CN104194431A - Dampness and corrosion resistant organic silicone resin paint for copper sculpture - Google Patents

Abstract

The invention relates to paint and in particular relates to dampness and corrosion resistant organic silicone resin paint for a copper sculpture. The dampness and corrosion resistant organic silicone resin paint is prepared from the following raw materials in parts by weight: 30-34 parts of organic silicone resin, 10-12 parts of amino resin, 10-12 parts of polytrifluorochloroethylene resin, 4-6 parts of tetra-iso-propyl titanate, 10-12 parts of butyl acetate, 2-3 parts of dicyandiamide, 1-2 parts of stearic acid, 10-12 parts of 1,6-hexanediol diacrylate, 1-2 parts of vinyl-containing polysiloxane, 1-2 parts of ployoxyethylene stearic acid, 4-5 parts of glycerol rosin ester, 4-5 parts of turpentine, 1-2 parts of 3-amino propyl trimethoxy silane, 0.5-1 part of crosslinking agent TAC, 20-24 parts of N550 carbon black, 1-2 parts of dicumyl peroxide, 1-2 parts of methyl stannum mercaptide, 5-6 parts of adjuvant, 10-12 parts of xylene and 10-12 parts of butyl acetate. The dampness and corrosion resistant organic silicone resin paint has the advantages of strong adhesion, high glossiness, rust, impact, water and cold resistance, delays environmental corrosion, is relatively simple in production process and can be widely used for protecting various copper sculpture artware.

Description

The damp anticorrosion silicone resin paint of resistance for a kind of copper sculpture

Technical field

The present invention relates to a kind of paint, be specifically related to the damp anticorrosion silicone resin paint of a kind of copper sculpture resistance and preparation technology thereof.

Background technology

Copper sculpture is a class artwork common in daily life, there is higher artistic value and enjoying value, but, copper sculpture artwork is due to itself material character and the feature of putting environment, easily there is the problems such as oxidation corrosion, affect attractive in appearance and work-ing life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and copper sculpture is had to certain requirement with paint, such as sticking power, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, make the paint that is applicable to different use occasions, increase its artistic value.

Summary of the invention

The object of the invention is to, provide the resistance of a kind of copper sculpture damp anticorrosion silicone resin paint, to protect sculpture, to achieve these goals, the technical solution used in the present invention is as follows:

The damp anticorrosion silicone resin paint of resistance for a kind of copper sculpture, it is characterized in that, material of the present invention is made up of the raw material of following weight part: silicone resin 30-34, aminoresin 10-12, daiflon 10-12, isopropyl titanate 4-6, N-BUTYL ACETATE 10-12, Dyhard RU 100 2-3, stearic acid 1-2, 1, 6 hexanediyl ester 10-12, vinyl polysiloxane 1-2, polyoxyethylene 8 stearate ether 1-2, esterase 4-5, turps 4-5, 3-aminopropyl trimethoxysilane 1-2, linking agent TAC 0.5-1, N550 carbon black 20-24, dicumyl peroxide 1-2, Methyl stannum mercaptide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.

Described auxiliary agent is made up of the raw material of following weight part: clay 13-16, light calcium carbonate 2-3, zinc oxide 1-2, anilinomethyl triethoxysilane 2-3, triethylene tetramine 4-5, Tremoliteor Tremoliteasbestos 2-3, aluminium hydroxide 2-3, Vanay 35-40, Tenox PG 2-3, coix seed oil 1-2, vanadium diboride 2-3, l-Epicatechol 2-3; Its preparation method is that clay, light calcium carbonate, Tremoliteor Tremoliteasbestos are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds to form slurry, to obtain final product.

The damp anticorrosion silicone resin paint of resistance for described a kind of copper sculpture, its preparation technology is:

(1) N-BUTYL ACETATE, 1,6 hexanediyl ester, N550 carbon black, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 DEG C, adds isopropyl titanate, stearic acid, esterase, dicumyl peroxide, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.

Compared with prior art, copper sculpture provided by the invention is painted possesses following advantage: gloss of film degree is high, satisfactory mechanical property, and electrical insulation capability is superior, and moisture resistance waterproof is antirust cold-resistant, and resistance to ozone ageing can be widely used in all kinds of copper carving handicraft articles of protection.

Embodiment

Embodiment

The present embodiment paint is made up of following weight part raw material: silicone resin 34, aminoresin 12, daiflon 12, isopropyl titanate 6, N-BUTYL ACETATE 12, Dyhard RU 100 3, stearic acid 2,1,6 hexanediyl ester 12, vinyl polysiloxane 2, polyoxyethylene 8 stearate ether 2, esterase 5, turps 5,3-aminopropyl trimethoxysilane 2, linking agent TAC 1, N550 carbon black 22, dicumyl peroxide 2, Methyl stannum mercaptide 2, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.

Described auxiliary agent is made up of the raw material of following weight part: clay 15, light calcium carbonate 3, zinc oxide 2, anilinomethyl triethoxysilane 3, triethylene tetramine 5, Tremoliteor Tremoliteasbestos 3, aluminium hydroxide 3, Vanay 40, Tenox PG 3, coix seed oil 2, vanadium diboride 3, l-Epicatechol 3; Its preparation method is that clay, light calcium carbonate, Tremoliteor Tremoliteasbestos are sent in calcining furnace and at 720-740 DEG C, calcined 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, cleans with clear water, dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 50 minutes is cooling, grinds to form slurry, to obtain final product.

The damp anticorrosion silicone resin paint of resistance for described a kind of copper sculpture, its preparation technology is:

(1) N-BUTYL ACETATE, 1,6 hexanediyl ester, N550 carbon black, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 DEG C, adds isopropyl titanate, stearic acid, esterase, dicumyl peroxide, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.

The performance test results of the present invention's paint is:

Above-mentioned test is all followed relevant criterion and is carried out.

Claims (2)

1. the damp anticorrosion silicone resin paint of resistance for copper sculpture, it is characterized in that, this paint is made up of the raw material of following weight part: silicone resin 30-34, aminoresin 10-12, daiflon 10-12, isopropyl titanate 4-6, N-BUTYL ACETATE 10-12, Dyhard RU 100 2-3, stearic acid 1-2, 1, 6 hexanediyl ester 10-12, vinyl polysiloxane 1-2, polyoxyethylene 8 stearate ether 1-2, esterase 4-5, turps 4-5, 3-aminopropyl trimethoxysilane 1-2, linking agent TAC 0.5-1, N550 carbon black 20-24, dicumyl peroxide 1-2, Methyl stannum mercaptide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,

Described auxiliary agent is made up of the raw material of following weight part: clay 13-16, light calcium carbonate 2-3, zinc oxide 1-2, anilinomethyl triethoxysilane 2-3, triethylene tetramine 4-5, Tremoliteor Tremoliteasbestos 2-3, aluminium hydroxide 2-3, Vanay 35-40, Tenox PG 2-3, coix seed oil 1-2, vanadium diboride 2-3, l-Epicatechol 2-3; Its preparation method is that clay, light calcium carbonate, Tremoliteor Tremoliteasbestos are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filter, obtain filter residue, clean with clear water, dry, grind to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds to form slurry, to obtain final product.

2. the damp anticorrosion silicone resin paint of resistance for a kind of copper sculpture as claimed in claim 1, its manufacture craft is:

(1) N-BUTYL ACETATE, 1,6 hexanediyl ester, N550 carbon black, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 DEG C, adds isopropyl titanate, stearic acid, esterase, dicumyl peroxide, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.