CN1042104C - Zirconium silicate grinding medium and method of milling - Google Patents
Zirconium silicate grinding medium and method of milling Download PDFInfo
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- CN1042104C CN1042104C CN95190048A CN95190048A CN1042104C CN 1042104 C CN1042104 C CN 1042104C CN 95190048 A CN95190048 A CN 95190048A CN 95190048 A CN95190048 A CN 95190048A CN 1042104 C CN1042104 C CN 1042104C
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C17/00—Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
- B02C17/18—Details
- B02C17/20—Disintegrating members
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C23/00—Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
- B02C23/18—Adding fluid, other than for crushing or disintegrating by fluid energy
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- Disintegrating Or Milling (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
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Abstract
A grinding medium including naturally occurring zirconium silicate sand characterized by a density in the range of from about 4 g/cc absolute to about 6 g/cc absolute is provided. Also provided is a method for milling a powder which includes steps of forming a milling slurry including a naturally occurring zirconium silicate sand grinding medium having a density in the range of from about 4 g/cc absolute to about 6 g/cc absolute.
Description
Background of invention
1 invention field
The present invention relates to grinding medium, more particularly relate to Zirconium silicate grinding medium and method of milling.
2 prior aries
Many application, as: the manufacturing of ceramic component, the manufacturing of magnetic medium and the manufacturing of coating all need in each specific application ceramic powder, magnetic powder or colorant powder to be dispersed in the suitable special tackiness agent as far as possible up hill and dale respectively.The parts that the ceramic component made from the ceramic powder of high dispersing is made than the thorough dispersed solids of those origin have higher density and intensity.The data storage capacity of magnetic medium is limited by particle size, and thoroughly the Powdered magnetic medium of dispersive, fine segmentation can cause maximum information storage.The optical property of coating, as hiding power, brightness, color and weather resistance, mainly be fixed against colorant degree of scatter extremely.Have only the powder of fine segmentation just can reach such dispersity of powder completely.Generally, as disc type grinding machine, squirrel cage mill and or the grinding plant of masher and the powder that grinding medium is used for producing fine segmentation like this together, it is desirable to powder is cut apart to the final cutting state as monocrystal.
The grinding of these powder relates to the process of a depolymerization, chemical bond in this process, as with the surface moisture of hydrogen bonding, as intergranular Van der Waals force and electrostatic force, reach other and make particle aggregation key together, all must be interrupted and/or overcome, to obtain being in the particle of final cutting state.Must pass through the process of lapping of depolymerization so that its colorant powder of reducing to the fine segmentation pulverulence is a titanium dioxide.The titanium dioxide colorant of optimum dispersion can cause optimized performance, has particularly improved gloss, weather resistance and hiding power.
Separate collecting process and preferably implement when using grinding medium, this grinding medium is characterised in that its particle size is very little, only is the minimum multiple of the physical size of the product particle that will grind, and can be in fact and the product powder separation.In a successive processes, grinding medium can separate with product particle by the density separation technology.In normally used pearl mill of successive processes institute or sand milling, can realize the separation between them by the difference of the subsidence rate, particle size or both parameters that exist between grinding medium and the product powder particle.
It is grinding medium that the coml measure of grinding is adopted usually as quartz sand, granulated glass sphere, ceramic dielectic or steel ball.Wherein, the density of quartz sand and granulated glass sphere is very low, has only 2.6g/cc, the hardness of granulated glass sphere is very low again, and this has just limited the material that can grind with quartz sand and granulated glass sphere.The use of small ball can only be limited in the situation that the iron pollution that is produced by the abrasion of small ball in the process of lapping can allow.
Therefore, just needs are a kind of cheaply, density is high and avirulent grinding medium, and this grinding medium is characterised in that particle size is little, are enough to reach the high-density of separating purpose, so just can be used to grind the material of relative broad range, and can not produce the abrasion by product that causes the product powder to pollute.
The present invention's general introduction
One object of the present invention is to provide a kind of silicic acid zircon sand grinding medium that generates naturally.
Another object of the present invention is to provide a method with the silicic acid zircon sand grinding medium abrasive flour that generates naturally.
The invention provides a kind of relatively cheap, density is high and the avirulent silicic acid zircon sand grinding medium that generates naturally, this media particle size is little, has the high-density that is enough to be suitable for grinding the wide region material, and its abrasion by product is the polluted product powder not, and the method for coming abrasive flour with this grinding medium.
According to an aspect of the present invention, the silicic acid zircon sand that generates naturally that is provided is characterised in that its density range is at about 4g/cc (definitely) extremely between about 6g/cc (definitely), preferred scope be at about 4.6g/cc (definitely) between about 4.9g/cc (definitely), most preferred scope is at about 4.75g/cc (definitely) extremely between about 4.85g/cc.
