CN104201363A - Carbon-coated Li3VO4 lithium ion battery anode material and preparation method thereof - Google Patents
Carbon-coated Li3VO4 lithium ion battery anode material and preparation method thereof Download PDFInfo
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- CN104201363A CN104201363A CN201410305710.5A CN201410305710A CN104201363A CN 104201363 A CN104201363 A CN 104201363A CN 201410305710 A CN201410305710 A CN 201410305710A CN 104201363 A CN104201363 A CN 104201363A
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- coated
- carbon
- ion battery
- lithium ion
- li3vo4
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 31
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 23
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000010405 anode material Substances 0.000 title abstract description 6
- 229910011312 Li3VO4 Inorganic materials 0.000 title abstract 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000000463 material Substances 0.000 claims abstract description 26
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 10
- 239000004312 hexamethylene tetramine Substances 0.000 claims abstract description 10
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims abstract description 8
- 238000005245 sintering Methods 0.000 claims abstract description 6
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 5
- 229910003481 amorphous carbon Inorganic materials 0.000 claims abstract description 4
- 239000012265 solid product Substances 0.000 claims abstract 4
- 239000002994 raw material Substances 0.000 claims abstract 2
- 229910021541 Vanadium(III) oxide Inorganic materials 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 239000012071 phase Substances 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 239000007790 solid phase Substances 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000003763 carbonization Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 abstract 2
- 229960004011 methenamine Drugs 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 230000004087 circulation Effects 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000010276 construction Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002243 precursor Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention provides a carbon-coated Li3VO4 lithium ion battery anode material. The anode material is prepared according to the following method: employing vanadium pentoxide, lithium carbonate and hexamethylene tetramine as raw materials, performing a hydrothermal reaction to obtain an intermediate-phase solution, then adding citric acid into the intermediate-phase solution, mixing uniformly, and drying to obtain a solid product, and sintering the solid product in a high-temperature atmosphere, so as to obtain the lithium ion battery anode material with the Li3VO4 surface coated by amorphous carbon. The anode material is granular, and has the particle size of 90-120 nm. The carbonization effect of citric acid is utilized for fining Li3VO4 particles and uniformly coating the particle size with a carbon layer. The synthetic technology simple and easy to operate, and the material preparation cost is low. The prepared sample Li3VO4 is a uniform nano-particle, and has the dimension of 90-120 nm. In the obtained sample, the Li3VO4 particle surface is uniformly coated by amorphous carbon. The prepared material is high in charge/discharge capacity and excellent in cycle performance.
Description
Technical field
The present invention relates to a class new type lithium ion battery composite negative pole material, particularly the coated Li of a kind of carbon
3vO
4the technology of preparing of composite material and storage lithium characteristic thereof, belong to electrochemistry field of novel.
Background technology
Lithium ion battery has the advantages such as operating voltage is high, specific energy large, discharge potential curve is steady, self discharge is little, have extended cycle life, cryogenic property is good, memoryless, pollution-free, be widely used at present mobile communication equipment as in notebook computer and mobile phone, also had broad application prospects in as electric automobile and electric bicycle at following electric vehicle.A key factor that affects lithium ion battery development is research and development and the application of positive and negative electrode material.Li
3vO
4as a kind of Novel anode material, there is more high-volume and capacity ratio and better security performance than commercial graphite negative electrodes material, than Li
4ti
5o
12negative material has higher specific capacity, lower charge and discharge voltage, and current commercial positive electrode coupling is good, in lithium ion battery, has broad application prospects.There are some researches show, by Li
3vO
4can obviously improve its capacity and stable circulation performance with Graphene is compound, but Graphene cost is too high, is unfavorable for extensive preparation.In addition, by Li
3vO
4direct precipitation has also effectively improved its chemical property in nickel foam.Prepare the coated Li of carbon by straightforward procedure
3vO
4composite construction is expected to improve Li
3vO
4material electrochemical performance, for Li
3vO
4practical application in lithium ion battery also tool is of great significance.Up to the present, the coated Li of carbon
3vO
4the research of the preparation of composite construction and the application in lithium ion battery thereof there is not yet report.Based on above background, this patent is invented a kind of effective ways and is prepared the coated Li of carbon
3vO
4nano particle composite construction, with the coated Li of prepared carbon
3vO
4composite material has shown higher specific capacity and excellent cyclical stability as lithium ion battery negative.
