CN104223589A - Emery wear-resisting spike and manufacturing method thereof - Google Patents
Emery wear-resisting spike and manufacturing method thereof Download PDFInfo
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- CN104223589A CN104223589A CN201410462274.2A CN201410462274A CN104223589A CN 104223589 A CN104223589 A CN 104223589A CN 201410462274 A CN201410462274 A CN 201410462274A CN 104223589 A CN104223589 A CN 104223589A
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- Prior art keywords
- diamond dust
- main body
- shoe tack
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- per liter
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Classifications
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43C—FASTENINGS OR ATTACHMENTS OF FOOTWEAR; LACES IN GENERAL
- A43C15/00—Non-skid devices or attachments
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B5/00—Footwear for sporting purposes
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43C—FASTENINGS OR ATTACHMENTS OF FOOTWEAR; LACES IN GENERAL
- A43C15/00—Non-skid devices or attachments
- A43C15/16—Studs or cleats for football or like boots
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/38—Chromatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D21/00—Processes for servicing or operating cells for electrolytic coating
- C25D21/08—Rinsing
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
Abstract
The invention belongs to the technical field of spikes and particularly relates to an emery wear-resisting spike. The emery wear-resisting spike comprises a spike main body and a nickel-plated layer attached to the surface of the spike main body, wherein the surface of the spike main body is also provided with an emery layer, and the nickel-plated layer is arranged between the spike main body and the emery layer. Compared with the prior art, the emery wear-resisting spike has the advantages that the wear resistance performance of the spike can be greatly improved and the service life of sports shoes using the spike is prolonged since the outer surface of the nickel-plated layer is provided with the emery layer and the emery layer has the characteristics of good toughness, high hardness, good wear resistance and the like. In addition, when the emery layer is in contact with the ground, the friction coefficient can be increased, so that the spike plays an anti-slippage role while contacting the ground, so as to prevent a user from falling down, and thus the using safety of the sports shoes using the spike is improved.
Description
Technical field
The invention belongs to shoe tack technical field, particularly relate to a kind of diamond dust wear-resistant spike and preparation method thereof.
Background technology
Shoes are the necessitys in people's daily life, and for the people be keen on sports, the comfortable wear-resisting sport footwear of a pair of is also required.The environment for use of sport footwear and mechanical characteristic require that its shoe tack has higher anti-wear performance, but simple electroplating processes has generally only been carried out in the shoe tack surface of at present shoes manufacturing enterprise and market being produced and sold, and generally only adopt ordinary plating process, electrodeposited coating (as nickel coating) is formed on the surface of shoe tack, and Common platings layer only has corrosion resistance, without any anti-wear performance, therefore in use, the anti-wear performance of shoe tack is not ideal enough, causes the service life of sport footwear shorter.
In view of this, necessaryly a kind of diamond dust wear-resistant spike with higher anti-wear performance and preparation method thereof is provided.
Summary of the invention
The object of the invention is to: for the deficiencies in the prior art, and a kind of diamond dust wear-resistant spike with higher anti-wear performance is provided.
In order to achieve the above object, the present invention adopts following technical scheme:
A kind of diamond dust wear-resistant spike, comprise shoe tack main body and the nickel coating being attached to described shoe tack body surfaces, the surface of described shoe tack main body is also provided with silicon carbide layer, and described nickel coating is arranged between described shoe tack main body and described silicon carbide layer.
One as diamond dust wear-resistant spike of the present invention is improved, and the thickness of described nickel coating is 40 μm ~ 60 μm, and the thickness of described silicon carbide layer is 40 μm ~ 100 μm.One of effect of nickel coating prevents shoe tack from getting rusty, it also has an effect to be improve the adhesive strength of silicon carbide layer in shoe tack body surfaces, and the thickness of nickel coating can not be too large, otherwise can cause the waste of the energy and material, can not be too little, otherwise good rust inhibition can not be played.Silicon carbide layer can not be too large, otherwise can cause the waste of the energy and material, can not be too little, otherwise can not play the effect well improving anti-wear performance.