Another aspect of the present invention provides a kind of method of abrasive flour, this method may further comprise the steps: the silicic acid zircon sand grinding medium that initial powder is provided and generates naturally, described initial powder is characterised in that particle size, the density that described Zirconium silicate grinding medium and method of milling is characterised in that grinding medium, is mixed described initial powder and grinding medium to form a kind of slurry between about 6.0g/cc (definitely) then at about 4.0g/cc (definitely) with liquid medium; Grind this slurry to the sufficiently long time, with generation comprise product powder with required product powder particle size and haply with the product slurry of initial powder same composition, product slurry is separated from slurry.
Other and further purpose of the present invention, feature and advantage, those skilled in the art will be conspicuous by reading the explanation of following preferred enforcement.The explanation of preferred embodiment
In specification sheets and in the claim, the implication of term " naturally generate " is exploited out with the form of the silicic acid zircon sand of specific particle size for silicic acid zircon sand, in order to distinguish zirconium silicate material synthetic, manufacturing or that other manual method obtains.Silicic acid zircon sand grinding medium of the present invention is born in nature with suitable size and shape, but so just sorting obtains being used for the suitable silicic acid zircon sand of specific grinding operation partly as grinding medium.In this specification and claims book, term " grinding medium " is meant with being ground carefullyyer or the powder of depolymerization is put into material as the grinding plant of disc type grinding machine, squirrel cage mill or masher, pass on the just processed powder in order to shearing force, with broken particles of powder grinding plant.
The invention provides a kind of grinding medium that contains the silicic acid zircon sand of nature generation, it is characterized in that, between about 6g/cc, preferable range is 4.6g/cc to 4.9g/cc to its density range at about 4g/cc, and most preferred scope is between 4.75g/cc to 4.85g/cc.
Naturally the silicic acid zircon sand of Sheng Chenging is tending towards monophasic, and the general heterogenetic of synthetic Zirconium silicate ceramic pearl.Surface contaminant such as aluminium, iron, uranium, thorium and other heavy metals and titanium dioxide is arranged on the surface of the zirconium silicate particles that generates naturally.In case these surface contaminants are by process for surface preparation known to those skilled in the art, as cleaning and gradation, can be removed, chemical analysis shows that then residual pollutent is can play disadvantageous effect to wanting polished powder in the zirconium silicate crystalline structure and not.
As mentioned above, naturally the density of the silicic acid zircon sand of Sheng Chenging has surpassed the general feature density 3.8g/cc of the zirconium silicate pearl of making, so the silicic acid zircon sand that generates naturally that particle size is also littler than the size of the zirconium silicate pearl of making grinds to be situated between and still can use, and silicic acid zircon sand is floated on the slurry, lost effect as grinding medium.
Silicic acid zircon sand grinding medium is characterised in that its particle size only is the finished product particle size, the minimum multiple of a powder size of the product powder of grinding, and can from the abrasive product powder, separate effectively.Generally speaking, the particle size of the silicic acid zircon sand of Sheng Chenging is greater than 100 microns naturally, can about 100 microns between about 1500 micrometer ranges, preferable range is between about 100 microns to about 500 microns, optimized scope is between about 150 microns to about 250 microns.The silicic acid zircon sand that generates naturally that exploitation is come out can sieve by method well-known to those skilled in the art, sub-elect be used as effective grinding medium have a suitable dimension particulate coarse sand part.
Grinding medium can be any and abrasive product and the suitable liquid medium of Ginding process, can comprise water, oil, any other organic compound or their mixture, and can be used in combination to form slurry with the silicic acid zircon sand that generates naturally.Liquid medium is selected according to the product that will grind.After process of lapping was finished, the product powder of grinding can not separate from liquid medium yet, but grinding medium will be separated from liquid medium after process of lapping is finished usually.
If the powder that grinds is to be used for the coating of oil base or the colorant of printing ink, this liquid medium can be isolating grease from nature so, as: tung oil, linseed oil, Oleum Glycines or Yatall MA or their mixing.More than these greases that generate naturally can mix with solvent phase, as petroleum spirit, petroleum naphtha or toluene or their mixture, this solvent also further comprises following material, as natural gum, resin, dispersion agent and/or siccative.Liquid medium can comprise that also other are used to make the material of oil-based paint and printing ink, as Synolac, Resins, epoxy, nitre benzylcellulose, three polyoxies (acyl) amine, aminobenzoic acid ester and siloxanes.
If the powder that grinds is to be used for water-based paint, as: the colorant in the emulsion paint, this liquid medium can be water, optionally comprises foam preventer and/or dispersion agent.If powder is pottery or magnetic powder, this medium also can be water, and also can comprise dispersion agent.
Naturally the silicic acid zircon sand of Sheng Chenging can be united use to form slurry with liquid medium, this slurry is further characterized in that: its viscosity at about 1.0cps to about 10, between the 000cps, between about 500cps, most preferred range is at about 1.0cps extremely between about 100cps at about 1.0cps for preferable range.Generally, the viscosity of slurry is decided according to solid concentration in the slurry, and therefore, solid concentration is high more in the slurry, and the viscosity of slurry and density are just big more.For the viscosity of slurry, do not have the absolute upper limit, but under the situation that does not need grinding medium, as when being used for plastics extruder blended plastics, barreling etc. and not having grinding medium, its viscosity can reach a peak dot.
The present invention provides the method for an abrasive flour simultaneously, and this method may further comprise the steps: the initial powder that is of a size of feature with an initial powder material is provided; The grinding medium of the silicic acid zircon sand that comprises that nature generates is provided, it is characterized in that, the density of grinding medium is at about 4.0g/cc (definitely) extremely between about 6.0g/cc (definitely) scope; Liquid medium is provided; Initial powder is mixed with liquid medium, to form slurry; Grind this slurry to the sufficiently long time, comprise the product powder and the product slurry of the component identical with initial powder in a large number with generation, the described product powder of liquid is characterised in that to have required product powder particle size; The product slurry that will comprise the product powder is separated from slurry then.
Used initial powder can be a powder agglomerant and/or that gather in the method for the present invention.Agglomerant powder is characterised in that agglomerant powder particle size less than 500 microns, and preferable range is between about 0.01 micron to 200 microns.With titanium dioxide colorant powder is example, the particle size of its agglomerating powder about 0.05 micron between 100 micrometer ranges, it just can be milled to the particle size near single titanium dioxide crystal like this.
The feature of initial powder also is, its density range at about 0.8g/cc (definitely) between about 5.0g/cc (definitely).Method of the present invention is suitable for generally having in the above-mentioned scope organic dust than low value density, and inorganic powder, as titanium dioxide, lime carbonate, wilkinite or kaolin or their mixture.The titanium dioxide initial powder can be agglomerant titanium dioxide colorant, its density range at about 3.7g/cc between about 4.2g/cc.
The feature of the used silicic acid zircon sand that generates naturally also can be in the method for the present invention, the particle size of silicic acid zircon sand is greater than about 100 microns, can be between about 100 microns to about 1500 microns, preferable range is between about 100 microns to about 500 microns, and most preferred range is between about 150 microns to about 250 microns.
Liquid medium used in the method for the present invention can be selected grease or water for use according to aforesaid standard.
The grinding step in the 5th step can be in any use finish in the grinding plant of grinding medium, for example: but be not limited only to this, ball mill, squirrel cage mill, disc type grinding machine or pin type grinding machine (pin mill) all can be used to hold in the palm and carry longitudinally or horizontal slurry stream.Ginding process is batch-wise or successive.
The 6th step product slurry isolating operation from slurry can be finished by the following method: the difference that exists between the physical properties according to the physical properties of initial powder and grinding medium and product powder, as particle size, pellet density and particles settling speed, the product slurry that will contain product powder and liquid medium is told from slurry.As described in being, the product powder can or can be not after grinding step is finished from liquid matter he from coming out; But after grinding step was finished, slurry normally will be separated with liquid medium.The product powder can be told from product slurry, and is applied in the further operation, as powder being dispersed in the dispersion medium to form dispersion system.According to this dispersion system is coating or the printing ink or water base coating or the ink or powder pottery or magnetic of oil base, and dispersion medium can be according to choosing with the above-mentioned identical standard of liquid medium of selecting for use.If the product powder will use, then no longer want further dispersion step in product slurry.
By following examples, the present invention is further illustrated.The special compound, method and the condition that are used for these embodiment only are used for illustrating the present invention, this non-limitation ot it.
Embodiment 1
That following examples are used for is the comparison routine, commercially available, the performance between 10-40 order (U.S.) quartz sand of synthetic Zirconium silicate ceramic pearl grinding medium and standard.
At normal abrasive chamber capacity is that 275 gallons and total volume are in 500 sand mills that add, be respectively charged into nominal size and be 3000 pounds on the synthetic silicic acid zircon ceramic pearl of 300 microns and 210 microns, and the quartz sand of 1200 pounds standard 0-40 order (U.S.), the grinding machine of peak capacity is suitable for loading quartz sand.The grinding machine that the grinding machine of 300 pounds of synthetic Zirconium silicate ceramic pearls is housed and 1200 pounds of 10-40 orders (U.S.) quartz sand is housed all moves under the flow velocity of 16 gallons, 23 gallons and 30 gallons per minutes respectively.The density that enters into the feed slurry of all grinding machines is 1.35g/cc, and contains titanium dioxide, and the size of about 4% titanium dioxide in water is less than 0.6 micron.The size of the titanium dioxide granule in the product slurry can be passed through Leeds﹠amp; The Microtrac of 9200 types of Northrupp
TMThe grain size analysis instrument is that tensio-active agent is measured in water with 0.2% Sodium hexametaphosphate 99 at room temperature.The results are shown in Table 1, it is expressed as with size and is less than or equal to the mill efficiency of the synthetic silicic acid zircon ceramic that 0.5 micron the shared percentage of product powder recently represents and the comparison of 10-40 order (U.S.) quartz sand mill efficiency.
Table 1
| Grinding machine | Flow velocity (gpm) | Grinding medium | % product≤0.5 micron |
| A | 30 | 300 microns synthetic silicic acid zircon ceramic pearl | 66.57 |
| B | 30 | 300 microns synthetic silicic acid zircon ceramic pearl | 64.42 |
| A | 23 | 300 microns synthetic silicic acid zircon ceramic pearl | - |
| Grinding machine | Flow velocity (gpm) | Grinding medium | % product≤0.5 micron |
| B | 23 | 300 microns synthetic silicic acid zircon ceramic pearl | 70.41 |
| A | 16 | 300 microns synthetic silicic acid zircon ceramic pearl | 79.96 |
| B | 16 | 300 microns synthetic silicic acid zircon ceramic pearl | 71.26 |
| A | 30 | 210 microns synthetic silicic acid zircon ceramic pearl | 85.29 |
| B | 30 | 210 microns synthetic silicic acid zircon ceramic pearl | 74.72 |
| A | 23 | 210 microns synthetic silicic acid zircon ceramic pearl | 91.51 |
| B | 23 | 210 microns synthetic silicic acid zircon ceramic pearl | 83.11 |
| A | 16 | 210 microns synthetic silicic acid zircon ceramic pearl | 95.22 |
| B | 16 | 210 microns synthetic silicic acid zircon ceramic pearl | 95.22 |
| A | 30 | 10-40 order (U.S.) quartz sand | 65.17 |
| B | 30 | 10-40 order (U.S.) quartz sand | 54.28 |
| A | 23 | 10-40 order (U.S.) quartz sand | 61.96 |
| B | 23 | 10-40 order (U.S.) quartz sand | 57.76 |
| A | 16 | 10-40 order (U.S.) quartz sand | 67.09 |
| B | 16 | 10-40 order (U.S.) quartz sand | 59.48 |
Say that further the character of the colorant that will be machined by 210 microns Zirconium silicate ceramic pearls is compared with the character of the colorant of being handled by quartz sand, will find that the character of the colorant of being finished dealing with by quartz sand has many raisings.These raisings comprise that the break time shortens 57% approximately, the time of this timing definition for colorant is mixed Synolac; It is about 42% that denseness reduces, and mixes in case this denseness is defined as colorant, stirs the required moment of phthalic resin coating system; B235 semi-gloss (semi-gloss) increases about 6 units, and this semi-gloss is defined as 60 degree gloss in the emulsion paint system; B202H turbidity about 12 units that descend, this turbidity is defined as the relative depth of the image that can feel from coating surface; The B202 glossiness improves 2 units approximately, and this glossiness is defined as coating and the reflected light that acrylic resin makes and is determined as 20 degree.
Notice that owing to the silicic acid zircon sand grinding medium that generates naturally has high-density and monophasic microstructure the colorant powder of producing with it has the better character of colorant powder of producing than the synthetic silicic acid zircon ceramic pearl of using as previously discussed.
Embodiment 2
Embodiment 2 is the character of comparison synthetic silicic acid zircon ceramic pearl and the performance of the silicic acid zircon sand medium that generates naturally of the present invention.Notice, naturally the silicic acid zircon sand of Sheng Chenging has the bigger density of 3.8g/cc density than synthetic silicic acid zirconium product, like this, compares with the particle size of synthetic silicic acid zirconium product, the silicic acid zircon sand particle that generates naturally of smaller szie can be used, higher mill efficiency can be provided whereby.
In squirrel cage mill, use the shop trial of the silicic acid zircon sand grinding medium that naturally generate of particle size range between 180-210 is little to show, can be successfully under product flow rate remove in titanium dioxide colorant particle size greater than 0.5 micron coarse grain with the silicic acid zircon sand of generation naturally.Not observing has tangible medium to run off in the grinding machine.
Embodiment 2 realizes by conversion flow velocity in the grinding machine C that conventional quartz sand grinding machine B and the silicic acid zircon sand that the nature generation is housed are housed.Be contained in used similar of the sand of grinding machine B and grinding machine C and embodiment 1, promptly 1200 pounds stone sand is contained among the grinding machine B, and 3000 pounds the silicic acid zircon sand that generates naturally is contained among the grinding machine C.Sample obtains from two sand mills simultaneously.The grinding machine charging also will be taken a sample, with the variation of the particle size of the charging of measuring any particle size.
The particle size data that table 2 provided show, when low flow velocity (about 13 gpms) or high flow rate (about 35 gpms), compare with the effect of conventional quartz sand, and the silicic acid zircon sand of Sheng Chenging can both more effectively reduce particle size naturally.
Continuously after operation for some time, from the overflow sampling of two grinding machines, to measure the optical property and the pollution condition of colorant.
Detect colorant solid in the grinding machine overflow through XRF, the pollution of the colorant product of being made by the silicic acid zircon sand grinding medium of generation naturally is extremely low.The same level of the metal pollutant of measuring through XRF is to viewed similar in the colorant that uses conventional quartz sand grinding medium to grind.Optical property with B381 dry color and brightness test determination by the colorant of the zirconium silicate sand milling system that generates naturally, equally matched with the character of the sample gained that uses conventional quartz sand to grind, said B381 dry color and brightness test are defined as light summation and catoptrical spectrum, the i.e. color by the reflection of powder solid surface.These tests the results are shown in Table 3.