Summary of the invention
Object of the present invention is exactly taking vanadic oxide, lithium carbonate, hexamethylenetetramine and citric acid as precursor, by hydro-thermal reaction and in conjunction with the coated Li of sintered at high temperature New Type of Carbon
3vO
4lithium ion battery composite material.Its principle is exactly first to utilize hydro-thermal reaction to prepare precursor solution, then introduces citric acid and fully stirs citric acid is mixed with precursor liquid, dries and utilize high-temperature heating that reaction energy is provided, and obtains the coated Li of carbon by solid phase reaction
3vO
4nano particle composite construction.
Li involved in the present invention
3vO
4synthesis material is vanadic oxide, lithium carbonate, hexamethylenetetramine and citric acid.In material preparation process, first by vanadic oxide, lithium carbonate and hexamethylenetetramine by molar ratio 1:3:5: take, be positioned over and in beaker, add appropriate distilled water and stir, be then positioned in hydrothermal reaction kettle and at 120 ~ 180 DEG C, react 12 ~ 48 hours.The solution that reaction is obtained is transferred in beaker and adds a certain amount of citric acid, after fully stirring, in baking oven, dries, and finally under condition of nitrogen gas, is heated at 500 ~ 600 DEG C sintering 2 ~ 10 hours, and the naturally cooling carbon that obtains is coated Li
3vO
4sample.
The coated Li of carbon involved in the present invention
3vO
4negative material and preparation method have following distinguishing feature:
(1) the present invention has utilized the carbonization refinement Li of citric acid
3vO
4particle is also evenly coated carbon-coating at particle surface.
(2) synthesis technique is simple, easy operating, and material preparation cost is low.
(3) Li in prepared sample
3vO
4for uniform nano particle, be of a size of 90 ~ 120 nm.
(4) in gained sample, amorphous carbon is evenly coated on Li
3vO
4particle surface.
(5) prepared material charge/discharge capacity is high, cycle performance excellence.
Brief description of the drawings
The XRD collection of illustrative plates of Fig. 1 embodiment 1 prepared sample.
The Raman collection of illustrative plates of Fig. 2 embodiment 1 prepared sample.
The SEM figure (a) of Fig. 3 embodiment 1 prepared sample and TEM figure (b).
The curve of charge and discharge first (a) of prepared sample and cycle performance figure (b) (current density 0.1 mA cm in Fig. 4 embodiment 1
-2).
The curve of charge and discharge first (a) of prepared sample and cycle performance figure (b) (current density 0.1 mA cm in Fig. 5 embodiment 2
-2).
The curve of charge and discharge first (a) of prepared sample and cycle performance figure (b) (current density 0.1 mA cm in Fig. 6 embodiment 3
-2).
Embodiment
Embodiment 1
Take 1mmol vanadic oxide, 3mmol lithium carbonate and 5mmol hexamethylenetetramine to beaker, adding appropriate distilled water stirs, be transferred in hydro-thermal axe and react 140 degree 24 hours, reaction gained solution is transferred in beaker and adds 0.05mmol citric acid, fully stir post-drying.Oven dry product is positioned in crucible, and crucible is moved in high temperature process furnances, at 550 DEG C, calcine 5 hours under condition of nitrogen gas, the naturally cooling carbon that can obtain is coated Li
3vO
4sample.Result shows, prepared sample, through XRD atlas analysis, is positioned at 16.3
o, 21.6
o, 22.9
o, 24.4
o, 28.2
o, 32.8
o, 36.3
o, 37.6
o, 49.8
o, 58.7
o, 66.2
owith 70.9
othe diffraction maximum at place corresponds respectively to rhombic system Li
3vO
4(100), (110) of (XRD card JCPDS, No. 38-1247), (011), (101), (111), (200), (002), (201), (202), (320), (203) and (322) crystal face.Prepared sample is through Raman analysis, is positioned at 1358 and 1601cm
-1the peak at place derives from carbon.The coated Li of prepared carbon
3vO
4composite material characterizes through SEM and TEM, can be found out Li by Fig. 3 (a)
3vO
4for nano particle, average-size approximately 100 nm.Can be found out by Fig. 3 (b), carbon is evenly coated on Li
3vO
4nano grain surface.With the coated Li of prepared carbon
3vO
4nano particle shows that as lithium ion battery negative material charge and discharge capacity is 537 and 688 mAh/g first, and after 100 circulations, charge and discharge capacity is 562 and 565 mAh/g, has shown higher specific capacity and excellent stable circulation performance.
