CN104193312B - Tourmalinite matter chromatic ceramics and application apparatus thereof - Google Patents
Tourmalinite matter chromatic ceramics and application apparatus thereof Download PDFInfo
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- CN104193312B CN104193312B CN201410421250.2A CN201410421250A CN104193312B CN 104193312 B CN104193312 B CN 104193312B CN 201410421250 A CN201410421250 A CN 201410421250A CN 104193312 B CN104193312 B CN 104193312B
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Abstract
The present invention discloses a kind of tourmalinite matter chromatic ceramics and application apparatus thereof, it is characterized in that: this stupalith comprises: tourmalinite 1 ~ 35wt%, tinting material 1 ~ 65wt%, shale 0 ~ 55wt%, red soil 0 ~ 50wt%, without the glassiness fusing assistant 15 ~ 35wt% of MgO, ZnO, additional shaping additive 0 ~ 15wt%.Obtained product application, at the device of energy-conservation, healthcare field and articles for use, comprises the efficient desalting equipment of solar energy sea water, the water pre-treatment means improving thermal power generation evaporation of water efficiency, people and animals and plants health-care product etc.
Description
Technical field
The present invention relates to tourmalinite matter chromatic ceramics technical field, and the device of multiple energy-efficient, the environment-protecting health-care to make with obtained product or articles for use, comprise the efficient desalting equipment of solar energy sea water, the pretreatment system improving thermal power generation evaporation of water efficiency, people and animals and plants health-care product.
Background technology
Tourmalinite is commonly called as tourmaline, English name Tourmaline (Tourmaline), is to contain the ring texture silicate minerals that boron is characteristic feature.There is spontaneous electrode, in surface thickness tens micrometer range, have 10 in tourmalinite
4~ 10
7the high field intensity of V/m ... these characteristics make tourmalinite have many critical functions, as produced negative aeroion, emitting far-infrared, brine electrolysis, generation hydrogen, optimizing tap water, shielding electromagnetic wave etc., thus in improvement air and water pollution, raising people ' s health level, tap a new source of energy, promote to play a significant role in social sustainable development.Research finds, after tourmalinite and water effect, associated molecule number can be made to be generally the large water clusters of 30 ~ 40, resolve into the subset that 5 ~ 6 associated water molecules become, the momentum of water clusters is increased, and the surface tension causing water is reduced to 72.049mNm by 72.571 of initial value
-1(Hank ' surface tension of s simulated body fluid reduces to 71.868mNm by 72.485
-1), so, water molecules more easily breaks through capillary constraint, can evaporate sooner, and actual test shows, after water contacts with tourmalinite, its velocity of evaporation can improve 10.4%; Tourmalinite can also significantly improve perviousness and the dissolving power of water, oxygen in water speed improve 7.8%, specific conductivity improve 9.8%, calcium, magnesium salts become more soluble in water, and in water the more Ca of stripping
2+, Mg
2+, allow hard water more easily be softened, effectively reduce incrustation scale ..., etc.Evaporation of water speed is made to improve the characteristic of 10% after tourmalinite and water effect, light for producing with evaporation mode
the desalination process of water, and existing conventional Power Generation Mode (water-heat-be evaporated to steam-pushing turbine-generating), have huge energy-saving and emission-reduction meaning.But up to the present, tourmalinite and the goods with tourmalinite made by raw material and device, all do not use the performance that tourmaline capable improves water velocity of evaporation.
In the past, all kinds of tourmaline ceramic was not painted specially, result, can not obtain more purposes, higher using function, win wider market, obtained larger commercial value.In fact, color increases product artistic value, raising using function, broaden application field, and then improve the important channel of commodity value.