Table 2
The pigment granules dimensional data
| Parameter | Grinding machine B | Grinding machine C |
| Flow velocity (gpm) | 13.2 | 13.2 |
| Me average particulate diameter leter | 0.37 | 0.24 |
| Particulate fraction less than 0.5 micron | 86.94 | 99.55 |
| Flow velocity (gpm) | 35.2 | 35.2 |
| Average particulate diameter | 0.38 | 0.37 |
| Particulate fraction less than 0.5 micron | 75.64 | 87.55 |
Ta table 3
The chemical ingredients of colorant and optical property
| Character | Grinding machine B | Grinding machine C |
| ％Al 2O 3 | 0.71 | 0.72 |
| ％ZrO 2 | 0.01 | 0.01 |
| ％Calgon | 0.06 | 0.06 |
| Fe ppm | 35 | 34 |
| Ni ppm | 10 | 8 |
| B381 brightness | 97.87 | 97.94 |
| The B381 color | 1.14 | 1.09 |
With the silicic acid zircon sand operation that generates naturally after 19 days, grinding machine C checks the sign whether wearing and tearing are arranged on the rubber lining with the fibre-optical probe that is embedded among the inboard wheel rim of grinding machine.For showing, do not find to have on the rubber lining sign of wearing and tearing with the situation of the weaving master drawing case on the lip-deep rubber mill liner of the grinding machine that appears at brand-new lining usually basically.On the contrary, only after a week, grinding machine just manifests considerable wear to the lining in the grinding machine operation of using conventional quartz sand grinding medium, and particularly in the leading edge of grinding machine rotating rod, knitting on it spun the master drawing case and be worn totally.
Embodiment 3
Following examples are in order to illustrate the difference on particle size, foreign matter content and nonferromagnetic substance between the silicic acid zircon sand that generates naturally that is obtained by difference nature mineral resources.
After this three kinds of zirconium silicate sand sample product that generate naturally are called sample 1, sample 2 and sample 3, at Rotap
TMLast execution 30 minutes is analyzed with screening and is estimated its particle size.Referring to the data in the table 4, sample 2 and sample 3 are approximate on particle size, sample 1 then want littler, like this, it is difficult in the successive method sample 1 being remained in the squirrel cage mill.
The particle size of table 4 zirconium silicate sand sample product
| Sample source | Sample 1 | Sample 2 | Sample 3 |
| The %180 micron | 0.61 | 75 1 | 67.2 |
| The %150 micron | 5.73 | 16 | 32.1 |
| % is less than 150 microns | 93.66 | 8.9 | 0.7 |
Three kinds of zirconium silicate samples that generate naturally are again through using the ultimate analysis of XRF technology.Ultimate analysis the results are shown in Table 5.
Table 5
The element chemical analysis of silicic acid zircon sand
| Sample source | Sample 1 | Sample 2 | Sample 3 |
| The % element | |||
| ％Na | 0.38 | 0.41 | 0.2 |
| ％Al | 0.16 | 0.16 | 0.73 |
| ％Si | 15.15 | 15.43 | 14.5 |
| ％Cl | 0.2 | 0.24 | 0.1 |
| ％Ti | 0.13 | 0.13 | 0.21 |
| ％Y | 0.2 | 0.19 | 0.19 |
| ％Zr | 48.16 | 47.69 | 48.88 |
| ％Hf | 0.92 | 0.99 | 0.93 |
| ％O | 34.4 | 35 | 34.07 |
| Trace analysis | |||
| P(ppm) | 659 | - | - |
| K(ppm) | - | - | 134 |
| Ca(ppm) | 327 | 614 | 689 |
| Cr(ppm) | - | 177 | - |
| Mn(ppm) | - | 201 | - |
| Fe(ppm) | 729 | 714 | 711 |
| sr(ppm) | 81 | - | - |
| Pb(ppm) | 50 | - | - |
| Th(ppm) | 90 | 200 | 180 |
| U(ppm) | 180 | 200 | 220 |
Carry out once laboratory scale grinding research with these the three kinds silicic acid zircon sands that generate naturally again.This research is to carry the sand amount with the laboratory of standard to carry out in squirrel cage mill, and zircon sand is 1.8: 1 with the carrying capacity ratio of colorant.Table 6 shown after grinding 2,4 and 8 minutes, the percentage of particle by 0.5 micron, and promptly a material size is less than 0.5 micron, and the average particulate diameter when these times.Colorant is the titanium dioxide colorant of undressed low enamel level.Its particle size is by using foregoing Microtrac
TMThe grain size analysis instrument is measured.
Table 6 colorant nonferromagnetic substance
| Sample source | Sample 1 | Sample 2 | Sample 3 | |||
| Particle size | Particle size | Particle size | ||||
| Time | Mean diameter | % is by 0.5 micron | Mean diameter | % is by 0.5 micron | Mean diameter | % is by 0.5 micron |
| Feeding (0 minute) | 1 | 21.09 | 1 | 21.09 | 1 | 21.09 |
| 2 minutes | 0.45 | 61.93 | 0.48 | 53.45 | 0.48 | 53.66 |
| 4 minutes | 0.38 | 80.96 | 0.42 | 69.84 | 0.42 | 71.53 |
| 8 minutes | 0.33 | 94.02 | 0.35 | 87.97 | 0.36 | 88.66 |
Claims (38)
1 contains the grinding medium of the silicic acid zircon sand that nature generates, it is characterized in that, the density of silicic acid zircon sand at 4g/cc (definitely) between 6g/cc (definitely) scope.
2 grinding mediums as claimed in claim 1 is characterized in that, the density of said silicic acid zircon sand at 4.6g/cc (definitely) between 4.9g/cc (definitely) scope.
3 grinding mediums as claimed in claim 1 is characterized in that, the density of said silicic acid zircon sand at 4.75g/cc (definitely) between 4.85g/cc (definitely) scope.
4 grinding mediums as claimed in claim 1, it is characterized in that, the said silicic acid zircon sand that generates naturally is characterised in that the particle size of silicic acid zircon sand, and the particle size of said silicic acid zircon sand is the minimum multiple of the abrasive product particles of powder size that can separate from the product powder that grinds.
5 grinding mediums as claimed in claim 4 is characterized in that, said silicic acid zircon sand particle size is greater than 100 microns.
6 grinding mediums as claimed in claim 5 is characterized in that, said silicic acid zircon sand particle size is between 100 microns to 1500 microns.
7 grinding mediums as claimed in claim 6 is characterized in that, said silicic acid zircon sand particle size is between 100 microns to 500 microns.
8 grinding mediums as claimed in claim 6 is characterized in that, said silicic acid zircon sand particle size is between 150 microns to 250 microns.
9 grinding mediums as claimed in claim 1 further comprise liquid medium.
10 grinding mediums as claimed in claim 9 is characterized in that, said liquid medium is the liquid medium that selects in the group that free water, oil, organic compound and composition thereof form.
11 grinding mediums as claimed in claim 9 is characterized in that, said silicic acid zircon sand and the said liquid medium that generates naturally will be united use, to form slurry.
12 grinding mediums as claim 11 is characterized in that said slurry is further characterized in that the viscosity of slurry, and the viscosity of said slurry is between 1.0cps to 1000cps.
13 grinding mediums as claim 12 is characterized in that the viscosity of said slurry is between 1.0cps to 500cps.
14 grinding mediums as claim 12 is characterized in that the viscosity of said slurry is between 1.0cps to 100cps.
The method of 15 1 kinds of abrasive flours, this method may further comprise the steps:
1) provide initial powder, this powder characteristics is initial powder particulate size;
2) provide the grinding medium that contains the silicic acid zircon sand that nature generates, this medium is characterised in that the density of grinding medium arrives between the scope of 6.0g/cc (definitely) at 4.g/cc (definitely), and particle size is between 100 microns to 500 microns scope;
3) provide liquid medium;
4) mix said initial powder, said grinding medium and said night body medium, with the form slurry;
5) in grinding plant, grind said slurry to the sufficiently long time, produce comprise with the desired product powder particle size be the product powder product of feature with haply with product slurry with the identical component of the initial powder said; And
6) from slurry, separate the product slurry that comprises said product powder, so that said grinding medium still is deposited in the said slurry.
16 methods as claim 15 is characterized in that said grinding plant is selected from disc type grinding machine and squirrel cage mill.
17 methods as claim 15 is characterized in that, said initial powder is a kind of agglomerating powder.
18 methods as claim 17 is characterized in that said agglomerating powder is further characterized in that the particle size of agglomerating powder, and the particle size range of said agglomerating powder is between 0.01 micron to 500 microns.
19 methods as claim 18 is characterized in that, said agglomerating powder has from about 0.01 micron particle size to about 200 micrometer ranges.
20 methods as claim 15 is characterized in that, said initial powder is a kind of powder that gathers.
21 methods as claim 15 is characterized in that, the further feature of said initial powder and said product powder is that the density of said powder arrives between the scope of 5g/cc (definitely) at 0.8g/cc (definitely).
22 methods as claim 15 is characterized in that, said initial powder is a kind of organic dust.
23 methods as claim 15 is characterized in that, said initial powder is a kind of inorganic powder.
24 methods as claim 15 is characterized in that, said initial powder is a kind of agglomerant titanium dioxide colorant.
25 methods as claim 15 is characterized in that the particle size of said silicic acid zircon sand is between 150 microns to 250 microns scope.
26 methods as claim 15 is characterized in that, said liquid medium be a kind of can with described method and the suitable liquid of said powder.
27 methods as claim 15 is characterized in that said grinding plant has vertical flow design.
28 methods as claim 15 is characterized in that, said grinding plant has the transverse flow design.
29 methods as claim 15, it is characterized in that, said the 6th step separates said product slurry from said slurry operation, be to finish by coming according to the difference that between the physical properties of initial powder and grinding medium and product powder, exists and with said product slurry and said slurry branch, physical properties wherein is selected from particle size, pellet density and particles settling speed.
30 methods as claim 15 is characterized in that, described each step is carried out continuously.
31 methods as claim 15 is characterized in that, described each step is carried out continuously.
32 methods as claim 15, it further comprises following steps: said product powder is separated from described product slurry, then said product powder is dispersed in the dispersion medium, to form dispersion system.
33 methods as claim 32 is characterized in that, said dispersion medium be a kind of can with said powder and the suitable liquid medium of said method.
34 methods as claim 15 is characterized in that, the particle size of said silicic acid zircon sand only is the minimum multiple of the abrasive product end particle size that can separate from the product that grinds.
35 methods as claim 15, wherein said liquid medium are a kind of liquid mediums that is selected from water, oil, organic compound and their mixture.
36 methods as claim 15 is characterized in that, the density of said grinding medium at 4.6g/cc (definitely) between the scope of 4.9g/cc (definitely).
37 methods as claim 36 is characterized in that, the density of said grinding medium at 4.75g/cc (definitely) between the scope of 4.85g/cc (definitely).
38 methods as claim 34 is characterized in that, the particle size of said silicic acid zircon sand is between 150 microns to 250 microns.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18608594A | 1994-01-25 | 1994-01-25 | |
| US08/186,085 | 1994-01-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1122112A CN1122112A (en) | 1996-05-08 |
| CN1042104C true CN1042104C (en) | 1999-02-17 |
Family
ID=22683601
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95190048A Expired - Lifetime CN1042104C (en) | 1994-01-25 | 1995-01-24 | Zirconium silicate grinding medium and method of milling |
Country Status (18)
| Country | Link |
|---|---|
| EP (2) | EP0930098B1 (en) |
| JP (1) | JP2693039B2 (en) |
| KR (1) | KR0164652B1 (en) |
| CN (1) | CN1042104C (en) |
| AT (2) | ATE235318T1 (en) |
| AU (1) | AU671248B2 (en) |
| BR (1) | BR9506238A (en) |
| CA (1) | CA2158969C (en) |
| CZ (1) | CZ284563B6 (en) |
| DE (2) | DE69515935T2 (en) |
| ES (2) | ES2190624T3 (en) |
| FI (1) | FI954466A0 (en) |
| MX (1) | MX9504066A (en) |
| PL (1) | PL176837B1 (en) |
| SK (1) | SK117895A3 (en) |
| TW (1) | TW276208B (en) |
| WO (1) | WO1995019846A1 (en) |
| ZA (1) | ZA95590B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2315505B (en) * | 1996-07-24 | 1998-07-22 | Sofitech Nv | An additive for increasing the density of a fluid and fluid comprising such additve |
| DE102004040368B3 (en) * | 2004-08-20 | 2006-02-23 | Juhnke, Michael, Dipl.-Ing. | Grinding body for producing very finely ground product has surface consisting of material which is rigid at grinding temperature but not at room temperature |
| US20080022900A1 (en) * | 2006-07-25 | 2008-01-31 | Venkata Rama Rao Goparaju | Process for manufacturing titanium dioxide pigment |
| CN101722085B (en) * | 2008-10-15 | 2012-06-13 | 许兴康 | Grinding technology of high purity sub-nano level superfine zirconium silicate powder |
| CN102795848B (en) * | 2012-08-02 | 2013-10-23 | 江苏锡阳研磨科技有限公司 | Low-temperature sintered zirconium silicate grinding ball and preparation method thereof |
| CN111180719A (en) * | 2020-01-07 | 2020-05-19 | 马鞍山科达普锐能源科技有限公司 | Method for preparing nano silicon by three-stage grinding |
| CN115043620B (en) * | 2022-03-09 | 2023-03-10 | 湖北工业大学 | Method for preparing early-strength precast concrete by taking sand as grinding medium |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3337140A (en) * | 1964-06-03 | 1967-08-22 | Pittsburgh Plate Glass Co | Dispersion process |
