CN104213178B - A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof - Google Patents
A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof Download PDFInfo
- Publication number
- CN104213178B CN104213178B CN201410316350.9A CN201410316350A CN104213178B CN 104213178 B CN104213178 B CN 104213178B CN 201410316350 A CN201410316350 A CN 201410316350A CN 104213178 B CN104213178 B CN 104213178B
- Authority
- CN
- China
- Prior art keywords
- cake
- nickel
- hole
- formed pipe
- containing sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Cell Electrode Carriers And Collectors (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
A kind of Active Nickel Containing Sulphur cake, it is cake, rib cake, round platform cake or terrace with edge pie structure.Manufacture the nickel cake minus plate of above-mentioned Active Nickel Containing Sulphur cake, including a metal basal board being connected to contact rod；Metal basal board two sides is all covered with template；Template is provided with through hole；The special-shaped formed pipe for the growth of nickel cake it is set with in through hole；Abnormity formed pipe one end is stretched into through hole and is in close contact with metal basal board；Abnormity formed pipe stretches out the one end outside through hole and is provided with and blocks with through hole outer face to prevent abnormity formed pipe from coming off from through hole when taking cake mutually, be easy to the flange that separated from abnormity formed pipe by nickel cake.The Active Nickel Containing Sulphur cake growth cycle that the present invention provides is short, the quality of production is stable, qualification rate is high, single quality is big, low cost, and it is high that it manufactures equipment nickel cake minus plate production efficiency, and service life is long.
Description
Technical field
The present invention relates to a kind of Active Nickel Containing Sulphur cake and manufacture equipment thereof.
Background technology
At present, electrolytic nickel international and domestic market being used as galvanic anode mainly has sheet nickel and nickel angle.Sheet nickel and nickel angle are common electrolytic nickels, do not dissolve activity, are easily passivated during use, or form the corrosion of hornet's nest shape, produce a large amount of dissolved residue, cause the waste of nickel plate.
Active Nickel Containing Sulphur, is a kind of Novel electroplating anode material, and compared with common nickel, it has the highest electro-chemical activity, and this mainly introduces the element sulphur of certain content in the fabrication process.
Manufacture Active Nickel Containing Sulphur, be the most abroad based on planar type cathodes plate, produce plum blossom-shaped product, therefore referred to as Flos Mume nickel, also Active Nickel Containing Sulphur button it is, mainly by VALE INCO(fresh water river valley) company's production, its key technology is the structure of planar type cathodes plate and produces control.The product of circulation on current document both domestic and external, patent and market, is all that this technology is manufactured.Its deficiency existed is: one, Flos Mume nickel (i.e. nickel button) is that two dimension (i.e. axially and through upwards) growth forms on planar cathode plate, it is only connected by adhesive force with minus plate, when adhesive force is excessive, produce complete take during button highly difficult, when adhesive force is too small, weight increases, and easily departs from pole plate and falls off, becomes defective work；Two, the initial diameter of nickel button only has 5-14mm, and in growth course, the diameter of nickel button is become larger about 25mm by little, and owing to early stage diameter is little, the electric current of use is the least, and production efficiency is low；Three, nickel button thickness is thin, light weight, consumes fast, increase the labor intensity of workman, be not suitable for large scale application during use.
Summary of the invention
It is an object of the invention to overcome deficiencies of the prior art and provide that a kind of growth cycle is short, the quality of production is stable, qualification rate is high, single quality big, the Active Nickel Containing Sulphur cake of low cost.
The present invention also aims to provide a kind of nickel cake minus plate being exclusively used in and producing Active Nickel Containing Sulphur cake.
Technical program of the present invention lies in: Active Nickel Containing Sulphur cake is cake, rib cake, round platform cake or terrace with edge pie structure.
Described Active Nickel Containing Sulphur cake is cake or round platform pie structure, its a height of 2-50mm, a diameter of 4-49mm of upper bottom surface, a diameter of 5-50mm of bottom surface.
Described Active Nickel Containing Sulphur cake is rib cake or terrace with edge pie structure, its a height of 2-50mm, and the area of upper bottom surface is 45-490 mm2, the area of bottom surface is 50-500 mm2。
Manufacture the nickel cake minus plate of above-mentioned Active Nickel Containing Sulphur cake, including a metal basal board being connected to contact rod；Metal basal board two sides is all covered with template；Template is provided with through hole；The special-shaped formed pipe for the growth of nickel cake it is set with in through hole；Abnormity formed pipe one end is stretched into through hole and is in close contact with metal basal board；Abnormity formed pipe stretches out the one end outside through hole and is provided with and blocks with through hole outer face to prevent abnormity formed pipe from coming off from through hole when taking cake mutually, be easy to the flange that separated from abnormity formed pipe by nickel cake.
Described template includes strengthening template, at the foundation forms strengthened between template and metal basal board.
Described foundation forms is glass plate or ceramic wafer；Described reinforcement template is epoxy resin board, phenol resin plate or titanium plate.
Described template is connected through bolt or screw with metal basal board.
Described through hole is circular hole；The endoporus of described abnormity formed pipe is circular hole.
One end inwall that described abnormity formed pipe contacts with metal basal board is provided with the chamfering being easy to the growth of nickel cake.
Angle α at described chamfering is 0 15 °.
Degree of depth L of described chamfering is less than or equal to the thickness of template.
Described metal basal board is titanium plate or corrosion resistant plate.
Active Nickel Containing Sulphur cake provided by the present invention not only activity is high, electrochemical dissolution is good, also have with short production cycle, the quality of production is stable, qualification rate advantages of higher, the nickel button produced relative to planar type cathodes plate, present invention have the advantage that one, minus plate of the present invention is by the stereochemical structure of several unit constructions, is combined cathode plate.Two, the product design produced by the present invention is not plum blossom-shaped, is round pie.Three, the combined cathode plate of the present invention, changes growth bore dia and can produce the sulfur-bearing nickel active nickel cake of different-diameter and weight, to meet the demand of different user.Four, the nickel produced compared to plate minus plate is buckled, growth hole of the present invention, and its diameter is fixing, is equivalent to the diameter after nickel is fastened as shape.When producing at the beginning, it is amassed by surfacing and is equivalent to the geometric projection area that the nickel in plate minus plate later stage is buckled, so can use bigger electric current at the very start, production efficiency is high.
Accompanying drawing explanation
Fig. 1 is the structural representation of nickel cake (round platform pie).
Fig. 2 is the structural representation of nickel cake (terrace with edge pie).
Fig. 3 be nickel cake minus plate perspective view.
Fig. 4 is the front view of nickel cake minus plate.
Fig. 5 is the B-B sectional view of Fig. 4.
Fig. 6 is the A portion enlarged drawing of Fig. 5.
In figure, 1, metal basal board, 2, template, 3, through hole, 4, abnormity formed pipe, 5, flange, 6, bolt, 7, Active Nickel Containing Sulphur cake, 8, upper bottom surface, 9, bottom surface.
Detailed description of the invention
In Fig. 1, Active Nickel Containing Sulphur cake 7 in round platform pie structure, a height of 4mm, a diameter of 20mm of upper bottom surface 8, a diameter of 24mm of bottom surface 9.
In Fig. 2, Active Nickel Containing Sulphur cake 7 is in terrace with edge pie structure, and a height of 5mm, the area of upper bottom surface 8 is 225 mm2, the area of bottom surface 9 is 256 mm2。
In Fig. 3, Fig. 4, Fig. 5, using titanium plate as metal basal board 1, titanium plate two surface being coated with template 2, be connected with bolt 6 between titanium plate with template 2, uniform through hole 3 in template 2, through hole 3 inner close fitting has the special-shaped formed pipe 4 for the growth of nickel cake.Abnormity formed pipe 4 internal via shape is consistent with through hole 3, for circular hole or square hole.Abnormity formed pipe 4 one end is stretched into through hole 3 and is pushed up mutually with titanium plate, and the other end of abnormity formed pipe 4 stretches out outside template 2.Abnormity formed pipe 4 has chamfering near one end inwall of titanium plate.Abnormity formed pipe 4 stretches out the one end outside through hole 3 and is provided with and blocks with through hole 3 outer face to prevent abnormity formed pipe 4 from coming off from through hole 3 when taking cake mutually, be easy to the flange 5 that separated from abnormity formed pipe 4 by nickel cake.Titanium plate is connected by connecting plate with contact rod.
Wherein, template 2 includes strengthening template, at the foundation forms strengthened between template and metal basal board 1.Foundation forms is glass plate or ceramic wafer；Reinforcement template is epoxy resin board, phenol resin plate or titanium plate.
In Fig. 6, at abnormity formed pipe 4 chamfering, angle α is 0 15 °, and degree of depth L of chamfering is less than or equal to the thickness of template 2.
Claims (7)
1. the nickel cake minus plate manufacturing Active Nickel Containing Sulphur cake, it is characterised in that: include a metal basal board (1) being connected to contact rod；Metal basal board (1) two sides is all covered with template (2)；Template (2) is provided with through hole (3)；The special-shaped formed pipe (4) for the growth of nickel cake it is set with in through hole (3)；Abnormity formed pipe (4) one end is stretched into through hole (3) and is in close contact with metal basal board (1)；Abnormity formed pipe (4) stretches out through hole (3) one end outward and is provided with and blocks with through hole (3) outer face to prevent abnormity formed pipe (4) from coming off from through hole (3) when taking cake mutually, be easy to the flange (5) that separated from special-shaped formed pipe (4) by nickel cake, and described Active Nickel Containing Sulphur cake (7) is cake, rib cake, round platform cake or terrace with edge pie structure.
