CN104193403A - Marble rust spot removing liquid - Google Patents

Marble rust spot removing liquid Download PDF

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Publication number
CN104193403A
CN104193403A CN201410417458.7A CN201410417458A CN104193403A CN 104193403 A CN104193403 A CN 104193403A CN 201410417458 A CN201410417458 A CN 201410417458A CN 104193403 A CN104193403 A CN 104193403A
Authority
CN
China
Prior art keywords
marble
rust
removing liquid
liquid
rust staining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410417458.7A
Other languages
Chinese (zh)
Inventor
蔡元兴
徐淑波
孙爱花
李东东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Jianzhu University
Original Assignee
Shandong Jianzhu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Jianzhu University filed Critical Shandong Jianzhu University
Priority to CN201410417458.7A priority Critical patent/CN104193403A/en
Publication of CN104193403A publication Critical patent/CN104193403A/en
Pending legal-status Critical Current

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  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention relates to a marble rust spot removing liquid. According to the process formula, the liquid comprises triammonium citrate, oxalic acid and ammonium bifluoride. According to the marble rust spot removing liquid, due to the balance effect that the three above substances are adopted to complex, dissolve and deposit with calcium ions, rust can be easily removed from the surface of marble, so that the rust removing effect is improved, and meanwhile the surface smoothness of the marble is protected.

Description

A kind of marble rust staining is removed liquid
Technical field
The present invention relates to marble surface machining field, relate in particular to a kind of rust staining Transformatin that has rust staining marble surface.
Background technology
Polishing, smooth as fat, very magnificent high-end.Marble in use, is easy to contaminated and pathology, particularly for white marbles such as white marbles.In many illnesss, it is modal that marble surface produces rust staining.Therefore, the genesis mechanism of research rust staining, removes rust staining to greatest extent, has extraordinary practical value.
Summary of the invention
Marble be limestone and dolomite under high temperature, High Pressure again crystalline metamorphism form, main component is taking calcium carbonate as main, other also has magnesiumcarbonate, calcium oxide, manganese oxide and silicon-dioxide etc.Marble stone matter exquisiteness, is to provide a kind of marble rust staining of removing marble surface rust staining through the technical problem to be solved in the present invention and removes liquid.
The present invention adopts following technical scheme to realize goal of the invention:
A kind of marble rust staining is removed liquid, it is characterized in that, technical recipe comprises Triammonium citrate, oxalic acid and ammonium bifluoride, and technical recipe content is Triammonium citrate 10~60g/L, oxalic acid 20~80g/L, ammonium bifluoride 10~50 g/L.
Compared with prior art, advantage of the present invention and positively effect are: technical recipe comprises Triammonium citrate, oxalic acid and ammonium bifluoride.The present invention utilizes the counterbalance effect of the complexing Solution and precipitation of these three kinds of materials and calcium ion, and iron rust is more easily departed from from marble surface, thereby increases rust cleaning effect, protects marmorean surface smoothness simultaneously.
Embodiment
Below in conjunction with specific embodiment, the present invention is done further to describe in detail.
Embodiment 1
Weigh Triammonium citrate 10g, oxalic acid 20g, ammonium bifluoride 10g, adds in the water of 900ml, and wiring solution-forming is diluted with water to 1L after dissolving completely, then stirs.Prepare and remove after liquid, the marble with rust staining was soaked after 8 hours,, take out marble surface, rust staining is removed clean.
Embodiment 2
Weigh Triammonium citrate 60g, oxalic acid 80, ammonium bifluoride 50, adds in the water of 900ml, and wiring solution-forming is diluted with water to 1L after dissolving completely, then stirs.Prepare and remove after liquid, the marble with rust staining was soaked after 8 hours,, take out marble surface, rust staining is removed clean.
Embodiment 3
Weigh Triammonium citrate 10g, oxalic acid 40, ammonium bifluoride 30, adds in the water of 900ml, and wiring solution-forming is diluted with water to 1L after dissolving completely, then stirs.Prepare and remove after liquid, the marble with rust staining was soaked after 8 hours,, take out marble surface, rust staining is removed clean.

Claims (1)

1. marble rust staining is removed a liquid, it is characterized in that, technical recipe comprises Triammonium citrate, oxalic acid and ammonium bifluoride, and technical recipe content is Triammonium citrate 10~60g/L, oxalic acid 20~80g/L, ammonium bifluoride 10~50 g/L.
CN201410417458.7A 2014-08-24 2014-08-24 Marble rust spot removing liquid Pending CN104193403A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410417458.7A CN104193403A (en) 2014-08-24 2014-08-24 Marble rust spot removing liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410417458.7A CN104193403A (en) 2014-08-24 2014-08-24 Marble rust spot removing liquid

Publications (1)

Publication Number Publication Date
CN104193403A true CN104193403A (en) 2014-12-10

Family

ID=52078819

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410417458.7A Pending CN104193403A (en) 2014-08-24 2014-08-24 Marble rust spot removing liquid

Country Status (1)

Country Link
CN (1) CN104193403A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106024A (en) * 1986-09-11 1987-02-25 上海市日用化学工业研究所 Cleaner compositions and preparation thereof and application
KR20020023901A (en) * 2001-12-27 2002-03-29 지경호 Cleaning agent composition of stone surface
CN1425732A (en) * 2002-12-26 2003-06-25 天津市长芦精细生化有限公司 Anti-rust snow melting anti-freezing agent
CN103525591A (en) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 Environment-friendly cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86106024A (en) * 1986-09-11 1987-02-25 上海市日用化学工业研究所 Cleaner compositions and preparation thereof and application
KR20020023901A (en) * 2001-12-27 2002-03-29 지경호 Cleaning agent composition of stone surface
CN1425732A (en) * 2002-12-26 2003-06-25 天津市长芦精细生化有限公司 Anti-rust snow melting anti-freezing agent
CN103525591A (en) * 2013-10-21 2014-01-22 柳州鑫磊科技有限公司 Environment-friendly cleaning agent

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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20141210