CN104194033A - Preparation method of porous polyimide film - Google Patents
Preparation method of porous polyimide film Download PDFInfo
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- CN104194033A CN104194033A CN201410424288.5A CN201410424288A CN104194033A CN 104194033 A CN104194033 A CN 104194033A CN 201410424288 A CN201410424288 A CN 201410424288A CN 104194033 A CN104194033 A CN 104194033A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E60/10—Energy storage using batteries
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Abstract
The invention discloses a preparation method of a porous polyimide film. The method comprises the following steps: uniformly dispersing a pore forming substance in a polyamic acid solution to obtain a precursor solution, coating the obtained precursor solution onto a base surface, drying, carrying out thermal imidization, putting the obtained polyimide-pore forming substance composite film in an etching solution, etching to remove the pore forming substance, washing and drying to obtain the porous polyimide film, wherein the pore forming substance is nano-scale iron powder, nickel powder, ferronickel alloy powder or nickel zinc alloy powder. Compared with the prior art, by using the nano-scale metal iron powder, nickel powder, ferronickel alloy powder or nickel zinc alloy powder as the pore forming substance, the film material has favorable mechanical properties and favorable lithium ion electrolyte resistance on the premise of obtaining uniform nano pore distribution and high pore size uniformity.
Description
Technical field
The present invention relates to Kapton, be specifically related to a kind of preparation method of porous polyimide film.
Background technology
Power lithium-ion battery has the feature such as high discharge capacity, high current charge-discharge, and this just requires the diaphragm of power lithium ion battery must be thin and in the time of high temperature, possess good mechanical property (thermostability).The corrosion of polyimide is high temperature resistant owing to having, resistance to organic chemistry and the feature such as environmentally friendly, its porous film material is a good selection as the barrier film of power lithium-ion battery, thereby porous polyimide film becomes a current focus as the research of battery diaphragm.
Publication number is the preparation method that the patent of invention of CN101000951A, CN101665580A all discloses a kind of porous polyimide film, use non-volatile organic solvent (as whiteruss or mineral oil, epoxy soybean wet goods) as pore-forming substance, be mixed with polyamic acid-pore-forming substance laminated film with polyamic acid, then add hot imidization and obtain polyimide-pore-forming substance laminated film, finally use phase transfer method to remove pore-forming substance and obtain nanometer polyimide porous film.Though Nano film of multiporous polyimide prepared by aforesaid method has better mechanical property, but because the pore-forming substance adopting in method and polyamic acid can not dissolve each other, can not form more stable mixture, thereby can produce into material agglomeration in polyamic acid solidification process, affect homogeneity or the consistence in porous polyimide film hole.
Publication number is CN102516582A, CN101659753A, CN101638490A, in the preparation method of the disclosed Kaptons such as the patent of invention of CN101645497A and CN101656306A and US Patent No. 20100028779, use the oxide compound of alkaline-earth metal, oxyhydroxide, carbonate compound, alkali-metal phosphoric acid salt, the material such as carbonate compound and aluminium hydroxide is as pore-forming substance, previously prepared polyimide-pore-forming substance laminated film, then use phase transfer method to remove pore-forming substance and obtain the porous polyimide film of aperture between 50～300 nanometers.These inorganic pore-forming substance materials and polyamic acid can form uniform laminated film, cause that the porous polyimide film nanoporous obtaining is evenly distributed, microtexture is good, but the mechanical property of gained porous membrane is not good enough, there is the fragility as pottery, can not curling, bending.
In order to improve the mechanical property of porous polyimide film, researchist has carried out a large amount of research, if publication number is the patent of invention of CN102582138A, CN 1O2203174A, CN102844362A, adopt the method (thering is suitable aperture (0.01～5 micron) but the not good enough porous polyimide film of mechanical property is coated in the good macropore polyimide coating of mechanical property (cradling function) above) of multilayer polyimide film, to reach the mechanical property of improving porous film material, but this method has obviously increased the thickness of film.In addition, publication number is that the patent of invention of CN103383996A discloses a kind of method that uses soluble polyimide and inorganic pore-forming substance to prepare porous polyimide film, the porous polyimide film aperture of preparation evenly, good mechanical properties, but gained thin-film material can significantly reduce in mechanical property after the immersion of lithium-ion electrolyte, uncomfortable cooperation battery diaphragm.
