CN104159447B - 针对海洋木蛀虫的曲洛比利的用途 - Google Patents

针对海洋木蛀虫的曲洛比利的用途 Download PDF

Info

Publication number
CN104159447B
CN104159447B CN201380013015.5A CN201380013015A CN104159447B CN 104159447 B CN104159447 B CN 104159447B CN 201380013015 A CN201380013015 A CN 201380013015A CN 104159447 B CN104159447 B CN 104159447B
Authority
CN
China
Prior art keywords
lip river
bent lip
timber
billy
river billy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201380013015.5A
Other languages
English (en)
Other versions
CN104159447A (zh
Inventor
M.A.J.范德弗拉亚斯
D.B.赫梅
J.R.奈斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Janssen Pharmaceutica NV
Original Assignee
Janssen Pharmaceutica NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Janssen Pharmaceutica NV filed Critical Janssen Pharmaceutica NV
Publication of CN104159447A publication Critical patent/CN104159447A/zh
Application granted granted Critical
Publication of CN104159447B publication Critical patent/CN104159447B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M99/00—Subject matter not provided for in other groups of this subclass
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/343—Heterocyclic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/38—Aromatic compounds
    • B27K3/40—Aromatic compounds halogenated
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M2200/00—Kind of animal

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Forests & Forestry (AREA)
  • Toxicology (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

