CN104212921B - Thin assorted skin chrome retanned method - Google Patents

Thin assorted skin chrome retanned method Download PDF

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Publication number
CN104212921B
CN104212921B CN201410479162.8A CN201410479162A CN104212921B CN 104212921 B CN104212921 B CN 104212921B CN 201410479162 A CN201410479162 A CN 201410479162A CN 104212921 B CN104212921 B CN 104212921B
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CN
China
Prior art keywords
kilogram
chrome retanned
dried bark
nacl
rotary drum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410479162.8A
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Chinese (zh)
Other versions
CN104212921A (en
Inventor
徐建龙
郑超斌
徐志敏
张江山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING FANBO CHEMICAL Co Ltd
TONGXIANG NEW ERA fur CO Ltd
Original Assignee
BEIJING FANBO CHEMICAL Co Ltd
TONGXIANG NEW ERA fur CO Ltd
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Publication date
Application filed by BEIJING FANBO CHEMICAL Co Ltd, TONGXIANG NEW ERA fur CO Ltd filed Critical BEIJING FANBO CHEMICAL Co Ltd
Priority to CN201410479162.8A priority Critical patent/CN104212921B/en
Publication of CN104212921A publication Critical patent/CN104212921A/en
Application granted granted Critical
Publication of CN104212921B publication Critical patent/CN104212921B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The present invention relates to leather tanning field, especially a kind of thin assorted skin chrome retanned method, the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 35-38 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 2-3 hour, then heat to 43-46 DEG C, then 5-10 minute per hour ground intermittence stirs 8-12 hour, skin can be gone out, dry;This thin assorted chrome retanned method, adopts rotary drum to carry out the chrome retanned of thin assorted skin by the method, decreases the adjustment operation such as pH value, scouring of wool, has saved more water consumption, reduces energy consumption, saves chemical materials, reduce process time, shortens the process-cycle.

Description

Thin assorted skin chrome retanned method
Technical field
The present invention relates to leather tanning field, especially a kind of thin assorted skin chrome retanned method.
Background technology
Fur industry overall technology low SI, the thin assorted skin (more than 95%) of the overwhelming majority is required for through chrome retanned, so the chrome retanned operation output value is big.But in traditional chrome retanned process, the paddle-tumble of employing is as instrument, and the amount of the chemical articles such as the chromium powder used, Nacl, wetting agent is big, also huge with hourly water consumption, and operation is relatively complicated, and energy resource consumption is big.
Existing thin assorted skin is after dried bark adds after paddling 8-12 hour, it is necessary to is adjusted pH value, it is ensured that pH value is about 4, then is warming up to 38 DEG C, continues paddling 6-8 hour, finally go out skin, dry after also need to carry out changing hand washed wool process;Operation relative complex, consumes substantial amounts of water simultaneously, and process time is extremely long, extremely inefficient simultaneously.
Summary of the invention
The invention aims to solve the deficiency of above-mentioned technology and a kind of thin assorted skin chrome retanned method that working (machining) efficiency is high, energy consumption is low, operation is few is provided.
In order to achieve the above object, the thin assorted skin chrome retanned method designed by the present invention, the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 35-38 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 2-3 hour, then heat to 43-46 DEG C, then 5-10 minute per hour ground intermittence stirs 8-12 hour, skin can be gone out, dry;Wherein: the water yield that 1 kilogram of dried bark uses is 3-7 kilogram, the chromium powder amount that 1 kilogram of dried bark uses is 0.09-0.21 kilogram, the Nacl amount that 1 kilogram of dried bark uses is 0.09-0.21 kilogram, the wetting agent that 1 kilogram of dried bark uses is 3-7 milliliter, and the chrome retanned amount of auxiliary that 1 kilogram of dried bark uses is 40 milliliters.
The rotary drum used in technique scheme is the patent No.: 2014201342209, and patent name is: the all-in-one in energy-efficient low emission fur polychromatic dyeing all-in-one.
The thin assorted chrome retanned method that the present invention is obtained, adopts rotary drum to carry out the chrome retanned of thin assorted skin by the method, decreases the adjustment operation such as pH value, scouring of wool, save more water consumption, reduce energy consumption, save chemical materials, reduce process time, shorten the process-cycle;Temperature is maintained at 43-46 DEG C simultaneously, and chromium ion can be promoted better to penetrate into inside hide fiber, more firm with hide fiber protein binding;The method can reduce and puies forward alkali process, it is to avoid carries and occurs in alkali process that chromium ion precipitates the situation being attached on fur, makes retanning process safety and stability more.
Detailed description of the invention
The present invention is further described by the following embodiment.
Embodiment 1:
The thin assorted skin chrome retanned method that the present embodiment describes, the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 35 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 2 hours, then heat to 43 DEG C, then 5 minutes per hour ground intermittences stir 8 hours, skin can be gone out, dry;Wherein: the water yield that 1 kilogram of dried bark uses is 3 kilograms, the chromium powder amount that 1 kilogram of dried bark uses is 0.09 kilogram, the Nacl amount that 1 kilogram of dried bark uses is 0.09 kilogram, and the wetting agent that 1 kilogram of dried bark uses is 3 milliliters, and the chrome retanned amount of auxiliary that 1 kilogram of dried bark uses is 40 milliliters.
Embodiment 2:
The thin assorted skin chrome retanned method that the present embodiment describes, the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 38 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 3 hours, then heat to 46 DEG C, then 10 minutes per hour ground intermittences stir 12 hours, skin can be gone out, dry;Wherein: the water yield that 1 kilogram of dried bark uses is 7 kilograms, the chromium powder amount that 1 kilogram of dried bark uses is 0.21 kilogram, the Nacl amount that 1 kilogram of dried bark uses is 0.21 kilogram, and the wetting agent that 1 kilogram of dried bark uses is 7 milliliters, and the chrome retanned amount of auxiliary that 1 kilogram of dried bark uses is 50 milliliters.
Embodiment 3:
The thin assorted skin chrome retanned method that the present embodiment describes, the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 36 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 2.5 hours, then heat to 45 DEG C, then 8 minutes per hour ground intermittences stir 10 hours, skin can be gone out, dry;Wherein: the water yield that 1 kilogram of dried bark uses is 5 kilograms, the chromium powder amount that 1 kilogram of dried bark uses is 0.15 kilogram, the Nacl amount that 1 kilogram of dried bark uses is 0.16 kilogram, and the wetting agent that 1 kilogram of dried bark uses is 5 milliliters, and the chrome retanned amount of auxiliary that 1 kilogram of dried bark uses is 45 milliliters.
Two kinds of technology consume contrast table

Claims (1)

1. a thin assorted skin chrome retanned method, is characterized in that: the retanning equipment of use is rotary drum;In rotary drum, first add water, chromium powder, Nacl, wetting agent, chrome retanned auxiliary agent, temperature controls at 35-38 DEG C, then chromium powder, Nacl, wetting agent are stirred in water, add dried bark, continuously stirred 2-3 hour, then heat to 43-46 DEG C, then 5-10 minute per hour ground intermittence stirs 8-12 hour, skin can be gone out, dry;Wherein: the water yield that 1 kilogram of dried bark uses is 3-7 kilogram, the chromium powder amount that 1 kilogram of dried bark uses is 0.09-0.21 kilogram, the Nacl amount that 1 kilogram of dried bark uses is 0.09-0.21 kilogram, the wetting agent that 1 kilogram of dried bark uses is 3-7 milliliter, and the chrome retanned amount of auxiliary that 1 kilogram of dried bark uses is 40-50 milliliter.
CN201410479162.8A 2014-09-19 2014-09-19 Thin assorted skin chrome retanned method Expired - Fee Related CN104212921B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410479162.8A CN104212921B (en) 2014-09-19 2014-09-19 Thin assorted skin chrome retanned method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410479162.8A CN104212921B (en) 2014-09-19 2014-09-19 Thin assorted skin chrome retanned method

Publications (2)

Publication Number Publication Date
CN104212921A CN104212921A (en) 2014-12-17
CN104212921B true CN104212921B (en) 2016-06-29

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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831512B (en) * 2009-03-13 2013-09-18 上海喜若飞精细化工有限公司 Retaining agent with compound function and preparation method thereof
CN102586509A (en) * 2011-12-31 2012-07-18 河北东明皮革有限公司 Tanning method of sheep skins
CN103103296B (en) * 2012-11-09 2015-10-07 际华三五一五皮革皮鞋有限公司 The method of tear strength of leather is improved without deashing and softening
CN103088168A (en) * 2013-01-25 2013-05-08 陕西科技大学 Process for circularly tanning cowhide sofa leather by using waste liquor for pickling without bath salt
CN103290151B (en) * 2013-06-19 2015-05-13 海宁瑞星皮革有限公司 Method for preparing leather by using chromium-free retanning agent

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