CN104209498A - Preparing method of interface modification layer of ceramic particle enhanced metal base composite material - Google Patents
Preparing method of interface modification layer of ceramic particle enhanced metal base composite material Download PDFInfo
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- CN104209498A CN104209498A CN201410352403.2A CN201410352403A CN104209498A CN 104209498 A CN104209498 A CN 104209498A CN 201410352403 A CN201410352403 A CN 201410352403A CN 104209498 A CN104209498 A CN 104209498A
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- 239000002245 particle Substances 0.000 title claims abstract description 73
- 239000000919 ceramic Substances 0.000 title claims abstract description 55
- 239000002131 composite material Substances 0.000 title claims abstract description 49
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 46
- 239000002184 metal Substances 0.000 title claims abstract description 46
- 238000012986 modification Methods 0.000 title claims abstract description 32
- 230000004048 modification Effects 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title abstract description 23
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- 238000005266 casting Methods 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 9
- 239000011159 matrix material Substances 0.000 claims description 18
- 239000007767 bonding agent Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 229910001018 Cast iron Inorganic materials 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- DHAHRLDIUIPTCJ-UHFFFAOYSA-K aluminium metaphosphate Chemical compound [Al+3].[O-]P(=O)=O.[O-]P(=O)=O.[O-]P(=O)=O DHAHRLDIUIPTCJ-UHFFFAOYSA-K 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910000838 Al alloy Inorganic materials 0.000 claims description 2
- 229910001208 Crucible steel Inorganic materials 0.000 claims description 2
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 2
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 2
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 2
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- -1 modifying element Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 238000002844 melting Methods 0.000 abstract 4
- 230000008018 melting Effects 0.000 abstract 4
- 230000000903 blocking effect Effects 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 17
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910004349 Ti-Al Inorganic materials 0.000 description 4
- 229910004692 Ti—Al Inorganic materials 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000011156 metal matrix composite Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention discloses a preparing method of an interface modification layer of a ceramic particle enhanced metal base composite material, and belongs to the technical field of a metal base composite material. The method comprises the following steps that ceramic particles and modification element particles are uniformly mixed according to a certain proportion, are pressed into a prefabricated body and are sintered, then, the sintered prefabricated body is placed into a casting die cavity, a metal substrate with the melting point lower than the melting point of the modification elements is cast on the sintered prefabricated body, next, the metal base composite material is prepared by adopting a pressure casting method, the melting point of the modification elements is a little higher than the melting point of molten liquid, so the modification elements are in a molten state when the molten liquid is cast into the die cavity, then, the modification elements move together with the molten liquid under the pressure effect, when meeting the blocking effect of the ceramic particles, the modification elements and the molten metal can go around the surface of the ceramic particles for forming a micrometer level interface modification layer on the surfaces of the ceramic particles, and the bonding intensity of the ceramic particles and the metal interfaces can be improved. When the method provided by the invention is adopted, great significance can be realized on the preparation of high-performance and low-cost metal base composite material.
Description
Technical field
The present invention relates to a kind of preparation method of ceramic particle reinforced metal base composites interface modification layer, belong to metal-base composites technical field.
Background technology
Due to wear resistence, the high-temperature behavior of metal-base composites excellence, lower cost etc., obtains application in fields such as high-temperature structural material, high-abrasive material, tool die materials gradually.But ceramic particle and metallic matrix interface bond strength often poor, cause composite macro-mechanical property undesirable.At present, improve the method that in composite, wild phase and basal body interface combine and substantially have three classes: 1. at wild phase overlay coating.2. in parent metal, add the alloying element that can react with wild phase.3. reaction in-situ self-generating wild phase.In order to solve the problem of Metal Matrix Composite Interface poor bonding strength:
Chinese invention patent CN103302268A proposes first with the ceramic preform of ceramic powders preparation band hole; Again by mode nickel plating on ceramic preform of chemical nickel plating, the thickness of nickel coating is 10 μm-200 μm; Be fixed in casting mold by the ceramic preform after nickel plating, negative pressure casting matrix molten metal obtains metal ceramic composite wear-resistant material.Comparison of the present invention is simple, is particularly suitable for the production of large part plate part.Yield rate is high, stable performance, and the combination of matrix and precast body can form good metallurgical binding.But the method is by the mode of chemical nickel plating, and cost is higher, higher to equipment requirement.