本发明涉及一种用于减少或预防处于海洋环境中的木材受海洋木蛀虫攻击的方法，其特征在于将所述木材用包含曲洛比利的杀生物组合物浸渍。

Description

针对海洋木蛀虫的曲洛比利的用途
本发明涉及一种用于减少或预防处于海洋环境中的木材受海洋木蛀虫攻击的方法，其特征在于将所述木材浸渍在含有曲洛比利的杀生物组合物中。
海洋木蛀虫(也被称作船蛆)不是蛆，而是一群不寻常的长蠕虫状的的咸水蛤，其壳仅能覆盖该动物前端的一部分，因它们能钻穿浸在海水中的木质结构例如桥墩、船坞以及木船而声名狼藉。如果木质结构被船蛆侵染，可能只需几个月的时间，其结构完整性就到受损到其中有必要完全替换所述木质结构的程度。海洋木蛀虫属于若干个属，其中最常提到的是凿船虫。最著名的物种是船蛆(软体动物，船蛆科)。
船蛆攻击仅仅显现为小洞，幼虫已经进入该小洞消失。该幼虫钻穿该木质结构并用一薄层的石灰内衬该通道。一只长成的船蛆可以达60cm长以及0.8cm直径。海洋木蛀虫严重损坏木质外壳和水上打桩，并且成为很多研究的对象以找出避免它们攻击的方法。从18世纪后期以及后来在木船上使用铜覆皮作为预防海洋木蛀虫损坏的方法。
曲洛比利(tralopyril)，或者4-溴代-2-(4-氯苯基)-5-(三氟甲基)-1H-吡咯-3-甲腈在EP-0,312,723中披露用于控制软体动物。所述化合物可以用下式表示：
EP-0,746,979描述了曲洛比利在防污剂组合物中的用途，该防污剂组合物被施用到水下表面以预防污着生物附着到所述水下表面。
现已发现海洋木蛀虫对处于海洋环境中的木材的攻击可以通过将所述木材浸渍在含有曲洛比利的杀生物组合物中以获得保留在所述木材中的曲洛比利浓度为至少1000g/m3(＝1mg/cm3)来极大程度地减少或甚至预防。
如果将另外的杀生物剂-具有针对海洋木蛀虫的杀生物活性-添加到根据本发明的杀生物组合物中，那么浸渍木材中的为至少1000g/m3的更低浓度的曲洛比利也足以减少或预防海洋木蛀虫对处于海洋环境中的木材的攻击。例如，当使用另外的杀生物剂如杂酚油或CCA(铬化砷酸铜)时，浸渍木材中保留的曲洛比利的浓度可以低至100至200g/m3。
海洋木蛀虫属于若干个属，其中最常提到的是凿船虫。最著名的凿船虫物种是船蛆。海洋蛀虫的其他物种是例如木琴背(Xylophagadorsalis)(软体动物，海笋科)，Psiloteredomegotara(软体动物，船蛆科)，Nototeredonorvagica(软体动物，船蛆科)以及卂虫虫(Limnorialignorum)(甲壳动物，蛀木水虱科)(即“蛀木水虱”)。
如在此使用的，“木材”、“木质材料”、“木制品”应当是指所有形式的木材，例如，实木(例如圆木、横梁、厚板、薄片以及薄板形式的木料或木材)，木材复合材料(例如胶合板、积层板材、以及木塑复合材料)和所有由木材和木材复合材料制成的产品(例如船体、港口设备、干船坞、桥墩、水门、水闸、系泊杆、木杆、桥、防水壁以及类似物)。
用于浸渍木材的杀生物组合物包括曲洛比利和一种载体介质。特别地，预期根据本发明即刻使用的用于浸渍木材的组合物包含基于该组合物的总重量低至0.01wt％的量的曲洛比利。特别地，此类即刻使用的组合物包含基于该组合物的总重量从0.01wt％至10wt％的量的曲洛比利。包含曲洛比利的杀生物组合物的其他浓度范围为基于该组合物的总重量0.01wt％至1wt％和0.1wt％至1.0wt％。在许多情况下，有待直接使用的杀生物组合物可以从浓缩组合物，诸如例如可乳化的浓缩物、悬浮液浓缩物、或者可溶的浓缩物中得到。一旦用有机介质进行稀释，此种浓缩物意在由如在本发明的定义之内所使用的术语组合物所涵盖。曲洛比利在此类浓缩组合物中的浓度可以高达50wt％并且这些浓缩物在使用之前进行稀释以得到如以上对于即刻使用的组合物所陈述的曲洛比利的浓度。
该杀生物组合物的合适的载体介质是任何不对活性成分产生负面影响的液体，例如，醇类(例如甲醇、乙醇、乙二醇、丙二醇、二甘醇、甘油等)，酮类(例如丙酮、甲基乙基酮、苯乙酮等)，醚类(例如二噁烷、四氢呋喃、溶纤剂、二甘醇二甲基醚等)，脂肪烃类(例如己烷、煤油等)，芳香烃类(例如苯、甲苯、二甲苯、溶剂石脑油、甲基萘等)，卤代烃类(例如氯仿、四氯化碳等)，酰胺类(例如二甲基甲酰胺等)，酯类(例如甲基乙酸酯、乙基乙酸酯、丁基乙酸酯、脂肪酸甘油酯等)，以及腈类(例如乙腈等)。典型的溶剂为甲醇、乙醇或者二甲苯。这些溶剂可以单独使用或者两种或更多种种类结合使用。
根据本发明用途的杀生物组合物的可乳化浓缩物也可以在稀释曲洛比利与至少一种合适的有机溶剂(即一种液体载体)的组合物紧接着添加至少一种溶剂可溶的乳化剂后获得。适合于这种类型的配制的溶剂通常是与水不混溶的并且属于烃、氯代烃、酮、酯、醇以及酰胺类的溶剂，并且它们可以由本领域技术人员基于曲洛比利的溶解度适当地选择。除了一种或多种有机溶剂之外，可乳化浓缩物通常包含按重量计从0.5％至50％的活性成分的组合，从2％至20％的一种或多种乳化剂，以及高达20％的其他添加剂(例如稳定剂)。
