CN104211895B - Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof - Google Patents
Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof Download PDFInfo
- Publication number
- CN104211895B CN104211895B CN201410477866.1A CN201410477866A CN104211895B CN 104211895 B CN104211895 B CN 104211895B CN 201410477866 A CN201410477866 A CN 201410477866A CN 104211895 B CN104211895 B CN 104211895B
- Authority
- CN
- China
- Prior art keywords
- resistant
- parts
- floor material
- flame
- wear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4812—Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
- C08G18/7642—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The invention relates to a flame-retardant wear-resistant pressure-resistant polyurethane floor material and a preparation method thereof. The polyurethane floor material comprises the following components in parts by weight: 18-40 parts of polyether dibasic alcohol, 13-25 parts of polyether tribasic alcohol, 8-30 parts of polyisocyanate, 6-12 parts of ammonium polyphosphate, 3-10 parts of melamine, 2-8 parts of pentaerythritol and 0.3-1 part of dibutyltin dilaurate. The preparation method comprises the following steps: mixing the polyether dibasic alcohol and polyether tribasic alcohol according to the formula, adding the ammonium polyphosphate, melamine and pentaerythritol, and continuing mixing; and adding the polyisocyanate and dibutyltin dilaurate into the uniform mixture, and continuing mixing uniformly to obtain the flame-retardant wear-resistant pressure-resistant polyurethane floor material. The flame-retardant wear-resistant pressure-resistant polyurethane floor material has the advantages of accessible raw materials, simple preparation method and environment friendliness. Compared with the double-component polyurethane floor material, the flame-retardant wear-resistant pressure-resistant polyurethane floor material has favorable flame retardancy, wear resistance and pressure resistance, and can obviously improve the use effect of the floor paint.
Description
Technical field
The present invention relates to polyurethane terrace material preparing technical field, and in particular to a kind of wear-resisting pressure polyurethane of flame retardant type
Floor material and preparation method thereof.
Background technology
At present, the polyurethaness floor material for producing on market is bi-component air-curing coatings, by elastic polyurethane
Prepolymer first component and mixed the second component for constituting by hydroxy-containing resin component and pigment, auxiliary agent etc. and constituted, during construction by first,
Second component is mixed in proportion, crosslinking coatings film-forming after application, the resilient colour ground film of tool is formed, with excellent
Elasticity, adhesive force and wearability, are that senior machine room, laboratory, stadiums, ultra-clean Factory Building, and meeting room, cinema etc. are each
Plant and require the resilient industry of tool and the good selection of civil buildings ground coating.But, this kind of bi-component polyurethane esters ground
Coating coating in level ground is inflammable product, there is larger disaster hidden-trouble, is particularly useful for flooring, need before construction accurate measurement and
Burden process, using inconvenience, abnormal smells from the patient is big.
CN 1765950A disclose a kind of polyurethane elastomer for sports field and preparation method thereof, by following elasticity
Body first component, second component and the third component composition, wherein first component are 1 with the weight ratio of second component:2-1:4, the percentage of the third component
Than with the gross weight meter of first, second component, wherein first component is consisted of:Methyl diphenylene diisocyanate, polyether Glycols, illiteracy are de-
Soil；Second component is consisted of:Polyether-tribasic alcohol, 3,5 dichloros are to trifluoromethyl ethyl phenyl ether, chlorinated paraffin, Pulvis Talci, calcium oxide, ferrum
Red or lemon yellow-phthalocyanine green mixture, pentachlorophenol；Third component is consisted of:Waste rubber grain, metallic catalyst.
CN 102134442A disclose a kind of compound method of single-component flame retardant polyurethane floor coating, and this method includes
Raw material ratio and production technology.
Polyurethane terrace material of the prior art is difficult to accomplish that the various aspects of performance such as anti-flammability, wearability, resistance to pressure are equal
It is very excellent.
The content of the invention
It is an object of the invention to provide wear-resisting pressure polyurethane terrace material of a kind of flame retardant type and preparation method thereof.
It is that, up to this purpose, the present invention is employed the following technical solutions：
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
The parts by weight of the polyether Glycols may be selected 18.02~38.9,19.6~35,21~32.5,26~30,
28.5 etc., all can be used to implement the present invention.
The parts by weight of the polyether-tribasic alcohol may be selected 13.02~24.8,15~22.4,16.8~20,19.5 etc., all
Can be used to implement the present invention.
The parts by weight of the polyisocyanates may be selected 8.03~28.9,10~26,13~24.7,16~22,18.6
Deng, all can be used for implement the present invention.
The parts by weight of the APP may be selected 6.03~11.8,6.7~10.4,7.3~9,8.4 etc., all can use
It is of the invention in implementing.
The parts by weight of the tripolycyanamide may be selected 3.04~9.6,3.6~9,5~8.4,5.6~8,6.3~7,6.8
Deng, all can be used for implement the present invention.
The parts by weight of the tetramethylolmethane may be selected 2.03~7.9,2.6~7,3.5~6.4,4~6,5.3 etc., all may be used
For implementing the present invention.
