CN104177998A - Unsaturated polyester photosensitive coating for ceramics - Google Patents
Unsaturated polyester photosensitive coating for ceramics Download PDFInfo
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- CN104177998A CN104177998A CN201410453086.3A CN201410453086A CN104177998A CN 104177998 A CN104177998 A CN 104177998A CN 201410453086 A CN201410453086 A CN 201410453086A CN 104177998 A CN104177998 A CN 104177998A
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- unsaturated polyester
- pottery
- photoactive coating
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Abstract
The invention discloses an unsaturated polyester photosensitive coating for ceramics. The coating is prepared from the following raw materials: unsaturated polyester, diethylene glycol, epoxy polyurethane, styrene, water, stannous chloride, coloring pigment, hydroquinone, polyethylene wax, ethanol, a crosslinker, benzoin ethyl ether, polytetrafluoroethylene wax, diphenyl ketone and silane. The coating cannot cause bubbling and wrinkling when being soaked in calcium hydroxide for 15-25 days, cannot cause bubbling and falling phenomena after being soaked in water for 20-30 days, has the glossiness of 110%-130% and the hardness of 4-6H, can not expose base after being wiped for 500-1,000 times, can be extensively produced and continuously replaces an existing material; the surface drying time is 10-30 seconds and the hard drying time is 15-35 minutes.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of pottery unsaturated polyester photoactive coating.
Background technology
Development due to ceramic science technology.And market increases day by day to the demand of ceramic product innovation, force Ceramics Enterprises to want development product innovation, and must consider problem that this factor of change of product is brought rationalization's production process and the impact of generation.In order to strengthen adaptability, Ceramics Enterprises not only needs to improve energetically the Research Ability of scientific and technical application level and product innovation, constantly make model change, also must adopt the advanced production organization method such as program evaluation and review technique, group technology and the production of many kinds mixed flow, adopt adaptable machinery equipment and flexible production manufacturing system, to adapt to the needs of producing change.And universal along with humanity concept, and the formation of novel harmonious society, design a kind of corrosion-resistant, resistance to solvent, chemical-resistant resistance, resistance to wiping and the high pottery of hardness and be very important with unsaturated polyester photoactive coating.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of pottery unsaturated polyester photoactive coating, solves the technical problems such as not corrosion-resistant, the not resistance to solvent of unsaturated polyester photoactive coating for existing pottery, chemical-resistant resistance, not resistance to wiping and hardness is not low.
Technical scheme:
A pottery unsaturated polyester photoactive coating, described pottery is as follows by the raw materials by weight portion proportioning of unsaturated polyester photoactive coating: 100 parts of unsaturated polyesters; Diethylene Glycol 40-60 part; Epoxy polyurethane 40-50 part; Vinylbenzene 45-55 part; Water 80-100 part; Tin protochloride 0.1-1 part; Tinting pigment 5-10 part; Resorcinol 0.5-1.5 part; Polyethylene wax 10-30 part; Ethanol 30-50 part; Linking agent 5-15 part; Benzoin ethyl ether 1-10 part; Tetrafluoroethylene wax 15-25 part; Benzophenone 10-20 part; Silane 20-30 part.
As a preferred technical solution of the present invention: described pottery is as follows by the raw materials by weight portion proportioning of unsaturated polyester photoactive coating: unsaturated polyester is 100 parts; 50 parts of Diethylene Glycols; 45 parts of epoxy polyurethanes; 50 parts of vinylbenzene; 90 parts, water; 0.5 part of tin protochloride; 8 parts of tinting pigments; 1 part of Resorcinol; 20 parts of polyethylene waxs; 40 parts of ethanol; 10 parts of linking agents; 5 parts of Benzoin ethyl ethers; 20 parts, tetrafluoroethylene wax; 15 parts of benzophenone; 25 parts, silane.
As a preferred technical solution of the present invention: described tinting pigment adopts ultramarine or deep chrome yellow.
As a preferred technical solution of the present invention: described linking agent adopts hexamethoxymethyl melamine.
Beneficial effect:
A kind of pottery of the present invention adopts above technical scheme compared with prior art with unsaturated polyester photoactive coating, has following technique effect: 1, product soaks in saturated calcium hydroxide that 15-25d is non-foaming, elephant skin; 2, surface drying time 10-30s, does solid work 15-35min, soaks after 20-30d without bubbling, obscission in water; 3, glossiness 110%-130%, hardness 4-6H; 4, product wiping 500-1000 time is not show-through, can the not division of history into periods of widespread production for current material.
Embodiment
Embodiment 1:
Pottery is used a unsaturated polyester photoactive coating, and its raw materials by weight portion proportioning is as follows: 100 parts of unsaturated polyesters; 40 parts of Diethylene Glycols; 40 parts of epoxy polyurethanes; 45 parts of vinylbenzene; 80 parts, water; 0.1 part of tin protochloride; 5 parts, ultramarine; 0.5 part of Resorcinol; 10 parts of polyethylene waxs; 30 parts of ethanol; 5 parts of hexamethoxymethyl melamines; 1 part of Benzoin ethyl ether; 15 parts, tetrafluoroethylene wax; 10 parts of benzophenone; 20 parts, silane.
First unsaturated polyester, Diethylene Glycol, epoxy polyurethane, vinylbenzene, water and tin protochloride are mixed and add surplus stock again in reactor, be warming up to after 210 ℃ of reaction 2h, be cooled to room temperature, after filtration, be coated on pottery, with uviolizing, solidify.
Product soaks in saturated calcium hydroxide that 15d is non-foaming, elephant skin; Surface drying time 30s, does solid work 35min, soaks after 20d without bubbling, obscission in water; Glossiness 110%, hardness 4H, resistance to wiping 500 times is not show-through.
Embodiment 2:
Pottery is used a unsaturated polyester photoactive coating, and its raw materials by weight portion proportioning is as follows: 100 parts of unsaturated polyesters; 60 parts of Diethylene Glycols; 50 parts of epoxy polyurethanes; 55 parts of vinylbenzene; 100 parts, water; 1 part of tin protochloride; 10 parts, ultramarine; 1.5 parts of Resorcinol; 30 parts of polyethylene waxs; 50 parts of ethanol; 15 parts of hexamethoxymethyl melamines; 10 parts of Benzoin ethyl ethers; 25 parts, tetrafluoroethylene wax; 20 parts of benzophenone; 30 parts, silane.
First unsaturated polyester, Diethylene Glycol, epoxy polyurethane, vinylbenzene, water and tin protochloride are mixed and add surplus stock again in reactor, be warming up to after 230 ℃ of reaction 4h, be cooled to room temperature, after filtration, be coated on pottery, with uviolizing, solidify.
Product soaks in saturated calcium hydroxide that 20d is non-foaming, elephant skin; Surface drying time 20s, does solid work 25min, soaks after 25d without bubbling, obscission in water; Glossiness 120%, hardness 5H, resistance to wiping 800 times is not show-through.
Embodiment 3:
Pottery is used a unsaturated polyester photoactive coating, and its raw materials by weight portion proportioning is as follows: 100 parts of unsaturated polyesters; 50 parts of Diethylene Glycols; 45 parts of epoxy polyurethanes; 50 parts of vinylbenzene; 90 parts, water; 0.5 part of tin protochloride; 8 parts of deep chrome yellows; 1 part of Resorcinol; 20 parts of polyethylene waxs; 40 parts of ethanol; 10 parts of hexamethoxymethyl melamines; 5 parts of Benzoin ethyl ethers; 20 parts, tetrafluoroethylene wax; 15 parts of benzophenone; 25 parts, silane.
First unsaturated polyester, Diethylene Glycol, epoxy polyurethane, vinylbenzene, water and tin protochloride are mixed and add surplus stock again in reactor, be warming up to after 220 ℃ of reaction 3h, be cooled to room temperature, after filtration, be coated on pottery, with uviolizing, solidify.
Product soaks in saturated calcium hydroxide that 25d is non-foaming, elephant skin; Surface drying time 10s, does solid work 15min, soaks after 30d without bubbling, obscission in water; Glossiness 130%, hardness 6H, resistance to wiping 1000 times is not show-through.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, rather than restriction, therefore in the implication suitable with claims of the present invention and any change in scope, all should think to be included in the scope of claims.
Claims (4)
1. pottery is used a unsaturated polyester photoactive coating, it is characterized in that described pottery is as follows by the raw materials by weight portion proportioning of unsaturated polyester photoactive coating: 100 parts of unsaturated polyesters; Diethylene Glycol 40-60 part; Epoxy polyurethane 40-50 part; Vinylbenzene 45-55 part; Water 80-100 part; Tin protochloride 0.1-1 part; Tinting pigment 5-10 part; Resorcinol 0.5-1.5 part; Polyethylene wax 10-30 part; Ethanol 30-50 part; Linking agent 5-15 part; Benzoin ethyl ether 1-10 part; Tetrafluoroethylene wax 15-25 part; Benzophenone 10-20 part; Silane 20-30 part.
2. a kind of pottery unsaturated polyester photoactive coating according to claim 1, is characterized in that described pottery is as follows by the raw materials by weight portion proportioning of unsaturated polyester photoactive coating: 100 parts of unsaturated polyesters; 50 parts of Diethylene Glycols; 45 parts of epoxy polyurethanes; 50 parts of vinylbenzene; 90 parts, water; 0.5 part of tin protochloride; 8 parts of tinting pigments; 1 part of Resorcinol; 20 parts of polyethylene waxs; 40 parts of ethanol; 10 parts of linking agents; 5 parts of Benzoin ethyl ethers; 20 parts, tetrafluoroethylene wax; 15 parts of benzophenone; 25 parts, silane.
3. a kind of pottery unsaturated polyester photoactive coating according to claim 1, is characterized in that: described tinting pigment adopts ultramarine or deep chrome yellow.
4. a kind of pottery unsaturated polyester photoactive coating according to claim 1, is characterized in that: described linking agent adopts hexamethoxymethyl melamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410453086.3A CN104177998B (en) | 2014-09-09 | 2014-09-09 | Unsaturated polyester (UP) photoactive coating used by a kind of pottery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410453086.3A CN104177998B (en) | 2014-09-09 | 2014-09-09 | Unsaturated polyester (UP) photoactive coating used by a kind of pottery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104177998A true CN104177998A (en) | 2014-12-03 |
| CN104177998B CN104177998B (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410453086.3A Active CN104177998B (en) | 2014-09-09 | 2014-09-09 | Unsaturated polyester (UP) photoactive coating used by a kind of pottery |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010002409A1 (en) * | 1998-11-30 | 2001-05-31 | Randall T. Lake | Lamp reflectors and uv curable compositions useful as basecoats for same |
| CN1754929A (en) * | 2004-09-29 | 2006-04-05 | 上海保诺杰企业发展有限公司 | UV cured protective coating of reflective film |
| CN101760124A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Light-cured epoxy polyurethane resin coating and preparation method thereof |
| CN102585691A (en) * | 2012-02-13 | 2012-07-18 | 长沙市原鹏化工科技有限公司 | Ultraviolet-cured hydrophilic coating composition and preparation method thereof |
| CN102942836A (en) * | 2012-11-28 | 2013-02-27 | 长沙岱勒新材料科技有限公司 | Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof |
-
2014
- 2014-09-09 CN CN201410453086.3A patent/CN104177998B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010002409A1 (en) * | 1998-11-30 | 2001-05-31 | Randall T. Lake | Lamp reflectors and uv curable compositions useful as basecoats for same |
| CN1754929A (en) * | 2004-09-29 | 2006-04-05 | 上海保诺杰企业发展有限公司 | UV cured protective coating of reflective film |
| CN101760124A (en) * | 2008-11-24 | 2010-06-30 | 王虹 | Light-cured epoxy polyurethane resin coating and preparation method thereof |
| CN102585691A (en) * | 2012-02-13 | 2012-07-18 | 长沙市原鹏化工科技有限公司 | Ultraviolet-cured hydrophilic coating composition and preparation method thereof |
| CN102942836A (en) * | 2012-11-28 | 2013-02-27 | 长沙岱勒新材料科技有限公司 | Photo-cured coating, photo-cured wire saw made of same and preparation method and device thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104177998B (en) | 2016-08-24 |
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Effective date of registration: 20230824 Address after: 213000 Weitang Chemical Industry Zone, Chunjiang Town, Xinbei District, Changzhou City, Jiangsu Province Patentee after: CHANGZHOU FEI TENG CHEMICAL Co.,Ltd. Address before: 215101 room 4721, Tianlong building, 378 Pearl River Road, Wuzhong District, Suzhou, Jiangsu Patentee before: SUZHOU SHENGPULA NEW MATERIAL TECHNOLOGY Co.,Ltd. |