CN101403124A - Cathode plate used for producing nickel buckle and its production method - Google Patents

Cathode plate used for producing nickel buckle and its production method Download PDF

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Publication number
CN101403124A
CN101403124A CNA2007103036170A CN200710303617A CN101403124A CN 101403124 A CN101403124 A CN 101403124A CN A2007103036170 A CNA2007103036170 A CN A2007103036170A CN 200710303617 A CN200710303617 A CN 200710303617A CN 101403124 A CN101403124 A CN 101403124A
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CN
China
Prior art keywords
negative plate
rubber
nickel
cathode plate
plate
Prior art date
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Pending
Application number
CNA2007103036170A
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Chinese (zh)
Inventor
李娟�
鲍德志
石文堂
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Jinchuan Group Co Ltd
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Jinchuan Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinchuan Group Co Ltd filed Critical Jinchuan Group Co Ltd
Priority to CNA2007103036170A priority Critical patent/CN101403124A/en
Publication of CN101403124A publication Critical patent/CN101403124A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a cathode plate which is used for manufacturing nickel buttons and a preparing method thereof and relates to a cathode plate which is used in the process of manufacturing electroforming-used nickel buttons in a mixed acid system (sulfate and hydrochloric acid) or a pure acid system. The cathode plate is characterized in that the cathode plate comprises the following structures: a substrate of the cathode plate which is a stainless steel plate or a titanium plate; a rubber insulating film layer which is porous with round holes distributed uniformly in a shape of Chinese character 'pin'; and the rubber insulating film layer is adhered to the substrate of the cathode plate by binder. The proposal of the invention is reasonable and practical. The rubber film has good insulating property, strong corrosion resistance and temperature resistance and can meet the demand of growth of the nickel buttons completely with low cost. The nickel button cathode plate film adhere technology can ensure the nickel button stripping to realize automation easily, thus improving the production efficiency and reducing the labor intensity.