Publication number is that the patents such as CN103132238A, CN 102383222A, CN103474600A, CN102251307A and CN102754242A all disclose and use the adhesive-bonded technology of electrostatic blended spinning to prepare polyimide nano-fiber film, the good mechanical properties of gained film, but be difficult to take into account the small and thickness index of two thin aspects again in aperture.
As the porous polyimide film of diaphragm of power lithium ion battery, its hole will be evenly distributed, good mechanical properties and solvent resistance better, therefore the porous polyimide film that, uses aforesaid method to obtain can not meet the requirement as diaphragm of power lithium ion battery.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of preparation method of porous polyimide film.The film nano pore distribution prepared by the method is even, aperture evenly, good mechanical properties and resistance to lithium-ion electrolyte good.
The preparation method of porous polyimide film of the present invention, comprise: pore-forming substance is dispersed in polyamic acid solution, obtain precursor solution, gained precursor solution is coated on matrix surface, after oven dry, carry out hot imidization, gained polyimide-pore-forming substance laminated film is placed in etching liquid etching and removes pore-forming substance, and washing obtains porous polyimide film after being dried; Wherein, described pore-forming substance is nano level iron powder, nickel powder, FeNi powders or nickel zinc alloy powder.
In above-mentioned preparation method; described polyamic acid solution is prepared by existing ordinary method; can be specifically: under gas shield condition, aromatic diamine is dissolved in organic solvent; then in mixing solutions, add dianhydride lentamente while stirring, reaction certain hour obtains polyamic acid solution.Wherein said aromatic diamine can be to be selected from Ursol D (PDA), mphenylenediamine (MDA), 4,4
/the combination of one or more of-diaminodiphenyl oxide (ODA) and benzidine; Described organic solvent can be one or more the combination that is selected from N-Methyl pyrrolidone, N,N-dimethylacetamide and DMF; Described dianhydride can be pyromellitic acid anhydride or 3,3 ', 4, and 4 '-biphenyl tetracarboxylic acid anhydrides etc.; The mol ratio of aromatic diamine and dianhydride is generally 1:1～1.02, and the mass concentration of polyamic acid solution is 10～20%.
In above-mentioned preparation method, be preferably between 30～80nm as the particle diameter of the nano level metal iron powder of pore-forming substance, nickel powder, FeNi powders or nickel zinc alloy powder, be controlled in 100nm with the maximum diameter of hole that ensures the porous polyimide film of preparing.In Nanoscale Iron nickel alloy powder described in the application, iron nickel ratio is 1:1, and in described nickel zinc alloy powder, iron nickel ratio is 1:1.
In above-mentioned preparation method, normally with stirring or ultrasonic mode, pore-forming substance is dispersed in polyamic acid solution.For pore-forming substance is better scattered in polyamic acid solution, preferably first by pore-forming substance with organic solvent moistening or disperse after join again in polyamic acid solution, organic solvent described in this can be N-Methyl pyrrolidone, N,N-dimethylacetamide or DMF.
In above-mentioned preparation method, the volume ratio of described pore-forming substance and polyimide is 0.43～1:1, with ensure that the porosity of porous polyimide film of preparation requires in lithium ion battery separator 30～50% between.
In above-mentioned preparation method, the precursor solution of gained is coated on to matrix surface, after oven dry, carry out hot imidization, obtain covering the polyimide-pore-forming substance laminated film on matrix, first be placed in remover and soak 0.5～1h demoulding covering polyimide-pore-forming substance laminated film on matrix, obtain polyimide-pore-forming substance laminated film, wherein, described releasing agent is that mass concentration is 10～30% mineral acid, and described mineral acid can be one or more the combination in hydrochloric acid, sulfuric acid and nitric acid etc.