Such as, tourmaline ceramic is fired into black, greatly can increase its absorption to photo-thermal, effectively add the working medium such as warm air, water, simultaneously, tourmalinite can make evaporation of water speed improve more than 10%, and this makes aphrizite pottery can be used for the pre-treatment of solar energy sea water distillation desalination, thermal power generation water ...Although have production technology and the product of many black porcelain at present, but generally all burn till more than 1000 DEG C, not only energy consumption is high, discharge is large, and, tourmaline ceramic is fired with the high temperature firing technology of existing more than 1000 DEG C, tourmalinite will be made when burning till because breaking through its qualitative change stagnation point (900 DEG C) to decompose melting, lose its original function;
And for example, tourmaline ceramic is made the product (such as various sculpture, mural painting) that the product of multiple color or multiple color are combined, can broaden application field, increase artistic grade, meet people's multiple demands, thus increase desire to purchase, expand market;
For another example, the existing multiple patent of current tourmaline purple sand pottery, comprise " a kind of tourmaline purple sand goods " (application number: 03141973.9), " light-weight foaming tourmaline purple sand material and preparation method thereof " (application number: 200810041318.9), " anion healthy boccaro teapot " (application number: 201210009248.5), " to cardiovascular purple-clay product with health role and preparation method " (application number: 201210134046.3), " purple-clay product of removal garden stuff pesticide residue thing and heavy metal " (application number: 201210298358.8), but they are all utilize the natural Cr contained in purple clay, the color development of Mn compound, and burn out Zhu with strong chinese tradition tone, purple, cream colour three looks (true qualities for boccaro ware), and derive the color of nearly tens kinds., on European Union, the U.S., Japan, Korea S and other places, have strict restriction to Cr, the Mn in daily utensil, this causes the inherent electrothermal dark-red pottery just containing Cr, Mn compound, can not export sales to above-mentioned country.And, above-mentioned patented technology, be tourmalinite or the binary batching containing the negative ion powder+purple clay of tourmalinite, all do not allocate fusing assistant into specially, but utilize the unit of fluxing that purple clay and tourmalinite self contain usually to burn till, cause the sintering temperature of product up to 900 ~ 1100 DEG C, and the decomposition of tourmalinite, melt temperature is below 890 ~ 900 DEG C, so high temperature can cause that tourmalinite decomposes when burning till, melting, reduces effect of tourmalinite product.
Although patent application " tourmaline integral honeycomb ceramic and preparation method thereof " (application number 201110161532.X) also uses fusing assistant to reduce firing temperature, realize completing easy fired before tourmalinite decomposition, melting, but its fusing assistant forms containing magnesium raw material by containing magnesia clinker+talcum, talc clay, rhombspar etc., this patent is also that key element is prepared burden with attaclay simultaneously, and MgO is the raw material being unfavorable for toner color development, its existence can water down the painted of toner, even makes toner colour killing, completely colourless.
In view of this, should by innovation, take to add healthy, safe tinting material and make product painted, and adopt without the efficient fusing assistant of impact, the problems referred to above are solved to toner.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of prior art, provide one can increase steam productive rate, the tourmalinite matter chromatic ceramics of energy-saving and environmental protection more.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: a kind of tourmalinite matter chromatic ceramics, this pottery is prepared from by each component of following weight percent hundred: tourmalinite 1 ~ 35wt%, tinting material 1 ~ 65wt%, shale 0 ~ 55wt%, red soil 0 ~ 50wt%, without the glassiness fusing assistant 15 ~ 35wt% of MgO, ZnO, additional shaping additive 0 ~ 15wt%.
Tourmalinite of the present invention is one or more mixture of iron tourmaline, elbaite, dravite, and fineness is that less than 10 μm particles account for more than 95%.