Chinese invention patent CN101899631A discloses a kind of coating modified method of metal-based composite material reinforcement surface high wettability, comprises the steps: 1. to utilize conventional coating production at the coating of metal oxides of reinforcement surface coating lower than magnesium; 2. the reinforcement of coated metal oxide coating and pure magnesium are put into vacuum drying oven, pure magnesium is placed in furnace bottom, reinforcement is placed in above pure magnesium, vacuumize, keep low vacuum in 10Pa, be warming up to 600-700 DEG C, insulation 5-60 minute, make magnesium vapor and increase surface coating of metal oxides generation oxidation-reduction reaction, generating the composite bed that skin that the internal layer that is made up of compound and reduced metal form is formed.But the method needs to complete in vacuum environment, and operation more complicated, lower for industrial possibility.
Chinese invention patent CN103193507A relates to a kind of method improving metal pair SiC ceramic wetability.The present invention, by injecting the metal ion of doses in SiC ceramic surface, reduces the contact angle of metal pair SiC ceramic surface, improves metal and the interface cohesion of pottery, improves heat, the electrical property at SiC ceramic and Metal Contact interface.Although the method can improve the wetability of metal on ceramic, be confined to SiC, range of application is not very wide.
These improve the method for the bond strength between metal-base composites ceramic particle and metallic matrix at present, more or less all can there is cost higher, complicated operation, DeGrain, inapplicable industrial production, the problems such as range of application is wideless.
Summary of the invention
In order to solve metallic matrix and ceramic particle poor bonding strength in metal-base composites preparation process, the critical problem that composite property is poor, the object of the present invention is to provide a kind of preparation method of ceramic particle reinforced metal base composites interface modification layer, specifically comprise the following steps:
(1) batch mixing: ceramic particle, modifying element powder, bonding agent are mixed and obtain mixture, the mass percent of ceramic particle is 75% ~ 95% in the mixture, and the mass percent of modifying element is 5% ~ 25%, and bonding agent mass percent is 3% ~ 5%;
(2) preparation of precast body: take out ceramic particle, make the precast body of required form at 5 ~ 40MPa pressure;
(3) cast: by precast body at 100 DEG C ~ 1200 DEG C roasting 30min ~ 120min, be placed in casting mold die cavity fast after coming out of the stove, casting metals liquid matrix, adopt compression casting, in the gap that molten metal is infiltrated up between ceramic particle, obtain composite material interface modified layer.
Described in step of the present invention (1), batch mixing can mix in ball mill, and incorporation time is 30min ~ 120min, and rotating speed is 50 ~ 300r/min.
Ceramic particle of the present invention is A1
2o
3, ZrO
2, SiO
2, SiC, B
4c, TiC, TiN, TiB
2in one or more, its granularity is 10-300 order.
Modifying element of the present invention is the one in Ni, Ti, Cr, Cu, Si, B, Co, Al element, and its granularity is 100-500 order.
Molten metal basic material of the present invention is the one in cast steel, cast iron, Al alloy, Cu alloy, Zn alloy, Mg alloy, Ti alloy, Ni alloy.
In steps A of the present invention bonding agent be water glass solution, Ludox, aluminium metaphosphate solution, poly-vinyl alcohol solution one or more.
The fusing point of modifying element of the present invention is than the fusing point height 100-400 DEG C of metallic matrix, because the fusing point of modifying element is a little more than the fusing point of molten metal, be cast in die cavity at molten metal, modifying element is in molten condition, and then molten metal moves together under the effect of the pressure again, when running into the inhibition of ceramic particle, around ceramic grain surface, can form on its surface the bond strength that the micron-sized interface modification layer of one deck can improve ceramic particle and metal interface.
Principle of the present invention: after ceramic particle and modifying element particle are mixed according to a certain percentage, be pressed into precast body and sinter, then be positioned in mould cavity, to cast above the metal of fusing point a little less than modifying element fusing point, then prepared the metal-base composites of interface modification by the method for compression casting, because the fusing point of modifying element is a little more than the fusing point of molten metal, be cast in die cavity at molten metal, modifying element is in molten condition, and then molten metal moves together under the effect of the pressure again, when running into the inhibition of ceramic particle, can around ceramic grain surface, the micron-sized interface modification layer of one deck is formed on its surface, because the wetability of ceramic particle and metallic matrix is generally poor, this layer of micron-sized interface modification layer is in the interface of ceramic particle and metallic matrix, the angle of wetting between ceramic particle and metallic matrix can be reduced, thus the bond strength of ceramic particle and metal interface can be improved.
The invention has the beneficial effects as follows:
(1) by metal-base composites prepared by the method, the modified layer that its ceramic grain surface has layer coated, can increase bond strength between ceramic particle and metallic matrix, improves the combination property of composite; Hardness weighs an important indicator of Metal Matrix Composite Interface bond strength, and hardness is higher, and interface bond strength is better, Al
2o
3the macrohardness of-40Cr as cast condition is 28.7, and after adding Si powder, hardness reaches 39.4, illustrates that interface bond strength improves significantly;
(2) selective comparatively wide between modifying element and matrix, preparation method is simple, easily operates, and with low cost, is applicable to suitability for industrialized production;
(3) metal-base composites prepared by the method ensure that the reliability used under top load wear working condition; Compared to Castingother method, adopt pressure casting processes, ceramic particle reinforced metal base composites once infiltrates and is shaped, and products obtained therefrom interface cohesion is tightr, and do not have microdefect, good in conjunction with uniformity, intensity and toughness are all improved.
Accompanying drawing explanation
Fig. 1. be precast body schematic diagram prepared by the present invention;
Fig. 2 is preparation method's schematic diagram of Metal Matrix Composite Interface modified layer of the present invention;
Fig. 3 be Metal Matrix Composite Interface modified layer of the present invention organize schematic diagram;
Fig. 4 is 5%Ti-Al
2o
3-45 structure of steel schematic diagrames;
Fig. 5 is 5%Ti-Al
2o
3-45 steel and Al
2o
3wear extent contrast under-45 steel different rotating speeds;
In figure: 1-ceramic particle, 2-modifying element particle, 3-precast body, 4-metallic matrix, 5-interface modification layer.
Detailed description of the invention
Below in conjunction with drawings and the specific embodiments, the present invention is described in further detail, but protection scope of the present invention is not limited to described content.
Embodiment 1
Method described in the present embodiment is used for preparing Al
2o
3particle reinforced iron matrix composites, specifically comprises the following steps:
(1) taking granularity is 10 ~ 50 object Al
2o
3particle 375g, granularity are 500 object pure Ni powder 125g, and with 3%Na
2siO
3and 2%H
2the bonding agent 25g of O preparation mixes, in ball mill, fully mix 30min;
(2) take out the particle that step (1) mixes, make at 20MPa pressure the circular precast body (as Fig. 1) that diameter is 90mm;
(3) by precast body 800 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, water liquid cast-iron, pouring temperature is 1380 ~ 1430 DEG C, casts at 70MPa pressure, makes iron immersion be seeped into Al
2o
3in gap between particle (as Fig. 2), obtain densified composite interface modification layer (as Fig. 3).
The Al of surface bag Ni
2o
3wetability between pottery and molten steel improves, and bond strength is from Al
2o
30.7 MPa between/Fe brings up to nickel coat Al
2o
34.05 MPa of/Fe, and interface has better non-oxidizability.There is Ni and do not add the Al of Ni
2o
3the wearability of particle reinforced steel-base composite material is 2. 5 times and 1. 6 times of homogeneity base steel respectively.
Embodiment 2
Method described in the present embodiment is used for preparing Al
2o
3particle reinforce 45 base steel composite material, specifically comprises the following steps:
(1) taking granularity is 80 ~ 120 object Al
2o
3particle 425g, granularity are 100 object Ti powder 75g, and with 4%Na
2siO
3and 2%H
2the bonding agent 30g of O preparation mixes, in ball mill, fully mix 1 hour;
(2) take out the particle that step (1) mixes, make at 10MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 1000 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, 45 molten steel of casting, pouring temperature is 1500 ~ 1550 DEG C, casts at 40MPa pressure, makes molten steel be infiltrated up to Al
2o
3in gap between particle, obtain densified composite interface modification layer.
The 5%Ti-Al that the present embodiment prepares
2o
3-45 structure of steel schematic diagrames as shown in Figure 4, can find out Al by metallographic structure schematic diagram
2o
3particle and 45 steel matrix interface cohesion closely, do not have microdefect, good in conjunction with uniformity, have coated one deck Ti and titaniferous compound thereof, can increase Al at interface
2o
3bond strength between ceramic particle and 45 steel matrix, improves the anti-wear performance of composite.5%Ti-Al
2o
3-45 steel and Al
2o
3under-45 steel different rotating speeds, wear extent contrast schematic diagram as shown in Figure 5, can show that the composite-material abrasive of interface modification layer is better.
Embodiment 3
Method described in the present embodiment is used for preparing SiC particle enhanced aluminum-based composite material, specifically comprises the following steps:
(1) take that granularity is 150 ~ 180 object SiC particle 450g, granularity is 500 object pure Cu powder 50g, and with 5% Ludox and 3%H
2the bonding agent 40g of O preparation mixes, in ball mill, fully mix 1.5 hours;
(2) take out the particle that step (1) mixes, make at 20MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 500 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, water aluminium liquid, pouring temperature is 660 ~ 680 DEG C, cast at 40MPa pressure, in the gap that aluminium immersion is seeped between SiC particle, obtain densified composite interface modification layer.
Embodiment 4
Method described in the present embodiment is used for preparing Al
2o
3granule reinforced copper base composite material, specifically comprises the following steps:
(1) taking granularity is 80 ~ 150 object Al
2o
3particle 400g, granularity are 500 object pure Cr powder 100g, mix with 5% aluminium metaphosphate solution bonding agent 25g, in ball mill, fully mix 1.5 hours;
(2) take out the particle that step (1) mixes, make at 30MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 600 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, water copper liquid, pouring temperature is 950 ~ 1000 DEG C, casts at 60MPa pressure, makes copper immersion be seeped into Al
2o
3in gap between particle, obtain densified composite interface modification layer.
Embodiment 5
Method described in the present embodiment is used for preparing TiN granule reinforced copper base composite material, specifically comprises the following steps:
(1) take that granularity is 250 ~ 300 object TiN particle 475g, granularity is 500 object pure Ti powder 25g, and with 2%Na
2siO
3the bonding agent 25g of solution and the preparation of 3% Ludox mixes, in ball mill, fully mix 2 hours;
(2) take out the particle that step (1) mixes, make at 40MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 800 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, water titanium liquid, pouring temperature is 950 ~ 1000 DEG C, cast at 70MPa pressure, in the gap that copper immersion is seeped between TiN particle, obtain densified composite interface modification layer.
Embodiment 6
Method described in the present embodiment is used for preparing WC particle and strengthens iron base composite material, specifically comprises the following steps:
(1) take that granularity is 80 ~ 150 object WC particle 450g, granularity is 500 object pure Co powder 50g, mix with 5% Ludox bonding agent 25g, fully mixing 2 hours in ball mill;
(2) take out the particle that step (1) mixes, make at 20MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 1000 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, water rich chromium cast iron molten metal, pouring temperature is 1500 ~ 1550 DEG C, cast at 50MPa pressure, in the gap that iron immersion is seeped between WC particle, obtain densified composite interface modification layer.
Embodiment 7
Method described in the present embodiment is used for preparing TiC particle reinforced steel-base composite material, specifically comprises the following steps:
(1) take that granularity is 80 ~ 120 object TiC particle 425g, granularity is 300 object pure Si powder 75g, mix with 5% polyvinyl alcohol bonding agent 25g, fully mixing 1 hour in ball mill;
(2) take out the particle that step (1) mixes, make at 10MPa pressure the circular precast body that diameter is 90mm;
(3) by precast body 600 DEG C of roastings 2 hours, be placed in mold cavity fast after coming out of the stove, casting 40Cr steel molten metal, pouring temperature is 1450 ~ 1550 DEG C, cast at 60MPa pressure, in the gap that molten steel is infiltrated up between TiC particle, obtain densified composite interface modification layer.
Claims (7)
1. a preparation method for ceramic particle reinforced metal base composites interface modification layer, is characterized in that, specifically comprises the following steps:
(1) batch mixing: ceramic particle, modifying element, bonding agent are mixed and obtain mixture, the mass percent of ceramic particle is 75% ~ 95% in the mixture, and the mass percent of modifying element is 5% ~ 25%, and bonding agent mass percent is 3% ~ 5%;
(2) preparation of precast body: take out ceramic particle, make the precast body of required form at 5 ~ 40MPa pressure;
(3) cast: by precast body at 100 DEG C ~ 1200 DEG C roasting 30min ~ 120min, be placed in casting mold die cavity fast after coming out of the stove, casting metals liquid matrix, adopt compression casting, in the gap that molten metal is infiltrated up between ceramic particle, obtain composite material interface modified layer.
2. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: described in step (1), batch mixing mixes 30min ~ 120min in ball mill, and rotating speed is 50 ~ 300r/min.
3. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: described ceramic particle is A1
2o
3, ZrO
2, SiO
2, SiC, B
4c, TiC, TiN, TiB
2in one or more, its granularity is 10-300 order.
4. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: described modifying element is the one in Ni, Ti, Cr, Cu, Si, B, Co, Al element, and its granularity is 100-500 order.
5. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: described molten metal basic material is the one in cast steel, cast iron, Al alloy, Cu alloy, Zn alloy, Mg alloy, Ti alloy, Ni alloy.
6. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: described bonding agent be water glass solution, Ludox, aluminium metaphosphate solution, poly-vinyl alcohol solution one or more.
7. the preparation method of ceramic particle reinforced metal base composites interface modification layer according to claim 2, is characterized in that: the fusing point of modifying element is than the fusing point height 100-400 DEG C of metallic matrix.
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| US20220023944A1 (en) * | 2020-03-27 | 2022-01-27 | Magotteaux International S.A. | Composite wear component |
| CN112658229A (en) * | 2020-11-27 | 2021-04-16 | 中国船舶重工集团公司第十二研究所 | Preparation method of ZTA ceramic reinforced wear-resistant part |
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