In above-mentioned preparation method, described matrix can be conventional matrix in other prior art such as sheet glass or polyfluortetraethylene plate.
In above-mentioned preparation method, described etching liquid is that mass concentration is 10～30% mineral acid, and described mineral acid can be one or more the combination in hydrochloric acid, sulfuric acid and nitric acid etc.
Compared with prior art, it is pore-forming substance that the present invention adopts nano level metal iron powder, nickel powder, FeNi powders or nickel zinc alloy powder, make gained thin-film material obtain nanoporous be evenly distributed and the even proterties in aperture in, also there is good mechanical property and good resistance to lithium-ion electrolyte performance; The porosity of gained porous film material is between 30～50%, and aperture is approximately distributed in 20～100nm, and tensile strength is greater than 19.7Mpa, pierces through intensity and is greater than 145gf, and electrical conductivity of solution is less than 3.4 × 10
-5s/cm (in 1mol/L LiPB solution); Research to gained Kapton solvent resistance shows, the porous polyimide film of gained soaks after 180 days and still keeps original mechanical property in lithium-ion electrolyte.
Brief description of the drawings
Fig. 1 is the SEM figure of the thin-film material that makes of the embodiment of the present invention 1
Embodiment
With specific embodiment, the invention will be further described below, but the present invention is not limited to these embodiment.
Embodiment 1
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (1.08g) Ursol D (PDA) adds in 20g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.02 × 10
-2mole (2.22g) pyromellitic acid anhydride (PMDA), stirs after adding 8 hours, will obtain thickness polyamic acid polymer solution;
2) the nanometer iron powder 12.34g that is averaged particle diameter 50nm adds in 10g N-Methyl pyrrolidone solution, stir moistening (iron powder: it is 0.67:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 2 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to glass basis surface, at 60 DEG C of temperature, keep 1 hour, at 100 DEG C of temperature, keep after 1 hour again, then at 300 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 2 hours, obtains covering the polyimide-nanometer iron powder composite membrane on glass basis;
4) the above-mentioned polyimide-nanometer iron powder composite membrane covering on glass basis is soaked in 10% (quality) aqueous hydrochloric acid, at room temperature soaks 0.5 hour, polyimide-Nanoscale Iron composite membrane comes off from glass basis;
5) by step 4) gained polyimide-nanometer iron powder composite membrane is soaked in 10% (quality) aqueous hydrochloric acid, at 45 DEG C, process 1 hour to remove the iron in laminated film, with after deionized water repetitive scrubbing, at 120 DEG C, be dried 1 hour, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 20 μ m, and aperture is between 20～80nm, and porosity is 40%, porous nickel distributes (as shown in Figure 1), tensile strength is 20.8Mpa, and piercing through intensity is 157gf, and electrical conductivity of solution is 2.6 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/L LiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Embodiment 2
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (2.00g) 4,4
/-diaminodiphenyl oxide (ODA) adds in 25g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.00 × 10
-2mole (2.18g) pyromellitic acid anhydride (PMDA), stirs after adding 7 hours, will obtain thickness polyamic acid polymer solution;
2) the nanometer iron powder 10.01g that is averaged particle diameter 30nm adds in 20g N-Methyl pyrrolidone solution, stir moistening (nanometer iron powder: it is 0.43:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 3 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to glass basis surface, at 70 DEG C of temperature, keep 1 hour, at 120 DEG C of temperature, keep after 0.5 hour again, then at 320 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 1 hour, obtains covering the polyimide-Nanoscale Iron composite membrane on glass basis;
4) the above-mentioned polyimide-Nanoscale Iron composite membrane covering on glass basis is soaked in 25% (quality) aqueous sulfuric acid, at room temperature soaks 1 hour, polyimide-Nanoscale Iron composite membrane comes off from glass basis;
5) by step 4) gained polyimide-Nanoscale Iron composite membrane is soaked in 25% (quality) aqueous sulfuric acid, at 60 DEG C, process 0.5 hour to remove the iron in laminated film, with after deionized water repetitive scrubbing, at 120 DEG C, be dried 1 hour, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 18 μ m, and aperture is between 20～50nm, and porosity is 30%, and tensile strength is 19.7Mpa, and piercing through intensity is 163gf, and electrical conductivity of solution is 3.4 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/LLiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Embodiment 3
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (1.84g) 4,4
/-benzidine adds in 21g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.00 × 10
-2mole (2.18g) pyromellitic acid anhydride (PMDA), stirs after adding 6 hours, will obtain thickness polyamic acid polymer solution;
2) the nano-nickel powder 25.58g that is averaged particle diameter 50nm adds in 20g N-Methyl pyrrolidone solution, stir moistening (nickel powder: it is 1:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 3 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to glass basis surface, at 60 DEG C of temperature, keep 2 hours, at 120 DEG C of temperature, keep after 0.5 hour again, then at 300 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 2 hours, obtains covering the polyimide-nano nickel composite membrane on glass basis;
4) the above-mentioned polyimide-nano nickel composite membrane covering on glass basis is soaked in 15% (quality) aqueous hydrochloric acid, at room temperature soaks 0.5 hour, polyimide-nano nickel composite membrane comes off from glass basis;
5) by step 4) gained polyimide-nano nickel composite membrane is soaked in 15% (quality) aqueous hydrochloric acid, at 50 DEG C, process 1 hour to remove the nickel in laminated film, with after deionized water repetitive scrubbing, at 110 DEG C, be dried 2 hours, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 22 μ m, and aperture is between 20～80nm, and porosity is 50%, and tensile strength is 24.1Mpa, and piercing through intensity is 145gf, and electrical conductivity of solution is 2.4 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/LLiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Embodiment 4
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (1.08g) Ursol D (PDA) adds in 25g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.02 × 10
-2mole (3.00g) 3,3
/, 4,4
/-bibenzene tetracarboxylic dianhydride (BPDA), stirs after adding 6 hours, will obtain thickness polyamic acid polymer solution;
2) the nano nickel Zinc alloy powder 12.58g that is averaged particle diameter 80nm adds in 10g N-Methyl pyrrolidone solution, stir moistening (nickel zinc alloy powder (wherein iron nickel ratio is 1:1): it is 0.54:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 3 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to glass basis surface, at 60 DEG C of temperature, keep 1 hour, at 100 DEG C of temperature, keep after 1 hour again, then at 300 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 2 hours, obtains covering the polyimide-nano nickel zinc alloy composite membrane on glass basis;
4) the above-mentioned polyimide-nano nickel zinc alloy composite membrane covering on glass basis is soaked in 10% (quality) aqueous hydrochloric acid, at room temperature soak 0.5 hour, polyimide-nano nickel zinc alloy composite membrane comes off from glass basis;
5) by step 4) gained polyimide-nano nickel zinc alloy composite membrane is soaked in 10% (quality) aqueous hydrochloric acid, at 45 DEG C, process 1 hour to remove the nickel zinc alloy in laminated film, with after deionized water repetitive scrubbing, at 120 DEG C, be dried 1 hour, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 25 μ m, and aperture is between 50～100nm, and porosity is 35%, and tensile strength is 21.5Mpa, and piercing through intensity is 172gf, and electrical conductivity of solution is 2.6 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/LLiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Embodiment 5
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (2.00g) 4,4
/-diaminodiphenyl oxide (ODA) adds in 30g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.00 × 10
-2mole (2.94g) 3,3
/, 4,4
/-bibenzene tetracarboxylic dianhydride (BPDA), stirs after adding 7 hours, will obtain thickness polyamic acid polymer solution;