Tinting material of the present invention is pottery, enamel, the synthesis colorant of glass is (as Fe-Cr-Co, Fe-Cr-Co-Mn, Fe-Cr-Cu system black pigment, parcel carbon black colorant, parcel cadmium yellow colorant, chrome green colorant), containing Fe, Ti, Mn, Cr, Ni, Co, Cu, the chemical industry of V and nonferrous smelting product are (as iron oxide red, titanium dioxide, titanium slag, industrial oxidation manganese), containing Fe, Ti, Mn, Cr, Ni, Co, Cu, V natural mineral and precision work mineral thereof are (as iron ore fine powder, ilmenite, chromite, vanadium titano-magnetite), containing Fe, Ti, Mn, Cr, Ni, Co, Cu, the mine tailing of V and slag are (as iron alloy and Iron And Steel Industry waste residue, vanadium titano-magnetite vanadium extraction mine tailing, electrolytic manganese residues, the pyrite cinder of chemical engineering industry) one or more, fineness all requires below 325 orders, tinting material proportion optimization shared by blank is 3 ~ 65wt%.
Shale of the present invention be opal light shale, dunn bass (argillaceousshale), irony shale, carbonaceous shale one or more, require that fineness meets below 200 orders.
Does is red soil of the present invention (also known as red soil, shown in Baidupedia http://baike.baidu.com/view/56804.htm? fr=aladdin) for growing the soil under Perenniporia martius rain woods ﹑ monsoonal forest or evergreen broad-leaved forest vegetation.Its principal character lacks alkali and alkaline earth metal ions and is rich in Tie ﹑ aluminum oxide, and in acid, color and luster is red, and particle is trickle, has fine plasticity-and viscosity, requires that fineness is below 250 orders.
Glassiness fusing assistant system without MgO, ZnO of the present invention consists of SiO
253 ~ 55%, Al
2o
321 ~ 23%, B
2o
36.5 ~ 8.5%, the glass of CaO12 ~ 14%, BaO2.5 ~ 3.5%, this fusing assistant is not unfavorable for the compound of toner color development containing MgO, ZnO etc., also not containing Toxics such as PbO, CdO, and fusing point low (650 DEG C start melting), therefore can broadly adapt to various toner, guarantee normal color development, nontoxic, environmental protection in addition, low temperature, energy-conservation advantage.Fusing assistant requires that granularity is less than 45 μm.
Shaping additive of the present invention comprise in W-Gum, dextrin, carboxymethyl cellulose, polyvinyl alcohol, Vltra tears, tung oil, glycerine one or more, they work to increase blank plasticity-, associativity and be convenient to be shaped and improve work in-process intensity in technological process, because they are all organism, all can burn when burning till and lose, pottery can be made to retain certain porosity.
The preparation technology of colored tourmalinite matter pottery of the present invention is except firing temperature is lower than except 850 DEG C, and other are all identical with conventional ceramic production technique, and its technical process is: feed proportioning → pulverize, mix → be shaped → dry → burn till → product.
A kind of solar energy sea water desalination apparatus utilizing above-mentioned tourmalinite matter chromatic ceramics of the present invention, this device comprises the framework holding seawater, and framework top is provided with lens, and lens inwall is provided with fresh water collecting groove; The inner bottom part of described framework is provided with thermal insulation layer, is provided with tourmalinite matter color ceramic enamel coating above thermal insulation layer, is provided with sea water layer above tourmalinite matter color ceramic enamel coating.
The present invention's another kind utilizes the thermal power generation evaporation of water pretreatment unit of tourmalinite matter chromatic ceramics, this device comprises tourmalinite matter chromatic ceramics housing, and described tourmalinite matter chromatic ceramics enclosure interior is provided with latticed tourmalinite matter chromatic ceramics water stream channel.
Advantage of the present invention and beneficial effect:
1. colored tourmalinite matter pottery of the present invention have employed the special glassiness fusing assistant without MgO, ZnO, the compound of toner color development is not unfavorable for containing MgO, ZnO etc., also not containing Toxics such as PbO, CdO, and fusing point low (650 DEG C of meltings), tourmalinite is not easily decomposed when burning till, melting, thus improve effect of tourmalinite product
and can broadly adapt to various toner, guarantee normal color development, nontoxic, environmental protection in addition, low temperature, energy-conservation advantage; The product made can be used for making multiple energy-conservation, protection device or articles for use.Such as: solar energy sea water desalination apparatus (Fig. 1).In this device, the tourmalinite matter pottery (corrugated or plate shaped) of black is installed.Like this, not only effectively can absorb the heat energy of solar radiation, and tourmaline ceramic can reduce water clusters, the momentum of the son effusion water surface that moisturizes, more water can be made to be evaporated to steam, thus there is the efficiency of the distillation fresh water higher than common solar energy sea water desalination apparatus; The high-efficiency evaporating pretreatment unit (Fig. 2) of thermal power generation water.The outdoor tourmalinite honeycomb ceramic hydraulic pipe installing black additional before entering boiler, when water flows through in ceramic honey comb pipeline, on the one hand the ceramic honey comb of black accepts solar light irradiation and accumulation of heat, intensification, transfer heat to ducted current, water preheat is heated up, tourmaline ceramic carries out electropolarization to the current flow through in pipe on the other hand, makes water clusters reduce and activate, becomes and more easily change into gaseous state.Like this, through preheating with the water of (namely water molecules is more easily converted into gaseous state) of activation, water temperature improves and the increase of water molecules molecular momentum, after it enters boiler, steam productive rate will increase, thus reduces the fire coal consumption and dust, CO of producing steam per ton
2, SO
2, NO
xdeng discharge; Can also directly make to human body and animals and plants have healthy be worth daily utensil, potted landscape artificial hillock and decorating aquarium thing, household screen, mural painting, sculpture.
2. colored tourmalinite matter pottery of the present invention, due to uniqueness of filling a prescription, the employing of such as special glassiness fusing assistant, auxiliary agent, red soil, tinting material etc. without MgO, ZnO, and specific formula rate each other, give full play to synergy each other; Particularly its fusing assistant is without the employing of the glassiness fusing assistant of MgO, ZnO, efficiently solves prior art owing to generally using containing magnesium raw material, causes the problems such as toner color development is bad, lighten; The employing of the above-mentioned each raw material of the present invention and formula consumption, fully can improve effect of pottery and increase steam productive rate, advantageously in energy-saving and environmental protection.
Accompanying drawing explanation
Fig. 1 utilizes the solar energy sea water desalination apparatus structural representation of tourmalinite matter chromatic ceramics.
As shown in the figure: 1. framework, 2. lens, 2.1. fresh water collecting groove, 3. sea water layer, 4. tourmalinite matter color ceramic enamel coating, 5. thermal insulation layer.
Fig. 2 utilizes the thermal power generation evaporation of water pretreatment unit structural representation of tourmalinite matter chromatic ceramics.
As shown in the figure: 1. tourmalinite matter chromatic ceramics housing, 2. latticed tourmalinite matter chromatic ceramics water stream channel.
Embodiment
Below by embodiment, the present invention is described in further detail, but the present invention is not only confined to following examples.Raw material of the present invention, does not do specified otherwise, is commercially available prod, as tinting material of the present invention be the various tinting materials of the former Industrial Co., Ltd. in Chaozhou three production and sales as the parcel chrome yellow etc. of SYG122 model, be industry conventional coloring agents.
Case study on implementation 1
Prepare burden by aphrizite 18.5kg, fusing assistant powder 22kg, dunn bass 26kg, Fe-Cr-Co system black developing agent 7kg, chromite powder 26.5kg; Above-mentioned each raw material is placed in the ball mill surplus after grinding to 250 mesh sieve that adds water and is less than 0.1%; Then after dehydration, wet method rolling process is adopted to make corrugated, or dry powder pressing process makes tabular, after work in-process body is dried, insert in kiln and burn till, in 20 ~ 450 DEG C of intervals, heat by the heat-up rate of 3 ~ 4 DEG C/min, the heat-up rate in 450 ~ 850 DEG C of intervals by 1 ~ 2 DEG C/min heats, at 850 DEG C of insulation 90min, burn till omnidistance employing oxydizing flame, kiln discharge after cooling.The product burnt out is black, can paving in the distillation pond of solar seawater desalination (Fig. 1), become high efficiency solar sea water desalinating plant, this tourmaline ceramic can play and absorb solar radiation heat, reduce seawater surface tension force strengthening evaporation of seawater simultaneously, and (in this tourmaline ceramic, allocate the chromite that proportion is higher into for pond accumulation of heat, product unit weight can be increased, promote heat storage capacity, after setting to the sun, tourmaline ceramic still sustainable evaporation seawater for some time of high accumulation of heat) multiple action.
