CN104177993A - Ultraviolet curable alkene polyester coating for ceramics - Google Patents
Ultraviolet curable alkene polyester coating for ceramics Download PDFInfo
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- CN104177993A CN104177993A CN201410455851.5A CN201410455851A CN104177993A CN 104177993 A CN104177993 A CN 104177993A CN 201410455851 A CN201410455851 A CN 201410455851A CN 104177993 A CN104177993 A CN 104177993A
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- polyester coating
- ultraviolet light
- pottery
- acrylate
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- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 238000000576 coating method Methods 0.000 title claims abstract description 21
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 20
- 229920000728 polyester Polymers 0.000 title claims abstract description 20
- 239000000919 ceramic Substances 0.000 title abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 8
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 8
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 8
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 claims abstract description 6
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- -1 1,2-cyclohexane dicarboxylic acid acid anhydride Chemical class 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 5
- 150000007974 melamines Chemical class 0.000 claims description 5
- 229940042596 viscoat Drugs 0.000 claims description 5
- KMNCBSZOIQAUFX-UHFFFAOYSA-N 2-ethoxy-1,2-diphenylethanone Chemical compound C=1C=CC=CC=1C(OCC)C(=O)C1=CC=CC=C1 KMNCBSZOIQAUFX-UHFFFAOYSA-N 0.000 claims description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000001035 drying Methods 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
- 230000005587 bubbling Effects 0.000 abstract description 6
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 230000002159 abnormal effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- MUTGBJKUEZFXGO-UHFFFAOYSA-N hexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21 MUTGBJKUEZFXGO-UHFFFAOYSA-N 0.000 abstract 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 abstract 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an ultraviolet curable alkene polyester coating for ceramics. The coating is prepared from the following raw materials: epoxy acrylate, triglycidyl isocyanurate, urethane acrylate, 1,2-cyclohexanedicarboxylic anhydride, Diethylene glycol diacrylate, dimethylbenzene, a photoinitiator, para toluic acid, trimethylolpropane triacrylate, ethylene, an antioxidant, vinyl acetate, acrylate, ethyl acrylate and hexamethoxy methyl melamine. The coating has the adhesion force of 1-2 grade and the hardness of 3-6H, cannot cause bubbling and falling phenomena after being soaked in water for 10-20 days, cannot generate an abnormal state when being soaked in a 5% hydrochloric acid solution for 2-3 days, cannot cause bubbling and wrinkling when being soaked in gasoline, and can be washed and brushed for 800-1,000 times; the surface drying time is 1-5 seconds and the hard drying time is 5-15 seconds.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of pottery ultraviolet light polymerization alkene kind polyester coating.
Background technology
Epocryl claims again vinyl ester resin, is after epoxy resin and vinylformic acid react, to be dissolved in the denaturation loop epoxy resins in vinylbenzene.Epocryl has the good characteristic of epoxy resin, but solidified nature and formability aspect are more outstanding, does not resemble epoxy resin loaded down with trivial detailsly, is a kind of heat-curing resin.It has excellent water tolerance, hot water resistance, resistance physical property, cohesiveness, toughness.By organo-peroxide solidification method (low temperature-high temperature) just or photocuring method can be cured, be widely used in following field: corrosion-resistant FRP goods, as glass fibre reinforced plastic groove tank, pipeline, tower and corrosion-resistant grid etc.; Anticorrosion engineering, as in cement based or iron based glasses steel lining, highly corrosion resistant terrace; High-strength FRP, such as pulling and extruding glass fiber section bar, sports goods, FRP ships and light boats etc.; Heavy Anti-corrosion glass flake paint; Other are as UV ink, heavy anticorrosion industry ground slab etc.And universal along with humanity concept, and the formation of novel harmonious society, designs that a kind of sticking power is good, fast drying, resistance to solvent and wear-resisting pottery ultraviolet light polymerization alkene kind polyester coating is very important.
Summary of the invention
The technical problem solving:
The application is for above-mentioned technical problem, and a kind of pottery ultraviolet light polymerization alkene kind polyester coating is provided, solve existing pottery low with ultraviolet light polymerization alkene kind polyester paint adhesion, be dried slowly, not resistance to solvent and the technical problem such as wear no resistance.
Technical scheme:
Ultraviolet light polymerization alkene kind polyester coating for a kind of pottery, described pottery is as follows by the raw materials by weight portion proportioning of ultraviolet light polymerization alkene kind polyester coating: 100 parts of epoxy acrylates; Three-glycidyl chlorinated isocyanurates 20-30 part; Urethane acrylate 50-70 part; 1,2-cyclohexane dicarboxylic acid acid anhydride 5-15 part; Diethylene glycol diacrylate 70-90 part; Dimethylbenzene 25-35 part; Light trigger 10-20 part; Para Toluic Acid 40-60 part; Viscoat 295 20-40 part; Ethene 40-50 part; Oxidation inhibitor 1-5 part; Vinyl acetate 10-30 part; Acrylate 20-30 part; Ethyl propenoate 30-40 part; Hexamethoxymethyl melamine 5-15 part.
As a preferred technical solution of the present invention: described pottery is as follows by the raw materials by weight portion proportioning of ultraviolet light polymerization alkene kind polyester coating: 100 parts of epoxy acrylates; 25 parts of three-glycidyl chlorinated isocyanurates; 60 parts of urethane acrylates; 10 parts of 1,2-cyclohexane dicarboxylic acid acid anhydrides; 80 parts of diethylene glycol diacrylates; 30 parts of dimethylbenzene; 15 parts of light triggers; 50 parts of para Toluic Acids; 30 parts of Viscoat 295s; 45 parts of ethene; 3 parts, oxidation inhibitor; 20 parts of vinyl acetates; 25 parts of acrylate; 35 parts of ethyl propenoates; 10 parts of hexamethoxymethyl melamines.
As a preferred technical solution of the present invention: described light trigger adopts Benzoin ethyl ether or 1-hydroxy-cyclohexyl phenyl ketone.
As a preferred technical solution of the present invention: described oxidation inhibitor adopts antioxidant 1010.
Beneficial effect:
A kind of pottery of the present invention adopts above technical scheme compared with prior art with ultraviolet light polymerization alkene kind polyester coating, has following technique effect: 1, product sticking power 1-2 level, hardness 3-6H; 2, in water, soak after 10-20d without bubbling, obscission, surface drying time 1-5s, does solid work 5-15s; 3, in 5% hydrochloric acid soln, soak 2-3d without extremely, in gasoline, soak that 5-10d is non-foaming, elephant skin; 4, the washable wiping of product 800-1000 time, can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
Ultraviolet light polymerization alkene kind polyester coating for a kind of pottery, its raw materials by weight portion proportioning is as follows: 100 parts of epoxy acrylates; 20 parts of three-glycidyl chlorinated isocyanurates; 50 parts of urethane acrylates; 5 parts of 1,2-cyclohexane dicarboxylic acid acid anhydrides; 70 parts of diethylene glycol diacrylates; 25 parts of dimethylbenzene; 10 parts of Benzoin ethyl ethers; 40 parts of para Toluic Acids; 20 parts of Viscoat 295s; 40 parts of ethene; Antioxidant 1010 is 1 part; 10 parts of vinyl acetates; 20 parts of acrylate; 30 parts of ethyl propenoates; 5 parts of hexamethoxymethyl melamines.
After above-mentioned raw materials is mixed in reactor, keep in Dark Place, be coated on pottery upper, ultra violet lamp for film.
2 grades of product sticking power, hardness 3H; In water, soak after 10d without bubbling, obscission, surface drying time 5s, does solid work 15s; In 5% hydrochloric acid soln, soak 2d without extremely, in gasoline, soak that 5d is non-foaming, elephant skin; The washable wiping of product 800 times.
Embodiment 2:
Ultraviolet light polymerization alkene kind polyester coating for a kind of pottery, its raw materials by weight portion proportioning is as follows: 100 parts of epoxy acrylates; 30 parts of three-glycidyl chlorinated isocyanurates; 70 parts of urethane acrylates; 15 parts of 1,2-cyclohexane dicarboxylic acid acid anhydrides; 90 parts of diethylene glycol diacrylates; 35 parts of dimethylbenzene; 20 parts of 1-hydroxy-cyclohexyl phenyl ketones; 60 parts of para Toluic Acids; 40 parts of Viscoat 295s; 50 parts of ethene; Antioxidant 1010 is 5 parts; 30 parts of vinyl acetates; 30 parts of acrylate; 40 parts of ethyl propenoates; 15 parts of hexamethoxymethyl melamines.
After above-mentioned raw materials is mixed in reactor, keep in Dark Place, be coated on pottery upper, ultra violet lamp for film.
2 grades of product sticking power, hardness 5H; In water, soak after 15d without bubbling, obscission, surface drying time 3s, does solid work 10s; In 5% hydrochloric acid soln, soak 2d without extremely, in gasoline, soak that 8d is non-foaming, elephant skin; The washable wiping of product 900 times.
Embodiment 3:
Ultraviolet light polymerization alkene kind polyester coating for a kind of pottery, its raw materials by weight portion proportioning is as follows: 100 parts of epoxy acrylates; 25 parts of three-glycidyl chlorinated isocyanurates; 60 parts of urethane acrylates; 10 parts of 1,2-cyclohexane dicarboxylic acid acid anhydrides; 80 parts of diethylene glycol diacrylates; 30 parts of dimethylbenzene; 15 parts of 1-hydroxy-cyclohexyl phenyl ketones; 50 parts of para Toluic Acids; 30 parts of Viscoat 295s; 45 parts of ethene; Antioxidant 1010 is 3 parts; 20 parts of vinyl acetates; 25 parts of acrylate; 35 parts of ethyl propenoates; 10 parts of hexamethoxymethyl melamines.
After above-mentioned raw materials is mixed in reactor, keep in Dark Place, be coated on pottery upper, ultra violet lamp for film.
Product adhesion 1 grade, hardness 6H; In water, soak after 20d without bubbling, obscission, surface drying time 1s, does solid work 5s; In 5% hydrochloric acid soln, soak 3d without extremely, in gasoline, soak that 10d is non-foaming, elephant skin; The washable wiping of product 1000 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.
Claims (4)
1. a ultraviolet light polymerization alkene kind polyester coating for pottery, is characterized in that the raw materials by weight portion proportioning of described pottery ultraviolet light polymerization alkene kind polyester coating is as follows: 100 parts of epoxy acrylates; Three-glycidyl chlorinated isocyanurates 20-30 part; Urethane acrylate 50-70 part; 1,2-cyclohexane dicarboxylic acid acid anhydride 5-15 part; Diethylene glycol diacrylate 70-90 part; Dimethylbenzene 25-35 part; Light trigger 10-20 part; Para Toluic Acid 40-60 part; Viscoat 295 20-40 part; Ethene 40-50 part; Oxidation inhibitor 1-5 part; Vinyl acetate 10-30 part; Acrylate 20-30 part; Ethyl propenoate 30-40 part; Hexamethoxymethyl melamine 5-15 part.
2. ultraviolet light polymerization alkene kind polyester coating for a kind of pottery according to claim 1, is characterized in that the raw materials by weight portion proportioning of described pottery ultraviolet light polymerization alkene kind polyester coating is as follows: 100 parts of epoxy acrylates; 25 parts of three-glycidyl chlorinated isocyanurates; 60 parts of urethane acrylates; 10 parts of 1,2-cyclohexane dicarboxylic acid acid anhydrides; 80 parts of diethylene glycol diacrylates; 30 parts of dimethylbenzene; 15 parts of light triggers; 50 parts of para Toluic Acids; 30 parts of Viscoat 295s; 45 parts of ethene; 3 parts, oxidation inhibitor; 20 parts of vinyl acetates; 25 parts of acrylate; 35 parts of ethyl propenoates; 10 parts of hexamethoxymethyl melamines.
3. ultraviolet light polymerization alkene kind polyester coating for a kind of pottery according to claim 1, is characterized in that: described light trigger adopts Benzoin ethyl ether or 1-hydroxy-cyclohexyl phenyl ketone.
4. ultraviolet light polymerization alkene kind polyester coating for a kind of pottery according to claim 1, is characterized in that: described oxidation inhibitor adopts antioxidant 1010.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455851.5A CN104177993B (en) | 2014-09-09 | A kind of pottery ultraviolet light polymerization alkenes polyester coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410455851.5A CN104177993B (en) | 2014-09-09 | A kind of pottery ultraviolet light polymerization alkenes polyester coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104177993A true CN104177993A (en) | 2014-12-03 |
| CN104177993B CN104177993B (en) | 2017-01-04 |
Family
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530925A (en) * | 2015-01-08 | 2015-04-22 | 湖州中辰建设有限公司 | Novel photocurable acrylate coating for ceramic |
| CN109370393A (en) * | 2018-06-08 | 2019-02-22 | 湖南阳光新材料有限公司 | A kind of open air high-weatherability terrace composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
| US20060286383A1 (en) * | 2005-06-16 | 2006-12-21 | Eastman Chemical Company | Abrasion resistant coatings |
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| CN102181192A (en) * | 2011-01-24 | 2011-09-14 | 上海宏盾防伪材料有限公司 | Dual-curing coating and preparation method thereof |
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1486960A (en) * | 2002-08-07 | 2004-04-07 | 珠海东诚化工有限公司 | Ultraviolet light cured ceramic paint |
| US20060286383A1 (en) * | 2005-06-16 | 2006-12-21 | Eastman Chemical Company | Abrasion resistant coatings |
| CN1927971A (en) * | 2006-09-18 | 2007-03-14 | 深圳清华大学研究院 | Ultraviolet light curing nano antibacterial woodenware paint and preparation method thereof |
| CN102181192A (en) * | 2011-01-24 | 2011-09-14 | 上海宏盾防伪材料有限公司 | Dual-curing coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530925A (en) * | 2015-01-08 | 2015-04-22 | 湖州中辰建设有限公司 | Novel photocurable acrylate coating for ceramic |
| CN109370393A (en) * | 2018-06-08 | 2019-02-22 | 湖南阳光新材料有限公司 | A kind of open air high-weatherability terrace composition |
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Effective date of registration: 20161128 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Applicant after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: Zhujiang Road Wuzhong District Mudu town of Suzhou city in Jiangsu Province Tianlong 215101 No. 378 building room 4721 Applicant before: SUZHOU SHENGPULA NEW MATERIAL TECHNOLOGY Co.,Ltd. Effective date of registration: 20161128 Address after: 528000 Foshan Gaoming District, the town of the town of small hole Industrial Park North Applicant after: FOSHAN GAOMING BAICHUAN CHEMICAL ENGINEERING CO.,LTD. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Applicant before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. |
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Address after: 528522 Foshan Gaoming District, the town of the town of small hole Industrial Park North Patentee after: GUANGDONG BAICHUAN CHEMICAL CO.,LTD. Address before: 528000 Foshan Gaoming District, the town of the town of small hole Industrial Park North Patentee before: FOSHAN GAOMING BAICHUAN CHEMICAL ENGINEERING CO.,LTD. |
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Denomination of invention: A UV curable alkenyl polyester coating for ceramics Effective date of registration: 20220725 Granted publication date: 20170104 Pledgee: Foshan Dali sub branch of Bank of Guangzhou Co.,Ltd. Pledgor: GUANGDONG BAICHUAN CHEMICAL CO.,LTD. Registration number: Y2022980011102 |
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Denomination of invention: A UV curable alkene polyester coating for ceramics Effective date of registration: 20230817 Granted publication date: 20170104 Pledgee: Foshan branch of Bank of Guangzhou Co.,Ltd. Pledgor: GUANGDONG BAICHUAN CHEMICAL CO.,LTD. Registration number: Y2023980052464 |
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