2) the nano nickel Zinc alloy powder 23.23g that is averaged particle diameter 80nm adds in 20g N-Methyl pyrrolidone solution, stir moistening (nickel zinc alloy powder (wherein nickel zinc ratio is 1:1): it is 0.82:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 3 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to polyfluortetraethylene plate matrix surface, at 70 DEG C of temperature, keep 1 hour, at 120 DEG C of temperature, keep after 0.5 hour again, then at 320 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 1 hour, obtains covering the polyimide-nano nickel zinc alloy composite membrane on tetrafluoroethylene board substrate;
4) the above-mentioned polyimide-nano nickel zinc alloy composite membrane covering on tetrafluoroethylene board substrate is soaked in 25% (quality) aqueous sulfuric acid, at room temperature soak 1 hour, polyimide-nano nickel zinc alloy composite membrane comes off from tetrafluoroethylene board substrate;
5) by step 4) gained polyimide-nano nickel zinc alloy composite membrane is soaked in 25% (quality) aqueous sulfuric acid, at 60 DEG C, process 0.5 hour to remove the nickel zinc alloy in laminated film, with after deionized water repetitive scrubbing, at 120 DEG C, be dried 1 hour, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 21 μ m, and aperture is between 50～100nm, and porosity is 45%, and tensile strength is 21.3Mpa, and piercing through intensity is 155gf, and electrical conductivity of solution is 2.5 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/LLiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Embodiment 6
1) under nitrogen atmosphere protection, by 1.00 × 10
-2mole (1.84g) 4,4
/-benzidine adds in 30g N-Methyl pyrrolidone solution, and stirring at room temperature is dissolved, more slowly adds 1.00 × 10
-2mole (2.94g) 3,3
/, 4,4
/-bibenzene tetracarboxylic dianhydride (BPDA), stirs after adding 8 hours, will obtain thickness polyamic acid polymer solution;
2) the Nanoscale Iron nickel alloy powder 19.12g that is averaged particle diameter 50nm adds in 20g N-Methyl pyrrolidone solution, stir moistening (FeNi powders (wherein iron nickel ratio is 1:1): it is 0.67:1 that polyimide is amounted to volume ratio), then join in above-mentioned polyamic acid polymer solution, be uniformly mixed 3 hours, obtain masking precursor solution;
3) gained masking presoma is coated on to sheet glass matrix surface, at 60 DEG C of temperature, keep 2 hours, at 120 DEG C of temperature, keep after 0.5 hour again, then at 300 DEG C of temperature, thermal treatment makes the sub-hot amination of polyamic acid for 2 hours, obtains covering the polyimide-Nanoscale Iron nickelalloy composite membrane on sheet glass matrix;
4) the above-mentioned polyimide-Nanoscale Iron nickelalloy composite membrane covering on sheet glass matrix is soaked in 15% (quality) aqueous hydrochloric acid, at room temperature soak 0.5 hour, polyimide-Nanoscale Iron nickelalloy composite membrane comes off from sheet glass matrix;
5) by step 4) gained polyimide-Nanoscale Iron nickelalloy composite membrane is soaked in 15% (quality) aqueous hydrochloric acid, at 50 DEG C, process 1 hour to remove the iron-nickel alloy in laminated film, with after deionized water repetitive scrubbing, at 110 DEG C, be dried 2 hours, obtain Nano film of multiporous polyimide.
The thickness of the present embodiment gained porous polyimide film is 24 μ m, and aperture is between 50～100nm, and porosity is 40%, and tensile strength is 22.7Mpa, and piercing through intensity is 176gf, and electrical conductivity of solution is 2.6 × 10
-5s/cm (1mol/L LiPF
6in solution), this porous polyimide film is at 1mol/LLiPF
6in lithium-ion electrolyte, soak after 180 days and still keep original mechanical property.
Claims (7)
1. the preparation method of a porous polyimide film, it is characterized in that: pore-forming substance is dispersed in polyamic acid solution, obtain precursor solution, gained precursor solution is coated on matrix surface, after oven dry, carry out hot imidization, gained polyimide-pore-forming substance laminated film is placed in etching liquid etching and removes pore-forming substance, and washing obtains porous polyimide film after being dried; Wherein, described pore-forming substance is nano level iron powder, nickel powder, FeNi powders or nickel zinc alloy powder.
2. preparation method according to claim 1, is characterized in that: the particle diameter of described pore-forming substance is 30～80nm.
3. preparation method according to claim 1, is characterized in that: will after moistening pore-forming substance organic solvent or dispersion, join in polyamic acid solution again.
4. preparation method according to claim 3, is characterized in that: described organic solvent is N-Methyl pyrrolidone, N,N-dimethylacetamide or DMF.
5. preparation method according to claim 1, is characterized in that: the mass concentration of described polyamic acid solution is 10～20%.
6. preparation method according to claim 1, is characterized in that: the volume ratio of described pore-forming substance and polyimide is 0.43～1:1.
7. preparation method according to claim 1, is characterized in that: described etching liquid is that mass concentration is one or more the combination in 10～30% mineral acid.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106142592A (en) * | 2015-04-01 | 2016-11-23 | 深圳光启尖端技术有限责任公司 | A kind of vacuum bag transfer moulding method and for the molded isolating membrane of vacuum bag |
| CN107099048A (en) * | 2017-03-13 | 2017-08-29 | 桂林电器科学研究院有限公司 | A kind of preparation method of solvent-proof porous polyimide film |
| CN108327377A (en) * | 2018-03-13 | 2018-07-27 | 广西师范大学 | A kind of preparation facilities of polyimide film or polyimide copper clad lamination |
| CN108539097A (en) * | 2018-04-10 | 2018-09-14 | 深圳市摩码科技有限公司 | A kind of lithium battery diaphragm, preparation method and lithium battery |
| CN111234304A (en) * | 2020-01-22 | 2020-06-05 | 北京工商大学 | Polyaniline @ silver nanowire/polyimide porous gradient composite film, preparation method and application |
| CN114425893A (en) * | 2022-02-09 | 2022-05-03 | 高梵(浙江)信息技术有限公司 | High-strength anti-tearing fabric structure |
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2014
- 2014-08-26 CN CN201410424288.5A patent/CN104194033A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106142592A (en) * | 2015-04-01 | 2016-11-23 | 深圳光启尖端技术有限责任公司 | A kind of vacuum bag transfer moulding method and for the molded isolating membrane of vacuum bag |
| CN107099048A (en) * | 2017-03-13 | 2017-08-29 | 桂林电器科学研究院有限公司 | A kind of preparation method of solvent-proof porous polyimide film |
| CN107099048B (en) * | 2017-03-13 | 2020-05-08 | 桂林电器科学研究院有限公司 | Preparation method of solvent-resistant porous polyimide film |
| CN108327377A (en) * | 2018-03-13 | 2018-07-27 | 广西师范大学 | A kind of preparation facilities of polyimide film or polyimide copper clad lamination |
| CN108327377B (en) * | 2018-03-13 | 2023-05-23 | 广西师范大学 | Polyimide film or polyimide copper-clad plate's preparation facilities |
| CN108539097A (en) * | 2018-04-10 | 2018-09-14 | 深圳市摩码科技有限公司 | A kind of lithium battery diaphragm, preparation method and lithium battery |
| CN111234304A (en) * | 2020-01-22 | 2020-06-05 | 北京工商大学 | Polyaniline @ silver nanowire/polyimide porous gradient composite film, preparation method and application |
| CN111234304B (en) * | 2020-01-22 | 2022-09-06 | 北京工商大学 | Polyaniline @ silver nanowire/polyimide porous gradient composite film, preparation method and application |
| CN114425893A (en) * | 2022-02-09 | 2022-05-03 | 高梵(浙江)信息技术有限公司 | High-strength anti-tearing fabric structure |
| CN114775288A (en) * | 2022-02-09 | 2022-07-22 | 高梵(浙江)信息技术有限公司 | Preparation method of flame-retardant tear-resistant fabric |
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