Case study on implementation 2
Prepare burden by aphrizite 18kg, fusing assistant powder 19kg, red soil 48.5kg, iron oxide red 12kg, titanium dioxide 2.5kg, grinding to 250 mesh screen residue that adds water in ball mill is less than 0.5%, roll-in or dry process is adopted to be shaped after dehydration, make corrugated or tabular, after oven dry, put into kiln to burn till, in 20 ~ 450 DEG C of intervals, heat by the heat-up rate of 3 ~ 4 DEG C/min, heat-up rate in 450 ~ 700 DEG C of intervals by 1 ~ 2 DEG C/min heats, 20 ~ 700 DEG C of interval employing oxydizing flame, in 700 ~ 830 DEG C of intervals, the heat-up rate heating of 1 ~ 2 DEG C/min, at 830 DEG C high fire insulation 90min, all firing with reductive flame is adopted in 700 ~ 830 DEG C of intervals, this makes iron, titanium oxide is reduced to the Ti of low melting point
2o
3+ FeO and in black (partially blue).
Only after fire as naturally cooling, then obtained product surface because of contacting with freezing air, the Ti of black
2o
3+ FeO is heavily oxidized to TiO
2+ Fe
2o
3, become brown color, inner because oxidation is less than being still black.For rippled product, the mode that can spray with hydrofluoric acid or alkaline solution or soak, dissolves upper layer, obtains black ceramic; For tabular product, the method for grinding can be adopted, upper layer is removed, obtain black ceramic.
Stop the mode of spraying water in fiery backward kiln as adopted to cool, then because water is heated after entering kiln become steam, both completely cut off air to the Ti in tourmaline ceramic
2o
3the oxidation of+FeO, achieves rapid cooling again and makes Ti
2o
3+ FeO can not be fully oxidized, finally also can obtain the tourmaline ceramic product of black.
End-use is with case study on implementation one.
Case study on implementation 3
By aphrizite powder, fusing assistant powder is dried in advance respectively, schreyerite ground slag is calcined in advance, pulverize, press 20.5kg successively, 18kg, 61.5kg proportion ingredient, prepared by the ceramic honey comb production technique that follows conventional lines: raw material devotes in ball mill, add Vltra tears again, intergrinding, after mixing 1.5h, pour in stirrer, add water, glycerine and tung oil, abundant stirring, be placed in vacuum deairing machine again to rub and practice into mud section, wet method vacuum extruding process forming can be adopted after old, base substrate is through cutting, microwave is shaped, after oven dry, carry out refine, pick, put into kiln again to burn till, heat by the heat-up rate of 1 ~ 2 DEG C/min, at 830 DEG C high fire insulation 90min, burn till omnidistance employing oxydizing flame, kiln discharge after cooling.The product burnt out is black, can in fuel-burning power plant, as solar energy water primary heater unit with make water activate and become the pretreater (Fig. 2) being easy to be evaporated to water vapour.
Case study on implementation 4
By elbaite (white) 11kg, fusing assistant powder 24kg, opal light shale 26kg, chrome green colorant 13kg, dunn bass 26kg, the additional W-Gum 3kg playing shaping plasticising and burn till pore-creating effect prepares burden, add water grinding in ball mill, the technique of stiff-mud process hand finishing is used after adopting gypsum mould grouting or slurry dewatering, make the shape of rock or massif, after oven dry, put into kiln to burn till, in 20 ~ 450 DEG C of intervals, heat by the heat-up rate of 3 ~ 4 DEG C/min, heat-up rate in 450 ~ 840 DEG C of intervals by 1 ~ 2 DEG C/min heats, at 840 DEG C high fire insulation 90min, burn till omnidistance employing oxydizing flame, kiln discharge after cooling.Product in green, as the rock or the massif that cover with green vegetation, because of containing porous opoka, and the water that can absorb in bonsai pot and air, tourmalinite has and promotes the effect of vegetation growth in addition, therefore can spontaneous moss, being easy to the growth of little careless little tree, is the good material making bonsai landscape; Meanwhile, all right anion releasing of tourmalinite matter pottery artificial hillock, useful HUMAN HEALTH; Its abundant hole can moisture absorption, moisture releasing, play the effect of the humidity and temperature regulating local environment.
Case study on implementation 5
By elbaite (white) 12kg, fusing assistant powder 25kg, opal light shale 25.5kg, parcel cadmium yellow 12.5kg, dunn bass 25kg, the additional dextrin 4kg playing shaping plasticising and burn till pore-creating effect prepares burden, add water grinding in ball mill, after dehydration, adopt wet-method extrusion process forming, make Raschig ring shape, after oven dry, put into kiln to burn till, in 20 ~ 450 DEG C of intervals, heat by the heat-up rate of 3 ~ 4 DEG C/min, heat-up rate in 450 ~ 820 DEG C of intervals by 1 ~ 2 DEG C/min heats, at 820 DEG C high fire insulation 60min, burn till omnidistance employing oxydizing flame, kiln discharge after cooling.Product, in yellow, can be placed in aquarium, play degradation of ammonia nitrogen and COD, BOD, increases content of oxygen dissolved in water, bactericidal, absorbing toxin, promotes the effect of Shui nationality healthy growth.Meanwhile, the tourmalinite porous ceramics of yellow annular sinks to the bottom in the aquarium containing dark green waterplant, and together with the shoal of fish of shades of colour, structure weaves bright and colourful scene, makes us pleasing.
Case study on implementation 6
Prepare burden by aphrizite 19kg, fusing assistant powder 19kg, red soil 49kg, iron oxide red 13kg, grinding to 250 mesh screen residue that adds water in ball mill is less than 0.5%, adopt slip casting, roll extrusion, artisan craftsmanship to be shaped, after oven dry, put into kiln and burn till, in 20 ~ 450 DEG C of intervals, heat by the heat-up rate of 3 ~ 4 DEG C/min, the heat-up rate in 450 ~ 850 DEG C of intervals by 1 ~ 2 DEG C/min heats, at 850 DEG C high fire insulation 90min, burn till omnidistance employing oxydizing flame, kiln discharge after cooling.Product is serious, noble dark red, can be made into the base of tea set with health role, drinking utensils, be filled with water utensil and artistic lamp.
Application examples
As shown in Figure 1, a kind of solar energy sea water desalination apparatus utilizing tourmalinite matter chromatic ceramics, this device comprises the framework 1 holding seawater, and framework 1 top is provided with lens 2, and lens 2 inwall is provided with fresh water collecting groove 2; The inner bottom part of described framework 1 is provided with thermal insulation layer 5 (thermal insulation layer as the preparation such as foam materials, polyurethane material), be provided with tourmalinite matter color ceramic enamel coating 4 (the aphrizite matter pottery that embodiment 1 can be adopted to prepare) above thermal insulation layer 5 herein, above tourmalinite matter color ceramic enamel coating 4, be provided with sea water layer 3.In this device, the tourmalinite matter pottery (can adopt corrugated or plate shaped) of black is installed, like this, not only effectively can absorb the heat energy of solar radiation, and tourmaline ceramic can reduce water clusters, moisturize the momentum of the son effusion water surface, more water can be made to be evaporated to steam and become fresh water and be collected in fresh water collecting groove, thus have the efficiency of the distillation fresh water higher than common solar energy sea water desalination apparatus.Three arrows in Fig. 1 above lens represent the direction that solar irradiation is injected, and water vapour then comes across between sea water layer and lens.