Embodiment 2
Take 1mmol vanadic oxide, 3mmol lithium carbonate and 5mmol hexamethylenetetramine to beaker, adding appropriate distilled water stirs, be transferred in hydro-thermal axe and react 140 degree 24 hours, reaction gained solution is transferred in beaker and adds 0.05mmol citric acid, fully stir post-drying.Oven dry product is positioned in crucible, and crucible is moved in high temperature process furnances, at 500 DEG C, calcine 5 hours under condition of nitrogen gas, the naturally cooling carbon that can obtain is coated Li
3vO
4sample.Result shows, with the coated Li of prepared carbon
3vO
4nano particle shows that as lithium ion battery negative material charge and discharge capacity is 355 and 445 mAh/g first, and after 100 circulations, charge and discharge capacity is 419 and 420 mAh/g, has shown higher specific capacity and good stable circulation performance.
Embodiment 3
Take 1mmol vanadic oxide, 3mmol lithium carbonate and 5mmol hexamethylenetetramine to beaker, adding appropriate distilled water stirs, be transferred in hydro-thermal axe and react 140 degree 24 hours, reaction gained solution is transferred in beaker and adds 0.05mmol citric acid, fully stir post-drying.Oven dry product is positioned in crucible, and crucible is moved in high temperature process furnances, at 600 DEG C, calcine 5 hours under condition of nitrogen gas, the naturally cooling carbon that can obtain is coated Li
3vO
4sample.Result shows, with the coated Li of prepared carbon
3vO
4nano particle shows that as lithium ion battery negative material charge and discharge capacity is 494 and 620 mAh/g first, and after 100 circulations, charge and discharge capacity is 496 and 498 mAh/g, has shown higher specific capacity and excellent stable circulation performance.
Claims (5)
1. the coated Li of carbon
3vO
4lithium ion battery negative material, is characterized in that: this negative material is taking vanadic oxide, lithium carbonate, hexamethylenetetramine and citric acid as basic material, the coated Li of carbon making
3vO
4lithium ion battery negative material, the particle diameter of this negative material is 90-120nm.
2. the coated Li of carbon according to claim 1
3vO
4lithium ion battery negative material, is characterized in that: the coated Li of described carbon
3vO
4lithium ion battery negative material is the coated Li of a kind of amorphous carbon
3vO
4lithium ion battery negative material, its carbon source is citric acid.
3. the coated Li of carbon
3vO
4the preparation method of lithium ion battery negative material, it is characterized in that: taking vanadic oxide, lithium carbonate and hexamethylenetetramine as raw material, phase solution in the middle of obtaining by hydro-thermal reaction, then in the middle of citric acid being joined, in phase solution, mix, oven dry obtains solid product, this solid product is made after high-temperature atmosphere sintering to the coated Li of carbon
3vO
4lithium ion battery negative material.
4. the coated Li of carbon according to claim 3
3vO
4the preparation method of lithium ion battery negative material, is characterized in that: described hydrothermal temperature is 120 ~ 180 DEG C, and the reaction time is 12 ~ 48 hours; Described solid-phase sintering atmosphere is nitrogen, and sintering temperature is 500 ~ 600 DEG C, sintering time 2 ~ 10 hours.
5. the coated Li of carbon according to claim 3
3vO
4the preparation method of lithium ion battery negative material, is characterized in that: the mol ratio of vanadic oxide, lithium carbonate, hexamethylenetetramine, citric acid is 1:3:5:1-4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410305710.5A CN104201363B (en) | 2014-07-01 | 2014-07-01 | The coated Li of a kind of carbon3VO4Lithium ion battery cathode material and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410305710.5A CN104201363B (en) | 2014-07-01 | 2014-07-01 | The coated Li of a kind of carbon3VO4Lithium ion battery cathode material and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104201363A true CN104201363A (en) | 2014-12-10 |
| CN104201363B CN104201363B (en) | 2016-05-11 |
Family
ID=52086627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410305710.5A Active CN104201363B (en) | 2014-07-01 | 2014-07-01 | The coated Li of a kind of carbon3VO4Lithium ion battery cathode material and its preparation method |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104852054A (en) * | 2015-04-13 | 2015-08-19 | 三峡大学 | N-doped carbon-coated Li3VO4 lithium ion battery composite anode material and preparation method |
| CN104868119A (en) * | 2015-04-16 | 2015-08-26 | 三峡大学 | Binder-free Li3VO4/C lithium ion battery cathode material and preparation method thereof |
| CN105529450A (en) * | 2016-03-02 | 2016-04-27 | 合肥国轩高科动力能源有限公司 | Preparation method of lithium ion battery cathode material fluorine-doped lithium vanadate with stable circulation |
| CN105552358A (en) * | 2016-02-03 | 2016-05-04 | 三峡大学 | Preparation method of chromium-doped Li<3>VO<4>/C anode material for lithium-ion battery |
| CN105742591A (en) * | 2016-03-02 | 2016-07-06 | 三峡大学 | Carbon coated Na3VO4 composite anode material and preparation method and application thereof |
| CN105958029A (en) * | 2016-06-24 | 2016-09-21 | 合肥国轩高科动力能源有限公司 | Preparation method of lithium vanadate/carbon nanotube/carbon as lithium ion battery cathode composite material |
| CN106356510A (en) * | 2016-10-13 | 2017-01-25 | 中南大学 | Preparation method for Li-ion anode material FeVO4/C |
| CN106941188A (en) * | 2017-05-03 | 2017-07-11 | 厦门大学 | One kind can discharge and recharge aluminium ion battery and its preparation technology |
| CN107039637A (en) * | 2016-02-03 | 2017-08-11 | 三峡大学 | A kind of high-performance negative material Li3VO4/ C preparation method and the application on sodium-ion battery |
| CN107293722A (en) * | 2017-07-10 | 2017-10-24 | 三峡大学 | A kind of self-supporting NaVPO4F/C compound potassium ion battery plus plates and preparation method thereof |
| CN107482181A (en) * | 2017-07-10 | 2017-12-15 | 三峡大学 | A kind of anode material for compound lithium ion battery Li3V2(PO4)3/ C and preparation method thereof |
| CN107492656A (en) * | 2017-07-10 | 2017-12-19 | 三峡大学 | A kind of self-supporting NaVPO4F/C sodium ion anode composites and preparation method thereof |
| CN107845781A (en) * | 2016-09-19 | 2018-03-27 | 微宏动力系统（湖州）有限公司 | Lithium ion secondary battery cathode active material, its preparation method and lithium rechargeable battery |
| CN108666541A (en) * | 2018-04-16 | 2018-10-16 | 华南理工大学 | A kind of sol-gel method preparation carbon coating VOMoO4The method of lithium ion battery negative material |
| CN112018373A (en) * | 2020-08-05 | 2020-12-01 | 嵊州市森拓新材料有限公司 | Carbon-coated Li with shell-core structure3VO4Lithium ion battery cathode material and preparation method thereof |
| CN112281258A (en) * | 2020-10-20 | 2021-01-29 | 三峡大学 | Li3VO4Negative electrode material of/C fiber lithium ion battery and preparation method |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104852054A (en) * | 2015-04-13 | 2015-08-19 | 三峡大学 | N-doped carbon-coated Li3VO4 lithium ion battery composite anode material and preparation method |
| CN104868119A (en) * | 2015-04-16 | 2015-08-26 | 三峡大学 | Binder-free Li3VO4/C lithium ion battery cathode material and preparation method thereof |
| CN105552358A (en) * | 2016-02-03 | 2016-05-04 | 三峡大学 | Preparation method of chromium-doped Li<3>VO<4>/C anode material for lithium-ion battery |
| CN107039637A (en) * | 2016-02-03 | 2017-08-11 | 三峡大学 | A kind of high-performance negative material Li3VO4/ C preparation method and the application on sodium-ion battery |
| CN105529450A (en) * | 2016-03-02 | 2016-04-27 | 合肥国轩高科动力能源有限公司 | Preparation method of lithium ion battery cathode material fluorine-doped lithium vanadate with stable circulation |
| CN105742591A (en) * | 2016-03-02 | 2016-07-06 | 三峡大学 | Carbon coated Na3VO4 composite anode material and preparation method and application thereof |
| CN105958029A (en) * | 2016-06-24 | 2016-09-21 | 合肥国轩高科动力能源有限公司 | Preparation method of lithium vanadate/carbon nanotube/carbon as lithium ion battery cathode composite material |
| CN107845781A (en) * | 2016-09-19 | 2018-03-27 | 微宏动力系统（湖州）有限公司 | Lithium ion secondary battery cathode active material, its preparation method and lithium rechargeable battery |
| CN107845781B (en) * | 2016-09-19 | 2022-01-18 | 微宏动力系统（湖州）有限公司 | Negative electrode active material for lithium ion secondary battery, method for producing same, and lithium ion secondary battery |
| CN106356510A (en) * | 2016-10-13 | 2017-01-25 | 中南大学 | Preparation method for Li-ion anode material FeVO4/C |
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