Description

A kind of negative plate of producing on the nickel button and preparation method thereof that is used to
Technical field
A kind of negative plate of producing on the nickel button and preparation method thereof that is used to relates to and adopts in the mixed acid system in (sulfuric acid and hydrochloric acid) or the pure acid system electrolysis production to electroplate with negative plate that uses in the nickel button process and preparation method thereof.
Background technology
Electrolytic nickle in the electroplating process, mainly is used as the anode material of basket plating industry as a kind of important electroplating industry raw material, compares with common electrical nickel, and bath voltage reduces 0.4V, saves electric energy 5%, uses more and more extensive on electroplating industry.From domestic and international nickel button market situation, this product has bigger potential market.And Nickel electrode plate is in the nickel button is produced, as the negative plate of producing the nickel button, in vitriol and hydrochloride mixed system, with the stainless steel column of stainless steel plate embedding is substrate, the adhering on surface material must good insulating, corrosion-resistant, ingredient does not pollute electrolytic solution, and cost is reasonable, technology is reliable, the nickel button of producing just can reach outward appearance evenly, smooth surface, be of close texture, production efficiency height, cost be reasonable.Pole plate performance and cost usually make the nickel of producing be fastened as originally too high and lack the market competitiveness.
Summary of the invention
The nickel button production that the objective of the invention is to exist at above-mentioned prior art negative plate production cost height, the defective that performance is not high, manufacturing process is complicated provide the nickel button production that a kind of manufacturing process is simple, preparation cost is low, performance is good pole plate and preparation method thereof.
The objective of the invention is to realize by following technology.
A kind of negative plate that is used to produce the nickel button is characterized in that this negative plate is made up of following structure:
Negative plate substrate-this substrate is with stainless steel plate or titanium plate;
Rubber insulation rete-this insulating film layer has the porous insulation rubber rete that is isosceles triangle uniform distribution circular hole on it; The rubber insulation rete sticks on the negative plate substrate with binding agent.
A kind of negative plate that is used to produce the nickel button is characterized in that its rubber insulation rete is the exhausted rubber diaphragm of polymer edge.
A kind of negative plate that is used to produce the nickel button is characterized in that the rubber insulation rete sticked to and uses binding agent to be 903# glue on the negative plate substrate.
A kind of preparation method who is used to produce the negative plate of nickel button is characterized in that its preparation process is:
A) at first with titanium or stainless steel plate surface finish, polishing, smooth after, clean again, remove surperficial dust and dirt and greasy dirt;
B) even application binding agent on rubber film;
C) punch its isosceles triangle uniform distribution at the rubber film that scribbles binding agent;
D) film after will punching is attached at titanium or stainless steel plate surface, makes the negative plate of producing the nickel button.
The negative plate that is used to produce the nickel button of the present invention behind a whole nickel button growth cycle, is buckled the nickel that generates on the negative plate and is peeled off, rubber film on the negative plate only need be torn and be got final product, after cleaning of negative plate process and the base treatment, can repeat preparation process, enter the next production cycle.
Nickel electrode plate adaptability of the present invention is wider, can be in other medium system: be used for the production of nickel button in as pure chlorination system, bright sulfur acid system.
The negative plate of production nickel button of the present invention adopts stainless steel plate or titanium plate as body material, utilizes the base material of its electroconductibility as the growth of nickel button.On stainless steel plate or titanium plate, utilize the binding agent that performance is very stable in electrolytic solution that one deck vesicular rubber plastic film is attached on the pole plate, the cohesive strength of binding agent and rubber and plastic greater than with the cohesive strength of metallic surface, use the back effectively to guarantee the non-cohesive binding agent of metallic matrix, help the base treatment of next cycle sheet material.The film phenomenons such as bubble layering that come off do not appear in the pole plate after attaching with rubber plastic film in nickel button growth cycle.In Nickel electrode plate membrane pores edge, binding agent is tight with the base material bonding all the time, and electrolytic solution can't enter the interface of film and base material, " series connection " phenomenon can not occur.
The solution of the present invention is rational, practical.Rubber plastic film self good insulating, corrosion-resistant, temperature tolerance is extremely strong, can satisfy the requirement of nickel button growth fully, and is and with low cost.Nickel button cathode plate film adhere technology of the present invention makes the nickel button peel off easy realization automatization, enhances productivity, and alleviates labor strength.It is simple, easy to operate that Nickel electrode plate of the present invention has manufacture craft.Adaptability is wider, can produce the nickel button in other medium system.
Embodiment
A kind of negative plate that is used to produce the nickel button is characterized in that this negative plate is made up of following structure: negative plate substrate-this substrate is for stainless steel plate or titanium plate; Rubber insulation rete-this insulating film layer has the porous insulation rubber rete that is isosceles triangle uniform distribution circular hole on it; And a kind of negative plate that is used to produce the nickel button is characterized in that this rubber insulation rete sticks on the negative plate substrate with binding agent.Preparation process is: a) at first with titanium plate or stainless steel surface polishing, polishing, smooth after, clean again, remove surperficial dust and dirt and greasy dirt.The quality of surface treatment quality will directly influence the rubber film bond effect, and the sheet material after the processing should attach in 4 hours, avoided secondary pollution; B) the application layer must be evenly during the application binding agent on rubber film.C) should be pollution-free in the coating process, the rubber film that the scribbles binding agent processing of punching, the hole is the isosceles triangle uniform distribution.D) film after will punching is attached at titanium plate surface, and the limit welt is removed bubble.E) behind the whole nickel button growth cycle, the nickel that generates on the negative plate buckled peel off, the rubber film on the negative plate only need be torn and be got final product, negative plate through cleaning and base treatment after, enter the next one production cycle.
Embodiment 1
At first with titanium plate surface finish, polishing, smooth after, clean again, remove surperficial dust and dirt and greasy dirt.The quality of surface treatment quality will directly influence the rubber film bond effect, and the sheet material after the processing should attach in 4 hours, avoided secondary pollution; On commercial polymer electro-insulating rubber film, evenly be coated with full 903# glue bond agent; C) should be pollution-free in the coating process, the rubber film that the scribbles binding agent processing of punching, aperture 10mm, pitch of holes 30mm * 25mm isosceles triangle uniform distribution.Film after the punching is attached at titanium plate surface, and the limit welt is removed bubble.E) behind the whole nickel button growth cycle, the nickel that generates on the negative plate buckled peel off, the rubber film on the negative plate only need be torn and be got final product, negative plate through cleaning and base treatment after, enter the next one production cycle, the nickel button of production.The nickel button outward appearance of producing evenly, smooth surface, be of close texture.
Embodiment 2
It is substrate that other condition adopts stainless steels with example 1., the nickel button outward appearance of production evenly, smooth surface, be of close texture.

Claims (4)

1. negative plate that is used to produce the nickel button is characterized in that this negative plate is made up of following structure:
Negative plate substrate-this substrate is with stainless steel plate or titanium plate;
Rubber insulation rete-this insulating film layer has the porous insulation rubber rete that is isosceles triangle uniform distribution circular hole on it; The rubber insulation rete sticks on the negative plate substrate with binding agent.
2. a kind of negative plate that is used to produce the nickel button according to claim 1 is characterized in that its rubber insulation rete is the exhausted rubber diaphragm of polymer edge.
3. a kind of negative plate that is used to produce the nickel button according to claim 1 is characterized in that the rubber insulation rete sticked to and uses binding agent to be 903# glue on the negative plate substrate.
4. preparation method who is used to produce the negative plate of nickel button is characterized in that its preparation process is:
A) at first with titanium or stainless steel plate surface finish, polishing, smooth after, clean again, remove surperficial dust and dirt and greasy dirt;
B) even application binding agent on rubber film;
C) punch its isosceles triangle uniform distribution at the rubber film that scribbles binding agent;
D) film after will punching is attached at titanium or stainless steel plate surface, makes the negative plate of producing the nickel button.
CNA2007103036170A 2007-12-20 2007-12-20 Cathode plate used for producing nickel buckle and its production method Pending CN101403124A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2007103036170A CN101403124A (en) 2007-12-20 2007-12-20 Cathode plate used for producing nickel buckle and its production method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007103036170A CN101403124A (en) 2007-12-20 2007-12-20 Cathode plate used for producing nickel buckle and its production method

Publications (1)

Publication Number Publication Date
CN101403124A true CN101403124A (en) 2009-04-08

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CNA2007103036170A Pending CN101403124A (en) 2007-12-20 2007-12-20 Cathode plate used for producing nickel buckle and its production method

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CN (1) CN101403124A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002736A (en) * 2010-12-08 2011-04-06 金川集团有限公司 Method for stripping nickel button
CN102337564A (en) * 2011-10-13 2012-02-01 金川集团有限公司 Electrodeposition electrolytic nickel negative plate
CN103820822A (en) * 2014-02-28 2014-05-28 金川集团股份有限公司 Permanent negative plate for production of nickel button
CN106056761A (en) * 2016-06-20 2016-10-26 湖南科技大学 Mechanical paper currency classification processing device
CN111575744A (en) * 2020-05-26 2020-08-25 中国科学院兰州化学物理研究所 Preparation method of cathode electrolytic polar plate for growing nickel button
CN113061938A (en) * 2021-03-09 2021-07-02 金川集团股份有限公司 Method for producing high-quality nickel button

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002736A (en) * 2010-12-08 2011-04-06 金川集团有限公司 Method for stripping nickel button
CN102002736B (en) * 2010-12-08 2013-03-20 金川集团有限公司 Method for stripping nickel button
CN102337564A (en) * 2011-10-13 2012-02-01 金川集团有限公司 Electrodeposition electrolytic nickel negative plate
CN103820822A (en) * 2014-02-28 2014-05-28 金川集团股份有限公司 Permanent negative plate for production of nickel button
CN103820822B (en) * 2014-02-28 2016-06-08 金川集团股份有限公司 A kind of permanent cathode plate for producing nickel button
CN106056761A (en) * 2016-06-20 2016-10-26 湖南科技大学 Mechanical paper currency classification processing device
CN106056761B (en) * 2016-06-20 2018-10-26 湖南科技大学 A kind of mechanical bank note classification processing unit
CN111575744A (en) * 2020-05-26 2020-08-25 中国科学院兰州化学物理研究所 Preparation method of cathode electrolytic polar plate for growing nickel button
CN113061938A (en) * 2021-03-09 2021-07-02 金川集团股份有限公司 Method for producing high-quality nickel button

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Open date: 20090408