The parts by weight of the dibutyl tin laurate may be selected 0.31~9.9,0.8~9.2,1.5~8.6,3~8,
4.3~6.5,5~6,5.2 etc., all can be used to implement the present invention.
The present invention is respectively the poly- of catalyst, carbon forming agent and foaming agent using polyphosphoric acid amine, tripolycyanamide and tetramethylolmethane
The flame-retardant system of urethane floor material, makes coating have good fire resistance.
The polyether Glycols are polyoxypropylene dihydroxylic alcohols.
The polyether-tribasic alcohol is glycerol polyoxypropylene.
The polyisocyanates includes toluene di-isocyanate(TDI), methyl diphenylene diisocyanate, the Carbimide. of 1,5- naphthalenes two
Ester, XDI, 3,3 '-dimethyl -4,4- biphenyl diisocyanates, triphenylmethane triisocyanate or
One kind or at least two mixture in PPDI.Typical but non-limiting example includes：Toluene diisocyanate
Acid esters, methyl diphenylene diisocyanate, 1,5- naphthalene diisocyanate, XDI, 3,3 '-dimethyl-
4,4- biphenyl diisocyanates, XDI and 3,3 '-dimethyl -4,4- biphenyl diisocyanates, triphen
Methylmethane triisocyanate and PPDI, toluene di-isocyanate(TDI), methyl diphenylene diisocyanate and 1,5- naphthalene
Diisocyanate, 1,5- naphthalene diisocyanate, XDI, PPDI and diphenyl methane two
Isocyanates etc., all can be used to implement the present invention.
Used as the preferred technical solution of the present invention, the polyurethane terrace material includes by weight following component：
Used as most preferably technical scheme of the invention, the polyurethane terrace material includes by weight following component：
" including " of the present invention, it is intended that it can also include other components, these other components in addition to the component
Give the polyurethane terrace material different characteristics.In addition, " including " of the present invention, may be replaced by closing
" being " of formula or " by ... constitute ".
A kind of preparation method of described polyurethane terrace material, the method comprising the steps of：
1) APP, tripolycyanamide and season will be added after polyether Glycols and polyether-tribasic alcohol stirring mixing by formula ratio
Penta tetrol continues to mix；
2) to step 1) in add polyisocyanates and dibutyl tin laurate in the material that stirs, continue to stir
Mix homogeneously obtains the wear-resisting pressure polyurethane terrace material of flame retardant type.
Compared with prior art scheme, the invention has the advantages that：
The wear-resisting pressure polyurethane terrace material raw material of flame retardant type of the present invention is easy to get, and preparation method is simple, the feature of environmental protection
It is good, compared with existing two component polyurethane floor material, with good anti-flammability, wearability and resistance to pressure, can substantially change
Kind polyurethaness floor coatings using effect.
Below the present invention is described in more detail.But following examples is only the simple example of the present invention, not generation
Table limits the scope of the present invention, and protection scope of the present invention is defined by claims.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
For the present invention is better described, technical scheme is readily appreciated, the present invention's is typical but non-limiting
Embodiment is as follows：
Embodiment 1
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
1) APP, tripolycyanamide and season will be added after polyether Glycols and polyether-tribasic alcohol stirring mixing by formula ratio
Penta tetrol continues to mix；
2) to step 1) in add polyisocyanates and dibutyl tin laurate in the material that stirs, continue to stir
Mix homogeneously obtains the wear-resisting pressure polyurethane terrace material of flame retardant type.
Embodiment 2
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
Its preparation method is with embodiment 1.
Embodiment 3
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
Its preparation method is with embodiment 1.
Embodiment 4
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
Its preparation method is with embodiment 1.
Embodiment 5
A kind of wear-resisting pressure polyurethane terrace material of flame retardant type, the polyurethane terrace material includes by weight following
Composition：
Its preparation method is with embodiment 1.
Comparative example
Using the embodiment disclosed in CN 102134442A as comparative example of the invention.
It is right that the anti-flammability of embodiment of the present invention 1-5 and comparative example, wearability and resistance to pressure test result are carried out in table 1
Than.
The performance comparison table of each embodiment of table 1 and comparative example
Applicant state, person of ordinary skill in the field on the basis of above-described embodiment, by above-described embodiment
The concrete content point value of component, it is combined with the technical scheme of Summary, so as to the new numerical range for producing, be also
One of record scope of the present invention, the application no longer enumerates these numerical rangies to make description simple and clear.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, the present invention range of the technology design in, various simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The compound mode of energy is no longer separately illustrated.
Additionally, combination in any can also be carried out between a variety of embodiments of the present invention, as long as it is without prejudice to this
The thought of invention, it should equally be considered as content disclosed in this invention.
