CN104178287B - Cotton picker cleansing composition and comprise the emulsion of said composition - Google Patents
Cotton picker cleansing composition and comprise the emulsion of said composition Download PDFInfo
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- CN104178287B CN104178287B CN201310192283.XA CN201310192283A CN104178287B CN 104178287 B CN104178287 B CN 104178287B CN 201310192283 A CN201310192283 A CN 201310192283A CN 104178287 B CN104178287 B CN 104178287B
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Abstract
The invention provides a kind of cotton picker cleansing composition and the emulsion comprising said composition.The cotton picker cleansing composition of the present invention includes compound emulsifying agent and major amount of base oil, described compound emulsifying agent is fatty acid ester ethoxylates, fatty alcohol-polyoxyethylene ether and the mixture of alkylethylene diamines triacetic acid, one or more in vegetable oil, epoxidized vegetable oil and biodiesel of described base oil.Cotton picker cleansing composition stable performance of the present invention, clear, there is good biological degradability, do not pollute Cotton Gossypii and soil, friendly with environment and human body, forming highly stable emulsion with water, have the good characteristic of resistance to hard water, room temperature stands and within 10 days, occurs without analysis oil or lamination, continuously or interval uses can there is outstanding cleaning, moistening, antirust, wear-resistant undermine cotton picking, de-cotton effect.Emulsion of the present invention has excellent cleaning, moistening, antirust, wear-resistant undermines cotton picking, de-woolliness energy.
Description
Technical field
The present invention relates to a kind of cotton picker cleansing composition, be applicable to cotton picker moistening particularly to one clear
Wash the cleansing composition of system.
Background technology
The big cotton growing area of China three: cotton region, the Yangtze river basin, cotton region, the Huanghe valley and cotton region, the Northwest, Cotton Gossypii kind
Plant area and reach 80,000,000 mu.Artificial cotton picking is low technical ability, a hard work, and labor productivity is the lowest.
Mechanization cotton picking is to plant the once leap in cotton history, is greatly enhanced cotton picking efficiency, and cotton picker every day is about
Cotton picking 300 mu.
During cotton picker work, cotton picker spindle is directly plucked and sloughs Cotton Gossypii, is the parts of cotton picker most critical.
The material plucking ingot surface contact mainly has dust, Cotton Gossypii, cotton branch juice and grease, and working condition requirement is necessary
Continue with abluent lubrication, moistening, cleaning cotton picker pluck ingot, and help to pluck ingot de-cotton, ability smoothly
Normal circulation works, and the therefore quality of cotton picker abluent becomes the key of cotton picker performance.
Cotton picker abluent is the high-efficiency washing product of a kind of oil-in-water type, base oil, emulsifying agent add with multiple
Add agent to be in harmonious proportion and form, it is desirable to there is special emulsifying, lubrication, moistening, clean, help cotton picking and de-cotton, prevent
Corrosion and wear resistance.
US3816346 describes a kind of textile machine spindle lubricant, and composition includes that a certain amount of anti-attrition is added
Agent, hydrofinishing paraffin or naphthene base lubrication oil or be hydrocracked the poly-of the paraffin base lubricating oil of isomery or hydrogenation
Alkene oil.Wear reducing additive is selected from carboxylate additive or fatty acid phosphate and fatty acid phosphate,
Preferably Trimethylamine dilauryl phosphate.This textile machine bobbin oil uses and Cotton Gossypii will not be caused pin hole break
Bad, fatty acid phosphate decreases the abrasion of spindle, but phosphate brings environmental hazard simultaneously.
CN101838593A discloses a kind of Spindling cleaning solution of cotton picker, and composition includes: 70～the mineral of 90%
Oil, 3～the nonionic surfactant of 20%, 0～the antirust agent of 5.0%, 0～the alcohols antifreeze of 6%, 0～3.0%
Corrosion inhibiter, 0～the alkaline agent of alcamines of 2%.Wherein, polyoxyethylene nonyl phenyl selected by nonionic surfactant
Vinyl Ether series emulsifying agent and Si Pan series emulsifying agent, petroleum sulfonate selected by antirust agent.Because formula does not contains
Phosphate, nitrite, the composition such as silicate, environmental hazard is relatively small.But, owing to this product uses
Based on mineral oil, oil, trickles down in soil, is difficult to degraded, causes soil, water source and surrounding
Pollute, add substantial amounts of induced by alkyl hydroxybenzene surfactant and ethanolamine alkaline agent simultaneously, to human body and environment also
Cause bigger harm.
US6063744 describes cleaning and lubricating function liquid, the group of spindle in a kind of cotton picker or harvesting machinery
Become to include unsaturated fatty acid anion surfactant, glycol ether, alcoholic solvent, non-ionic surface active
Agent, amine cosurfactant, polybasic carboxylic acid, and use alkaline reagent to regulate pH value.Wherein, nonionic
Surfactant is selected from alkoxyl phenols surfactant, and amine surfactants is selected from alkanolamide, many
Unit's carboxylic acid is as acylating reagent.This cleanout fluid liquid based on water, does not use petroleum distillate, does not results in
Cotton Gossypii and the pollution of soil.But at present, marketing users universally recognized cotton picker cleanout fluid remains oil base breast
Changing liquid, the cleaning lubricating function liquid of this invention in market and has not seen.
At present, domestic cotton picker has reached more than the 70% of market share, but domestic cotton picker abluent
Still mainly provide with cotton picker manufacturer Deere and CASE.At present, domestic cotton picker abluent is had no
Qualified products.
Tracing it to its cause, due to the particularity of operating mode, cotton picker work is the highest to the performance requirement of abluent.Adopt
Cotton machine abluent storage tank is without mixing stirring device, it is desirable to abluent must possess stronger self emulsifying power, in nothing
Under conditions of need to shaking or stir, meet water and can form homogeneous latex emulsion；Go out at cotton picker abluent reservoir bottom
Mouth has the thinnest defecator, it is desirable to abluent emulsion is without wall built-up, without undissolved lump in breast granule；Cotton picking worker
Condition requires to clean at any time to pluck dust, juice, grease and the velveteen on ingot, it is desirable to abluent wettability is strong,
Lubricity is good, good to oils and fats and the lyotropy of impurity, cleaning；Emulsion preparation need to be fetched water whenever and wherever possible,
Require that abluent has the general applicability of resistance to hard water；Cotton picker spindle is that a high speed plucks cotton, de-cotton following
Ring, it is desirable to abluent is to plucking ingot cotton picking and de-cotton has good help.
Therefore, cotton picker abluent is the harshest to the performance requirement of the surfactant that it forms, it is necessary to simultaneously
Meeting above performance requirement, the most domestic abluent is difficult to meet cotton picker working condition requirement.
Summary of the invention
The invention provides a kind of cotton picker cleansing composition and the emulsion comprising said composition.
The cotton picker cleansing composition of the present invention includes compound emulsifying agent and major amount of base oil, described multiple
Co-emulsifier is fatty acid ester ethoxylates, fatty alcohol-polyoxyethylene ether and the mixing of alkylethylene diamines triacetic acid
Thing, one or more in vegetable oil, epoxidized vegetable oil and biodiesel of described base oil.
Described fatty acid ester ethoxylates be reacted with ethylene oxide oligomer by C12-C20 fatty acid after prepare
Obtain, described C12-C20 fatty acid, can be satisfied fatty acid or unsaturated fatty acid, preferably Laurel
One or more in acid, myristic acid, Palmic acid, linoleic acid, oleic acid, linolenic acid and stearic acid, optimum
Select one or more in Palmic acid, oleic acid, linoleic acid and stearic acid.Dividing of described ethylene oxide oligomer
Son amount preferably 200,400,600, most preferably 400,600.The preferred Laurel of described fatty acid ester ethoxylates
In acid esters b-oxide, cetylate b-oxide, oleate b-oxide and stearate b-oxide
One or more, most preferably cetylate b-oxide and/or oleate b-oxide.Described fatty acid ester second
The trade mark that oxide can select commercial goods, such as Hai'an chemical company to produce is PEG ML, PEG OL
Product.
Described fatty alcohol-polyoxyethylene ether is to be prepared into after C8-C20 fatty alcohol reacts with ethylene oxide oligomer
Arrive, described fatty alcohol preferred C12-C18 fatty alcohol, most preferably C14-C16 fatty alcohol.Described epoxy second
The molecular weight of alkane oligomer preferably 200,400,600, most preferably 400,600.Described fatty alcohol polyoxy second
The preferred polyoxyethylene lauryl ether of alkene ether, tetradecyl alchohol polyoxyethylene ether, hexadecanol polyoxyethylene ether, octadecanol
One or more in polyoxyethylene ether, oleic alcohol polyoxyethylene ether and sub-oleic alcohol polyoxyethylene ether；The most preferably moon
One or more in cinnamic alcohol polyoxyethylene ether, tetradecyl alchohol polyoxyethylene ether and hexadecanol polyoxyethylene ether.Institute
State Hai'an chemical company can be selected to produce in the commercial goods of fatty alcohol-polyoxyethylene ether MOA3, MOA5,
MOA7, MOA9, MOA15, MOA20, blue star chemical company produce AEO3, AEO5, AEO8,
AEO9, AEO15, AEO20, O-3, O-5, O-8, O-9, O-10, O-15, O-20, preferably MOA3,
MOA5, MOA9, MOA15, AEO3, AEO9, AEO15, O-3, O-8, O-10 and O-15
In one or more.
Described alkylethylene diamines triacetic acid is C10-C20 alkylethylene diamines triacetic acid, optional lauryl ethylenediamine
Triacetic acid, myristyl ethylenediamine triacetic acid, cetyl ethylenediamine triacetic acid and octadecyl ethylenediamine three
One or more in acetic acid, described alkylethylene diamines triacetic acid preferred C12-C16 alkylethylene diamines triacetic acid,
Most preferably lauryl ethylenediamine triacetic acid and/or cetyl ethylenediamine triacetic acid.Described alkylethylene diamines three second
Acid can select the N-dodecyl ethylenediamine three of commercial goods, such as Beijing spark surfactant institute
Acetic acid, the N-cetyl ethylenediamine triacetic acid of mesophytization Manufacturing Co., Ltd is closed in Wuhan.
Fatty acid ethoxylates, fatty alcohol-polyoxyethylene ether and alkylethylene diamines three second in described compound emulsifying agent
Mass ratio between acid is 1:0.1-1.0:0.05-0.5, preferably 1:0.2-0.8:0.08-0.3, most preferably 1:0.3-0.5:
0.1-0.2。
Described compound emulsifying agent accounts for the 1～40% of compositions gross mass, preferably 3-30%, most preferably 5-20%.
One or more in vegetable oil, epoxidized vegetable oil and biodiesel of described base oil, preferably
OECD301B biological degradability is more than the one in vegetable oil, epoxidized vegetable oil and the biodiesel of 80%
Or it is multiple.
Described vegetable oil selected from rolling vegetable oil and/or through refinement treatment aftergrowth oil, preferably oleum lini,
One or many in Oleum Helianthi, Oleum Brassicae campestris, soybean oil, Petiolus Trachycarpi oil, Oleum Gossypii semen, Semen Maydis oil and olive oil
Kind, most preferably one or more in Oleum Helianthi, soybean oil, Petiolus Trachycarpi oil and Oleum Gossypii semen.
Described epoxidized vegetable oil is to make after vegetable oil carries out epoxidation reaction with oxirane and/or expoxy propane
The standby epoxidized vegetable oil obtained, preferably epoxidation Oleum Helianthi, epoxidized rapeseed oil, epoxidised soybean oil,
One or more in epoxidized palm oil, epoxidation Oleum Gossypii semen and epoxidized corn oil, most preferably epoxidation
One or more in Oleum Helianthi, epoxidised soybean oil, epoxidized palm oil and epoxidation Oleum Gossypii semen.
Described biodiesel is selected from sending out with methanol and/or ethanol with animal and plant fat and/or combination of reclaimed grease for raw material
The fatty acid mono alkyl ester that raw ester exchange reaction generates, preferably with oleum lini, Oleum Helianthi, Oleum Brassicae campestris, big
One or more in Oleum Glycines, Petiolus Trachycarpi oil, Oleum Gossypii semen, Semen Maydis oil, olive oil and aftergrowth oil and methanol
There is the fatty acid methyl ester that ester exchange reaction generates, most preferably with oleum lini, soybean oil, Petiolus Trachycarpi oil, Semen Gossypii
Oil and the oily fatty acid methyl ester generated with methanol generation ester exchange reaction of aftergrowth or their mixture.
The preferred described vegetable oil of described base oil and/or the oily mixed base with described biodiesel of aftergrowth
Oil, such as oleum lini, Oleum Helianthi, Oleum Brassicae campestris, soybean oil, Petiolus Trachycarpi oil, Oleum Gossypii semen, Semen Maydis oil and Fructus Canarii albi
One or more in oil and the mixed base oil of biodiesel, most preferably oleum lini, soybean oil, Petiolus Trachycarpi oil
Mixed base oil with one or more in Oleum Gossypii semen Yu biodiesel.
In described mixed base oil, vegetable oil and/or the oily mass ratio with biodiesel of aftergrowth are
95:5～50:50, preferably 90:10～60:40, most preferably 85:15～70:30.
Compositions of the present invention can also add other functional additive, such as antirust agent, anti-friction composition etc..
Described antirust agent is selected from C12-C18 carboxylic acid and/or the polyol ester of C12-C18 carboxylic acid, described
The sorbitol ester of polyol ester preferred C12-C18 carboxylic acid of C12-C18 carboxylic acid, pentaerythritol ester.Described
The adducible example of antirust agent includes oleic acid, linoleic acid, linolenic acid, dodecenylsuccinic acid, laurylene
One or more in base succinic acid butanediol monoesters, sorbitol monooleate and pentaerythritol monooleate,
Preferably oleic acid, dodecenylsuccinic acid, dodecenylsuccinic acid butanediol monoesters and sorbitol monooleate
In one or more, its addition is the 0.01%-5% of compositions gross mass, preferably 0.03%-2%.
Described anti-friction composition is selected from the fatty acid of C12-C18, fatty acid ester, fatty alcohol and dimeric dibasic acid
Kind or multiple, such as oleic acid, methyl oleate, oleic acid diethyl alcohol ester, lauryl alcohol, tetradecyl alchohol, hexadecanol,
One or more in octadecanol, oleyl alcohol, sub-oleyl alcohol, linoleic acid dimeric dibasic acid and oleic acid dimer acid, preferably fat
Fat acid polyol ester and/or dimeric dibasic acid, most preferably oleic acid glycol ester and/or oleic acid dimer acid, its addition is
The 0.01%-5% of compositions gross mass, preferably 0.05-2%.
Cotton picker cleansing composition of the present invention is will to prepare after above-mentioned compound emulsifying agent and base oil mix and blend
Obtain.
Cotton picker cleansing composition stable performance of the present invention, clear, have good biological degradability,
Do not pollute Cotton Gossypii and soil, friendly with environment and human body, form highly stable emulsion with water, have resistance to
The good characteristic of hard water, room temperature stand within 10 days, occur without analysis oil or lamination, can continuously or interval use,
There is outstanding cleaning, moistening, antirust, wear-resistant undermine cotton picking, de-cotton effect.
Present invention also offers a kind of emulsion, including above-mentioned cotton picker cleansing composition and water, described group
Compound mass fraction in emulsion is 0.1～5%, preferably 0.5～2%.Described emulsion is suitable for cotton picking
Machine hydraulic pressure cleans, dampening system.
Emulsion of the present invention has excellent cleaning, moistening, antirust, wear-resistant undermines cotton picking, de-woolliness energy.
Detailed description of the invention
The percentage ratio mentioned in the following embodiments, is mass percent, except special instruction.
Further illustrate the present invention below by example, but the present invention is not limited to this.
Raw material sources and character:
40 DEG C of viscosity of oleum lini are 24.26mm2/ s, viscosity index (VI) 207, cloud point-10 DEG C, open flash point
295 DEG C, Hebei Jin Gu oils and fats company limited；
40 DEG C of viscosity of Oleum Helianthi are 28.32mm2/ s, viscosity index (VI) 188, cloud point-6 DEG C, open flash point
305 DEG C, Hebei Jin Gu oils and fats company limited；
40 DEG C of viscosity of regenerable soybean oil are 31.52mm2/ s, viscosity index (VI) 175, cloud point-3 DEG C, open flash point
315 DEG C, Hebei Jin Gu oils and fats company limited；
40 DEG C of viscosity of biodiesel are 4.18mm2/ s, condensation point-6 DEG C, open flash point 165 DEG C, Hebei Jin Gu
Oils and fats company limited；
100 DEG C of viscosity of 100SN base oil are 3.992mm2/ s, 40 DEG C of viscosity are 20.56mm2/ s, viscosity
Index 81, pour point-15 DEG C, open flash point 236 DEG C, Yanshan Petrochemical company oil plant；
N-cetyl ethylenediamine triacetic acid, mesophytization Manufacturing Co., Ltd is closed in Wuhan；
N-dodecyl ethylenediamine triacetic acid, Beijing spark surfactant institute；
Fatty acid ethoxylates (PEG series): Hai'an, Jiangsu petrochemical industry company limited；
Fatty alcohol-polyoxyethylene ether (MOA series): Hai'an, Jiangsu petrochemical industry company limited；
Fatty alcohol-polyoxyethylene ether (AEO series, O series): Hebei blue star chemical assistant company limited；
Oleic acid glycol ester: Lanzhou refinery company；
Triethanolamine oleate: Hebei blue star chemical assistant company limited；
Dodecenylsuccinic acid butanediol monoesters: WUXI SOUTH PETROLEUM ADDITIVE Co., LTD.；
Sorbitan monooleate (Arlacel-80): Beijing Reagent Company of traditional Chinese medicines group；
NPE: Hebei blue star chemical assistant company limited；
Embodiment 1
Take oleum lini and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning, to add compound emulsifying agent cetylate b-oxide, tetradecyl alchohol poly-
Oxygen vinyl Ether, cetyl ethylenediamine triacetic acid, then 25 DEG C are stirred 40 minutes, are filtrated to get cotton picker clear
Detergent composition.
Embodiment 2
Take oleum lini and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning, to add compound emulsifying agent cetylate b-oxide, tetradecyl alchohol poly-
Oxygen vinyl Ether, cetyl ethylenediamine triacetic acid, antirust agent dodecenylsuccinic acid, anti-friction agent oleic acid second two
Alcohol ester, then 25 DEG C are stirred 40 minutes, are filtrated to get cotton picker cleansing composition.
Embodiment 3
Take Oleum Gossypii semen and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning, to add compound emulsifying agent cetylate b-oxide, tetradecyl alchohol poly-
Oxygen vinyl Ether, lauryl ethylenediamine triacetic acid, antirust agent dodecenylsuccinic acid butanediol monoesters, anti-friction agent
Oleic acid glycol ester, then 25 DEG C are stirred 40 minutes, are filtrated to get cotton picker cleansing composition.
Embodiment 4
Learnt from else's experience deodorize, deacidification refinement treatment regenerable soybean oil standby by the mass ratio of 77:23 with biodiesel
Good, add in the blending kettle of band agitating device, 25 DEG C are stirred 30 minutes, then press table 1 proportioning addition Composite Milk
Agent oleate b-oxide, Dodecyl Polyoxyethylene Ether, lauryl ethylenediamine triacetic acid, antirust agent 12
Alkenyl succinic acid butanediol monoesters, anti-friction agent oleic acid dimer acid, then 25 DEG C are stirred 40 minutes, are filtrated to get
Cotton picker cleansing composition.
Embodiment 5
Take Oleum Gossypii semen and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning addition compound emulsifying agent oleate b-oxide, tetradecyl alchohol polyoxy
Vinyl Ether, lauryl ethylenediamine triacetic acid, antirust agent dodecenylsuccinic acid butanediol monoesters, then 25 DEG C
Stir 40 minutes, be filtrated to get cotton picker cleansing composition.
Comparative example 1
Take 40 DEG C of viscosity 18～24mm2Mineral base oil 100SN between/s adds the tune of band agitating device
Close in still, then press table 1 proportioning addition compound emulsifying agent oleate b-oxide, tetradecyl alchohol polyoxyethylene ether,
Lauryl ethylenediamine triacetic acid, then 25 DEG C are stirred 60 minutes, are filtrated to get Comparative composition.
Comparative example 2
Take Oleum Gossypii semen and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, add compound emulsifying agent oleate b-oxide, lauryl alcohol polyoxy second by table 1 proportioning
Alkene ether, dodecenylsuccinic acid butanediol monoesters, anti-friction agent oleic acid glycol ester, then 25 DEG C are stirred 60 points
Clock, is filtrated to get Comparative composition.
Comparative example 3
Take oleum lini and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning, to add compound emulsifying agent cetylate b-oxide, tetradecyl alchohol poly-
Oxygen vinyl Ether, triethanolamine oleate, antirust agent dodecenylsuccinic acid, anti-friction agent oleic acid glycol ester, so
Latter 25 DEG C are stirred 60 minutes, are filtrated to get Comparative composition.
Comparative example 4
Take oleum lini and biodiesel to get ready by the mass ratio of 80:20, add in the blending kettle of band agitating device,
25 DEG C are stirred 30 minutes, then press table 1 proportioning addition emulsifier sorbitol oleate, NPE,
Co-emulsifier ethylene glycol, antirust agent dodecenylsuccinic acid, then 25 DEG C are stirred 40 minutes, and it is right to be filtrated to get
Compare compositions.
Comparative example 5
Take the cotton picker abluent spindle cleaner of commercially available Deere company, contrast physicochemical property.
In embodiment 1-5 and comparative example 1-4, the weight/mass percentage composition of each component is shown in Table 1, embodiment 1-5 and right
The physicochemical property of ratio 1-5 is shown in Table 3.
Evaluate the self emulsifying of abluent, emulsion stability and cotton picking, de-woolliness can use from construction method.
Determining after repeatedly screening test from construction method, repeatability and accuracy are good.
Abluent is self emulsifiable from construction method is in evaluation: takes 1mL abluent and puts into 100mL tool plug graduated cylinder,
Take 99mL tap water and be slowly added to graduated cylinder along graduated cylinder wall.After all adding, it is impossible to stir or shake, stand
5min, observe mixed liquor state, then mixed liquor is poured out, observed quantity barrel whether have wall cling phenomenon,
The not emulsified dissolving of oily soap whether is had bottom graduated cylinder.
Table 1
Automatic emulsifying performance is rated:
Self emulsifying is good: emulsion is uniform, dense, without obvious stereovision, pours out rear graduated cylinder wall existing without wall built-up
As, oil-free soap or undissolved oil clot bottom graduated cylinder；Self emulsifying is preferable: emulsion is uniform, thin, nothing
Substantially stereovision, pours out rear graduated cylinder wall without wall cling phenomenon, oil-free soap or undissolved oil clot bottom graduated cylinder；From
Emulsibility is poor: emulsion appearance uniform, thin, and without obvious stereovision, pouring out rear graduated cylinder wall has wall built-up existing
As, without substantially oil soap or undissolved oil clot bottom graduated cylinder；Self emulsifying is poor: emulsion outward appearance is uneven,
Have levels sense, and pouring out rear graduated cylinder wall has bottom wall cling phenomenon or graduated cylinder and have substantially oil soap or undissolved oil clot.
Evaluation abluent emulsion stability from construction method be: with 100mL tool plug graduated cylinder take abluent emulsifying
Liquid sample, is positioned under constant temperature, estimates sample state.Test selects 25 DEG C ± 2 DEG C to evaluate abluent breast
Changing the stability of liquid, stability grading is shown in Table 2.
Table 2 cotton picker abluent emulsion stability is graded
Cotton picker cotton picking with de-cotton operation principle is: high speed rotating (4000r/min) pluck ingot regularly
Stretch out screen, the horizontal cotton plant being extruded that is inserted perpendicularly into, utilize the briar tooth plucked on ingot to tangle unginned cotton,
Blow-of-cottons cotton lobe pulls out from the cotton boll of cracking, and is entangled in and plucks on ingot；Pluck ingot simultaneously and rotate (1000 with cylinder
R/min～1500r/min) by plucking room through the de-cotton region of screen entrance；Horizontal high speed rotating (1500r/min～2000
The unginned cotton plucked on ingot is reversely taken off by de-cotton dish r/min)；The unginned cotton taken off by air-flow from cotton collecting chamber, through defeated
Cotton pipe is delivered to hopper.
According to cotton picker cotton picking and de-cotton operation principle, utilize the cotton picker obtained from cotton picker factory
Ingot and de-cotton dish, use rotation lathe to fix cotton picker spindle, utilizes the fixing de-cotton dish of electric rotating machine, sets up
Simulation evaluation device, and devise the simulation evaluation method of abluent cotton picking and de-woolliness energy:
1. cotton picker abluent sample is accounted for 1% by abluent, water account for 99% percent by volume preparation emulsion
Sample, dips emulsion with hairbrush, brushes gently plucking ingot surface；
2. start motor, make the rotating speed of cotton picker spindle reach 1500r/min, after stabilization of speed, use tweezers
The gripping quantitatively unginned cotton of (10g) is wrapped in gently plucks on ingot；
3., after unginned cotton has twined, start the most de-cotton dish so that it is rotating speed reaches 1200r/min；
4., after de-cotton dish stabilization of speed, lathe slide rail translates cotton picker spindle.Plucking high speed rotating
Ingot shifts near the de-cotton dish of high speed rotating, evaluation pluck ingot and de-cotton dish close to time de-cotton effect；
The most each sample carries out 100 de-cotton tests, and record takes off cotton success rate, evaluates and pluck ingot outward appearance.
Measure 40 DEG C of kinematic viscositys, pour point, flash-point, biological degradabilities of cotton picker abluent in table 1 respectively.
And account for 1% according to abluent, water accounts for the percent by volume of 99% and is configured to emulsion, evaluate abluent from
The de-cotton test of stability in emulsibility, emulsion stability, cleaning rate, rustless property, hard water, cotton picking,
And carry out cotton picking scene real vehicle application test, the results are shown in Table 3,4.
Knowable to table 3,4 contrasts, the self emulsifying of cotton picker abluent, emulsion stability are good, biological fall
Solution is good.Cotton picker real vehicle application test shows, the cotton picker abluent excellent performance of the present invention.
Table 3
Table 4
Claims (15)
1. a cotton picker cleansing composition, including compound emulsifying agent and major amount of base oil, described compound
Emulsifying agent is the mixed of fatty acid ester ethoxylates, fatty alcohol-polyoxyethylene ether and alkylethylene diamines triacetic acid
Compound, one or more in vegetable oil, epoxidized vegetable oil and biodiesel of described base oil；
Fatty acid ester ethoxylates, fatty alcohol-polyoxyethylene ether and alkylethylene diamines three in described compound emulsifying agent
Mass ratio between acetic acid is 1:0.1-1.0:0.05-0.5；
Described compound emulsifying agent accounts for the 1～40% of compositions gross mass.
2. according to the compositions described in claim 1, it is characterised in that described fatty acid ester ethoxylates be by
C12-C20 fatty acid prepares after reacting with ethylene oxide oligomer.
3. according to the compositions described in claim 1, it is characterised in that described fatty acid ester ethoxylates is the moon
Cinnamic acid ester b-oxide, cetylate b-oxide, oleate b-oxide and stearate ethoxyquin
One or more in thing.
4. according to the compositions described in claim 1, it is characterised in that described fatty alcohol-polyoxyethylene ether is
C8-C20 fatty alcohol prepares after reacting with ethylene oxide oligomer.
5. according to the compositions described in claim 1, it is characterised in that described fatty alcohol-polyoxyethylene ether is the moon
Cinnamic alcohol polyoxyethylene ether, tetradecyl alchohol polyoxyethylene ether, hexadecanol polyoxyethylene ether, octadecanol polyoxy second
One or more in alkene ether, oleic alcohol polyoxyethylene ether and sub-oleic alcohol polyoxyethylene ether.
6. according to the compositions described in claim 1, it is characterised in that described alkylethylene diamines triacetic acid is
C10-C20 alkylethylene diamines triacetic acid.
7. according to the compositions described in claim 1, it is characterised in that described alkylethylene diamines triacetic acid is
C12-C16 alkylethylene diamines triacetic acid.
8. according to the compositions described in claim 1, it is characterised in that described base oil is OECD 301B
Biological degradability is more than one or more in vegetable oil, epoxidized vegetable oil and the biodiesel of 80%.
9. according to the compositions described in claim 1, it is characterised in that described vegetable oil is selected from rolling vegetable oil
And/or the aftergrowth oil through refinement treatment.
10. according to the compositions described in claim 1, it is characterised in that described epoxidized vegetable oil is vegetable oil
The epoxidized vegetable oil prepared after carrying out epoxidation reaction with oxirane and/or expoxy propane.
11. according to the compositions described in claim 1, it is characterised in that described biodiesel is selected from animals and plants
Oils and fats and/or combination of reclaimed grease are the fatty acid that raw material generates with methanol and/or ethanol generation ester exchange reaction
Mono alkyl ester.
12. according to the compositions described in claim 9, it is characterised in that the preferred described vegetable oil of described base oil
And/or the oily mixed base oil with described biodiesel of aftergrowth, vegetable oil in described mixed base oil
And/or the mass ratio of aftergrowth oil and biodiesel is 95:5～50:50.
13. according to the compositions described in claim 1, it is characterised in that add antirust agent in described compositions,
Its addition is the 0.01%-5% of compositions gross mass.
14. according to the compositions described in claim 1, it is characterised in that add anti-friction composition in described compositions,
Its addition is the 0.01%-5% of compositions gross mass.
15. 1 kinds of emulsions, including the cotton picker cleansing composition one of claim 1-14 Suo Shu and water, institute
Stating compositions mass fraction in emulsion is 0.1～5%.
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| CN201310192283.XA CN104178287B (en) | 2013-05-22 | 2013-05-22 | Cotton picker cleansing composition and comprise the emulsion of said composition |
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| CN201310192283.XA CN104178287B (en) | 2013-05-22 | 2013-05-22 | Cotton picker cleansing composition and comprise the emulsion of said composition |
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| CN104178287A CN104178287A (en) | 2014-12-03 |
| CN104178287B true CN104178287B (en) | 2016-08-10 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109705961A (en) * | 2019-02-21 | 2019-05-03 | 新疆甲子工贸有限公司 | A kind of cotton picker cleaning agent, its composition, its emulsion and preparation method thereof |
| CN110791360B (en) * | 2019-11-15 | 2022-05-17 | 湖北诚祥科技有限公司 | Environment-friendly cleaning agent for cotton picker |
| CN115873651B (en) * | 2022-12-09 | 2024-05-31 | 重庆化工职业学院 | Biodegradable emulsified oil with modified graphene synergistic effect and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6063744A (en) * | 1999-07-22 | 2000-05-16 | Mcquillen; Edwin F. | Cleaning and lubricant formulation for spindles |
| CN1948446A (en) * | 2006-06-16 | 2007-04-18 | 大连绿洲化工有限公司 | Environmental protection high concentration low foam rust proof metal cleaning agent and its technology |
| CN101503804A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Cleaning liquid composition and use thereof |
| CN101838593A (en) * | 2009-02-09 | 2010-09-22 | 乌鲁木齐现代石油化工有限公司 | Spindling cleaning solution of cotton picker |
-
2013
- 2013-05-22 CN CN201310192283.XA patent/CN104178287B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6063744A (en) * | 1999-07-22 | 2000-05-16 | Mcquillen; Edwin F. | Cleaning and lubricant formulation for spindles |
| CN1948446A (en) * | 2006-06-16 | 2007-04-18 | 大连绿洲化工有限公司 | Environmental protection high concentration low foam rust proof metal cleaning agent and its technology |
| CN101503804A (en) * | 2008-12-15 | 2009-08-12 | 中国石油化工股份有限公司 | Cleaning liquid composition and use thereof |
| CN101838593A (en) * | 2009-02-09 | 2010-09-22 | 乌鲁木齐现代石油化工有限公司 | Spindling cleaning solution of cotton picker |
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