为了减少处于海洋环境中的木材受海洋木蛀虫攻击，将所述木材浸渍在含有曲洛比利的杀生物组合物中。这样的浸渍处理通过若干个不同的程序而应用，诸如，例如，通过在封闭高压或真空系统中处理木材。该浸渍处理还可以通过依次施用波动压力或若干真空压力循环完成。另一种浸渍处理方法是将该木材浸或泡在本发明的杀生物组合物中。
封闭高压系统的一个实例是“填满细胞法(full-cellprocess)”，也被称作“贝氏木材防腐法(Bethellprocess)”，该方法是一种将木材用防腐剂浸渍的方法，是19世纪美国发明家约翰贝瑟尔(JohnBethell)发明的。该方法涉及将木材密封在一个压力室中并施加真空，从而将木材细胞中的空气和水分移除。该木材然后使用防腐剂压力处理以便使得全木材细胞(即细胞壁以及内腔、或内部)浸渍有能够抗腐烂、抗火、防虫、以及防海洋木蛀动物的物质。
封闭高压系统的另一实例是所谓的“Rüping过程”，其中木材在增压下被放置在浸渍锅炉中紧接着引入该杀生物组合物并释放压力。
为了通过将所述木材用含有曲洛比利的杀生物组合物浸渍而获得木材中残留的曲洛比利的浓度为至少1000g/m3(＝1mg/cm3)，需要重复浸渍过程多次直到达到所希望的残留曲洛比利的浓度。
实验部分
实验1：根据EN275的海洋现场试验
减少处于海洋环境中的木材中存在的海洋木蛀虫的效果是使用以下的指导和推荐而测定的：EN275:1992-木材防腐剂-预防海洋木蛀虫保护效果的测定。
木质材料
用于对照组(未处理)和实验组的木质材料都是苏格兰松树边材(樟子松)。木材样本的大小是25x70x200mm并且所有松树样品都是纯边材而且没有瑕疵。
浸渍
全细胞浸渍程序：
-将样品置于一个处理器皿中(如一个除湿器)
-抽真空直至达到7hPa并保持所述真空15分钟
-在真空下用处理溶液没过样品直到样品完全浸入
-释放真空并且确保样本保持完全浸入同时环境压力迫使处理溶液进入该样本
-将浸入在该处理溶液中的样品再放置2小时
-之后将该样品从处理溶液中移除，排滴溶液几分钟并将该样品容器置于惰性支持体上。
-保持样品处于封闭容器中3天(过周末)用于固定，之后每天打开一点盖子并在四天后完全移除
-在室温下在开口容器中再干燥该样品三天
实验溶液：
1a)水可稀释的配制品(可乳化浓缩物)
1b)基于溶剂的配制品
溶解在甲醇(1600ppm和400ppm)中的曲洛比利。
平均残留：
1a)水可稀释的配制品(可乳化浓缩物)：228g和46ga.i./m3
1b)基于溶剂的配制品：1087ga.i./m3
实验点名称与位置
克里斯蒂娜贝里海洋研究站(KristinebergMarineResearchStation)外的海湾(Gullmarfjord)，距瑞典哥德堡(Gothenburg,Sweden)北100km。
地点特征
水温和盐度：夏季温度在18℃至22℃之间变化隆冬在零下1.5℃。盐度在26g/kg和34g/kg之间变化。强大的水流带来良好的氧气水平。
钻蛀虫活动：全年均有钻蛀虫活动。最活跃的钻蛀虫物种，船蛆，12个月中有11个月活跃。由于遭受船蛆攻击(通道覆盖多于该样品区域的50％，如在X-光胶片中出现的)导致失败的标准针对未处理对照样品通常是六个月之内满足。未处理的对照的最长“服务”寿命为大约1.5年，之后该样品会被秋季风暴打成碎片。
安装条件
样品被挂在置于低潮期海底6±0.4m深的两个梯子状帆装的尼龙条(直径＝24mm)上。实验帆装(rigs)具有沉重的水泥基底并且每个帆装都通过直径50cm的浮标保持直立。作为该安排的结果，该样品在暴露期位于水面以下从4m至6.5m的深度变化。
现有的海洋穿孔动物的物种
蛀木水虱：Limnorialignorum(存在但不很活跃)
软体动物(已列出的特征是针对实际试验地点)：
船蛆(最常见物种)在一个生长季节(11个月)中长达7cm
Nototeredonorvagica(罕见)在一个生长季节中长达10cm
Psiloteredomegotara(罕见)在一个生长季节(5至6个月)中长达20cm
Xylophagadorsalis(主要在深海)在一个生长季节中长达3cm
木蛀虫攻击评估
表1：对照(未处理的苏格兰松树边材)和曲洛比利浸渍的木材受Limnorial.和T.navalis攻击一年后和两年后的评级
毁坏程度毁坏点及外观
该对照样本在一年内的海水浸泡中被海洋木蛀虫船蛆严重损坏，并且一些样本在第二年被毁掉(表1中用‘-’表示)。
浸渍有曲洛比利(其在该木材样本中残留的浓度为228g/m3)的木材样本平均表现出在一年内的海水浸泡中被海洋木蛀虫船蛆中等损坏并且在第两年后完全毁坏。
浸渍有曲洛比利(其在该木材样本中残留的浓度为846g/m3)的木材样本平均表现出在一年内的海水浸泡中被海洋木蛀虫船蛆极少损坏并且在第两年后中等损坏。
浸渍有曲洛比利(其在该木材样本中残留的浓度为1087g/m3)的木材样本表现出在一年内的海水浸泡中没有被海洋木蛀虫船蛆损坏并且在第两年平均仅仅极少损坏。
附图说明
图1：一年后对照的X射线图像
图2：曲洛比利浸渍的木材样本一年后和两年后的X射线图像