As shown in Figure 2, a kind of thermal power generation evaporation of water pretreatment unit utilizing tourmalinite matter chromatic ceramics, this device comprises tourmalinite matter chromatic ceramics housing 6 (the aphrizite matter pottery that embodiment 3 can be adopted to prepare) herein, and described tourmalinite matter chromatic ceramics housing 6 inside is provided with latticed tourmalinite matter chromatic ceramics water stream channel 7.The outdoor tourmalinite honeycomb ceramic hydraulic pipe installing black additional before entering boiler, when water flows through in ceramic honey comb pipeline, on the one hand the ceramic honey comb of black accepts solar light irradiation and accumulation of heat, intensification, transfers heat to ducted current, water preheat is heated up; Tourmaline ceramic carries out electropolarization to the current flow through in pipe on the other hand, makes water clusters reduce and activate, becomes and more easily change into gaseous state.Like this, through preheating with the water of (namely water molecules is more easily converted into gaseous state) of activation, water temperature improves and the increase of water molecules molecular momentum, after it enters boiler, steam productive rate will increase, thus reduces the fire coal consumption and dust, CO of producing steam per ton
2, SO
2, NO
xdeng discharge.Three arrows in Fig. 2 above lens represent the direction that solar irradiation is injected, and other two represent Inlet and outlet water direction.
Claims (6)
1. a tourmalinite matter chromatic ceramics, it is characterized in that: this pottery is prepared from by each component of following weight percent: tourmalinite 1 ~ 35wt%, tinting material 1 ~ 65wt%, shale 0 ~ 55wt%, red soil 0 ~ 50wt%, without the glassiness fusing assistant 15 ~ 35wt% of MgO, ZnO, additional shaping additive 0 ~ 15wt%; The described glassiness fusing assistant without MgO, ZnO is made up of each component of following weight percent: SiO
253 ~ 55%, Al
2o
321 ~ 23%, B
2o
36.5 ~ 8.5%, CaO12 ~ 14%, BaO2.5 ~ 3.5%; This fusing assistant requires that granularity is less than 45 μm.
2. tourmalinite matter chromatic ceramics according to claim 1, is characterized in that: described tourmalinite is one or more mixture of iron tourmaline, elbaite, dravite, and fineness is that less than 10 μm particles account for more than 95%.
3. tourmalinite matter chromatic ceramics according to claim 1, it is characterized in that: described tinting material is pottery, enamel, the synthesis colorant of glass, containing chemical industry and the nonferrous smelting product of Fe, Ti, Mn, Cr, Ni, Co, Cu, V, containing Fe, Ti, Mn, Cr, Ni, Co, Cu, V natural mineral and precision work mineral thereof, containing concrete one or more in the mine tailing of Fe, Ti, Mn, Cr, Ni, Co, Cu, V and slag, fineness all requires below 325 orders.
4. tourmalinite matter chromatic ceramics according to claim 1, is characterized in that: described shale be opal light shale, dunn bass, irony shale, carbonaceous shale one or more, require that fineness meets below 200 orders.
5. tourmalinite matter chromatic ceramics according to claim 1, is characterized in that: described red soil is grow the soil under Perenniporia martius rain woods ﹑ monsoonal forest or evergreen broad-leaved forest vegetation; Its principal character lacks alkali and alkaline earth metal ions and is rich in Tie ﹑ aluminum oxide, and in acid, color and luster is red, and particle is trickle, has plasticity-and viscosity, requires that fineness is below 250 orders.
6. tourmalinite matter chromatic ceramics according to claim 1, is characterized in that: described shaping additive comprise in W-Gum, dextrin, carboxymethyl cellulose, polyvinyl alcohol, Vltra tears, tung oil, glycerine one or more.
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