One as diamond dust wear-resistant spike of the present invention is improved, and the thickness of described nickel coating is 45 μm ~ 55 μm, and the thickness of described silicon carbide layer is 50 μm ~ 80 μm.
One as diamond dust wear-resistant spike of the present invention is improved, containing nickel in described silicon carbide layer.Due to the stable in properties of diamond dust (i.e. SiC) itself; can not be dissolved in water equal solvent; when therefore electroplating; diamond dust particulate is needed to be mixed into plating solution; during plating, diamond dust particulate homogenous is stirred; particulate just and coating be jointly deposited on surface of the work, diamond dust particulate is wherein micro powder grade particulate.
Relative to prior art, the present invention arranges silicon carbide layer by the outer surface at nickel coating, because silicon carbide layer has the features such as the high and wearability of good toughness, hardness is good, therefore greatly can improve the anti-wear performance of shoe tack, extend the service life of the sport footwear using this shoe tack.And when silicon carbide layer and earth surface, can coefficient of friction be strengthened, make shoe tack with play resistant slide effect during earth surface, prevent user from falling, improve the safety in utilization of sport footwear using this shoe tack.
Another object of the present invention is the preparation method providing a kind of diamond dust wear-resistant spike, comprises the following steps:
The first step, carries out ultrasonic oil removal to shoe tack main body, then washes, and activate it with acid solution; Ultrasonic oil removal can remove the greasy dirt and impurity etc. of shoe tack body surfaces, in order to avoid these greasy dirts or the bonding force between impurity effect nickel coating and shoe tack main body, carry out activation with acid solution and can form some rough indentations on the surface of shoe tack main body, thus the adhesion increased between shoe tack main body and nickel coating, prevent coming off of nickel coating.
Second step, is placed in nickeliferous electroplate liquid by the shoe tack main body through first step process and electroplates, thus forms nickel coating on the surface of shoe tack main body;
3rd step, electroplates the electroplate liquid that the shoe tack main body containing nickel coating is placed in containing diamond dust, thus forms silicon carbide layer on the surface of nickel coating;
4th step, washing, passivation, washes, after oven dry again.
One as the preparation method of diamond dust wear-resistant spike of the present invention is improved, and the ultrasonic solution that ultrasonic oil removal described in the first step adopts is the aqueous solution of degreasing powder, and ultrasonic temperature is 60-80 DEG C, and the ultrasonic lasting time is 10-15min.Degreasing powder is the low bubble oil removing degreasing agent adopting kinds of surface activating agent, detergent, bleeding agent, builder etc. refining, and have good soaking, the ability such as solubilising and emulsification, has stronger ability of deoiling.Surface of the work after cleaning is without visible oil film or oil mark.The degreasing powder used in the present invention adopts commercially available degreasing powder.Degreasing powder coordinate ultrasonic can well remove shoe tack body surfaces greasy dirt and impurity etc.
One as the preparation method of diamond dust wear-resistant spike of the present invention is improved, and the hydrochloric acid solution of to be mass concentration the be 10-20% of acid solution described in the first step, sulfuric acid solution or salpeter solution, the time that activation continues is 5-10s.This several acid solution has good corrasion, can increase the roughness of shoe tack body surfaces, and then increases the adhesion between shoe tack main body and nickel coating.
One as the preparation method of diamond dust wear-resistant spike of the present invention is improved, electroplate liquid nickeliferous in second step comprises following component: nickelous sulfate 230-280 grams per liter, nickel chloride 40-60 grams per liter, boric acid 40-50 grams per liter, cobaltous sulfate 8-12 grams per liter, the solvent that this electroplate liquid uses is water.