Claims (10)

1.一种用于减少或预防处于海洋环境中的木材受海洋木蛀虫攻击的方法，其特征在于，将所述木材用一种杀生物组合物浸渍，该杀生物组合物包含基于该组合物的总重量至少0.01wt%的量的曲洛比利，以获得保留在所述木材中的曲洛比利的浓度为至少1000g/m3。
2.如权利要求1所述的方法，其中该杀生物组合物包含基于该组合物的总重量的范围从0.01wt%至10wt%的量的曲洛比利。
3.如权利要求2所述的方法，其中该杀生物组合物包含基于该组合物的总重量的范围从0.01wt%至1wt%的量的曲洛比利。
4.如权利要求3所述的方法，其中该杀生物组合物包含基于该组合物的总重量的范围从0.1wt%至1wt%的量的曲洛比利。
5.如权利要求1至4中任一项所述的方法，其中木材在封闭高压系统中用包含曲洛比利的杀生物组合物浸渍。
6.如权利要求1至4中任一项所述的方法，其中木材在真空压力处理系统中用包含曲洛比利的杀生物组合物浸渍。
7.如权利要求1至4中任一项所述的方法，其中木材通过依次施用波动压力或若干真空压力循环的处理而用包含曲洛比利的杀生物组合物浸渍。
8.如前述权利要求1至4中任一项所述的方法，其中包含曲洛比利的该杀生物组合物是一种可乳化的浓缩物。
9.如前述权利要求1至4中任一项所述的方法，其中包含曲洛比利的该杀生物组合物是一种可溶的浓缩物。
10.如权利要求9所述的方法，其中该可溶的浓缩物的溶剂为甲醇、乙醇或者二甲苯。
CN201380013015.5A 2012-03-07 2013-03-06 针对海洋木蛀虫的曲洛比利的用途 Active CN104159447B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261607764P 2012-03-07 2012-03-07
US61/607764 2012-03-07
PCT/EP2013/054472 WO2013131940A1 (en) 2012-03-07 2013-03-06 Use of tralopyril against marine woodborers

Publications (2)

Publication Number Publication Date
CN104159447A CN104159447A (zh) 2014-11-19
CN104159447B true CN104159447B (zh) 2016-05-18

Family

ID=47827212

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201380013015.5A Active CN104159447B (zh) 2012-03-07 2013-03-06 针对海洋木蛀虫的曲洛比利的用途

Country Status (14)