| US4262851A (en) * | 1978-07-26 | 1981-04-21 | Basf Aktiengesellschaft | Process for converting crude and/or coarsely crystalline perylenetetracarboxylic acid diimides to a pigmentary form |
| US4547534A (en) * | 1983-03-18 | 1985-10-15 | Memorex Corporation | Method to disperse fine solids without size reduction |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB679552A (en) * | 1949-08-29 | 1952-09-17 | British Titan Products | Improvements relating to methods and apparatus for grinding, crushing and disintegrating |
| JPS5815079A (en) * | 1981-07-14 | 1983-01-28 | 日本化学陶業株式会社 | Crusher member comprising zirconia sintered body |
| JPS60211637A (en) * | 1984-04-05 | 1985-10-24 | Hitachi Maxell Ltd | Production of magnetic recording medium |
| JPH04166246A (en) * | 1990-10-31 | 1992-06-12 | Matsushita Electric Ind Co Ltd | Medium agitating mill and grinding method |
-
1995
- 1995-01-24 DE DE69515935T patent/DE69515935T2/en not_active Expired - Fee Related
- 1995-01-24 AT AT99103983T patent/ATE235318T1/en not_active IP Right Cessation
- 1995-01-24 KR KR1019950704087A patent/KR0164652B1/en not_active IP Right Cessation
- 1995-01-24 MX MX9504066A patent/MX9504066A/en not_active IP Right Cessation
- 1995-01-24 EP EP99103983A patent/EP0930098B1/en not_active Expired - Lifetime
- 1995-01-24 PL PL95310446A patent/PL176837B1/en not_active IP Right Cessation
- 1995-01-24 CA CA002158969A patent/CA2158969C/en not_active Expired - Fee Related
- 1995-01-24 ES ES99103983T patent/ES2190624T3/en not_active Expired - Lifetime
- 1995-01-24 DE DE69530132T patent/DE69530132T2/en not_active Expired - Fee Related
- 1995-01-24 CZ CZ952357A patent/CZ284563B6/en not_active IP Right Cessation
- 1995-01-24 JP JP7519738A patent/JP2693039B2/en not_active Expired - Fee Related
- 1995-01-24 CN CN95190048A patent/CN1042104C/en not_active Expired - Lifetime
- 1995-01-24 AU AU16900/95A patent/AU671248B2/en not_active Ceased
- 1995-01-24 EP EP95908662A patent/EP0690749B1/en not_active Expired - Lifetime
- 1995-01-24 WO PCT/US1995/000963 patent/WO1995019846A1/en active IP Right Grant
- 1995-01-24 BR BR9506238A patent/BR9506238A/en not_active IP Right Cessation
- 1995-01-24 ES ES95908662T patent/ES2143616T3/en not_active Expired - Lifetime
- 1995-01-24 AT AT95908662T patent/ATE191160T1/en not_active IP Right Cessation
- 1995-01-24 SK SK1178-95A patent/SK117895A3/en unknown
- 1995-01-25 ZA ZA95590A patent/ZA95590B/en unknown
- 1995-03-01 TW TW084101912A patent/TW276208B/zh active
- 1995-09-21 FI FI954466A patent/FI954466A0/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3337140A (en) * | 1964-06-03 | 1967-08-22 | Pittsburgh Plate Glass Co | Dispersion process |
| US4262851A (en) * | 1978-07-26 | 1981-04-21 | Basf Aktiengesellschaft | Process for converting crude and/or coarsely crystalline perylenetetracarboxylic acid diimides to a pigmentary form |
| US4547534A (en) * | 1983-03-18 | 1985-10-15 | Memorex Corporation | Method to disperse fine solids without size reduction |
Also Published As
| Publication number | Publication date |
|---|---|
| CZ235795A3 (en) | 1996-02-14 |
| TW276208B (en) | 1996-05-21 |
| WO1995019846A1 (en) | 1995-07-27 |
| AU1690095A (en) | 1995-08-08 |
| DE69530132T2 (en) | 2004-01-08 |
| CN1122112A (en) | 1996-05-08 |
| CA2158969A1 (en) | 1995-07-27 |
| ATE235318T1 (en) | 2003-04-15 |
| ATE191160T1 (en) | 2000-04-15 |
| ZA95590B (en) | 1996-07-25 |
| ES2190624T3 (en) | 2003-08-01 |
| EP0690749B1 (en) | 2000-03-29 |
| ES2143616T3 (en) | 2000-05-16 |
| JPH08506527A (en) | 1996-07-16 |
| EP0690749A1 (en) | 1996-01-10 |
| DE69515935T2 (en) | 2000-08-17 |
| KR0164652B1 (en) | 1998-12-15 |
| FI954466A (en) | 1995-09-21 |
| DE69530132D1 (en) | 2003-04-30 |
| DE69515935D1 (en) | 2000-05-04 |
| SK117895A3 (en) | 1996-01-10 |
| EP0930098A1 (en) | 1999-07-21 |
| EP0690749A4 (en) | 1996-10-30 |
| MX9504066A (en) | 1997-05-31 |
| PL310446A1 (en) | 1995-12-11 |
| CZ284563B6 (en) | 1999-01-13 |
| CA2158969C (en) | 2000-06-27 |
| EP0930098B1 (en) | 2003-03-26 |
| FI954466A0 (en) | 1995-09-21 |
| PL176837B1 (en) | 1999-08-31 |
| KR960700819A (en) | 1996-02-24 |
| AU671248B2 (en) | 1996-08-15 |
| JP2693039B2 (en) | 1997-12-17 |
| BR9506238A (en) | 1997-09-30 |
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