratio of mineral manure is 1-2.5:1:1.
4. the organic and inorganic fertilizer as described in claim 1 or 3, is characterized in that: described organic stopping composition is waste material, feces of livestock and poultry and the wooden chaff composition after fish processing, the waste material after fish processing: feces of livestock and poultry: the ratio of wooden chaff is 1:1:1.
5. the organic and inorganic fertilizer as described in claim 1 or 2 or 3, is characterized in that: described mineral manure is at least one in water-soluble nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, and described water-soluble nitrogenous fertilizer is at least one in ammonium sulfate, ammonium chloride or urea; Described water soluble phosphorous fertilizer is primary ammonium phosphate or potassium primary phosphate; Described water soluble potassic fertilizer is Repone K, potassium sulfate or saltpetre.
6. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: described metal chelating agent is TMT organosulfur, EDTA, citric acid, Padil, one or more in ammoniacal liquor.
7. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: described probiotics is one or more in root nodule bacterium, vinelandii, phosphorus bacteria and B. mucilaginocus, and described beneficial organism flora reaches 0.1-10 hundred million/gram.
8. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: described pH value regulator is liquefied ammonia, borate.
9. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: the metal ion in the waste water after described process is 1:1.5 ~ 5 with the mass content ratio of metal chelating agent.
10. organic and inorganic fertilizer as claimed in claim 1, is characterized in that: the bacterial content of described high temperature Bacillus coagulans bacterium liquid is >1 × 10 7/ ml is 1:100 with the portion rate being inoculated in molasses alcohol waste mash.
CN201410480402.6A 2014-09-19 2014-09-19 Environment-friendly organic and inorganic fertilizer prepared with molasses alcohol waste mash used as raw material Pending CN104230603A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105777216A (en) * 2016-03-17 2016-07-20 哈尔滨市企效生物科技有限公司 Technique of utilizing probiotic combination to quickly treat manure to produce feed and fertilizer
CN107382504A (en) * 2017-08-16 2017-11-24 广东省生物工程研究所(广州甘蔗糖业研究所) A kind of method that Liquid Fertilizer is prepared using molasses-spirit raffinate

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1356295A (en) * 2001-12-11 2002-07-03 广州甘蔗糖业研究所 Process for preparing orgnaic fertilizer mixture from molasses alcohol dregs for sugarcane
KR20120092290A (en) * 2011-02-11 2012-08-21 주식회사 신화성물산 Nutrient agent for plant and manufacturing method the same
JP2013043800A (en) * 2011-08-24 2013-03-04 Kazumi Shibata Liquid fertilizer and method for producing the same
CN103193521A (en) * 2013-04-10 2013-07-10 昆明康禄生物科技有限公司 Method for preparing fertilizer effect type molasses alcohol waste mash bacterial liquid through triple fermentation
CN103333010A (en) * 2013-07-04 2013-10-02 肇东市庆东肥业有限责任公司 Root-tuber crop organic, inorganic, microorganism blended fertilizer and its making method
CN103739385A (en) * 2013-12-30 2014-04-23 叶长东 Humic acid type sustained-release potash fertilizer using alcohol waste liquid of sugar refinery
CN103880500A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880498A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880520A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880499A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN104016747A (en) * 2014-05-07 2014-09-03 广西地源之本肥业有限公司 Novel environment-friendly bio-organic fertilizer for black leather sugarcane
CN104193535A (en) * 2014-09-19 2014-12-10 广西地源之本肥业有限公司 Environment-friendly organic and inorganic fertilizer prepared by taking molasses alcohol waste mash as raw material

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1356295A (en) * 2001-12-11 2002-07-03 广州甘蔗糖业研究所 Process for preparing orgnaic fertilizer mixture from molasses alcohol dregs for sugarcane
KR20120092290A (en) * 2011-02-11 2012-08-21 주식회사 신화성물산 Nutrient agent for plant and manufacturing method the same
JP2013043800A (en) * 2011-08-24 2013-03-04 Kazumi Shibata Liquid fertilizer and method for producing the same
CN103193521A (en) * 2013-04-10 2013-07-10 昆明康禄生物科技有限公司 Method for preparing fertilizer effect type molasses alcohol waste mash bacterial liquid through triple fermentation
CN103333010A (en) * 2013-07-04 2013-10-02 肇东市庆东肥业有限责任公司 Root-tuber crop organic, inorganic, microorganism blended fertilizer and its making method
CN103880500A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880498A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880520A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103880499A (en) * 2013-12-23 2014-06-25 广西地源之本肥业有限公司 Organic/inorganic composite fertilizer prepared from molasses fermentation liquor
CN103739385A (en) * 2013-12-30 2014-04-23 叶长东 Humic acid type sustained-release potash fertilizer using alcohol waste liquid of sugar refinery
CN104016747A (en) * 2014-05-07 2014-09-03 广西地源之本肥业有限公司 Novel environment-friendly bio-organic fertilizer for black leather sugarcane
CN104193535A (en) * 2014-09-19 2014-12-10 广西地源之本肥业有限公司 Environment-friendly organic and inorganic fertilizer prepared by taking molasses alcohol waste mash as raw material

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
吴松平 等: "糖蜜废水生化法处理的现状和最新进展", 《环境污染治理技术与设备》, vol. 2, no. 2, 30 April 2001 (2001-04-30), pages 1 - 8 *
孙巍 等: "高浓度发酵废水的生物处理及资源化利用研究进展", 《环境科学与技术》, vol. 34, no. 8, 31 August 2011 (2011-08-31), pages 189 - 194 *
张庆芝 等: "甘薯酒精蒸馏废液制备腐植酸和有机复肥", 《河南化工》, no. 3, 30 September 1987 (1987-09-30), pages 9 - 12 *
曾涛: "工农业生产之间的良性循环——糖蜜酒精废液农用资源化", 《生态科学》, vol. 15, no. 2, 31 December 1996 (1996-12-31), pages 87 - 90 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105777216A (en) * 2016-03-17 2016-07-20 哈尔滨市企效生物科技有限公司 Technique of utilizing probiotic combination to quickly treat manure to produce feed and fertilizer
CN107382504A (en) * 2017-08-16 2017-11-24 广东省生物工程研究所(广州甘蔗糖业研究所) A kind of method that Liquid Fertilizer is prepared using molasses-spirit raffinate

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Application publication date: 20141224