Country Link
US (1) US20150086719A1 (zh)
EP (1) EP2822385B1 (zh)
JP (1) JP6342340B2 (zh)
CN (1) CN104159447B (zh)
AU (1) AU2013229511B2 (zh)
CA (1) CA2863779A1 (zh)
CL (1) CL2014002345A1 (zh)
DK (1) DK2822385T3 (zh)
ES (1) ES2644266T3 (zh)
IN (1) IN2014MN01968A (zh)
NO (1) NO2864574T3 (zh)
NZ (1) NZ628968A (zh)
RU (1) RU2609373C2 (zh)
WO (1) WO2013131940A1 (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104397033A (zh) * 2014-12-10 2015-03-11 海南大学 防治团水虱和船蛆钻孔海洋生物的药物及其使用方法
US10829649B2 (en) 2018-04-20 2020-11-10 Redjak, L.L.C. Methods and coatings for protecting surfaces from bio-fouling species
US10689527B2 (en) 2018-04-20 2020-06-23 Redjak, L.L.C Methods and coatings for protecting surfaces from bio-fouling species
US10519327B2 (en) 2018-04-20 2019-12-31 Redjak, L.L.C. Methods and coatings for protecting surfaces from bio-fouling species
WO2024047144A1 (en) 2022-09-01 2024-03-07 I-Tech Ab Composition protecting wood against marine woodborers

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0312723A2 (en) * 1987-10-23 1989-04-26 American Cyanamid Company Method of and bait compositions for controlling mollusks
CN1145170A (zh) * 1995-05-23 1997-03-19 美国氰胺公司 吡咯化合物作为防污剂的用途
CN1224577A (zh) * 1997-08-08 1999-08-04 美国氰胺公司 用于保护木材、木制品和木质结构以防昆虫侵害的芳基吡咯
CN102245026A (zh) * 2008-12-11 2011-11-16 詹森药业有限公司 包含4-溴-2-(4-氯苯基)-5-(三氟甲基)-1h-吡咯-3-甲腈的防污组合

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU148203A1 (ru) * 1958-04-30 1961-11-30 И.В. Киркилевский Способ защиты древесины от морских древоточцев
US3279984A (en) * 1963-05-08 1966-10-18 Dow Chemical Co Methods and compositions comprising 1-bromo-3-nitrobenzene for controlling marine organisms
JPS6052726B2 (ja) * 1979-06-19 1985-11-21 株式会社片山化学工業研究所 海息付着生物防除剤
DE3516695A1 (de) * 1985-05-09 1986-11-13 Schering AG, 1000 Berlin und 4709 Bergkamen Biozide tributylzinnverbindungen
AU7200300A (en) * 1999-12-16 2001-06-21 Rohm And Haas Company 5-carboxanilido-haloalkylthiazoles as antimicrobial and marine antifouling agents
AU2002305154B2 (en) * 2001-04-11 2007-09-20 University Of Delaware Method and compositions for inhibiting cellulolytic symbionts
EP1446011B1 (en) * 2001-11-08 2009-01-14 Janssen Pharmaceutica N.V. Synergistic antifouling compositions comprising 4-bromo-2-(4-chlorophenyl)-5-(trifluoromethyl)-1h-pyrrole-3-carbonitrile
DE10301805A1 (de) * 2003-01-20 2004-07-29 Bayer Cropscience Ag 3-Phenylsubstituierte-3-substituierte-4-ketolaktame und -laktone
CN101355877B (zh) * 2006-02-01 2012-11-14 詹森药业有限公司 4-溴-2-（4-氯苯基）-5-（三氟甲基）-1h-吡咯-3-腈和金属化合物的组合物
US20110092518A1 (en) * 2008-05-16 2011-04-21 National University Of Singapore Antifouling Compounds And Use Thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0312723A2 (en) * 1987-10-23 1989-04-26 American Cyanamid Company Method of and bait compositions for controlling mollusks
CN1145170A (zh) * 1995-05-23 1997-03-19 美国氰胺公司 吡咯化合物作为防污剂的用途
CN1224577A (zh) * 1997-08-08 1999-08-04 美国氰胺公司 用于保护木材、木制品和木质结构以防昆虫侵害的芳基吡咯
CN102245026A (zh) * 2008-12-11 2011-11-16 詹森药业有限公司 包含4-溴-2-(4-氯苯基)-5-(三氟甲基)-1h-吡咯-3-甲腈的防污组合