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 1, it is characterised in that: described template (2) includes strengthening template, at the foundation forms strengthened between template and metal basal board.
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 2, it is characterised in that: described foundation forms is glass plate or ceramic wafer；Described reinforcement template is epoxy resin board, phenolic resin plate or titanium plate.
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 1, it is characterised in that: described template (2) is connected through bolt or screw with metal basal board (1).
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 1, it is characterised in that: described through hole (3) is circular hole；The endoporus of described abnormity formed pipe (4) is circular hole.
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 1, it is characterised in that: one end inwall that described abnormity formed pipe (4) contacts with metal basal board (1) is provided with the chamfering being easy to the growth of nickel cake.
The nickel cake minus plate of Active Nickel Containing Sulphur cake the most according to claim 1, it is characterised in that: described metal basal board (1) is titanium plate or corrosion resistant plate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410316350.9A CN104213178B (en) | 2014-07-04 | 2014-07-04 | A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410316350.9A CN104213178B (en) | 2014-07-04 | 2014-07-04 | A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104213178A CN104213178A (en) | 2014-12-17 |
| CN104213178B true CN104213178B (en) | 2016-08-24 |
Family
ID=52095071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410316350.9A Active CN104213178B (en) | 2014-07-04 | 2014-07-04 | A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104213178B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302787A (en) * | 2001-04-06 | 2002-10-18 | Sumitomo Metal Mining Co Ltd | Method of producing special-shaped electric nickel for plating |
| CN1958860A (en) * | 2006-09-26 | 2007-05-09 | 吴用 | Negative plate of permanent nickel fastener |
| CN201660702U (en) * | 2010-04-08 | 2010-12-01 | 襄樊化通化工有限责任公司 | Nickel column |
| CN103820822A (en) * | 2014-02-28 | 2014-05-28 | 金川集团股份有限公司 | Permanent negative plate for production of nickel button |
-
2014
- 2014-07-04 CN CN201410316350.9A patent/CN104213178B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002302787A (en) * | 2001-04-06 | 2002-10-18 | Sumitomo Metal Mining Co Ltd | Method of producing special-shaped electric nickel for plating |
| CN1958860A (en) * | 2006-09-26 | 2007-05-09 | 吴用 | Negative plate of permanent nickel fastener |
| CN201660702U (en) * | 2010-04-08 | 2010-12-01 | 襄樊化通化工有限责任公司 | Nickel column |
| CN103820822A (en) * | 2014-02-28 | 2014-05-28 | 金川集团股份有限公司 | Permanent negative plate for production of nickel button |
Non-Patent Citations (1)
| Title |
|---|
| 国外镀镍阳极;徐金全;《电镀与精饰》;19821231(第06期);第47页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104213178A (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105088323B (en) | Board-like Electropolating hangers | |
| CN104213149B (en) | Nickel briquette manufacturing method | |
| CN104213178B (en) | A kind of Active Nickel Containing Sulphur cake and the equipment of manufacture thereof | |
| CN104294313A (en) | Electrochemical gold dissolving device and method | |
| CN206127452U (en) | Electrolytic copper foil is with negative pole roller that prevents ablation | |
| CN101403124A (en) | Cathode plate used for producing nickel buckle and its production method | |
| CN208791783U (en) | A kind of membrane-electrode assembly | |
| CN104213150A (en) | Sulfur-containing active nickel briquette produced through electrolytic process | |
| CN219156997U (en) | Mastoid plate for alkaline electrolytic tank | |
| CN107779910A (en) | A kind of structure and method for reducing aluminium electrolysis anode steel charcoal pressure drop | |
| CN202871906U (en) | Carbon battery grid | |
| CN211848169U (en) | Profiling titanium basket | |
| CN208151498U (en) | A kind of annular button Winning cell novel cathode board structure | |
| CN201258356Y (en) | Mask clamping fixture with mosaic structure | |
| CN205329189U (en) | Preparation metal porous surface texture inlays electroplating device | |
| CN204311150U (en) | The Active Nickel Containing Sulphur cake that electrocasting is produced | |
| CN108251864A (en) | A kind of Zinc electrolysis additive and its application method | |
| CN214782194U (en) | Permanent type nickel button growth polar plate | |
| CN101503807A (en) | Cathode structure of membrane electrode electrolysis ozone generator | |
| CA2633347A1 (en) | Fuel cell including a hydrogen permeable membrane as anode and manufacturing method of the same | |
| CN201660702U (en) | Nickel column | |
| CN101260534A (en) | Ceramic diaphragm electrolytic cells, preparation method and application thereof | |
| CN216786275U (en) | Integrated electrode structure | |
| CN204088462U (en) | The effective tool of colloid storage battery positive plate insert row | |
| CN215828887U (en) | Conductive plate structure for lead electrolytic tank |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |