CN104151936A - Fluorine modified polyurethane resin based inkjet printer ink and preparation method thereof - Google Patents
Fluorine modified polyurethane resin based inkjet printer ink and preparation method thereof Download PDFInfo
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- CN104151936A CN104151936A CN201310174582.0A CN201310174582A CN104151936A CN 104151936 A CN104151936 A CN 104151936A CN 201310174582 A CN201310174582 A CN 201310174582A CN 104151936 A CN104151936 A CN 104151936A
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Abstract
The invention discloses fluorine modified polyurethane resin based inkjet printer ink which comprises the following components by weight: 0.5-5% of a fluorine modified polyurethane resin solution (with the solid content of 1-10%); 0.0001-0.1% of nano aluminum powder; 0.1-5% of a viscosity regulator; and the balance of a solvent. The fluorine modified polyurethane resin based inkjet printer ink product prepared by the method is printed onto the surface of a flexible or thin film solar cell by inkjet printing technology to directly improve the power generation efficiency of the flexible or thin film solar cell.
Description
Technical field
The present invention relates to a kind of fluorine modified polyurethane resin base ink for ink-jet printer and preparation method thereof, by using the surface of this ink printed at flexibility or thin-film solar cells incidence surface, directly improve the efficiency of flexibility or thin-film solar cells.
Background technology
In polyurethane chain, introduce fluorin radical, make it keep the original good characteristic of urethane, as excellent mechanical property and two-phase microstructure features, good snappiness, adhesivity and stretchiness, well wear-resisting, antifatigue, chemicals-resistant corrodibility etc. in addition, because fluorine has strong electronegativity, high bond energy, very little van der Waals radius and the shielding protection to carbochain, make it have good surface property, overall performance. the introducing of fluorin radical, make polyurethane material there is excellent low surface energy, heat-resisting chemical-resistant, low water absorbable, self-cleaning property and good biocompatibility and stability. according to different fluorine-containing raw materials, use different fluorin radical introducing modes to synthesize fluorochemical urethane. its raw material can be divided into fluorine-containing polyol compound, fluorine-containing polyisocyanates, fluorine-containing chainextender, fluorine-containing end-capping reagent and fluorinated acrylate etc. the fluorochemical urethane that different fluorine-containing raw materials make, because introduced fluoro-containing group on the different positions of urethane segment, can make the properties of urethane be greatly improved, show the superiority that has fluoropolymer and urethane concurrently, fluorochemical urethane is the novel macromolecular material with specific function of a class, be widely used in every field, the research emphasis of fluorochemical urethane will concentrate in the exploitation of fluoridizing raw material, and develop high performance fluorine containing polyurethane material and meet people for material high-performance, high yield, low cost, the requirement of high using value and environmental protection. wherein, aqueous fluorine-containing polyurethane material has high solids content, the feature of enhanced water resistance, there is very large market outlook and using value, the focus and emphasis of research and development will be become.
Effectively utilizing in the middle of project of sun power: solar photovoltaic utilization is research field with fastest developing speed in the last few years, most active.The making of general solar cell is mainly taking semiconductor material as basis, opto-electronic conversion reaction generating occurs after utilizing photoelectric material to absorb luminous energy.According to the difference of material therefor, solar cell can be divided into: 1, silicon solar cell; 2, taking inorganic salt if the multi-element compounds such as gallium arsenide III-V compound, Cadmium Sulfide, copper indium diselenide are as the solar cell of material; 3, the solar cell of preparing with functional high molecule material; 4, nano-crystalline solar battery etc.
What prior art working efficiency was the highest is taking III-V family semiconductor inorganic materials as raw-material product.For example: the quantum well of the single junction type of gallium arsenide/germanium falls into crystal structure, and its photoelectric transformation efficiency can reach >18 %; For example, and multiple junction quantum well falls into the solar cell of crystal structure: InGaP/gallium arsenide/germanium, its photoelectric transformation efficiency can be up to >30 %.Most widely used at present, taking silicon as main: comprise non-crystalline silicon, photoelectric transformation efficiency approximately 9 %; Polysilicon, photoelectric transformation efficiency approximately 14 %; Silicon single crystal, photoelectric transformation efficiency approximately 17 %.Although in price, VI family elements Si is more cheap than III-V family semiconductor GaAs, the price of its manufacture, compared with polymer organic solar batteries, or expensive many; And in application, the light weight again overall plasticization organic solar batteries of the anxiety of crack-free can be realized via the processing of printing, except price reduces, be more suitable for the demand of portable electronic product, and indoor or cloudyly all can normally use (this is that siliceous solar cell is beyond one's reach), its practicality and market application range are promoted more.
Solar cell is a gordian technique, can advance more clean Energy production.But the Cost Problems of solar cell, has reduced the economic competitiveness of heliotechnics.For overcoming this problem, thin-film solar cells is the technology of current widespread use, can reduce in a large number the usage quantity of expensive semiconductor material, but the absorbing amount of thin-film solar cells is lower, and Performance Ratio is not gone up traditional solar cell.
Thin-film solar module is to be made up of glass substrate, metal level, transparency conducting layer, electrical function box, glueing material, semiconductor layer etc.Organic and inorganic composite solar battery is the solar cell based on organic conjugate polymer-inorganic nano-crystal composite system, because of while tool organic polymer material good film-forming property, level structure and band gap are easy to regulate, can prepare low cost, big area, flexible solar battery device and inorganic nano-crystal material high stability by wet method, high mobility, can construct the advantages such as ordered nano-structure, and become the study hotspot of area of solar cell in recent years.Metal nanoparticle can direct light enter solar cell better, prevents light escape.In traditional " thick film " solar cell, nanoparticle does not have any effect, is all by this film because all light absorbs, and this just relies on its thickness.But for film, nanoparticle just can be brought into play great role.Their scattering has increased light and has rested on the time in film, makes the light of overall absorption reach a kind of level, and traditional solar cell can match in excellence or beauty.
Aluminium and Nano silver grain are in the frequency spectrum of visible part, and focused ray enters solar cell well.But optical resonance also can cause nanoparticle absorb light, this efficiency that just means solar cell can be lower.Nano grain of silver sub-resonance is just in time in the crucial absorption spectrum part of solar cell, so the absorption of light is appreciable.Aluminum nanoparticles resonance has exceeded the crucial spectra part of solar cell.Loss to energy is less, and in addition, aluminum particulate is easy to passivation, although can change shape and size, after passivation, nanoparticle attribute change is very little.Nanoparticle has rough surface, and scattered beam can enter wide spectrum wavelength region more.This can bring larger absorption, thereby improves the whole efficiency of battery.
Ink-jet printing technology can form thin film layer by the uniform deposition of liquid organic materials, and therefore, this technology can solve large photoactivation thing dimensional problem in theory better.Drop on demand ink jet technique, can be accurately by deposition of material in position in the desired amount.Because ink-jet system is very high to the utilization ratio of material, can reduce manufacture production cost.
For adapting to above industrial requirement, we have invented fluorochemical urethane type nanometer aluminium powder ink.This ink passes through ink jet printing device, both can be used in the backlight place of thin-film solar cells, also can be used in the light inlet film surface of thin-film solar cells, also can be used in the middle layer of thin-film solar cells simultaneously, improve the efficiency of light absorption of solar cell.Improve the generating efficiency of solar cell.
Summary of the invention
The object of this invention is to provide a kind of flexibility or thin-film solar cells fluorine modified polyurethane resin base ink for ink-jet printer and preparation method thereof, by using the surface of this ink printed at flexibility or thin-film solar cells incidence surface, directly improve the efficiency of flexibility or thin-film solar cells.And flexibility or thin-film solar cells that tool was processed through this ink have self-cleaning effect.
For achieving the above object, the technical solution used in the present invention is as follows:
Fluorine modified polyurethane resin base ink for ink-jet printer of the present invention, comprises following component by weight percentage:
Fluorine modified polyurethane resin solution (solid content is 1-10%) 0.5-5%;
Nanometer aluminium powder 0.0001-0.1%;
Viscosity-controlling agent 0.1-5%;
Surplus is solvent.
Described fluorine modified polyurethane resin is the fluorine modified polyurethanes such as fluorine-containing polyol compound (molecular weight is 100-10000g/mol), fluorine-containing polyisocyanates (molecular weight is 100-10000g/mol), fluorine-containing chainextender (molecular weight is 100-10000g/mol), fluorine-containing end-capping reagent (molecular weight is 100-10000g/mol) and fluorinated acrylate (C2-C18).
Described solvent is one or more in alcohol, ester, ether, amine, acid amides, ketone or hydrocarbon.
Described alcohol methyl alcohol, ethanol, propyl alcohol, Virahol, butanols, amylalcohol, hexanol, one or more in fluorinated alohol.
Described ketone is acetone, cyclohexanone, one or more in methylethylketone, first isopropyl acetone, methyl ethyl ketone, diisobutyl ketone, diacetone alcohol, N-Methyl pyrrolidone.
Described ester is one or more in methyl acetate, ethyl acetate, acetic acid 1-methoxyl group-2-propyl ester, propyl acetate, butylacetate, methyl propionate or ethyl propionate, glycol ethers acetic ester, butyl glycol acetate.
Described ether is one or more in diethyl ether, dipropyl ether, tetrahydrofuran (THF), dioxan, ethylene glycol ethyl ether or ethylene glycol monomethyl ether, methoxypropanol.
9. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 1, is characterized in that: described viscosity-controlling agent is METHYLPYRROLIDONE or poly-3 methyl thiophene.
The preparation method of fluorine modified polyurethane resin base ink for ink-jet printer of the present invention, comprises the steps:
(1) by fluorine modified polyurethane resin solution, viscosity-controlling agent, the solvent of formula ratio, process 10-60 minute in emulsor, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2), after above mix emulsion fluid machines, under rotating speed 10000-100000 rpm, in 10-20 minute, nanometer aluminium powder is added in batches continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, then under rotating speed 10000-100000 rpm emulsification 10-30 minute;
(4) the fluorine modified polyurethane resin base ink for ink-jet printer that both must need after strainer filterings more than 300 orders for above emulsion.
Beneficial effect of the present invention: nano metal aluminum particulate is easy to passivation, although can change shape and size, after passivation, nanoparticle attribute change is very little.Nanoparticle has rough surface, and scattered beam can enter wide spectrum wavelength region more.This can bring larger absorption, thereby improves the whole efficiency of battery.The scattering of metallic aluminium nanoparticle has increased light and has rested on the time in film, makes the light of overall absorption reach a kind of level, and traditional solar cell can match in excellence or beauty.Through using the thin-film solar cells of ink processing of the present invention to improve 3-15% than the thin-film solar cells performance without the processing of this ink.Thin-film solar cells is used after this ink, and metallic aluminium nanoparticle can direct light enter solar cell preferably, prevents light escape.Solve in traditional " thick film " solar cell, nanoparticle does not have any effect and all essential problems that relies on thickness solution of light absorption.
Embodiment
embodiment 1
(1) by 0.5Kg fluorine modified polyurethane resin SUA-114 solution, (resin solid content is 10%, Jiangmen city Xinhui District assistant chemical industry business department), viscosity-controlling agent (METHYLPYRROLIDONE) 0.1Kg, 99.395Kg N, dinethylformamide mixes, in emulsify at a high speed device, process 10-60 minute, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2) after above mix emulsion fluid machines with under same processing rotating speed environment, in 10-20 minute by 0.005Kg nanometer aluminium powder in batches trace add continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, more fully emulsified 10-30 minute; Above emulsion with after strainer filterings more than 500 orders both flexible or thin-film solar cells EVA ink for ink-jet printer.
By the ink of the present embodiment, respectively according to national QB/T2730.1-2005, QB/T2603-2007, GB/T13217.2-2009, GB/T 18724-2008/ISO 2836:2004 standard detection.To the quality inspection index of ink, as proportion, pH value, surface tension, viscosity, specific conductivity etc. detect, detected result all meets national GB.Tested ink is poured in cold-resistant packing bottle, put into (20 ± 1) DEG C cryostat and take out to 24h, return to after room temperature, detect its print performance.Detected result: its reductibility is good, never degenerates, not spoiled.
embodiment 2
(1) by 2Kg fluorine modified polyurethane resin SUA-114 solution, (resin solid content is 8%, Jiangmen city Xinhui District assistant chemical industry business department), viscosity-controlling agent (METHYLPYRROLIDONE) 0.3Kg, be mixed with solution with 10Kg ethanol, 20Kg acetone, 67.6999Kg glycol ethers acetic ester, in emulsify at a high speed device, process 10-60 minute, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2) after above mix emulsion fluid machines with under same processing rotating speed environment, in 10-20 minute by 0.0001Kg nanometer aluminium powder in batches trace add continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, more fully emulsified 10-30 minute; Above emulsion with after 1000 object strainer filterings both flexible or thin-film solar cells EVA ink for ink-jet printer.
By the ink of the present embodiment, respectively according to national QB/T2730.1-2005, QB/T2603-2007, GB/T13217.2-2009, GB/T 18724-2008/ISO 2836:2004 standard detection.To the quality inspection index of ink, as proportion, pH value, surface tension, viscosity, specific conductivity etc. detect, detected result all meets national GB.Tested ink is poured in cold-resistant packing bottle, put into (20 ± 1) DEG C cryostat and take out to 24h, return to after room temperature, detect its print performance.Detected result: its reductibility is good, never degenerates, not spoiled.
embodiment 3
(1) by 3Kg fluorine modified polyurethane resin SUA-114 solution, (resin solid content is 1%, Jiangmen city Xinhui District assistant chemical industry business department), viscosity-controlling agent (METHYLPYRROLIDONE) 0.8Kg, 25Kg methyl ethyl ketone, 31.15Kg ethylene glycol ethyl ether, 20Kg butylacetate mix, in emulsify at a high speed device, process 10-60 minute, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2) after above mix emulsion fluid machines with under same processing rotating speed environment, in 10-20 minute by 0.05Kg nanometer aluminium powder in batches trace add continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, more fully emulsified 10-30 minute; Above emulsion with after 800 object strainer filterings both flexible or thin-film solar cells EVA ink for ink-jet printer.
By the ink of the present embodiment, respectively according to national QB/T2730.1-2005, QB/T2603-2007, GB/T13217.2-2009, GB/T 18724-2008/ISO 2836:2004 standard detection.To the quality inspection index of ink, as proportion, pH value, surface tension, viscosity, specific conductivity etc. detect, detected result all meets national GB.Tested ink is poured in cold-resistant packing bottle, put into (20 ± 1) DEG C cryostat and take out to 24h, return to after room temperature, detect its print performance.Detected result: its reductibility is good, never degenerates, not spoiled.
embodiment 4
(1) by 4Kg fluorine modified polyurethane resin SUA-114 solution, (resin solid content is 6%, Jiangmen city Xinhui District assistant chemical industry business department), viscosity-controlling agent (poly-3 methyl thiophene) 1Kg, be mixed with solution with 20Kg butyl glycol acetate, 10Kg butanols, 20Kg tetrahydrofuran (THF), 44.9 Kg ethyl propionates mix, in emulsify at a high speed device, process 10-60 minute, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2) after above mix emulsion fluid machines with under same processing rotating speed environment, in 10-20 minute by 0.1Kg nanometer aluminium powder in batches trace add continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, more fully emulsified 10-30 minute; Above emulsion with after 800 object strainer filterings both flexible or thin-film solar cells EVA ink for ink-jet printer.
By the ink of the present embodiment, respectively according to national QB/T2730.1-2005, QB/T2603-2007, GB/T13217.2-2009, GB/T 18724-2008/ISO 2836:2004 standard detection.To the quality inspection index of ink, as proportion, pH value, surface tension, viscosity, specific conductivity etc. detect, detected result all meets national GB.Tested ink is poured in cold-resistant packing bottle, put into (20 ± 1) DEG C cryostat and take out to 24h, return to after room temperature, detect its print performance.Detected result: its reductibility is good, never degenerates, not spoiled.
embodiment 5
(1) by 5Kg fluorine modified polyurethane resin SUA-114 solution, (resin solid content is 6%, Jiangmen city Xinhui District assistant chemical industry business department), viscosity-controlling agent (poly-3 methyl thiophene) 0.6Kg, use 10KgN, dinethylformamide, 20Kg acetone, 20Kg tetrahydrofuran (THF), 44.92Kg butylacetate are mixed with solution, in emulsify at a high speed device, process 10-60 minute, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2) after above mix emulsion fluid machines with under same processing rotating speed environment, in 10-20 minute by 0.08Kg nanometer aluminium powder in batches trace add continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, more fully emulsified 10-30 minute; Above emulsion with after 600 object strainer filterings both flexible or thin-film solar cells EVA ink for ink-jet printer.
By the ink of the present embodiment, respectively according to national QB/T2730.1-2005, QB/T2603-2007, GB/T13217.2-2009, GB/T 18724-2008/ISO 2836:2004 standard detection.To the quality inspection index of ink, as proportion, pH value, surface tension, viscosity, specific conductivity etc. detect, detected result all meets national GB.Tested ink is poured in cold-resistant packing bottle, put into (20 ± 1) DEG C cryostat and take out to 24h, return to after room temperature, detect its print performance.Detected result: its reductibility is good, never degenerates, not spoiled.
Claims (10)
1. a fluorine modified polyurethane resin base ink for ink-jet printer, is characterized in that, comprises following component by weight percentage:
Fluorine modified polyurethane resin solution (solid content is 1-10%) 0.5-5%;
Nanometer aluminium powder 0.0001-0.1%;
Viscosity-controlling agent 0.1-5%;
Surplus is solvent.
2. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 1, is characterized in that: described fluorine modified polyurethane resin is fluorine-containing polyol compound, fluorine-containing polyisocyanates, fluorine-containing chainextender, fluorine-containing end-capping reagent and fluorinated acrylate fluorine modified polyurethane.
3. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 1, is characterized in that: described solvent is one or more in alcohol, ester, ether, amine, acid amides, ketone or hydrocarbon.
4. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 3 is characterized in that: in described ink, contain ketone, ester and ether simultaneously.
5. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 3, is characterized in that: described alcohol methyl alcohol, ethanol, propyl alcohol, Virahol, butanols, amylalcohol, hexanol, one or more in fluorinated alohol.
6. according to the fluorine modified polyurethane resin base ink for ink-jet printer described in claim 3 or 4, it is characterized in that: described ketone is acetone, cyclohexanone one or more in methylethylketone, first isopropyl acetone, methyl ethyl ketone, diisobutyl ketone, diacetone alcohol, N-Methyl pyrrolidone.
7. according to the fluorine modified polyurethane resin base ink for ink-jet printer described in claim 3 or 4, it is characterized in that: described ester is one or more in methyl acetate, ethyl acetate, acetic acid 1-methoxyl group-2-propyl ester, propyl acetate, butylacetate, methyl propionate or ethyl propionate, glycol ethers acetic ester, butyl glycol acetate.
8. according to the fluorine modified polyurethane resin base ink for ink-jet printer described in claim 3 or 4, it is characterized in that: described ether is one or more in diethyl ether, dipropyl ether, tetrahydrofuran (THF), dioxan, ethylene glycol ethyl ether or ethylene glycol monomethyl ether, methoxypropanol.
9. fluorine modified polyurethane resin base ink for ink-jet printer according to claim 1, is characterized in that: described viscosity-controlling agent is METHYLPYRROLIDONE or poly-3 methyl thiophene.
10. the preparation method of fluorine modified polyurethane resin base ink for ink-jet printer claimed in claim 1, is characterized in that comprising the steps:
(1) by fluorine modified polyurethane resin solution, viscosity-controlling agent, the solvent of formula ratio, process 10-60 minute in emulsor, rotating speed 10000-100000 rpm, is processed into even mix emulsion fluid;
(2), after above mix emulsion fluid machines, under rotating speed 10000-100000 rpm, in 10-20 minute, nanometer aluminium powder is added in batches continuously;
(3) above emulsion is after nanometer aluminium powder adds completely, then under rotating speed 10000-100000 rpm emulsification 10-30 minute;
(4) the fluorine modified polyurethane resin base ink for ink-jet printer that both must need after strainer filterings more than 300 orders for above emulsion.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109371719A (en) * | 2018-10-11 | 2019-02-22 | 珠海佳印数码科技有限公司 | A kind of water-fastness digit printing weaving white ink and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101010388A (en) * | 2005-03-04 | 2007-08-01 | 韩商英泰股份有限公司 | Conductive inks and manufacturing method thereof |
| US20110226321A1 (en) * | 2010-03-18 | 2011-09-22 | Hyundai Motor Company | Titanium dioxide nano particle modified by surface stabilizer, titanium dioxide nano ink comprising the same, solar cell employing the same, and producing method of the same |
| CN103073948A (en) * | 2012-12-31 | 2013-05-01 | 中原工学院 | Ink of polycarbonate ink-jet printer for flexible or thin-film solar battery and preparation method of same |
-
2013
- 2013-05-13 CN CN201310174582.0A patent/CN104151936A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101010388A (en) * | 2005-03-04 | 2007-08-01 | 韩商英泰股份有限公司 | Conductive inks and manufacturing method thereof |
| US20110226321A1 (en) * | 2010-03-18 | 2011-09-22 | Hyundai Motor Company | Titanium dioxide nano particle modified by surface stabilizer, titanium dioxide nano ink comprising the same, solar cell employing the same, and producing method of the same |
| CN103073948A (en) * | 2012-12-31 | 2013-05-01 | 中原工学院 | Ink of polycarbonate ink-jet printer for flexible or thin-film solar battery and preparation method of same |
Non-Patent Citations (1)
| Title |
|---|
| 王小妹等: "氟改性聚氨酯乳液的合成及其表面性能", 《应用化学》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109371719A (en) * | 2018-10-11 | 2019-02-22 | 珠海佳印数码科技有限公司 | A kind of water-fastness digit printing weaving white ink and preparation method thereof |
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Application publication date: 20141119 |