CN104193298A - Method of producing black spots used for ceramic antique green bricks by utilization of waste ceramic and coal slag - Google Patents
Method of producing black spots used for ceramic antique green bricks by utilization of waste ceramic and coal slag Download PDFInfo
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- CN104193298A CN104193298A CN201310448914.XA CN201310448914A CN104193298A CN 104193298 A CN104193298 A CN 104193298A CN 201310448914 A CN201310448914 A CN 201310448914A CN 104193298 A CN104193298 A CN 104193298A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
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Abstract
A method of producing black spots used for ceramic antique green bricks by utilization of waste ceramic and coal slag. The black spots comprise following components by weight: 16-18 parts of quartz sand, 11-14 parts of kaolin, 8-12 parts of the waste ceramic, 13-15 parts of potash feldspar, 3-5 parts of lithium feldspar, 5-8 parts of black feldspar, 23-29 parts of the coal slag, 6-8 parts of Henan black ore, 0.3 part of sodium humate, 0.1 part of hydroxymethyl cellulose and 0.2 part of sodium tripolyphosphate. The method fully utilizes the waste ceramic and the coal slag materials and the using amount is large, thus fully achieving waste utilization, reducing waste discharge in production lines and improving environment protection effects. The method accords with exploitation concepts of reasonably utilizing resources, protecting ecological balance, reducing the cost, saving energy and increasing benefit. Further, the black spots prepared by the method can effectively improve appearance effects of antique bricks and manifest high-end effects of ceramic.
Description
Technical field
The present invention relates to the preparation of ceramic antique bricks raw material, particularly a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain.
Background technology
The many making of existing Antique Imitation Tiles are comparatively meticulous, and price is higher.But also imperfect on antique effect.In Production of Ceramics, also produce a large amount of waste materials, in prior art, also propose to adopt these waste materials to prepare the method for Antique Imitation Tiles.
Chinese patent literature CN103044009A discloses a kind of Antique Imitation Tiles that utilizes the production of polishing brick field waste material and preparation method thereof, its formula comprises following component by weight: tile polished waste: 8-10 part, base raw material: 10-12 part, glaze raw material: 0.04-1 part, water: 10-15 part, wherein, described base is one or more combinations in clay, quartz and porcelain stone with raw material.This product water-intake rate is about 1-3%, can resistance of failure reach 2050N, and surface abrasion resistance is high, and 4 grade 2100 turns visible grinding marks, has very long work-ing life, and can turn waste into wealth.But the raw material in this invention is still limited to polished tile, and wherein dioxide-containing silica is higher, material choice face is narrower.
Chinese patent literature CN101654948 discloses a kind of ceramic antique bricks that utilizes taking construction waste stone powder as raw material and preparation method thereof, wherein mention and adopt waste stone powder to produce Antique Imitation Tiles, and mention buildings waste stone powder and be rich in irony, after burning till, can leave stain impact at brick face attractive in appearance, and easily split brick or distortion, sintering degree is poor.In this invention, by slowing down chilling speed, regulate the mode of proportioning, overcome and easily split the technical problems such as brick.But the substances content in waste stone powder is difficult to control, cause end product quality to be difficult to control, especially the problem of glaze pin hole is difficult to solve.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain, and can adopt useless porcelain and cinder is raw material, further, can promote the appearance effect of ceramic antique bricks.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain, is made up of the component of following weight part:
Quartz sand 16 ~ 18; Kaolin 11 ~ 14; Useless porcelain 8 ~ 12; Potassium felspar sand 13 ~ 15; Lithium feldspar 3 ~ 5; Black feldspar 5 ~ 8; Cinder 23 ~ 29; Henan black ore stone 6 ~ 8; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.
Raw material is passed through to wet ball grinding and is spray dried to as powder particle, put in storage for subsequent use.
Described black feldspar is the aluminum silicate mineral of calcic, sodium and potassium.
Described Henan black ore stone is wolframite.
Conventionally in idea, think, stain in Antique Imitation Tiles can affect the appearance effect of brick, but contriver finds, stain is become to adobe with other mixed raw materials after wet ball grinding is dry with spraying, can effectively promote the appearance effect of finished product, especially the stain mixing makes Antique Imitation Tiles really have the effect of the precipitation in elapsed time, effectively improves the economic worth of Antique Imitation Tiles.And different from the stain that is rich in the generation of ferriferous raw material sintering, the adobe modelled after an antique in the present invention can not have influence on the effect of glaze with stain.
A kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain provided by the invention; can make full use of useless porcelain and cinder raw material; and consumption is huge; fully realize utilization of waste material; the waste discharge that has reduced production line, has improved environment protecting, meets and makes rational use of resources; protect the eubiosis, and reduce costs the exploitation theory of energy efficiency.Further, adobe modelled after an antique stain prepared by the present invention can effectively improve the appearance effect of Antique Imitation Tiles, can show the high-end effect of pottery.
Embodiment
Embodiment 1:
Utilize waste ceramic porcelain and cinder to make a method for ceramic antique adobe stain, formed by the component of following weight part:
Quartz sand 16 ~ 18; Kaolin 11 ~ 14; Useless porcelain 8 ~ 12; Potassium felspar sand 13 ~ 15; Lithium feldspar 3 ~ 5; Black feldspar 5 ~ 8; Cinder 23 ~ 29; Henan black ore stone 6 ~ 8; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.
Useless porcelain in this example comprises produces the useless ceramics, the useless porcelain of sanitary equipment etc. that in ceramic tile process, produce.Black feldspar is the feldspar of black.Henan black ore stone is that color is the painted with ore of black, the mine tailing of such as coal gangue or schorl, obsidian, wolframite, purple copper, ilmenite, pyrolusite etc.Preferably adopt the Henan black ore stone of low iron content.
Raw material is passed through to wet ball grinding and is spray dried to as powder particle, put in storage for subsequent use.Stain raw material and other raw materials are weighed and are prepared into drum mixer dry-pressing formedly to press in product demand ratio, and portioned product, through glazing operation, then obtains Antique Imitation Tiles after sintering.
Black feldspar is the aluminum silicate rock forming mineral of the common calcic of a class, sodium and potassium, has higher ultimate compression strength, and acid is had to stronger chemical stability, because its K
2o content is up to 5-14%, so the stability to formula and reduction firing temperature play vital effect; Its Fe
2o
3content < 0.3%, has reduced the too high impact that glaze is caused of iron-holder.Henan black ore stone, claims again " wolframite ".Chemical formula (MnFe) WO
4.Wherein Mn and Fe, without fixed proportion, are generally 1:1 ~ 2.But also there is the ferberite less containing Mn and contain the less huebnerite of Fe.Make stain and select the less huebnerite of iron content, reduce the too high impact that glaze is caused of iron-holder.Selecting Henan black ore masonry is one of main raw material of making stain, is because it adds the mud that can directly obtain essential black after mixing and ball milling, reduces or directly cancels adding of colorant, thereby reaching the object reducing costs.
Embodiment 2:
On the basis of embodiment 1, preferred component proportion is quartz sand 16; Kaolin 11; Useless porcelain 8; Potassium felspar sand 13; Lithium feldspar 3; Black feldspar 5; Cinder 23; Henan black ore stone 6; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.
Embodiment 3:
Quartz sand 18; Kaolin 14; Useless porcelain 12; Potassium felspar sand 15; Lithium feldspar 5; Black feldspar 8; Cinder 29; Henan black ore stone 8; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.
Embodiment 4:
Quartz sand 17; Kaolin 12; Useless porcelain 10; Potassium felspar sand 14; Lithium feldspar 4; Black feldspar 7; Cinder 25; Henan black ore stone 7; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.This example is particularly useful for the earthenware brick of not glazing.
Embodiment 5:
Quartz sand 18; Kaolin 11; Useless porcelain 12; Potassium felspar sand 15; Lithium feldspar 3; Black feldspar 7; Cinder 29; Henan black ore stone 8; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.This example is particularly suited for the Antique Imitation Tiles of transparent glaze colours.
Embodiment 6:
Quartz sand 16; Kaolin 13; Useless porcelain 9; Potassium felspar sand 14; Lithium feldspar 5; Black feldspar 5; Cinder 29; Henan black ore stone 6; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.This example is particularly suited for the Antique Imitation Tiles of dark glaze colours.
Claims (4)
1. utilize waste ceramic porcelain and cinder to make a method for ceramic antique adobe stain, it is characterized in that being formed by the component of following weight part:
Quartz sand 16 ~ 18; Kaolin 11 ~ 14; Useless porcelain 8 ~ 12; Potassium felspar sand 13 ~ 15; Lithium feldspar 3 ~ 5; Black feldspar 5 ~ 8; Cinder 23 ~ 29; Henan black ore stone 6 ~ 8; Sodium salts humic acids 0.3; Walocel MT 20.000PV 0.1; Tripoly phosphate sodium STPP 0.2.
2. a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe use stain according to claim 1, is characterized in that: raw material is passed through to wet ball grinding and is spray dried to as powder particle, put in storage for subsequent use.
3. a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain according to claim 1, is characterized in that: described black feldspar is the aluminum silicate mineral of calcic, sodium and potassium.
4. a kind of method of utilizing waste ceramic porcelain and cinder to make ceramic antique adobe stain according to claim 1, is characterized in that: described Henan black ore stone is wolframite.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310448914.XA CN104193298B (en) | 2013-09-28 | 2013-09-28 | Method of producing black spots used for ceramic antique green bricks by utilization of waste ceramic and coal slag |
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| CN201310448914.XA CN104193298B (en) | 2013-09-28 | 2013-09-28 | Method of producing black spots used for ceramic antique green bricks by utilization of waste ceramic and coal slag |
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| CN104193298B CN104193298B (en) | 2015-04-29 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104944916A (en) * | 2015-05-29 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glaze blue-and-white porcelain |
| CN106007670A (en) * | 2016-05-25 | 2016-10-12 | 余清扬 | Low-cost ceramic material and preparation method thereof |
| CN109437852A (en) * | 2018-11-12 | 2019-03-08 | 湖北鑫来利陶瓷发展有限公司 | Shraff recycles the Antique Imitation Tiles and its production technology of production |
Citations (5)
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|---|---|---|---|---|
| CN101219910A (en) * | 2007-12-24 | 2008-07-16 | 钟旭东 | Method for producing color blank glaze archaizing brick by using iron mine tailing |
| CN101717275A (en) * | 2009-12-19 | 2010-06-02 | 江门市道氏标准制釉股份有限公司 | Black pigment for ceramic ink jet printing and preparation method thereof |
| CN101948298A (en) * | 2010-09-16 | 2011-01-19 | 华南理工大学 | Method for producing ceramic glazed tile from coal slag by double sintering |
| CN103044009A (en) * | 2012-12-26 | 2013-04-17 | 李建顺 | Archaized bricks produced by using polished brick factory waste materials and preparation method thereof |
| CN103073263A (en) * | 2011-10-25 | 2013-05-01 | 况学成 | Method for manufacturing ceramic antique brick by using various solid wastes |
-
2013
- 2013-09-28 CN CN201310448914.XA patent/CN104193298B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101219910A (en) * | 2007-12-24 | 2008-07-16 | 钟旭东 | Method for producing color blank glaze archaizing brick by using iron mine tailing |
| CN101717275A (en) * | 2009-12-19 | 2010-06-02 | 江门市道氏标准制釉股份有限公司 | Black pigment for ceramic ink jet printing and preparation method thereof |
| CN101948298A (en) * | 2010-09-16 | 2011-01-19 | 华南理工大学 | Method for producing ceramic glazed tile from coal slag by double sintering |
| CN103073263A (en) * | 2011-10-25 | 2013-05-01 | 况学成 | Method for manufacturing ceramic antique brick by using various solid wastes |
| CN103044009A (en) * | 2012-12-26 | 2013-04-17 | 李建顺 | Archaized bricks produced by using polished brick factory waste materials and preparation method thereof |
Non-Patent Citations (2)
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|---|
| 李玉峰: "陶瓷厂废料的开发和利用", 《佛山陶瓷》, no. 3, 31 March 2003 (2003-03-31) * |
| 程昭华: "关于使用矿渣制黑抛光砖的答疑", 《佛山陶瓷》, no. 9, 30 September 2008 (2008-09-30) * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104944916A (en) * | 2015-05-29 | 2015-09-30 | 苏州拓科仪器设备有限公司 | Glaze blue-and-white porcelain |
| CN106007670A (en) * | 2016-05-25 | 2016-10-12 | 余清扬 | Low-cost ceramic material and preparation method thereof |
| CN109437852A (en) * | 2018-11-12 | 2019-03-08 | 湖北鑫来利陶瓷发展有限公司 | Shraff recycles the Antique Imitation Tiles and its production technology of production |
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| Publication number | Publication date |
|---|---|
| CN104193298B (en) | 2015-04-29 |
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