Also Published As

Publication number Publication date
RU2014140333A (ru) 2016-04-27
ES2644266T3 (es) 2017-11-28
WO2013131940A1 (en) 2013-09-12
EP2822385A1 (en) 2015-01-14
CN104159447A (zh) 2014-11-19
CL2014002345A1 (es) 2015-01-16
NO2864574T3 (zh) 2018-01-06
AU2013229511B2 (en) 2016-04-14
JP2015509518A (ja) 2015-03-30
US20150086719A1 (en) 2015-03-26
NZ628968A (en) 2016-05-27
DK2822385T3 (en) 2017-10-30
CA2863779A1 (en) 2013-09-12
IN2014MN01968A (zh) 2015-07-03
AU2013229511A1 (en) 2014-08-21
JP6342340B2 (ja) 2018-06-13
EP2822385B1 (en) 2017-07-26
RU2609373C2 (ru) 2017-02-01

Similar Documents

Publication Publication Date Title
CN104159447B (zh) 针对海洋木蛀虫的曲洛比利的用途
Titah-Benbouzid et al. Marine renewable energy converters and biofouling: A review on impacts and prevention
Roche et al. Recreational vessels as a vector for marine non-natives: developing biosecurity measures and managing risk through an in-water encapsulation system
Treu et al. Durability and protection of timber structures in marine environments in Europe: an overview
Coutts et al. Removing vessels from the water for biofouling treatment has the potential to introduce mobile non-indigenous marine species
Brown et al. Effects of chromated copper arsenate (CCA) wood preservative on early fouling community formation
Palma et al. Shipwrecks and Global'worming'
US20230192247A1 (en) Catamaran centralized-transportation fishing ship and control method
Tagliapietra et al. Bioerosion effects of sea-level rise on the Doge’s Palace water doors in Venice (Italy)
Brown et al. Assessment of effects of chromated copper arsenate (CCA)—treated timber on nontarget epibiota by investigation of fouling community development at seven European sites
Eaton Preservation of marine timbers
Oevering et al. Invertebrate biodeterioration of marine timbers above mean sea level along the coastlines of England and Wales
Marimuthu et al. Seasonal Variability of Biofouling Community Structure in the Gulf of Mannar, Southeast Coast of India: A Multivariate Approach
Nayak et al. Molluscan wood-borers of Chilika Lagoon, east coast of India and their control measures
Muslich et al. Durabilty of 25 Local Specific Wood Species From Java Preserved with Ccb Against Marine Borers Attack
Saat et al. Performance of rosin modified antifouling coated on mild steel surface at various immersion orientation
Sreeja et al. Physical barriers: an alternative to prevent negative impacts of chemically treated wood
Brown et al. Effects of CCA (copper‐chrome‐arsenic) preservative treatment of wood on the settlement and recruitment of barnacles and tube building polychaete worms
COUGHLAN MARINE WOOD BORERS IN SOUTHAMPTON WATER
BR112018015777B1 (pt) Método para prevenir a deposição de incrustação biológica em uma superfície
Komorowicz et al. Research on physical and chemical properties of waterlogged wood
Edwin et al. Utilization of rubber wood for fishing canoe construction
Bai et al. Study on Assessment Approach of Antimicrobial and Antifouling Performance for Marine Antifouling Coating
Eaton 30 PRESERVATION OF WOOD IN THE SEA
Tarakanadha et al. Effects of wood preservatives (CCA, CCB, CDDC, ACZA, ACQ and CC) on the settlement and growth of marine biofouling organisms

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant