CN104178960B - Supercritical carbon-dioxide dynamically-circulating dyeing machine and dyeing method thereof - Google Patents

Supercritical carbon-dioxide dynamically-circulating dyeing machine and dyeing method thereof Download PDF

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Publication number
CN104178960B
CN104178960B CN201410432592.4A CN201410432592A CN104178960B CN 104178960 B CN104178960 B CN 104178960B CN 201410432592 A CN201410432592 A CN 201410432592A CN 104178960 B CN104178960 B CN 104178960B
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China
Prior art keywords
spray
carbon dioxide
supercritical carbon
dyeing
spray seat
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CN104178960A (en
Inventor
吴建华
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WUXI HUAYANG DYEING AND FINISHING MACHINERY
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WUXI HUAYANG DYEING AND FINISHING MACHINERY
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/28Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics propelled by, or with the aid of, jets of the treating material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B19/00Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B23/00Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
    • D06B23/20Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation
    • D06B23/205Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation for adding or mixing constituents of the treating material

Abstract

The invention discloses a supercritical carbon-dioxide dynamically-circulating dyeing machine which comprises a dyeing chamber and a high-pressure vat. A cloth laying device and a cloth lifting device are connected at the top of the high-pressure vat, the dyeing chamber comprises a spray shell, one end of the spray shell is connected with the cloth lifting device while the other end of the same is connected with a first spray tower, the first spray tower is connected with the cloth laying device, a second spray tower and a third spray tower are mounted inside the spray shell, the third spray tower, the second spray tower and the first spray tower are matched with the spray shell to form a mixing chamber, two ends of the mixing chamber are respectively provided with a nozzle a and a nozzle b, a liquid inlet and an air inlet which are communicated with the mixing chamber are mounted in the spray shell, a sedimentation outlet is formed in the bottom of the high-pressure vat and is connected with the liquid inlet through a liquid inlet pipeline, a filter, a carbon-dioxide circulating pump, a mixing device and a heat exchanger are sequentially arranged on the liquid inlet pipeline, and a rising outlet is formed in the top of the high-pressure vat and is connected with an exhaust inlet of a high-pressure fan which is connected with the air inlet. The supercritical carbon-dioxide dynamically-circulating dyeing machine is good in leveling property, high in degree of dyeing and large in cloth dyeing quantity.

Description

A kind of supercritical carbon dioxide dynamic circulation staining machine and its colouring method
Technical field
The present invention relates to textile printing and dyeing field, more particularly to a kind of supercritical carbon dioxide dynamic circulation staining machine and its dye Color method.
Background technology
In recent years, countries in the world are all being devoted to the research of waterless staining technique, with modern science technology it is quick Development, supercritical CO 2 dyeing technology is increasingly subject to the attention of world many countries, and its basic principle is, carbon dioxide There are good mass-transfer performance and solubility property in the supercritical state, for apolar substance has good solvability.
At present, supercritical CO 2 dyeing also rests on static dyeing, that is, fabric simply soaks in media as well, this Kind of staining method has that uniform dyeing property is poor, the problem that dye uptake is low, the amount of dying cloth is little.
The content of the invention
Present invention aims to the problems referred to above, there is provided a kind of supercritical carbon dioxide dynamic circulation staining machine and its Colouring method, rests on static dyeing to solve existing supercritical CO 2 dyeing, and it is poor to there is uniform dyeing property, dye uptake The little problem of the low, amount of dying cloth.
The purpose of the present invention is to be achieved through the following technical solutions:
A kind of supercritical carbon dioxide dynamic circulation staining machine, including dyeing chamber and the high pressure dye vat supported by supporting leg, institute State the one end at the top of high pressure dye vat and be provided with and control mouth, and be connected with plaiting device, the other end at the top of which is provided with and carries cloth mouth, and even It is connected to and carries cloth apparatus, the dyeing chamber includes spraying shell, and one end of the spray shell is connected with cloth apparatus are carried, and the other end is connected with hollow First spray seat of structure, first spray seat are connected with plaiting device, are sprayed Second spray seat of structure, and the 3rd spray seat that neighbouring one end for carrying cloth apparatus in shell is provided with hollow structure is sprayed, the 3rd spray Seat, the second spray seat, the first spray seat coordinate spray shell to be formed with mixing chamber, the two ends of the mixing chamber be respectively arranged with spout a, Spout b, the spout a are cooperatively formed with the 3rd spray seat by the second spray seat, and the spout b is with the second spray seat with the first spray seat Formed, inlet, the air inlet being connected with mixing chamber be installed on the spray shell, it is heavy that the bottom of the high pressure dye vat is provided with Drop outlet, the sedimentation outlet are connected with inlet by input duct, are exported to inlet along sedimentation in the input duct Direction be sequentially arranged filter, carbon dioxide recycle pump, mixing device, heat exchanger, be provided with ascension at the top of high pressure dye vat Outlet, the ascension outlet are connected with the inlet scoop of high pressure positive blower, and the air outlet of the high pressure positive blower is connected with air inlet.
Used as the preferred version of the present invention, described to carry cloth apparatus, high pressure positive blower, carbon dioxide recycle pump, mixing device equal High-voltage shielded electrical motor is adopted for power source.
Used as the preferred version of the present invention, the high-voltage shielded electrical motor includes casing, end cap and is separated into stator, rotor The housing of stator space, rotor space, is connected with pressure balance lid on the end cap, the pressure balance is covered and is provided with oiling Mouthful, the pouring orifice is connected with the pressure balance chamber inside pressure balance lid, and the pressure balance chamber is connected with stator space It is logical, and convoluted diaphragm between pressure balance chamber and rotor space, is provided with, the stator space, pressure balance intracavity are provided with change Depressor oil.
Used as the preferred version of the present invention, the runner of the spout a is truncated cone-shaped structure, and its radius edge flow direction is passed successively Subtract, and its flow direction moves towards identical with fabric, the runner of the spout b is truncated cone-shaped structure, its radius edge flow direction is successively decreased successively, and Its flow direction moves towards identical with fabric.
Used as the preferred version of the present invention, the inlet end of the spray shell is provided with atomizer.
Used as the preferred version of the present invention, the mixing device is propeller agitator.
Used as the preferred version of the present invention, the heat exchanger is plate-type exchanger.
A kind of supercritical carbon dioxide dynamic circulation colouring method, comprises the following steps:
A, by fabric add high pressure dye vat in, temperature, pressure are adjusted to desired value, and to supercritical carbon dioxide dynamic Supercritical carbon dioxide is filled with dyeing cycle machine;
B, unlatching carry cloth apparatus, plaiting device, make fabric in recurrent state, at the same time, open carbon dioxide recycle Pump, high pressure positive blower, make the supercritical carbon dioxide of ascension, the supercritical carbon dioxide of sedimentation be in recurrent state, ascension Supercritical carbon dioxide, the supercritical carbon dioxide of sedimentation after mixed aerosol, are injected in knitting through dyeing chamber in dyeing chamber Dyeing is realized on thing.
Further, described temperature is 70~155 °, and described pressure is 7.4~35Mpa.
Beneficial effects of the present invention are that the supercritical carbon dioxide dynamic circulation staining machine realizes dynamic coloring, its Dye liquor can in the state of atomization strong convection circulation to textile dyeing, fabric can in the presence of exterior power shuttling movement, Constantly dye so that dyestuff and fabric are fully contacted, it is to avoid dye liquor vortex, the color fastness of dyeing, dye-uptake is obtained significantly Lifting, solve the problems, such as that static uniform dyeing property is poor, dye uptake is low, the amount of dying cloth is little.
Description of the drawings
Fig. 1 is a kind of structural representation of supercritical carbon dioxide dynamic circulation staining machine of the invention;
Fig. 2 is the structural representation of high pressure dye vat of the present invention;
Fig. 3 is the structural representation of dyeing chamber of the present invention;
Fig. 4 is high-voltage shielded electrical motor structural representation of the present invention.
In figure:
1st, high pressure dye vat;2nd, dyeing chamber;3rd, plaiting device;4th, cloth apparatus are carried;5th, filter;6th, carbon dioxide recycle pump; 7th, mixing device;8th, heat exchanger;9th, high pressure positive blower;10th, supporting leg;11st, control mouth;12nd, carry cloth mouth;13rd, gathering hole;14th, ascension Outlet;15th, sedimentation outlet;16th, spray shell;17th, the first spray seat;18th, the second spray seat;19th, the 3rd spray seat;20th, mixing chamber;21、 Spout a;22nd, spout b;23rd, air inlet;24th, inlet;25th, fabric;26th, casing;27th, end cap;28th, stator;29th, rotor; 30th, housing;31st, pressure balance lid;32nd, convoluted diaphragm;33rd, pressure balance chamber.
Specific embodiment
Technical scheme is further illustrated below in conjunction with the accompanying drawings and by specific embodiment.May be appreciated It is that embodiment described herein is used only for explaining the present invention, rather than limitation of the invention.
Refer to shown in Fig. 1 to Fig. 3, in the present embodiment, a kind of supercritical carbon dioxide dynamic circulation staining machine, including Dyeing chamber 2 and the high pressure dye vat 1 supported by supporting leg 10, the right-hand member of the high pressure dye vat 1 are provided with for entering the gathering hole of fabric 25, Left end at the top of which is provided with controls mouth 11, and is connected with plaiting device 3, and the right-hand member at the top of which is provided with and carries cloth mouth 12, and connects Cloth apparatus 4 are carried, the dyeing chamber 2 includes spraying shell 16, and the right-hand member of the spray shell 16 is connected with cloth apparatus 4 are carried, and left end is connected with First spray seat 17 of hollow structure, the left end of first spray seat 17 are connected with plaiting device 3, during in spray shell 16, left end is provided with Second spray seat 18 of hollow structure, right-hand member are provided with the 3rd spray seat 19 of hollow structure, the 3rd spray seat 19, the second spray seat 18, First spray seat 17 coordinates spray shell 16 to be formed with mixing chamber 20, and the two ends of the mixing chamber 20 are respectively arranged with spout a21, spray Mouth b22, the spout a21 are cooperatively formed by the second spray seat 18 and the 3rd spray seat 19, and the runner of spout a21 is truncated cone-shaped structure, Its radius successively decreases successively along flow direction, and its flow direction and fabric 25 move towards identical, and the spout b22 is by the second spray seat 18 and first Spray seat 17 is cooperatively formed, and the runner of spout b22 is truncated cone-shaped structure, and its radius successively decreases successively along flow direction, and its flow direction and fabric 25 move towards is identical, and the top of the spray shell 16 is provided with the air inlet 23 being connected with mixing chamber 20, sprays the bottom of shell 16 The inlet 24 being connected with mixing chamber 20 is installed, the end of the inlet 24 is provided with atomizer, the high pressure The center of 1 bottom of dye vat is provided with sedimentation outlet 15, and the sedimentation outlet 15 is connected with inlet 24 by input duct, described Direction in input duct along sedimentation outlet 15 to inlet 24 has been sequentially arranged filter 5, carbon dioxide recycle pump 6, batch mixing Device 7, heat exchanger 8, the mixing device 7 be propeller agitator, the heat exchanger 8 be plate-type exchanger, high pressure dye vat 1 The center at top is provided with ascension outlet 14, and the ascension outlet 14 is connected with the inlet scoop of high pressure positive blower 9, the high pressure positive blower 9 air outlet is connected with air inlet 23.
A kind of supercritical carbon dioxide dynamic circulation colouring method, comprises the following steps:
A, fabric is added in high pressure dye vat 1, by temperature adjustment to 110 °, pressure is adjusted to 21Mpa, and to supercritical two Supercritical carbon dioxide is filled with carbonoxide dynamic circulation staining machine;
B, unlatching carry cloth apparatus 4, plaiting device 3, make fabric 25 in recurrent state, at the same time, open carbon dioxide Circulating pump 6, high pressure positive blower 9, make the supercritical carbon dioxide of ascension, the supercritical carbon dioxide of sedimentation be in recurrent state, The supercritical carbon dioxide of ascension, the supercritical carbon dioxide of sedimentation are injected in through dyeing after mixed aerosol in dyeing chamber 2 Dyeing is realized on the fabric 25 of room 2.
In order to working under the pressure of 7.4~35Mpa and keeping excellent sealing property, using high-voltage shielded electrical motor As high pressure positive blower 9, carbon dioxide recycle pump 6, mixing device 7, the power source for carrying cloth apparatus 4;As shown in figure 4, being the present invention High-voltage shielded electrical motor structural representation;The high-voltage shielded electrical motor includes casing 26, end cap 27 and separates stator 28, rotor 29 Into stator space, the housing 30 of rotor space, pressure balance lid 31, the pressure balance lid 31 on the end cap 27, are connected with On be provided with pouring orifice, the pouring orifice is connected with the pressure balance chamber 33 inside pressure balance lid 31, the pressure balance chamber 33 are connected with stator space, and convoluted diaphragm 32 is provided between pressure balance chamber 33 and rotor space, the stator space, Transformer oil is provided with pressure balance chamber 33.When high-voltage shielded electrical motor works, dye between rotor 29 and housing 30, is filled with Agent medium, its pressure cause convoluted diaphragm 32 to deform, and then the transformer oil in pressure balance chamber 33 is pressed to stator space, from And pressure transmission is given the housing 30 of subspace so that the pressure balance in 30 inside and outside two closed areas of housing, by This, housing 30 is inside and outside not to have pressure differential, so, relatively thin housing 30 can meet the requirement of high pressure.
Above-mentioned supercritical carbon dioxide dynamic circulation staining machine includes three blood circulation:First blood circulation is settled Supercritical carbon dioxide blood circulation, it is by high pressure dye vat 1, filter 5, carbon dioxide recycle pump 6, mixing device 7, heat exchange The duct elements such as device 8, the pressure pipeline of dyeing chamber 2, flange are sequentially connected in series, and in the presence of carbon dioxide recycle pump 6, sink The supercritical carbon dioxide of drop enters mixing device 7 from the sedimentation outlet 15 of high pressure dye vat 1 after filter 5 is filtered, in batch mixing Under the agitation of device 7 after dissolving dye, heated into heat exchanger 8, reached the feed liquor of the stain by dyeing chamber 2 of dyeing temperature Mouth 24 enters dyeing chamber 2, mixes with the fabric 25 in dyeing chamber 2, carries out dye exchange, so as to paint to fabric 25;Second Blood circulation is ascension supercritical carbon dioxide blood circulation, and it is that high pressure dye vat 1, high pressure positive blower 9, dyeing chamber 2 are used pressure The pipe fittings such as pipeline, flange are together in series, the supercritical carbon dioxide of ascension the entering by dyeing chamber 2 in the presence of high pressure positive blower 9 QI KOU 23 enters dyeing chamber 2, and the air-flow of high speed will circulate the stain that comes blows out fine particles makes which be more prone to penetrate into and knit In thing 25, preferably carry out stain exchange, at the same time, the fabric 25 in dyeing chamber 2 under the blowing of high velocity air, constantly Rub, swing, be conducive to the raising of dyeing quality;3rd blood circulation is fabric circulation system, and fabric 25 is by gathering hole 13 load high pressure dye vat 1, due to, under the collective effect of carbon dioxide recycle pump 6 and high pressure positive blower 9, carrying and being formed with cloth mouth 12 Negative pressure, fabric 25 enter dyeing chamber 2 in the case where the collective effect of cloth apparatus 4 and negative pressure is put forward, and meet with above-mentioned stain and are dyeed, so Afterwards, fabric 25 is uniformly arranged in high pressure dye vat 1 in the presence of plaiting device 3, and fabric 25 joins end to end constantly circulation directly Reach coloration requirements.
When above-mentioned supercritical carbon dioxide dynamic circulation staining machine works, fabric 25 is carrying cloth apparatus 4, plaiting device 3 Under effect, constantly circulate in high pressure dye vat 1, dyeing chamber 2, the supercritical carbon dioxide of sedimentation is in carbon dioxide recycle pump 6 Under driving, entered by the inlet 24 of dyeing chamber 2 after filter 5, mixing device 7, heat exchanger 8,24 end of Jing inlets Atomizer atomization after enter mixing chamber 20, the supercritical carbon dioxide of ascension under the driving of high pressure positive blower 9, by dyeing chamber 2 air inlet 23 enters mixing chamber 20, and both are atomized in the case of strong convection, and the stain of atomization is by spout a21, spout B22 sprays, and contacts with fabric 25, carries out stain exchange, and spout a21, the runner of spout b22 are truncated cone-shaped structure, radius Successively decrease along flow direction successively, so that the stain of atomization is injected on fabric 25 at a certain angle, additionally, spout a21, spout The flow direction of the stain of the atomization that b22 is ejected moves towards identical with fabric 25 such that it is able to which providing a power to fabric 25 makes Continuous circulation.
Above example simply elaborates the ultimate principle and characteristic of the present invention, and the present invention is not limited by above-described embodiment, Without departing from the spirit and scope of the present invention, the present invention also has various change and change, and these changes and change all fall Enter in scope of the claimed invention.The claimed scope of the invention is by appending claims and its equivalent thereof.

Claims (7)

1. a kind of supercritical carbon dioxide dynamic circulation staining machine, it is characterised in that:The height supported including dyeing chamber and by supporting leg Cylinder is padded, the one end at the top of the high pressure dye vat is provided with controls mouth, and is connected with plaiting device, and the other end at the top of which is provided with and carries Cloth mouth, and be connected with and carry cloth apparatus, the dyeing chamber includes spraying shell, and one end of the spray shell is connected with cloth apparatus are carried, the other end The first spray seat of hollow structure is connected with, first spray seat is connected with plaiting device, sprays one end of neighbouring first spray seat in shell Second spray seat of hollow structure is installed, and sprays the 3rd spray seat that neighbouring one end for carrying cloth apparatus in shell is provided with hollow structure, 3rd spray seat, the second spray seat, the first spray seat coordinate spray shell to be formed with mixing chamber, and the two ends of the mixing chamber set respectively Spout a, spout b are equipped with, the spout a is cooperatively formed with the 3rd spray seat by the second spray seat, the spout b is by the second spray seat and the One spray seat is cooperatively formed, and is provided with inlet, the air inlet being connected with mixing chamber on the spray shell, the high pressure dye vat Bottom is provided with sedimentation outlet, and the sedimentation outlet is connected with inlet by input duct, and in the input duct, edge settles out Mouth to the direction of inlet has been sequentially arranged filter, carbon dioxide recycle pump, mixing device, heat exchanger, the top of high pressure dye vat Portion is provided with ascension outlet, and the ascension outlet is connected with the inlet scoop of high pressure positive blower, the air outlet of the high pressure positive blower and air inlet Mouth is connected.
2. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 1, it is characterised in that:It is described to carry cloth Device, high pressure positive blower, carbon dioxide recycle pump, mixing device adopt high-voltage shielded electrical motor for power source.
3. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 2, it is characterised in that:The high pressure Shield electric machine includes casing, end cap and stator, rotor is separated into the housing of stator space, rotor space, on the end cap Pressure balance lid is connected with, the pressure balance is covered and is provided with pouring orifice, the pressure inside the pouring orifice and pressure balance lid Counter balance pocket is connected, and the pressure balance chamber is connected with stator space, and is provided between pressure balance chamber and rotor space Convoluted diaphragm, the stator space, pressure balance intracavity are provided with transformer oil.
4. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 1, it is characterised in that:The spout The runner of a is truncated cone-shaped structure, and its radius successively decreases successively along flow direction, and its flow direction moves towards identical with fabric, the stream of the spout b Road is truncated cone-shaped structure, and its radius successively decreases successively along flow direction, and its flow direction moves towards identical with fabric.
5. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 1 and 2, it is characterised in that:It is described The inlet end of spray shell is provided with atomizer.
6. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 1, it is characterised in that:The batch mixing Device is propeller agitator.
7. a kind of supercritical carbon dioxide dynamic circulation staining machine according to claim 1, it is characterised in that:The heat exchange Device is plate-type exchanger.
CN201410432592.4A 2014-08-27 2014-08-27 Supercritical carbon-dioxide dynamically-circulating dyeing machine and dyeing method thereof Active CN104178960B (en)

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CN105420972B (en) * 2015-10-30 2017-07-18 山东大学 Supercritical fluid continuously contaminates equipment
CN106637753B (en) * 2016-11-21 2019-10-22 大连工业大学 A kind of dyeing caldron, aramid fiber supercritical carbon dioxide non-aqueous dyeing device and colouring method

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CN2350412Y (en) * 1998-10-22 1999-11-24 孙传经 High-pressure dyeing vessel in supercritical carbon dioxide dyeing process
CN100359092C (en) * 2005-12-26 2008-01-02 大连轻工业学院 Dying still in supercritical CO2 dyeing device
CN100473774C (en) * 2006-10-27 2009-04-01 美晨集团股份有限公司 Dyeing caldron in supercritical CO2 dyeing device
CN101280496A (en) * 2008-06-04 2008-10-08 唐佳伟 High-temperature high-pressure air flow dyeing machine
CN102787459B (en) * 2012-07-17 2014-01-15 大连工业大学 Supercritical carbon dioxide cheese dyeing kettle and waterless supercritical carbon dioxide cheese dyeing method
CN203284609U (en) * 2013-06-20 2013-11-13 无锡市华洋染整机械有限公司 Device used for dyeing of supercritical carbon dioxide fluid
CN203602889U (en) * 2013-11-02 2014-05-21 侯勇 Supercritical carbon dioxide fluid dynamic dyeing device

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