Claims (2)
1. the wear-resisting pressure polyurethane terrace material of a kind of flame retardant type, it is characterised in that the polyurethane terrace material is by weight
Number includes following component：
2. a kind of preparation method of polyurethane terrace material as claimed in claim 1, it is characterised in that methods described include with
Lower step：
1) APP, tripolycyanamide and season penta 4 will be added after polyether Glycols and polyether-tribasic alcohol stirring mixing by formula ratio
Alcohol continues to mix；
2) to step 1) in add polyisocyanates and dibutyl tin laurate in the material that stirs, continue to stir mixing
Uniformly obtain the wear-resisting pressure polyurethane terrace material of flame retardant type.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410477866.1A CN104211895B (en) | 2014-09-18 | 2014-09-18 | Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410477866.1A CN104211895B (en) | 2014-09-18 | 2014-09-18 | Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104211895A CN104211895A (en) | 2014-12-17 |
| CN104211895B true CN104211895B (en) | 2017-05-17 |
Family
ID=52093826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410477866.1A Active CN104211895B (en) | 2014-09-18 | 2014-09-18 | Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104211895B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106639236B (en) * | 2016-11-28 | 2019-02-26 | 河南同伟建材有限公司 | A kind of elastic brick and preparation method thereof for accomodation ground |
| CN107057022A (en) * | 2017-03-31 | 2017-08-18 | 苏州铂邦胶业有限公司 | A kind of novel flexible gravity flowing levelling mortar terrace and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005033232A1 (en) * | 2003-10-02 | 2005-04-14 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e. V. | Composition for a fire-protection agent for materials and fire-protection method |
| CN102585293B (en) * | 2011-01-14 | 2013-10-16 | 中国林业科学研究院木材工业研究所 | Flame retardant, and preparation method and application thereof |
| CN103980810A (en) * | 2014-05-19 | 2014-08-13 | 上海正欧实业有限公司 | Waterproof solvent-free single-component polyurethane lacquer used on wet surface and preparation method thereof |
-
2014
- 2014-09-18 CN CN201410477866.1A patent/CN104211895B/en active Active
Non-Patent Citations (2)
| Title |
|---|
| 聚氨酯复合材料的研究;康永等;《PU技术》;20101231(第101期);第64-66页 * |
| 聚醚N220、N330 的合成条件研究;钱亚杰;《天津化工》;20081231;第22卷(第4期);第46-47页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104211895A (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102775900B (en) | Water curing asphalt polyurethane composite waterproof coating and preparation method thereof | |
| EP1098862B1 (en) | Use of aqueous polyurethane dispersions in formulations for sports floor coverings | |
| EP3006524A1 (en) | Urethane composition for coating film waterproof material | |
| CN107586510B (en) | Preparation method of corrosion-resistant polyurethane modified epoxy resin emulsion | |
| DE102006011153A1 (en) | Fluoromodified additive for cementitious products, process for its preparation and its use | |
| WO2008000831A1 (en) | Voc-free or voc-poor polyurethane coating | |
| CN101805436A (en) | Bi-component reaction-type flame-retardant waterborne polyurethane and preparation method thereof | |
| EP2265653A1 (en) | Curable compounds comprising color indicators for displaying the curing progress | |
| CN110452610A (en) | A kind of epoxy resin modification monocomponent polyurethane water proof anti-corrosive paint and preparation method | |
| CN104559735A (en) | Single-component reactive thixotropic polyurethane waterproof paint and preparation method thereof | |
| CN104211895B (en) | Flame-retardant wear-resistant pressure-resistant polyurethane floor material and preparation method thereof | |
| JP2019199545A (en) | Resin composition, cured product, civil engineering and construction structure, and coating method | |
| CN105001776A (en) | Self-emulsifying type water curing environment-friendly polyurethane waterproof paint | |
| DE19732313A1 (en) | Polyurethane resin composition curable at room temperature, is useful as rapidly curing waterproof coating material | |
| CN104004394B (en) | A kind of expandable flame retardant type double-component waterborne polyurethane wood lacquer | |
| JP2019199544A (en) | Resin composition, cured product, civil engineering and construction structure, and coating method | |
| CN109912767A (en) | A kind of polyurethane sealant composition, gap-filling glue and preparation method thereof | |
| CN101418185A (en) | Polyurethane sound absorption coating composite and preparation method thereof | |
| DE3915426A1 (en) | METHOD FOR PRODUCING HIGH-ELASTIC, CHEMICAL-RESISTANT POLYURETHANE AND COATINGS | |
| JP2019199541A (en) | Resin composition, method for producing resin composition, cured product, civil engineering and construction structure, and coating method | |
| WO2013120719A1 (en) | Antistatic flooring composition | |
| JP2015151492A (en) | Two component environment-friendly urethane waterproof material composition | |
| JPH0232113A (en) | Application material containing bitumen | |
| CN109266193A (en) | A kind of fire-retardant single-component polyurethane water-proof paint and preparation method thereof | |
| JP4098914B2 (en) | Room temperature curing polyurethane resin paving material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: He Jianxiong Inventor after: Wang Yiliang Inventor before: He Jianxiong Inventor before: Wang Yiliang |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |