CN104195433B - A kind of high-strength tenacity pearlite steel rail and production method thereof - Google Patents

A kind of high-strength tenacity pearlite steel rail and production method thereof Download PDF

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Publication number
CN104195433B
CN104195433B CN201410443977.0A CN201410443977A CN104195433B CN 104195433 B CN104195433 B CN 104195433B CN 201410443977 A CN201410443977 A CN 201410443977A CN 104195433 B CN104195433 B CN 104195433B
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rail
pearlite steel
strength tenacity
steel rail
finish
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CN104195433A (en
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韩振宇
邹明
陶功明
郭华
李大东
邓勇
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Pangang Group Panzhihua Steel and Vanadium Co Ltd
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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Pangang Group Panzhihua Steel and Vanadium Co Ltd
Pangang Group Panzhihua Iron and Steel Research Institute Co Ltd
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Priority to CN201410443977.0A priority Critical patent/CN104195433B/en
Publication of CN104195433A publication Critical patent/CN104195433A/en
Priority to AU2015205937A priority patent/AU2015205937B2/en
Priority to US14/813,209 priority patent/US20160060736A1/en
Priority to BR102015020622A priority patent/BR102015020622A2/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/84Controlled slow cooling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/04Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rails
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

Present invention relates particularly to a kind of high-strength tenacity pearlite steel rail.A kind of high-strength tenacity pearlite steel rail, chemical composition meets: C:0.75 0.84%, Si0.3 0.8%, Mn0.5 1.5%, V0.04 0.12%, Ti0.004 0.02%, 0.1%≤V+10Ti≤0.25%, [N]≤30ppm, P≤0.02%, S≤0.008%, surplus is Fe and inevitable impurity;Control the technique in rolling process during preparation: start rolling temperature 1,120 1180 DEG C, finishing temperature 840 880 DEG C, the section minification 6 12% of last two passages, after finish to gauge, be cooled to less than 600 DEG C with the cooling rate of≤2 DEG C/s, continue air cooling to room temperature.The rail pearlitic grain using the method manufacture significantly refines, tensile strength >=1000MPa, and elongation percentage >=14% has good tough combination property.

Description

A kind of high-strength tenacity pearlite steel rail and production method thereof
Technical field
The present invention relates to a kind of rail, more particularly, relate to a kind of high-strength tenacity pearlite steel rail and production method thereof.
Background technology
The fast development of railway proposes requirements at the higher level to the military service performance of rail, particularly large conveying quantity, the weight of big axle weight Carrying railway, the too fast abrasion of rail cause descending road to become the key factor affecting rail transportation efficiency in advance, wear-resisting for improving The combination properties such as damage, typically use alloying, heat treatment or mode that both combine during Rail Production.But, by force The toughness plasticity causing pearlite steel rail the most relatively low is reduced by hardness improve further, situation about particularly improving in carbon content Under, even if using Technology for Heating Processing to play strong refined crystalline strengthening effect, the elongation percentage of rail still presents the trend of reduction, limits The pearlite steel rail development to more high-carbon content, more high wear resistance direction.Research shows, conventional pearlitic rail is studied It is concentrated mainly on chemical composition, Technology for Heating Processing aspect, for the operation of rolling of rail to microscopic structure and mechanical performance index Impact ignored.Pearlite steel rail combination property develop the most further the most difficult in the case of, meet roll By to operation of rolling Precise control on the premise of condition processed, and coordinate corresponding chemical composition, roller repairing technical study, Rail toughness plasticity particularly elongation percentage under conditions of keeping same intensity rank will significantly improve, and meet railway transportation rail Long service life and service safety demand.
Summary of the invention
It is an object of the invention to provide a kind of high-strength tenacity pearlite steel rail, gained pearlite steel rail intensity and toughness are equal More excellent.
Technical scheme:
The present invention provides a kind of high-strength tenacity pearlite steel rail,
The satisfied following requirement of this rail chemical composition: C:0.75%-0.84%, Si:0.30%-0.80%, Mn: 0.50%-1.50%, V:0.04%-0.12%, Ti:0.004%-0.02%, and meet 0.10%≤V+10Ti≤0.25%, [N]≤30ppm, P≤0.020%, S≤0.008%, surplus is Fe and inevitable impurity;
Further, the following process conditions in its rolling process are controlled when preparing described high-strength tenacity pearlite steel rail: steel Rail starts rolling temperature 1120-1180 DEG C, finishing temperature 840-880 DEG C, rolls the rail profile minification of last two passages 6%-12%, after finish to gauge, rail is cooled to less than 600 DEG C with the cooling rate of≤2.0 DEG C/s, is further continued for air cooling to room temperature.
After finish to gauge, rail is cooled to less than 600 DEG C employing compressed airs as cooling medium using the cooling rate of≤2.0 DEG C/s.
After finish to gauge, rail is cooled to less than 600 DEG C with the cooling rate of≤2.0 DEG C/s in cold bed standing.
The section of described rail is 50-75kg/m.
Inventor finds in research process, if the rail reaching fining austenite grains final excellent produces Product, need to be to the chemical composition of steel billet, heating and holding temperature, start rolling temperature, finishing temperature, last two passage amounts of rolling and remaining Hot rail carries out being uniformly coordinated control at cold bed process air cooler, could finally realize the production of high quality rail.
First, the restriction reason of essential element content in rail of the present invention is described in detail.
C is that pearlite steel rail improves strong hardness, promotes the element that perlitic transformation is most important, the most cheap, when C content < When 0.75%, under production technology of the present invention, intensity, hardness number are too low, it is impossible to ensure the abrasion resistance properties needed for rail;Work as C During content > 0.84%, even if using the acceleration cooling of≤2.0 DEG C/s after finish to gauge, trace secondary carburizing will be separated out at grain boundaries Body, deteriorates the toughness plasticity of rail;Therefore, C content is limited to 0.75%-0.84%.
Si is present in the intensity improving tissue in ferrite and austenite as the solution strengthening element in steel.When Si content During < 0.30%, solid solution capacity is on the low side to be caused strengthening DeGrain;As Si content > 0.80%, mould reducing the tough of rail Property, deteriorate the lateral performance of rail, be unfavorable for the use safety of rail.Therefore, Si content is limited to 0.30%-0.80%.
Mn can form solid solution with Fe, improves ferrite and the intensity of austenite.Meanwhile, Mn is again that carbide forms unit Element, can partly substitute Fe atom after entering cementite, increase the hardness of carbide, the final hardness increasing steel.As Mn content < When 0.50%, strengthening effect is not notable, is only capable of making the performance of steel slightly improve by solution strengthening;As Mn content > 1.50% Time, carbide much higher hard in steel, toughness plasticity substantially reduces;Meanwhile, Mn is notable on Carbon diffusion impact at steel, though air cooling bar Under part, Mn segregation zones still may produce the abnormal structures such as B, M.Therefore, Mn content is limited between 0.50%-1.50%.
When V is under room temperature condition, the dissolubility in steel is the lowest, and is the most such as present in austenite grain boundary Or other region, separate out with the vanadium carbonitride form of micronized particles shape, or precipitation compound with the Ti in steel, suppress austenite crystal The growth of grain, thus reach crystal grain thinning and put forward high performance purpose.When V content is less than 0.04%, the Carbonitride Precipitation containing V has Limit, it is difficult to play strengthening effect;As V content > 0.12%, it is easily formed thick carbonitride, deteriorates the toughness plasticity of rail. Therefore, V content is limited to 0.04%-0.12%.
Ti Main Function in steel is refinement heating, austenite crystal when rolling and cool down, and final increases prolonging of rail Stretch rate and rigidity, be one of important addition element of the present invention.As Ti content < 0.004%, the carbonization formed in rail Thing quantity is extremely limited;As Ti content > 0.02%, one side is strong carbonitride-forming elements due to Ti, the TiC of generation On the high side will make rail much higher hard;On the other hand, TiC is on the high side forms thick carbide by segregation enrichment, not only reduces toughness plasticity, Rail contact surface under impact loading is also made to be prone to cracking and cause fracture.Therefore, Ti content is limited to 0.004%- Between 0.02%.
V, Ti constituent content sum is explained in detail below and meets the reason of 0.10%≤V+10Ti≤0.25%: V, Ti in steel with The affinitys such as C, N and the quantity of formation carbide and form are clearly distinguished from, but form carbonitride fining austenite grains Effect be similar.As a example by V, in the steel that N content is relatively low, it is solid-solution in the V content of ferrite matrix more than 50%, and N contains Measuring in higher steel, the V being solid-solution in steel is about 20%, and the form of residue 70% vanadium carbonitride the most separates out.In the present invention In, individually add V or Ti the most notable to the improvement of performance, as add 0.10% V while without Ti rail strength still Can reach 1000MPa but elongation percentage is generally below 12%, and individually add Ti microalloying, the intensity of rail is unable to reach 1000MPa requirement, by repeatedly screening, it is believed that V, Ti content sum can reach when meeting 0.10%≤V+10Ti≤0.25% Purpose of the present invention.
Within N content is limited to 30ppm in the present invention, primarily to suppress the thick nitride containing V, Ti thick Change, thus reach to be formed the purpose of the carbide suppression Austenite Grain Growth of small and dispersed.
S mainly forms the difference of fragility and the vertically and horizontally performance causing steel in steel with MnS field trash, when S content≤ When 0.008%, purity of steel is higher, can be prevented effectively under wheel stress effect and be formed at the cavity of field trash and formation thereof Defect, and then affect the military service performance of rail.
Beneficial effects of the present invention:
The rail pearlitic grain using the method manufacture significantly refines, tensile strength >=1000MPa, and elongation percentage >= 14%, there is good tough combination property.
Detailed description of the invention
The satisfied following requirement of rail chemical composition of the present invention: C:0.75%-0.84%, Si:0.30%-0.80%, Mn: 0.50%-1.50%, V:0.04%-0.12%, Ti:0.004%-0.02%, and meet 0.1%≤V+10Ti≤0.25%, [N]≤30ppm, P≤0.020%, S≤0.015%, surplus is Fe and inevitable impurity.Use converter or electric furnace smelting Containing the molten steel of mentioned component, al-free deoxidation, reduce after LF refine after S content in steel, RH application of vacuum or VD process and carry out Molten steel continuous casting in target zone, is that cooling enters after 250mm × 250mm-450mm × 450mm section steel billet by trimming Heating furnace heats.Billet heating temperature >=1200 DEG C, insulation guarantees to go out after steel billet section blank temperature is uniformly to less than 3h Stove, removes iron scale through water under high pressure, and rail carries out the start rolling temperature of the first passage and is 1120-1180 DEG C, selects above-mentioned heating And thicker V, Ti precipitate that the reason of rolling temperature mainly solves to be formed in casting process dissolves or big portion again Dividing and dissolve, separate out tiny V, Ti carbonitride during steel rail rolling, pinning is in the austenite grain boundary of austenite phase field, Fining austenite grains, to reach the effect of the present invention.Finishing temperature 840-880 DEG C after five frames or seven frames roll, rolls Making rail profile minification 6%-12% of last two passages, after finish to gauge, rail stands cold with the cooling rate of≤2.0 DEG C/s at cold bed But to continuing air cooling when less than 600 DEG C to room temperature.Finishing temperature control is to ensure that have certain particle size the reason of 840-880 DEG C Precipitate stable, uniformly separate out;When temperature is higher than 880 DEG C, precipitate has the trend of roughening, has relied on the effect separated out Weaken;When temperature is less than 840 DEG C, precipitate is the most tiny, it is impossible to continue to play the effect of pinning austenite grain boundary;It addition, In the range of 840-880 DEG C, finishing temperature is the lowest, and in steel, the precipitation effect of V, Ti carbonitride is the most notable.Equally, rail is last Two passage deformation amount controlling are also the better performances being experimentally verified that at 6%-12%, and being simultaneously in mill load can bear Deflection scope.Rail completes to continue to continue cool to 600 DEG C with the cooling rate less than 2.0 DEG C/s after rolling arrives cold bed Main purpose is the formation of thick austenite structure before being still to ensure that pearlitic structrure phase transformation, jointly reaches the present invention with abovementioned steps Purpose.When rail temperature is less than 600 DEG C, continues to naturally cool to suitable temperature in atmosphere and complete to align, detect a flaw, add The operations such as work, final acquisition finished product rail.
Hereinafter, a kind of high-strength tenacity pearlite steel rail and production method thereof will be specifically described in conjunction with the embodiments.
Embodiment and corresponding comparative example all select following six groups of rail chemical compositions of the present invention.
Six groups of embodiments of table 1 present invention and comparative example chemical composition
Steel billet containing mentioned component is all rolled into 60kg/m rail, cool down technique after rolling and finish to gauge as shown in table 2; Comparative example uses existing routine techniques, as shown in table 3.
Six groups of embodiment rollings and roller repairing technological parameter in table 2 present invention
Six groups of comparative example rollings and roller repairing technological parameter in table 3 present invention
By the above-mentioned rail air cooling completing to process to room temperature, carry out rail head tension impact and microscopic structure test, knot respectively Fruit is shown in Table 4, and wherein, Rm represents tensile strength, and A is elongation after fracture, and wherein tension impact performance test is entered according to GB/T 228 Row test.
Six groups of embodiments of table 4 present invention and comparative example Some Mechanical Properties and microscopic structure
The present invention have chosen has identical chemical composition, different rolling and six groups of embodiments of roller repairing technique and corresponding Comparative example contrast, all rail tissues are pearlite.In an embodiment, the technique of employing is side of the present invention Method, separates out uniform, tiny carbonitride particle pinning austenite grain boundary in steel by V, Ti, significantly improves the tough of rail Plasticity particularly elongation percentage, six groups of rail strengths in the range of 1020MPa-1100MPa while elongation percentage reach 14.5%- 16.0%, there is more excellent obdurability coupling.By contrast, existing maturation process is used the most not to steel rail rolling and to roll rear high temperature Quite but elongation percentage is significantly lower than embodiment for the comparative example intensity level that section air cooling is controlled and embodiment, and higher plasticity is not only Ensure that the traffic safety of train, additionally aid the raising of rail contact fatigue.
Although specifically described a kind of controlled rolling pearlite steel rail and production method thereof, but the technology of this area Personnel it should be understood that without departing from the spirit and scope of the present invention, and the present invention can make various forms of changing Become.

Claims (6)

1. a high-strength tenacity pearlite steel rail, it is characterised in that this rail chemical composition meets following requirement: C:0.75%- 0.84%, Si:0.30%-0.80%, Mn:0.50%-1.50%, V:0.04%-0.12%, Ti:0.004%-0.02%, and Meeting 0.10%≤V+10Ti≤0.25%, [N]≤30ppm, P≤0.020%, S≤0.008%, surplus is Fe and can not keep away The impurity exempted from;
Further, the following process conditions in its rolling process are controlled when preparing described high-strength tenacity pearlite steel rail: rail is opened Beginning rolling temperature 1120-1180 DEG C, finishing temperature 840-880 DEG C, roll rail profile minification 6%-of last two passages 12%, after finish to gauge, rail is cooled to less than 600 DEG C with the cooling rate of≤2.0 DEG C/s, is further continued for air cooling to room temperature.
A kind of high-strength tenacity pearlite steel rail the most according to claim 1, it is characterised in that after finish to gauge, rail is with≤2.0 DEG C/cooling rate of s is cooled to less than 600 DEG C and uses compressed airs as cooling medium.
A kind of high-strength tenacity pearlite steel rail the most according to claim 1 and 2, it is characterised in that after finish to gauge rail with≤ The cooling rate of 2.0 DEG C/s stands at cold bed and is cooled to less than 600 DEG C.
4. the production method of a high-strength tenacity pearlite steel rail, it is characterised in that
The following process conditions in its rolling process are controlled: rail starts rolling when preparing described high-strength tenacity pearlite steel rail Temperature 1120-1180 DEG C, finishing temperature 840-880 DEG C, roll rail profile minification 6%-12% of last two passages, finish to gauge Rear rail is cooled to less than 600 DEG C with the cooling rate of≤2.0 DEG C/s, is further continued for air cooling to room temperature;
The satisfied following requirement of this rail chemical composition: C:0.75%-0.84%, Si:0.30%-0.80%, Mn:0.50%- 1.50%, V:0.04%-0.12%, Ti:0.004%-0.02%, and meet 0.10%≤V+10Ti≤0.25%, [N]≤ 30ppm, P≤0.020%, S≤0.008%, surplus is Fe and inevitable impurity.
The production method of a kind of high-strength tenacity pearlite steel rail the most according to claim 4, it is characterised in that steel after finish to gauge Rail is cooled to less than 600 DEG C employing compressed airs as cooling medium using the cooling rate of≤2.0 DEG C/s.
6. according to the production method of a kind of high-strength tenacity pearlite steel rail described in claim 4 or 5, it is characterised in that finish to gauge Rear rail is cooled to less than 600 DEG C with the cooling rate of≤2.0 DEG C/s in cold bed standing.
CN201410443977.0A 2014-09-02 2014-09-02 A kind of high-strength tenacity pearlite steel rail and production method thereof Active CN104195433B (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201410443977.0A CN104195433B (en) 2014-09-02 2014-09-02 A kind of high-strength tenacity pearlite steel rail and production method thereof
AU2015205937A AU2015205937B2 (en) 2014-09-02 2015-07-24 Pearlitic steel rail with high strength and toughness and producing method thereof
US14/813,209 US20160060736A1 (en) 2014-09-02 2015-07-30 Pearlitic steel rail with high strength and toughness and producing method thereof
BR102015020622A BR102015020622A2 (en) 2014-09-02 2015-08-26 high strength and toughness perlite steel rail and production method

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CN104195433B true CN104195433B (en) 2016-08-31

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CN106086663B (en) * 2016-07-14 2018-03-06 攀钢集团攀枝花钢铁研究院有限公司 A kind of hypereutectoid rail and preparation method thereof
CN106636916A (en) * 2016-11-30 2017-05-10 内蒙古包钢钢联股份有限公司 Rolled steel for steel rails of America railways and production method of rolled steel
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CN110468347B (en) * 2019-09-02 2021-07-06 鞍钢股份有限公司 Bainite steel rail with high strength and toughness and manufacturing method thereof
CN112195413A (en) * 2020-10-19 2021-01-08 攀钢集团攀枝花钢铁研究院有限公司 Fatigue-resistant steel rail of freeze-thaw circulating line and production method thereof
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CN114855082B (en) * 2022-04-26 2023-06-20 包头钢铁(集团)有限责任公司 Manufacturing method for improving low-temperature toughness of hot-rolled U75V steel rail by rare earth elements

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US20160060736A1 (en) 2016-03-03
AU2015205937B2 (en) 2016-07-28
BR102015020622A2 (en) 2016-05-31
CN104195433A (en) 2014-12-10

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