One as the preparation method of diamond dust wear-resistant spike of the present invention is improved, electroplate liquid containing diamond dust in 3rd step comprises following component: nickelous sulfate 230-280 grams per liter, nickel chloride 40-60 grams per liter, boric acid 40-50 grams per liter, cobaltous sulfate 8-12 grams per liter, diamond dust particulate 500-700 grams per liter, the solvent that this electroplate liquid uses is water, and the average grain diameter of diamond dust particulate is 10-50 μm.The average grain diameter of diamond dust particulate can not be too large, otherwise its too easily sedimentation, be unfavorable for electroplating operations.This plating solution can form nickel-phosphorus-diamond dust composite deposite on the surface of shoe tack main body, and this composite deposite has good scratch-resistant performance.Wherein, diamond dust particulate can carry out boiling with the salpeter solution that mass concentration is 10-20% before use, to remove the adsorption layer on its surface, improves the adhesion of itself and nickel coating.
One as the preparation method of diamond dust wear-resistant spike of the present invention is improved, and passivation described in the 4th step uses the chromic acid of 50-200g/L, and the time that passivation continues is 30-60s, and passivation temperature is 20-30 DEG C.The effect of passivation is to make the nickel etc. in silicon carbide layer be converted into not easily oxidized state, to extend the service life of shoe tack.
Relative to prior art, method of the present invention is simple to operate, and can be formed firmly on the surface of shoe tack main body, fine and close and wear-resisting silicon carbide layer, thus service life and the safety in utilization of the sport footwear using this shoe tack can be improved.
Detailed description of the invention
Below with reference to specific embodiment, the present invention and beneficial effect thereof are described in further detail, but the specific embodiment of the present invention is not limited to this.
Embodiment 1
A kind of diamond dust wear-resistant spike that the present embodiment provides, comprise shoe tack main body and the nickel coating being attached to shoe tack body surfaces, the surface of shoe tack main body is also provided with silicon carbide layer, and nickel coating is arranged between shoe tack main body and silicon carbide layer.The thickness of nickel coating is 50 μm, and the thickness of silicon carbide layer is 70 μm, containing nickel in silicon carbide layer.
Its preparation method comprises the following steps:
The first step, carries out ultrasonic oil removal to shoe tack main body, then washes, and activate it with acid solution; Wherein, the ultrasonic solution that ultrasonic oil removal adopts is the aqueous solution of degreasing powder, ultrasonic temperature is 70 DEG C, the ultrasonic lasting time is 12min, to remove the greasy dirt and impurity etc. of shoe tack body surfaces, then wash twice, with eccysis degreasing powder, acid solution to be mass concentration be 15% hydrochloric acid solution, to carry out etching activation process to the surface of shoe tack main body.
Second step, is placed in nickeliferous electroplate liquid by the shoe tack main body through first step process and electroplates, thus formed on the surface of shoe tack main body fine and close, combine firmly nickel coating; Wherein, nickeliferous electroplate liquid comprises following component: nickelous sulfate 250 grams per liter, nickel chloride 50 grams per liter, boric acid 45 grams per liter, cobaltous sulfate 10 grams per liter, and the solvent that this electroplate liquid uses is water.
3rd step, electroplates the electroplate liquid that the shoe tack main body containing nickel coating is placed in containing diamond dust, thus forms silicon carbide layer on the surface of nickel coating; Electroplate liquid containing diamond dust comprises following component: nickelous sulfate 250 grams per liter, nickel chloride 50 grams per liter, boric acid 45 grams per liter, cobaltous sulfate 10 grams per liter, diamond dust particulate 600 grams per liter, and the solvent that this electroplate liquid uses is water, and the average grain diameter of diamond dust particulate is 20 μm.Stirred by diamond dust particulate homogenous during plating, diamond dust particulate just and be jointly deposited on the surface of nickel coating containing nickel coating, thus forms nickel-phosphorus-diamond dust composite deposite, and this composite deposite has good scratch-resistant performance.Wherein, diamond dust particulate carries out boiling with the salpeter solution that mass concentration is 15% before use, to remove the adsorption layer on its surface, improves the adhesion of itself and nickel coating.The operation of plating silicon carbide layer (the 3rd step) repeats twice.
4th step, wash three times, passivation, wash three times, after oven dry again.Wherein, passivation uses the chromic acid of 100g/L, and the time that passivation continues is 40s, and passivation temperature is 25 DEG C.
Embodiment 2
A kind of diamond dust wear-resistant spike that the present embodiment provides, comprise shoe tack main body and the nickel coating being attached to shoe tack body surfaces, the surface of shoe tack main body is also provided with silicon carbide layer, and nickel coating is arranged between shoe tack main body and silicon carbide layer.The thickness of nickel coating is 42 μm, and the thickness of silicon carbide layer is 90 μm, containing nickel in silicon carbide layer.
Its preparation method comprises the following steps:
The first step, carries out ultrasonic oil removal to shoe tack main body, then washes, and activate it with acid solution; Wherein, the ultrasonic solution that ultrasonic oil removal adopts is the aqueous solution of degreasing powder, ultrasonic temperature is 60 DEG C, the ultrasonic lasting time is 10min, to remove the greasy dirt and impurity etc. of shoe tack body surfaces, then wash twice, with eccysis degreasing powder, acid solution to be mass concentration be 10% sulfuric acid solution, to carry out etching activation process to the surface of shoe tack main body.
Second step, is placed in nickeliferous electroplate liquid by the shoe tack main body through first step process and electroplates, thus formed on the surface of shoe tack main body fine and close, combine firmly nickel coating; Wherein, nickeliferous electroplate liquid comprises following component: nickelous sulfate 270 grams per liter, nickel chloride 40 grams per liter, boric acid 50 grams per liter, cobaltous sulfate 8 grams per liter, and the solvent that this electroplate liquid uses is water.
3rd step, electroplates the electroplate liquid that the shoe tack main body containing nickel coating is placed in containing diamond dust, thus forms silicon carbide layer on the surface of nickel coating; Electroplate liquid containing diamond dust comprises following component: nickelous sulfate 270 grams per liter, nickel chloride 40 grams per liter, boric acid 50 grams per liter, cobaltous sulfate 8 grams per liter, diamond dust particulate 550 grams per liter, and the solvent that this electroplate liquid uses is water, and the average grain diameter of diamond dust particulate is 30 μm.Stirred by diamond dust particulate homogenous during plating, diamond dust particulate just and be jointly deposited on the surface of nickel coating containing nickel coating, thus forms nickel-phosphorus-diamond dust composite deposite, and this composite deposite has good scratch-resistant performance.Wherein, diamond dust particulate carries out boiling with the salpeter solution that mass concentration is 12% before use, to remove the adsorption layer on its surface, improves the adhesion of itself and nickel coating.The operation of plating silicon carbide layer repeats twice.
4th step, wash three times, passivation, wash three times, after oven dry again.Wherein, passivation uses the chromic acid of 150g/L, and the time that passivation continues is 50s, and passivation temperature is 20 DEG C.
Embodiment 3
A kind of diamond dust wear-resistant spike that the present embodiment provides, comprise shoe tack main body and the nickel coating being attached to shoe tack body surfaces, the surface of shoe tack main body is also provided with silicon carbide layer, and nickel coating is arranged between shoe tack main body and silicon carbide layer.The thickness of nickel coating is 60 μm, and the thickness of silicon carbide layer is 45 μm, containing nickel in silicon carbide layer.
Its preparation method comprises the following steps:
The first step, carries out ultrasonic oil removal to shoe tack main body, then washes, and activate it with acid solution; Wherein, the ultrasonic solution that ultrasonic oil removal adopts is the aqueous solution of degreasing powder, ultrasonic temperature is 75 DEG C, the ultrasonic lasting time is 15min, to remove the greasy dirt and impurity etc. of shoe tack body surfaces, then wash twice, with eccysis degreasing powder, acid solution to be mass concentration be 20% salpeter solution, to carry out etching activation process to the surface of shoe tack main body.
Second step, is placed in nickeliferous electroplate liquid by the shoe tack main body through first step process and electroplates, thus formed on the surface of shoe tack main body fine and close, combine firmly nickel coating; Wherein, nickeliferous electroplate liquid comprises following component: nickelous sulfate 230 grams per liter, nickel chloride 60 grams per liter, boric acid 40 grams per liter, cobaltous sulfate 12 grams per liter, and the solvent that this electroplate liquid uses is water.
3rd step, electroplates the electroplate liquid that the shoe tack main body containing nickel coating is placed in containing diamond dust, thus forms silicon carbide layer on the surface of nickel coating; Electroplate liquid containing diamond dust comprises following component: nickelous sulfate 230 grams per liter, nickel chloride 60 grams per liter, boric acid 40 grams per liter, cobaltous sulfate 12 grams per liter, diamond dust particulate 650 grams per liter, and the solvent that this electroplate liquid uses is water, and the average grain diameter of diamond dust particulate is 4 μm.Stirred by diamond dust particulate homogenous during plating, diamond dust particulate just and be jointly deposited on the surface of nickel coating containing nickel coating, thus forms nickel-phosphorus-diamond dust composite deposite, and this composite deposite has good scratch-resistant performance.Wherein, diamond dust particulate carries out boiling with the salpeter solution that mass concentration is 20% before use, to remove the adsorption layer on its surface, improves the adhesion of itself and nickel coating.The operation of plating silicon carbide layer repeats twice.
4th step, wash three times, passivation, wash three times, after oven dry again.Wherein, passivation uses the chromic acid of 200g/L, and the time that passivation continues is 50s, and passivation temperature is 30 DEG C.
The diamond dust wear-resistant spike of embodiment 1 to 3 is tested as follows with the shoe tack (surface has only processed nickel coating, comparative example) not carrying out plating silicon carbide layer process:
By wear-resisting testing equipment, the overlay coating of shoe tack is carried out to the friction treatment of 30min, and the shoe tack weight recorded respectively before friction treatment and the shoe tack weight after friction treatment, calculate its weight-loss ratio, acquired results is in table 1:
Table 1: the wear-resisting test result of the shoe tack that 3 and comparative example of embodiment 1 provide.
| Group | Weight (g) before process | Weight (g) after process | Weight-loss ratio (%) |
| Embodiment 1 | 4.2138 | 4.1918 | 0.522 |
| Embodiment 2 | 4.2246 | 4.2028 | 0.516 |
| Embodiment 3 | 4.2356 | 4.2140 | 0.510 |
| Comparative example | 4.1543 | 4.0313 | 2.96 |
As can be seen from Table 1: by arranging silicon carbide layer on the surface of shoe tack main body, under same friction treatment condition, its weight-loss ratio reduces greatly, as can be seen here: arranging of silicon carbide layer can improve its anti-wear performance greatly.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also carry out suitable change and amendment to above-mentioned embodiment.Therefore, the present invention is not limited to detailed description of the invention disclosed and described above, also should fall in the protection domain of claim of the present invention modifications and changes more of the present invention.In addition, although employ some specific terms in this description, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (10)
1. a diamond dust wear-resistant spike, comprise shoe tack main body and the nickel coating being attached to described shoe tack body surfaces, it is characterized in that: the surface of described shoe tack main body is also provided with silicon carbide layer, and described nickel coating is arranged between described shoe tack main body and described silicon carbide layer.
2. diamond dust wear-resistant spike according to claim 1, is characterized in that: the thickness of described nickel coating is 40 μm ~ 60 μm, and the thickness of described silicon carbide layer is 40 μm ~ 100 μm.
3. diamond dust wear-resistant spike according to claim 2, is characterized in that: the thickness of described nickel coating is 45 μm ~ 55 μm, and the thickness of described silicon carbide layer is 50 μm ~ 80 μm.
4. diamond dust wear-resistant spike according to claim 1, is characterized in that: containing nickel in described silicon carbide layer.
5. a preparation method for the diamond dust wear-resistant spike described in 4 any one of claim 1, is characterized in that, comprise the following steps:
The first step, carries out ultrasonic oil removal to shoe tack main body, then washes, and activate it with acid solution;
Second step, is placed in nickeliferous electroplate liquid by the shoe tack main body through first step process and electroplates, thus forms nickel coating on the surface of shoe tack main body;
3rd step, electroplates the electroplate liquid that the shoe tack main body containing nickel coating is placed in containing diamond dust, thus forms silicon carbide layer on the surface of nickel coating;
4th step, washing, passivation, washes, after oven dry again.
6. the preparation method of diamond dust wear-resistant spike according to claim 5, is characterized in that: the ultrasonic solution that ultrasonic oil removal described in the first step adopts is the aqueous solution of degreasing powder, and ultrasonic temperature is 60-80 DEG C, and the ultrasonic lasting time is 10-15min.
7. the preparation method of diamond dust wear-resistant spike according to claim 5, is characterized in that: the hydrochloric acid solution of to be mass concentration the be 10-20% of acid solution described in the first step, sulfuric acid solution or salpeter solution, the time that activation continues is 5-10s.
8. the preparation method of diamond dust wear-resistant spike according to claim 5, it is characterized in that: electroplate liquid nickeliferous in second step comprises following component: nickelous sulfate 230-280 grams per liter, nickel chloride 40-60 grams per liter, boric acid 40-50 grams per liter, cobaltous sulfate 8-12 grams per liter, the solvent that this electroplate liquid uses is water.
9. the preparation method of diamond dust wear-resistant spike according to claim 5, it is characterized in that: the electroplate liquid containing diamond dust in the 3rd step comprises following component: nickelous sulfate 230-280 grams per liter, nickel chloride 40-60 grams per liter, boric acid 40-50 grams per liter, cobaltous sulfate 8-12 grams per liter, diamond dust particulate 500-700 grams per liter, the solvent that this electroplate liquid uses is water, and the average grain diameter of diamond dust particulate is 10-50 μm.
10. the preparation method of diamond dust wear-resistant spike according to claim 5, is characterized in that: passivation described in the 4th step uses the chromic acid of 50-200g/L, and the time that passivation continues is 30-60s, and passivation temperature is 20-30 DEG C.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410462274.2A CN104223589B (en) | 2014-09-11 | 2014-09-11 | A kind of diamond dust wear-resistant spike and preparation method thereof |
| US14/907,136 US20170231328A1 (en) | 2014-09-11 | 2015-08-31 | Carborundum wear-resistant shoe spike and preparation method thereof |
| PCT/CN2015/088513 WO2016037535A1 (en) | 2014-09-11 | 2015-08-31 | Wear-resistant silicon carbide footwear cleat and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410462274.2A CN104223589B (en) | 2014-09-11 | 2014-09-11 | A kind of diamond dust wear-resistant spike and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104223589A true CN104223589A (en) | 2014-12-24 |
| CN104223589B CN104223589B (en) | 2015-12-30 |
Family
ID=52213189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410462274.2A Expired - Fee Related CN104223589B (en) | 2014-09-11 | 2014-09-11 | A kind of diamond dust wear-resistant spike and preparation method thereof |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20170231328A1 (en) |
| CN (1) | CN104223589B (en) |
| WO (1) | WO2016037535A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016037535A1 (en) * | 2014-09-11 | 2016-03-17 | 东莞诚兴五金制品有限公司 | Wear-resistant silicon carbide footwear cleat and preparation method therefor |
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| JPS6234504A (en) * | 1985-08-08 | 1987-02-14 | 東芝タンガロイ株式会社 | Antiskid spike |
| JPS642362B2 (en) * | 1984-05-02 | 1989-01-17 | Ashitsukusu Kk | |
| DE4138941A1 (en) * | 1991-11-27 | 1993-06-03 | Winfried Heinzel | Sports shoe with coated metal studs - sprayed with ceramic and anti-stick coatings |
| JPH06197804A (en) * | 1991-06-21 | 1994-07-19 | Hanshin Mekki Seikosho:Kk | Spike, spike shoes, and manufacture thereof |
| JPH07171008A (en) * | 1993-12-17 | 1995-07-11 | Mizuno Corp | Shoe rivet |
| US5732484A (en) * | 1996-09-18 | 1998-03-31 | Di-Coat Corporation | Shoe cleats and methods of producing and utilizing same |
| DE29814628U1 (en) * | 1998-08-18 | 1999-01-07 | Hollik Eckhard | Non-slip footwear |
| EP1643015A2 (en) * | 2004-09-29 | 2006-04-05 | Dowa Mining Co., Ltd. | Tin-plated product |
| CN1986213A (en) * | 2005-12-22 | 2007-06-27 | 鸿富锦精密工业（深圳）有限公司 | Antiwear magnetic coating and its making process |
| CN101781786A (en) * | 2010-02-24 | 2010-07-21 | 戴亚洲 | Ceramic composite alloy coat ink scraping knife and manufacturing method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104223589B (en) * | 2014-09-11 | 2015-12-30 | 东莞诚兴五金制品有限公司 | A kind of diamond dust wear-resistant spike and preparation method thereof |
-
2014
- 2014-09-11 CN CN201410462274.2A patent/CN104223589B/en not_active Expired - Fee Related
-
2015
- 2015-08-31 WO PCT/CN2015/088513 patent/WO2016037535A1/en active Application Filing
- 2015-08-31 US US14/907,136 patent/US20170231328A1/en not_active Abandoned
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5815803A (en) * | 1981-07-18 | 1983-01-29 | 住友電気工業株式会社 | Ceramic spike |
| JPS642362B2 (en) * | 1984-05-02 | 1989-01-17 | Ashitsukusu Kk | |
| JPS6234504A (en) * | 1985-08-08 | 1987-02-14 | 東芝タンガロイ株式会社 | Antiskid spike |
| JPH06197804A (en) * | 1991-06-21 | 1994-07-19 | Hanshin Mekki Seikosho:Kk | Spike, spike shoes, and manufacture thereof |
| DE4138941A1 (en) * | 1991-11-27 | 1993-06-03 | Winfried Heinzel | Sports shoe with coated metal studs - sprayed with ceramic and anti-stick coatings |
| JPH07171008A (en) * | 1993-12-17 | 1995-07-11 | Mizuno Corp | Shoe rivet |
| US5732484A (en) * | 1996-09-18 | 1998-03-31 | Di-Coat Corporation | Shoe cleats and methods of producing and utilizing same |
| DE29814628U1 (en) * | 1998-08-18 | 1999-01-07 | Hollik Eckhard | Non-slip footwear |
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| US20070148462A1 (en) * | 2005-12-22 | 2007-06-28 | Hon Hai Precision Industry Co., Ltd. | Article having diamond-like carbon composite film and method for manufacturing the same |
| CN101781786A (en) * | 2010-02-24 | 2010-07-21 | 戴亚洲 | Ceramic composite alloy coat ink scraping knife and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016037535A1 (en) * | 2014-09-11 | 2016-03-17 | 东莞诚兴五金制品有限公司 | Wear-resistant silicon carbide footwear cleat and preparation method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104223589B (en) | 2015-12-30 |
| US20170231328A1 (en) | 2017-08-17 |
| WO2016037535A1 (en) | 2016-03-17 |
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